Search NASASearch

SEARCH · Search NASA

Results for “actinides, electronic spectroscopy, electronic structure, ligand field theory, f-orbital properties”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

747 records · Page 7

Second LDEF Post-Retrieval Symposium Abstracts

These abstracts from the symposium represent the data analysis of the 57 experiments flown on the LDEF. The experiments include materials, coatings, thermal systems, power and propulsion, science, (cosmic ray, interstellar gas, heavy ions, micrometeoroids, etc.), electronics, optics, and life science.

Arlene S. Levine

Bipolar Nickel-Metal Hydride Battery Being Developed

The NASA Lewis Research Center has contracted with Electro Energy, Inc., to develop a bipolar nickel-metal hydride battery design for energy storage on low-Earth-orbit satellites. The objective of the bipolar nickel-metal hydride battery development program is to approach advanced battery development from a systems level while incorporating technology advances from the lightweight nickel electrode field, hydride development, and design developments from nickel-hydrogen systems. This will result in a low-volume, simplified, less-expensive battery system that is ideal for small spacecraft applications. The goals of the program are to develop a 1-kilowatt, 28-volt (V), bipolar nickel-metal hydride battery with a specific energy of 100 watt-hours per kilogram (W-hr/kg), an energy density of 250 W-hr/liter and a 5-year life in low Earth orbit at 40-percent depth-of-discharge.

Manzo, Michelle A.

Uranus Orbiter and Probe: Mission Challenges and Concept Updates Since the Origins, Worlds, and Life Decadal Survey

Origins, Worlds, and Life: Planetary Science and Astrobiology in the Next Decade identified a Uranus Orbiter and Probe as the highest-priority strategic mission for the decade 2023–2032, as it enables broad cross-disciplinary science in the largely unexplored Uranian system. The mission architecture evaluated by the Decadal Survey was a singular proof of concept demonstrating that a moderately instrumented mission could deliver Decadal-priority science with a reduced cost and risk posture by leveraging existing technologies to the maximum extent possible. With revised assumptions since the Decadal, we have explored a large trade space including launch vehicles, propulsion options, cruise trajectories, available power sources, viable concept of operations, and science data return for later launch dates without a Jupiter gravity assist. The most repeatable trajectory solutions employ either a commercially derived solar electric propulsion (SEP) transfer stage or the availability of a more capable launch vehicle under development, such as the SpaceX Starship. Orbit insertion has been moved farther from Uranus to acknowledge the remaining uncertainty in Uranian ring structure. A streamlined, SEP-adaptable, orbiter design was developed using two Next Gen Radioisotope Thermoelectric Generators, and the probe design was matured, reducing the entry gravitational acceleration, and assuming the largest Decadal-recommended payload to provide margin for future instrument selections. With this updated design, we also constructed a detailed concept of operations for three representative science cases, returning 13–15 Gbit of science data and spacecraft telemetry per ∼34 day orbit.

Amy A Simon

Using Open Innovation in Reducing Risk to Crews

In the exploration of destinations outside of Earth's neighborhood, specifically Mars, scientific and engineering inquiries have occurred by two means; observations from satellites and observations by landed spacecraft. Satellite observations (Mariner, MRO, Mars Odyssey, provide global-scale spatial and temporal data while landed spacecraft (Viking, Mars Pathfinder, Spirit, Opportunity, Phoenix Mars Lander) investigate highly localized areas of the surface of the planet. In preparation for human exploration, extensive knowledge of the surface and atmospheric environments should be known before the first human leaves Earth. The primary goal of performing reconnaissance on Mars on a sub-global scale is to know as much as possible about the environment to which crews will be subjected. At the current rate of launching and landing probes to Mars, it will take a very long time to understand the surface and atmospheric conditions associated with the regions where prospective crews may land. Meanwhile electronics and electrical systems are rapidly getting smaller. One can argue that to acquire the knowledge of the region, one must take hundreds, maybe thousands of measurements simultaneously. One means to perform such a task is to deploy a swarm of sensors. Such a swarm would perform an in-situ assessment of the region. Imagine a close flyby mission to Mars for example, where mini- to micro-sensors are deposited into the atmosphere over half an orbit or more. The sensors, captured by the atmospheric drag and Martian gravity slowly descend buffeted about by Martian winds and weather until they settle on the surface a great time later (think of how long dust takes to settle). As they descend they communicate a vast array of data; temperature, chemistry, pressure, radiation dose, electric or magnetic properties from a region of the planet and an individual sensor need not measure the same quantity as its neighbors. Initially, they could move at the whim of the environment but later versions could have locomotion or propulsion mechanisms. Humans wouldn't need to decide where the sensors go, the sensors do that for themselves. This is a key strength of a sensor swarm. The intelligence relies on the group not on a decision maker on earth. Real time sensor inputs direct what the swarm considers most interesting to investigate resulting in emergent behavior. We issued a $20,000 challenge to the global innovators to provide solutions as to how such a swarm could be initialized and by what protocols and methodologies by which they operate. Over 400 innovators from 49 countries took a look at the problem, with three receiving partial awards for solutions.

