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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
DOE OSTI2026

Modeling an S N 2 Reaction Mechanism for Hydrolysis of Siloxane Linkages with Density Functional Theory under Basic Conditions and Implications for Dissolution of Quartz

An extended silicate molecular cluster was used to perform density functional theory calculations to determine if an S N 2 mechanism, where OH – attacks a Q 1 Si coupled with Na + charge balancing an adjacent siloxane bridging O atom, could explain the observed energy of activation of quartz dissolution under basic conditions.

chemical calculations↗
NASA NTRS1993

An approach to estimate the areal rain-rate distribution from spaceborne radar by the use of multiple thresholds

Estimates of rain rate derived from a spaceborne weather radar will be most reliable over an intermediate range of values. In forming an area average of the rain rate, an alternative to the averaging of the high-resolution estimates, irrespective of their individual accuracies, is a multiple threshold approach. The method is based on the fact that the fractional area above a particular rain-rate threshold R(j) is related to the cumulative distribution of rain rates evaluated at R(j). Varying the threshold over the effective dynamic range of the radar yields the cumulative distribution function over this range. To obtain the distribution at all rain rates, a lognormal or gamma test function is selected such that the mean-square error between the test function and the measured values is minimized. Once the unknown parameters are determined, the first-order statistics of the areawide rain-rate distribution can be found. Tests of the method with data from the SPANDAR radar provide comparisons between it and the single threshold and the direct averaging approaches.

Meneghini, R.↗
NASA NTRS1999

Terrestrial Ages of Antarctic Meteorites- Update 1999

We are continuing our ongoing study of cosmogenic nuclides in Antarctic meteorites. In addition to the studies of exposure histories of meteorites, we study terrestrial ages and pairing of Antarctic meteorites and desert meteorites. Terrestrial ages of Antarctic meteorites provide information on meteorite accumulation mechanisms, mean weathering lifetimes, and influx rates. The determination of Cl-36(half-life=3.01 x 10(exp 5) y) terrestrial ages is one of our long-term on-going projects, however, in many instances neither Cl-36 or C-14 (5,730 y) yields an accurate terrestrial age. Using Ca-14 (1.04 x 10(exp 5) y) for terrestrial age determinations solves this problem by filling the c,ap in half-life between 14-C and Cl-36 ages. We are now applying the new Ca-41- Cl-36 terrestrial age method as well as the Cl-36-Be-10 method to Antarctic meteorites. Our measurements and C-14 terrestrial age determinations by the University of Arizona group are always complementary. We have measured Cl-36 in over 270 Antarctic meteorites since our previous compilation of terrestrial ages. Since a large number of meteorites have been recovered from many different icefields in Antarctica, we continue to survey the trends of terrestrial ages for different icefields. We have also measured detailed terrestrial ages vs. sample locations for Allan Hills, Elephant Moraine, and Lewis Cliff Icefields, where meteorites have been found with very long ages. The updated histograms of terrestrial ages of meteorites from the Allan Hills Main Icefield and Lewis Cliff Icefield are shown. These figures include C-14 ages obtained by the University of Arizona group. Pairs of meteorites are shown as one object for which the age is the average of all members of the same fall. The width of the bars represents 70,000 years, which was a typical uncertainty for Cl-36 ages. We reduced the uncertainty of terrestrial age determinations to approx. 40,000 years by using pairs of nuclides such as Ca-41-Cl-36 or Cl-36-Be-10. Meteorites found at the Allan Hills Icefields are much older than any other meteorites. The terrestrial ages cover a wide range and are as old as 2 My. Many of the Lewis Cliff meteorites are as old as the Allan Hills meteorites. So far, no clear correlation has been found between the terrestrial ages and the locations of the Lewis Cliff meteorites.

