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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7

The use of analytical surface tools in the fundamental study of wear

This paper reviews the various techniques and surface tools available for the study of the atomic nature of the wear of materials. These include chemical etching, X-ray diffraction, electron diffraction, scanning electron microscopy, low-energy electron diffraction, Auger emission spectroscopy analysis, electron spectroscopy for chemical analysis, field ion microscopy, and the atom probe. Properties of the surface and wear surface regions which effect wear such as surface energy, crystal structure, crystallographic orientation, mode of dislocation behavior, and cohesive binding are discussed. A number of mechanisms involved in the generation of wear particles are identified with the aid of the aforementioned tools.

Buckley, D. H.↗

Astronomy satellites in the U.S. program

The Orbiting Astronomical Observatory (OAO) series demonstrated that necessary thermal control systems and high pointing stability are feasible on astronomical satellites. A geosynchronous International Ultraviolet Explorer (IUE) is being planned by the US, UK, and ESRO for stellar spectroscopy. High Energy Astronomy Observatories, HEAO-A B, and C, will concentrate on stellar X-ray objects, cosmic ray physics, and gamma ray astronomy. A Shuttle-compatible Solar Maximum Mission (SMM) is planned for studying solar flares and flare related phenomena during the next solar maximum. Now in the instrumentation definition stage is the Large Space Telescope (LST), to provide higher resolution and sensitivity, larger wavelength range (from ultraviolet to far infrared), and higher time resolution than ground-based telescopes.

Aucremanne, M. J.↗

Solid state polymerization and crystallography of polyimide precursors

Although the production of crystallinity in a polymeric system has historically led to commerically useful properties, the polyimides, prized for their high temperature characteristics, as customarily synthesized by melt or solution casting, are amorphous. It is shown that polymide containing residual crystallinity can be synthesized by isothermal annealing of crystals of the salt of the diisopropyl ester of pyromellitic acid and phenylene diamine. The reaction is topochemical in that the geometry of the polymer product is dependent upon that of the crystalline precursor. Infrared spectroscopy reveals the presence of imide absorption in the polymer, while powder diffractometry suggests residual crystallinity. Single crystal X-ray analysis of the monomer yields a structure of chains of alternating acid and base suggesting that the monomer is amenable to polymerization with a minimum of geometrical disruption.

Wakelyn, N. T.↗

Interaction of hydrogen chloride with alumina

The influence of temperature, pressure, and outgas conditions on the absorption of hydrogen chloride and water vapor on both alpha and gamma alumina was studied. Characterization of the adsorbents was performed using X-ray powder diffraction, scanning electron microscopy (SEM), low temperature nitrogen adsorption desorption measurements, BET nitrogen surface area measurements and electron spectroscopy for chemical analysis (ESCA). Water vapor adsorption isotherms at 30, 40, and 50 C were measured on alpha and gamma alumina after outgassing at 80, 200, and 400 C. Both outgas temperature and adsorption temperature influenced the adsorption of water vapor on the aluminas. The water vapor adsorption was completely reversible. Alpha alumina absorbed more water per unit area than gamma alumina. Differences in the adsorption capacity for water vapor of the two aluminas were explained on the basis of ideal surface models of alpha and gamma alumina. Isosteric heats of adsorption for water vapor on the aluminas were determined over a limited range of surface coverage.

Bailey, R. R.↗

Topics in Astrophysical X-Ray and Gamma Ray Spectroscopy

A number of topics relating to astrophysical observations that have already been made or are currently planned of spectral features, mostly emission lines, in the X-ray and gamma ray region of the electromagnetic spectrum are investigated. These topics include: the production of characteristic X-ray and gamma ray lines by nonthermal ions, spectral features induced by processes occurring in strong magnetic fields, and the positron annihilation line at 0.5 MeV. The rate of X-ray production at 6.8 keV by the 2p to 1s transition in fast hydrogen- and helium-like iron ions, following both electron capture to excited levels and collisional excitation is calculated. The cross section for electron-ion Coulomb collisions in strong fields is also calculated.

Bussard, R. W.↗

Pi-mesic X-rays

Pion-meson X-ray spectra of calcium, titanium, and aluminum energy shifts

TITANIUM↗

Apollo 15 geochemical X-ray fluorescence experiment - Preliminary report.

Although only part of the information from the X-ray fluorescence geochemical experiment has been analyzed, it is clear that the experiment was highly successful. Significant compositional differences among and possibly within the maria and highlands have been detected. When viewed in the light of analyzed lunar rocks and soil samples, and the data from other lunar orbital experiments (in particular, the Apollo 15 gamma-ray spectroscopy experiment), the results indicate the existence of a differential lunar highland crust, probably feldspathic. This crust appears to be related to the plagioclase-rich materials previously found in the samples from Apollo 11, Apollo 12, Apollo 14, Apollo 15, and Luna 16.

Adler, I.↗

The Identification of Scientific Programs to Utilize the Space Environment

A program to identify and develop ideas for scientific experimentation on the long duration exposure facility (LDEF) was completed. Four research proposals were developed: (1) Ultra pure germanium gamma ray radiation detectors in the space environment, intended to develop and demonstrate an X-ray and gamma-ray spectroscopy system incorporating a temperature cyclable high-purity germanium detector and diode heat pipe cryogenic system for cooling, (2) growth, morphogenesis and metabolism of plant embryos in the zero-gravity environment, to investigate if the space environment induces mutations in the embryogenic cells so that mutants of commercial significance with desirable attributes may be obtained, (3) effect of zero gravity on the growth and pathogenicity of selected zoopathic fungi. It is possible that new kinds of treatment for candidiasis, and tichophytosis could eventuate from the results of the proposed studies, and (4) importance of gravity to survival strategies of small animals. Gravitational effects may be direct or mediate the selection of genetic variants that are preadapted to weightlessness.

Kulacki, F. A.↗

Gamma ray spectroscopy in astrophysics

Experimental and theoretical aspects of gamma ray spectroscopy in high energy astrophysics are discussed. Line spectra from solar, stellar, planetary, and cosmic gamma rays are examined as well as HEAO investigations, the prospects of a gamma ray observatory, and follow-on X-ray experiments in space.

Cline, T. L.↗

Future directions in experimental gamma ray astronomy

Better vehicles and instruments are needed if gamma ray spectroscopy in astrophysics and cosmology is to advance. A gamma ray observatory will (1) permit long-term observations of selected sources to measure their variability and to achieve high sensitivity; (2) measure periods in days or weeks; and (3) assess the entire sky to observe various predicted sources, to measure the energy spectrum, and to map the isotropy of the cosmic ray background over larger collecting areas (of the order of a square meter). Conventional and unconventional instruments must cover the energy range from 0.1 MeV to 20 MeV with improved sensitivity. Angular resolution must be improved one degree or more to study discrete X-ray sources in the galactic center. Actively collimated detectors, improved double Compton instruments, and gamma ray correlators to actively synthesize the absolute energy spectrum of the sky protons are discussed as well as the need for scientific balloons.

Haymes, R. C.↗

Pulse phase spectroscopy of Hercules X-1

The 6-18 keV and the 40-60 keV X-ray spectrum of Hercules X-1 were simultaneously observed with the A-2 experiment on HEAO 1. By combining these measurements with the results of an earlier observation of this X-ray pulsar, evidence is found for a component of emission above 40 keV which is above an extrapolation from lower energies, by a factor which is pulse phase dependent. These data are compared to previous hard X-ray observations and possible models are discussed.

Pravdo, S. H.↗