Mel Ferebee

Spacecraft Water Impurity Monitor, a System for Water Quality Analysis on Exploration Missions Beyond Low Earth Orbit

Exploration missions beyond low-earth-orbit (LEO) will require advanced instrumentation to monitor water quality. Traveling beyond LEO means the transfer of water samples to an Earth-based laboratory for detailed analysis is not feasible. Detailed analysis of water composition during exploration is still necessary, because having the capability to determine the specific organic chemical causing a change in total organic carbon (TOC) or the specific metal or ionic species causing a change in conductivity has the potential to inform the crew health and system management decisions. On a new vehicle such as a lunar or Mars surface habitat or a Mars transit vehicle, finding “new” impurities not seen on ISS should be expected. The key is to identify the impurity so the correct action can be taken. On ISS we can measure TOC, conductivity, and other physical properties but do not have the capability for detailed analysis using vehicle instrumentation. This is acceptable because ISS can send samples down to Earth for further analysis and obtain the detailed composition. The Spacecraft Water Impurity Monitor (SWIM) will provide detailed water quality analysis for missions in which sample down mass is not available. SWIM is a system comprising organic and inorganic analysis modules. For organic chemicals, a gas chromatograph mass spectrometer (GCMS) detects and identifies organic impurities. For inorganic species, a capillary electrophoresis capacitively coupled contactless conductivity detection (CE-C4D) system as well as ion specific electrodes detect and identify metal ions and other inorganic salts / acids. The SWIM technology demonstration project has completed a System Requirements Review (SRR) to finalize detection requirements and is currently working to refine vehicle interface requirements for a future technology demonstration. The project also has begun preliminary flight design activities for the core analyzers in the instrument suite.

Water Monitoring

Spacecraft Water Impurity Monitor, a System for Water Quality Analysis on Exploration Missions Beyond Low Earth Orbit

Exploration missions beyond low-earth-orbit (LEO) will require advanced instrumentation to monitor water quality. Traveling beyond LEO means the transfer of water samples to an Earth-based laboratory for detailed analysis is not feasible. Detailed analysis of water composition during exploration is still necessary, because having the capability to determine the specific organic chemical causing a change in total organic carbon (TOC) or the specific metal or ionic species causing a change in conductivity has the potential to inform the crew health and system management decisions. On a new vehicle such as a lunar or Mars surface habitat or a Mars transit vehicle, finding “new” impurities not seen on ISS should be expected. The key is to identify the impurity so the correct action can be taken. On ISS we can measure TOC, conductivity, and other physical properties but do not have the capability for detailed analysis using vehicle instrumentation. This is acceptable because ISS can send samples down to Earth for further analysis and obtain the detailed composition. The Spacecraft Water Impurity Monitor (SWIM) will provide detailed water quality analysis for missions in which sample down mass is not available. SWIM is a system comprising organic and inorganic analysis modules. For organic chemicals, a gas chromatograph mass spectrometer (GCMS) detects and identifies organic impurities. For inorganic species, a capillary electrophoresis capacitively coupled contactless conductivity detection (CE-C4D) system as well as ion specific electrodes detect and identify metal ions and other inorganic salts / acids. The SWIM technology demonstration project has completed a System Requirements Review (SRR) to finalize detection requirements and is currently working to refine vehicle interface requirements for a future technology demonstration. The project also has begun preliminary flight design activities for the core analyzers in the instrument suite.