Nishiizumi, Kunihiko↗
NASA NTRS2000

Terrestrial Ages of Antarctic Meteorites: Up Date 1999

We are continuing our ongoing study of cosmogenic nuclides in Antarctic meteorites. In addition to the studies of exposure histories of meteorites, we study terrestrial ages and pairing of Antarctic meteorites and desert meteorites. Terrestrial ages of Antarctic meteorites provide information on meteorite accumulation mechanisms, mean weathering lifetimes, and influx rates. The determination of Cl-36 (half-life=3.01 x 10(exp 5) y) terrestrial ages is one of our long-term on-going projects, however, in many instances neither Cl-36 or C-14 (5,730 y) yields an accurate terrestrial age. Using Ca-41 (1.04 x 10(exp 5) y) for terrestrial age determinations solves this problem by filling the gap in half-life between C-14 and Cl-36 ages. We are now applying the new Ca-41 - Cl-36 terrestrial age method as well as the Cl-36 - Be-10 method to Antarctic meteorites. Our measurements and C-14 terrestrial age determinations by the University of Arizona group are always complementary.

Nishiizumi, K.↗
NASA NTRS2016

Soil Crystallinity As a Climate Indicator: Field Experiments on Earth and Mars

Soil crystallinity is largely determined by leaching rates, as high leaching rates favor the rapid precipitation of short order or poorly-crystalline phases like the aluminosilicate allophane. High leaching rates can occur due to high precipitation rates, seasonal monsoons, or weathering of glass, but are also caused by the rapid onset of seasonal melting of snow and ice in cold environments. Thus, cold climate soils are commonly dominated by poorly crystalline phases, which mature into kaolin minerals over time. Thus, we hypothesize that, in some contexts, soils with high abundances of poorly crystalline phases could indicate formation under cold climatic conditions. This model could be helpful in interpreting the poorly-constrained paleoclimate of ancient Mars, as the crystallinity of ancient soils and soil-derived sediments appears to be highly variable in time and space. While strong signatures of crystalline phyllosilicates have been identified in possible ancient paleosols on Mars, Mars Science Laboratory rover investigations of diverse ancient sediments at Gale Crater has shown that they can contain very high abundances (40-50 wt%) of poorly crystalline phases. We hypothesize that these poorly crystalline phases could be the result of weathering by ice/snow melt, perhaps providing support for sustained cold climates on early Mars punctuated by more limited warm climates. Furthermore, such poorly crystalline soils could be highly fertile growth media for future human exploration and colonization on Mars. To test this hypothesis, we are currently using rover-like instrumentation to investigate the mineralogy and chemistry of weathering products generated by snow and ice melt in a Mars analog alpine environment: the glaciated Three Sisters volcanic complex in central Oregon. Alteration in this glacial environment generates high abundances of poorly crystalline phases, many of which have compositions distinct from those identified in previous terrestrial investigations, and perhaps more similar to poorly crystalline phases identified on Mars.

Horgan, Briony↗
NASA NTRS1990

The accumulation rate of meteorite falls at the earth's surface - The view from Roosevelt County, New Mexico

The discovery of 154 meteorite fragments within an 11-sq km area of wind-excavated basins in Roosevelt County, New Mexico, permits a new calculation of the accumulation rate of meteorite falls at the earth's surface. Thermoluminescence dating of the coversand unit comprising the prime recovery surface suggests the maximum terrestrial age of the meteorites to be about 16.0 ka. The 68 meteorite fragments subjected to petrological analyses represent a minimum of 49 individual falls. Collection bias has largely excluded carbonaceous chondrites and achondrites, requiring the accumulation rate derived from the recovered samples to be increased by a factor of 1.25. Terrestrial weathering destroying ordinary chondrites can be modeled as a first-order decay process with an estimated half-life of 3.5 + or - 1.9 ka on the semiarid American High Plains. Having accounted for the age of the recovery surface, area of field searches, pairing of finds, collection bias and weathering half-life, an accumulation rate of 940 falls/a per 10 to the 6th sq km is calculated for falls greater than 10 g total mass. This figure exceeds the best-constrained previous estimate by more than an order of magnitude. One possible reason for this disparity may be the extraordinary length of the fall record preserved in the surficial geology of Roosevelt County. The high accumulation rate determined for the past 16 ka may point to the existence of periods when the meteorite fall rate was significantly greater than at present.

Zolensky, Michael E.↗
NASA NTRSDate not supplied

Enhancing Autonomous Satellite Communication Systems with Weather-Aware Scheduling and Reconfiguration

NASA currently provides communication support to over 100 satellite missions, and the agency is driving developments in Ka-band communications and network management automation to support additional future missions. At Ka-band frequencies, rain can degrade a communication link by more than 10 dB, which may be mitigated by agile scheduling and data rate control. We present a weather forecasting module for Ka-band communications that is intended to be used in an autonomous network management service that employs machine-to-machine scheduling systems for dynamic user access opportunities. Our forecasting module (NIMBUS) runs on AWS Cloud, consumes the freely and publicly available NOAA MRMS precipitation rate dataset (1km x 1km x 2-min), produces 30-minute Nowcasts using the pySTEPS algorithm, and publishes high level ground station specific link quality predictions. We evaluate two potential NIMBUS outputs, a binary classifier that predicts rain attenuation greater than 3 dB and a rain attenuation estimator, and we backtest these outputs using one year of power measurement data collected from observations of the geostationary ANIK F2 satellite’s Ka-band beacon. We report, with a 30-minute lead time, a binary classifier accuracy of 84% and an estimator RMSE of 1.67 dB. Additionally, we discuss how the NIMBUS module could be incorporated into a user-initiated service framework to enable weather-aware scheduling and reconfiguration. Operating a static link budget with minimal link margin can increase network operation costs by creating additional scheduling tasks due to failed packets, which may require human intervention and/or lead to inefficient asset utilization. The proposed system aims to increase throughput by reducing link margin, while mitigating increases in network operations costs by leveraging autonomous machine-to-machine scheduling, shortened prediction lead times, and advances in precipitation Nowcasting.

satellite communications↗
NASA NTRS2017

Analysis of Convective Weather Impact on Pre-Departure Routing of Flights from Fort Worth Center to New York Center

In response to severe weather conditions, Traffic Managers specify flow constraints and reroutes to route air traffic around affected regions of airspace. Providing analysis and recommendations of available reroute options and associated airspace capacities would assist Traffic Managers in making more efficient decisions in response to convective weather. These recommendations can be developed by examining historical data to determine which previous reroute options were used in similar weather and traffic conditions. This paper describes the initial steps and methodology used towards this goal. The focus of this work is flights departing from Fort Worth Center destined for New York Center. Dominant routing structures used in the absence of convective weather are identified. A method to extract relevant features from the large volume of weather data available to quantify the impact of convective weather on this routing structure over a given time range is presented. Finally, a method of estimating flow rate capacity along commonly used routes during convective weather events is described. Results show that the flow rates drop exponentially as a function of the values of the proposed feature and that convective weather on the final third of the route was found to have a greater impact on the flow rate restriction than other portions of the route.

traffic flow management↗
NASA NTRS1994

Cluster growth modeling of plateau erosion

The pattern of erosion of a plateau along an escarpment may be modeled usng cluster growth techniques, recently popularized in models of drainage network evolution. If erosion on the scarp takes place in discrete events at rates subject to local substrate strength, the whole range of behavior is described by a combination of three cluster growth mechanisms: invasion percolation, Eden growth and diffusion-limited aggregation (DLA). These model the relative importance of preexisting substrate strength, background weathering, and seepage weathering and erosion respectively. The rate of seepage processes is determined by the efflux of groundwater at the plateau margin, which in turn is determined by the pressure field in the plateau aquifer. If this process acted alone, it would produce erosion patterns in the form of Laplacian fractals, with groundwater recharge from a distant source, or Poissionian fractals, with groundwater recharge uniform over the plateau. DLA is used to mimic the Laplacian or Poissonian potential field and the corresponding seepage growth process. The scaling structure of clusters grown by pure DLA, invasion percolation, or Eden growth is well known; this study presents a model which combines all three growth mechanisms for the first time. Mixed growth processes create clusters with different scaling properties and morphologies over distinct length scale ranges, and this is demonstrable in natural examples of plateau erosion.