Water Monitoring

Hardware Design for the Autonomous Visibility Monitoring (AVM) Observatory

The hardware for the three Autonomous Visibility Monitoring (AVM) observatories was redesigned. Changes in hardware design include electronics components, weather sensors, and the telescope drive system. Operation of the new hardware is discussed, as well as some of its features. The redesign will allow reliable automated operation.

K Cowles

Polarized Resonant Soft X-ray Scattering (P-RSoXS) as a New Technique for Characterizing Amorphous Astromaterials

In the coming years, samples will be returned from several asteroids, the lunar surface, and the first material returned directly from the Martian surface. Previous in-situ and remote studies indicate these samples will contain abundant amorphous or weakly crystalline materials. However, detailed characterization and quantification of these amorphous materials remains challenging. Conventional techniques, including electron microscopy and X-ray diffraction, provide important information on material structure, but are generally limited to crystalline materials. Polarized resonant soft X-ray scattering (P-RSoXS) is a synchrotron-based X-ray scattering technique that has been used to characterize and quantify weakly crystalline systems, including soft materials. This research aims to translate this technique to geologic and extraterrestrial materials, building off the knowledge of using P-RSoXS to interrogate soft materials. P-RSoXS is well-suited to interrogate geologic materials, which are often multiphase, heterogeneous systems with crystalline and amorphous components, and domain sizes on the order of tens of nanometers. It is anticipated that future work will help reveal new chemical and structural information in geologic materials. Maturation of this preliminary work to develop P-RSoXS to characterize astromaterial-relevant samples will provide new understanding of the secondary processes responsible for the development of amorphous astromaterials and further elucidate our knowledge of the geologic history and past alteration processes.

Joshua H Litofsky

Analysis of LDEF micrometeoroid/debris data and damage to composite laminates

A nomogram based on the number/distribution of micrometeoroid/debris hits recorded on the Long Duration Exposure Facility (LDEF) is presented. The nomogram permits the user to estimate the total number of impacts that a space structure would encounter as a function of time in orbit, exposed area, and angular location associated with the LDEF. Examples are presented on the application of the nomogram to satellites and space structures of different cross-sections to that of the LDEF. The effects of altitude and orbit inclination are also discussed. To further demonstrate the usefulness of this nomogram, results are compared to impact data measured on the UTIAS polymer matrix composite experiment (AO180). The impact damage occurring on these composite materials is examined, and data on hole size, penetration depth, and delamination area are presented.

R. C. Tennyson

Characterization of Ternary NiTiPt High-Temperature Shape Memory Alloys

Pt additions substituted for Ni in NiTi alloys are known to increase the transformation temperature of the alloy but only at fairly high Pt levels. However, until now only ternary compositions with a very specific stoichiometry, Ni 50-x Pt x Ti 50 , have been investigated and then only to very limited extent. In order to learn more about this potential high-temperature shape memory alloy system, a series of over twenty alloys along and on either side of a line of constant stoichiometry between NiTi and TiPt were arc melted, homogenized, and characterized in terms of their microstructure, transformation temperatures, and hardness. The resulting microstructures were examined by scanning electron microscopy and the phase compositions quantified by energy dispersive spectroscopy. "Stoichiometric" compositions along a line of constant stoichiometry between NiTi to TiPt were essentially single phase but any deviations from a stoichiometry of (Ni,Pt) 50 Ti 50 resulted in the presence of at least two different intermetallic phases, depending on the overall composition of the alloy. Essentially all alloys, whether single or two-phase, still under went a martensitic transformation. It was found that the transformation temperatures were depressed with initial Pt additions but at levels greater than 10 at.% the transformation temperature increased linearly with Pt content. Also, the transformation temperatures were relatively insensitive to alloy stoichiometry within the range of alloys examined. Finally, the dependence of hardness on Pt content for a series of Ni 50-x Pt x Ti 50 alloys showed solution softening at low Pt levels, while hardening was observed in ternary alloys containing more than about 10 at.% Pt. On either side of these "stoichiometric" compositions, hardness was also found to increase significantly.