Stark, Colin P.↗
DOE OSTI2025

Unveiling the drivers contributing to global wheat yield shocks through quantile regression

Sudden reductions in crop yield (i.e., yield shocks) severely disrupt the food supply, intensify food insecurity, depress farmers' welfare, and worsen a country's economic conditions. Here, we study the spatiotemporal patterns of wheat yield shocks, quantified by the lower quantiles of yield fluctuations, in 86 countries over 30 years. Furthermore, we assess the relationships between shocks and their key ecological and socioeconomic drivers using quantile regression based on statistical (linear quantile mixed model) and machine learning (quantile random forest) models. Using a panel dataset that captures spatiotemporal patterns of yield shocks and possible drivers in 86 countries, we find that the severity of yield shocks has been increasing globally since 1997. Moreover, our cross-validation exercise shows that quantile random forest outperforms the linear quantile regression model. Despite this performance difference, both models consistently reveal that the severity of shocks is associated with higher weather stress, nitrogen fertilizer application rate, and gross domestic product (GDP) per capita (a typical indicator for economic and technological advancement in a country). While the unexpected negative association between more severe wheat yield shocks and higher fertilizer application rate and GDP per capita does not imply a direct causal effect, they indicate that the advancement in wheat production has been primarily on achieving higher yields and less on lowering the possibility and magnitude of sharp yield reductions. Hence, in the context of growing extreme weather stress, there is a critical need to enhance the technology and management practices that mitigate yield shocks to improve the resilience of the world food systems.

60 APPLIED LIFE SCIENCES↗
NASA NTRS2002

The Effects of Aviation Weather Information Systems on General Aviation Weather Information Systems on General Pilots' Workload

My work at NASA Langley has focused around Aviation Weather Information CAWING displays. The majority of my time at LYRIC has been spent on the Workload and Relative Position (WaRP) Study. The goal of this project is to determine how an AWIN display at various positions within the cockpit affects pilot performance and workload. The project is being conducted in Languages Cessna 206H research aircraft. During the past year the design of the experiment was finalized and approved. Despite facing several delays the data collection was completed in early February. Alter the completion of the data collection an extensive data entry task began. This required recording air speed, altitude, course heading, bank angle, and vertical speed information from videos of the primary flight displays. This data was then used to determine root mean square error (RMSE) for each experimental condition. In addition to the performance data (RMSE) taken from flight path deviation, the study also collected data on pilot;s accuracy in reporting weather information, and a subjective rating of workload from the pilot. The data for this experiment is currently being analyzed. Overall the current experiment should help to determine potential costs and benefits associated with AWIN displays. The data will be used to determine if a private pilot can safely fly a general aviation aircraft while operating a weather display. Clearly a display that adds to the pilot#s already heavy workload represents a potential problem. The study will compare the use of an AWIN display to conventional means of acquiring weather data. The placement of the display within the cockpit (i.e., either on the yoke, kneeboard, or panel) will be also compared in terms of workload, performance, and pilot preference.

Scerbo, Mark↗
NASA NTRS1986

Characteristics of precipitation regimes during the global weather experiment

Rainfall data were used in conjunction with heating rate values obtained from GLA/NASA to describe large scale heating changes and concurrent circulation fluctuations for weekly averages during the Special Observing Period I (January-March 1979) of the Global Weather Experiment. The GLA diabatic heating rates were obtained as residues of the thermodynamic energy equation during the four-dimensional data assimilation cycle (as described by Kalnay and Baker, 1984). In week one, the heating and rainfall rate profiles display a positive anomaly on the West Pacific in both fields. The anomaly appears to propagate eastward into the East Pacific and South America by the fifth week. By the week four, the negative anomaly over the Indian Ocean becomes positive. These heating patterns are reflected on positive divergent anomalies at 200 mb analyzed for the same periods. The stream-function anomalies display anticyclonic circulations over the heating anomalies.