Transformation Temperatures

Empirical Model Development for Predicting Shock Response on Composite Materials Subjected to Pyroshock Loading

The NASA Engineering and Safety Center (NESC) received a request to develop an analysis model based on both frequency response and wave propagation analyses for predicting shock response spectrum (SRS) on composite materials subjected to pyroshock loading. The model would account for near-field environment (approx. 9 inches from the source) dominated by direct wave propagation, mid-field environment (approx. 2 feet from the source) characterized by wave propagation and structural resonances, and far-field environment dominated by lower frequency bending waves in the structure. This report documents the outcome of the assessment.

Steven J Gentz

Empirical Model Development for Predicting Shock Response on Composite Materials Subjected to Pyroshock Loading

The NASA Engineering and Safety Center (NESC) received a request to develop an analysis model based on both frequency response and wave propagation analyses for predicting shock response spectrum (SRS) on composite materials subjected to pyroshock loading. The model would account for near-field environment (~9 inches from the source) dominated by direct wave propagation, mid-field environment (approximately 2 feet from the source) characterized by wave propagation and structural resonances, and far-field environment dominated by lower frequency bending waves in the structure. This document contains appendices to the Volume I report.

Steven J Gentz

Empirical Model Development for Predicting Shock Response on Composite Materials Subjected to Pyroshock Loading: Appendices

The NASA Engineering and Safety Center (NESC) received a request to develop an analysis model based on both frequency response and wave propagation analyses for predicting shock response spectrum (SRS) on composite materials subjected to pyroshock loading. The model would account for near-field environment (approx. 9 inches from the source) dominated by direct wave propagation, mid-field environment (approx. 2 feet from the source) characterized by wave propagation and structural resonances, and far-field environment dominated by lower frequency bending waves in the structure. This document contains appendices to the Volume I report.

Gentz, Steven J

Empirical Model Development for Predicting Shock Response on Composite Materials Subjected to Pyroshock Loading: Appendices - Volume 2, Part 1

The NASA Engineering and Safety Center (NESC) received a request to develop an analysis model based on both frequency response and wave propagation analyses for predicting shock response spectrum (SRS) on composite materials subjected to pyroshock loading. The model would account for near-field environment (approximately 9 inches from the source) dominated by direct wave propagation, mid-field environment (approximately 2 feet from the source) characterized by wave propagation and structural resonances, and far-field environment dominated by lower frequency bending waves in the structure. This document contains appendices to the Volume I report.

Steven J Gentz

An Improved Theoretical Ni-Cd Battery Performance Model

Previous reports have shown how a battery model was developed using porous electrode theory. Since then the model has been upgraded and expanded. These upgrades include oxygen reation and positive electrode intercalation and proton diffusion. The effects of additional details of the solid state physics of the nickel electrode will be reported here.

battery

On the isotopic signature of recent solar-wind nitrogen

One of the most intriguing discoveries yielded by the Apollo samples was evidence pointing towards a significant long-term change in the composition of the sun. Such a change, of the size inferred from the lunar sample data, is inconsistent with present theories of solar evolution. Consequently, there is much interest in exploring this phenomenon as closely as possible, to determine exactly what compositional changes have taken place and whether those changes really did take place in the sun, or whether the cause lies elsewhere. The reason why we can use the moon to analyze the elements in the sun is that the sun emits a stream of ions, known as the solar wind, whose composition, on average, is believed to be the same as that in the surface regions of the sun. When the solar-wind ions hit the surface of the moon, many of them penetrate a short distance into the dust grains lying on the lunar surface. Thus, after a grain has sat on the lunar surface for a while, it has a rim of material that is partly lunar and partly solar in composition. For most chemical elements, the difference between lunar and solar composition is so sufficiently small that the solar elements cannot be detected, but for a handful of elements that are missing from the moon, their solar 'signature' can be observed in samples of lunar soil brought back by the astronauts. Among those elements is nitrogen, the most common element in the air we breathe, but very rare indeed on the moon. Our analytical techniques are not sophisticated enough yet to enable us to analyze individual lunar soil grains for nitrogen, much less to zero in on just the nitrogen in the surface of such a grain. Consequently we are forced to analyze samples consisting of many different grains, each of which could have experienced its own individual history. This makes it difficult to identify the nitrogen implanted in grain surfaces, and also to define the age of a sample.

Kim, Y.