Ahrens, Glen D.↗
NASA NTRS2015

Dynamic Weather Routes: Two Years of Operational Testing at American Airlines

The Dynamic Weather Routes (DWR) tool continuously analyzes active flights in en-route airspace and finds simple route corrections to achieve more time- and fuel-efficient routes around convective weather. A strong partnership between NASA, American Airlines (AA), and the Federal Aviation Administration has enabled testing of DWR in real-world air traffic operations. NASA and AA have been conducting a trial of DWR at AA’s Integrated Operations Center in Fort Worth, Texas since July 2012. This paper describes test results based on AA’s use of DWR for their flights in and around Fort Worth Center (ZFW). Results indicate an actual savings of 3,290 flying minutes for 526 AA revenue flights from January 2013 through September 2014. Of these, 48 flights each indicate a savings of 15 minutes or more. Potential savings for all flights in ZFW airspace, corrected for savings flights achieve today through normal pilot requests and controller clearances, is about 100,000 flying minutes for 15,000 flights in 2013. Results indicate that AA flights with DWR in use realize about 20 percent more savings than non-AA flights. A weather forecast analysis examines the extent to which DWR routes rated acceptable by AA users remain clear of downstream weather. A sector congestion analysis indicates congestion could be reduced 19-38 percent if all flights fly DWR routes rather than nominal weather-avoidance routes.

Trajectory Automation↗
NASA NTRS1998

Total Lightning and Radar Storm Characteristics Associated with Severe Storms in Central Florida

This paper examines the three dimensional characteristics of lightning flashes and severe storms observed in Central Florida during 1997-1998. The lightning time history of severe and tornadic storms were captured during the on-going ground validation campaign supporting the Lightning Imaging Sensor (LIS) experiment on the Tropical Rainfall Measuring Mission (TRMM). The ground validation campaign is a collaborative experiment that began in 1997 and involves scientists at the Global Hydrology and Climate Center, MIT/Lincoln Laboratories, and the NWS Forecast Office at Melbourne, FL. Lightning signatures that may provide potential early warning of severe storms are being evaluated by the forecasters at the NWS/MLB office. Severe storms with extreme flash rates sometimes exceeding 300 per minute and accompanying rapid increases in flash rate prior to the onset of the severe weather (hall, damaging winds, tornadoes) have been reported by Hodanish et al. and Williams et al. (1998-this conference). We examine the co-evolving changes in storm structure (mass, echo top, shear, latent heat release) and kinematics associated with these extreme and rapid flash rate changes over time. The flash frequency and density are compared with the three dimensional radar reflectivity structure of the storm to help interpret the possible mechanisms producing the extreme and rapidly increasing flash rates. For two tornadic storms examined thus far, we find the burst of lightning is associated with the development of upper level rotation in the storm. In one case, the lightning burst follows the formation of a bounded weak echo region (BWER). The flash rates diminish with time as the rotation develops to the ground in conjunction with the decent of the reflectivity core. Our initial findings suggest the dramatic increase of flash rates is associated with a sudden and dramatic increase in storm updraft intensity which we hypothesize is stretching vertical vorticity as well as enhancing the development of the mixed phase region of the storm. We discuss the importance of these factors in producing both the observed extreme flash rates and the severe weather that follows in these storms and others to be presented.

Goodman, Steven J↗
NASA NTRS2013

Space Weathering of Lunar Rocks and Regolith Grains

The exposed surfaces of lunar soil grains and lunar rocks become modified and coated over time with a thin rind of material (patina) through complex interactions with the space environment. These interactions encompass many processes including micrometeorite impacts, vapor and melt deposition, and solar wind implantation/sputtering effects that collectively are referred to as "space weathering". Studies of space weathering effects in lunar soils and rocks provide important clues to understanding the origin and evolution of the lunar regolith as well as aiding in the interpretation of global chemical and mineralogical datasets obtained by remote-sensing missions. The interpretation of reflectance spectra obtained by these missions is complicated because the patina coatings obscure the underlying rock mineralogy and compositions. Much of our understanding of these processes and products comes from decades of work on remote-sensing observations of the Moon, the analysis of lunar samples, and laboratory experiments. Space weathering effects collectively result in a reddened continuum slope, lowered albedo, and attenuated absorption features in reflectance spectra of lunar soils as compared to finely comminuted rocks from the same Apollo sites. Space weathering effects are largely surface-correlated, concentrated in the fine size fractions, and occur as amorphous rims on individual soil grains. Rims on lunar soil grains are highly complex and span the range between erosional surfaces modified by solar wind irradiation to depositional surfaces modified by the condensation of sputtered ions and impact-generated vapors. The optical effects of space weathering effects are directly linked to the production of nanophase Fe metal in lunar materials]. The size of distribution of nanophase inclusions in the rims directly affect optical properties given that large Fe(sup o) grains (approx 10 nm and larger) darken the sample (lower albedo) while the tiny Fe(sup o) grains (<5nm) are the primary agent in spectral "reddening". More recent work has focused on the nature and abundance of OH/H2O in the lunar regolith using orbital data and samples analyses. Advances in sample preparation techniques have made possible detailed analyses of patina-coated rock surfaces. Major advances are occurring in quantifying the rates and efficiency of space weathering processes through laboratory experimentation.

Keller, L. P.↗
DOE OSTI2024

Soil management practices can contribute to net carbon neutrality in California

Stabilizing climate requires reducing greenhouse gas (GHG) emissions and storing atmospheric carbon dioxide (CO 2 ) in land or ocean systems. Soil management practices can reduce GHG emissions or sequester atmospheric CO 2 into inorganic and organic forms. However, whether soil carbon strategies represent a viable and impactful climate mitigation pathway is uncertain. A specific question concerns the role that land-management practices and soil amendments can play in realizing California's ambition for carbon neutrality by 2045. Here we examine the carbon flux impacts of soil conservation (i.e., compost, reduced tillage, cover crop) and enhanced silicate rock weathering (EW) practices at different areal extents of implementation in cropland, grassland, and savanna in California under two climate change cases. We show that with implementation areas of 15% or 50% of private cultivated land, grassland, and savanna in California, soil conservation practices alone can contribute $1.4^{2.1}_{0.7}$% ($-1.8^{-2.7}_{ -0.9}$ Mt CO 2 eq y -1 ) and $4.6^{6.9}_{2.3}$% ($-6.0^{-8.9}_{-3.0}$ Mt CO 2 eq y -1 ) of the additional emissions reduction needed (beyond previous targets) to meet the 2045 net neutrality goal (-129.3 Mt CO 2 eq y -1 ), respectively, on an average annual basis, including climate uncertainty. Including EW in these scenarios increases the total contributions of management practices to $4.1^{5.6}_{2.5}$% ($-5.2^{-7.3}_{-3.2}$ Mt CO 2 eq y -1 ) and $13.5^{18.6}_{8.2}$% ($-17.5^{-24.2}_{-10.7}$ Mt CO 2 eq y -1 ), respectively, of this reduction. This highlights that the extent of implementation area is a major factor in determining benefits and that EW has the potential to make a real contribution to net reduction targets. Results are similar across climate cases, indicating that contemporary field data can be used to make future projections. With EW there remains mechanistic uncertainties, however, such as rock dissolution rate and environmental controls on weathering products, which require additional field research to improve understanding of the technological efficacy of this approach for California's 2045 carbon neutrality goal.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1985

Synchronizing Heavily Encoded Data in Bad Weather

Deep space missions choose a data rate to ensure reliable communication under most conditions. Certain critical data can be more heavily encoded, to be decoded under particularly bad atmospheric conditions. It is shown that, in such a system, finding and synchronizing critical data will not be a problem.

Swanson, L.↗