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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7

High performance addition-type thermoplastics (ATTs) - Evidence for the formation of a Diels-Alder adduct in the reaction of an acetylene-terminated material and a bismaleimide

Recently, the concept and demonstration of a new versatile synthetic reaction for making a large number of high-performance addition-type thermoplastics (ATTs) were reported. The synthesis shows promise for providing polymers having an attractive combination of easy processability, good toughness, respectable high temperature mechanical performance, and excellent thermo-oxidative stability. The new chemistry involves the reaction of an acetylene-terminated material with a bismaleimide or benzoquinone. In order to clarify the reaction mechanism, model compound studies were undertaken in solutions as well as in the solid state. The reaction products were purified by flash chromatography and characterized by conventional analytical techniques including NMR, FT-IR, UV-visible, mass spectroscopy, and high pressure liquid chromatography. The results are presented of the model compound studies which strongly support the formation of a Diels-Alder adduct in the reaction of an acetylene-terminated compound and a bismaleimide or benzoquinone.

Pater, R. H.↗

Nondestructive spot tests allow rapid identification of metals

Ordered qualitative test sequence, presented in flow chart form, permits identification of all common metallurgical elements and many high-temperature, stainless, high and low carbon, and tool steels within about 30 minutes. Identification is made from colors or specific reactions produced by the addition of standard chemical reagents.

Wilson, M. L.↗

Some observations on uranium carbide alloy/tungsten compatibility

Chemical compatibility between both pure and thoriated tungsten and uranium carbide alloys was studied at 1800 C for up to 3300 hours. Alloying with zirconium carbide appeared to widen the homogeneity range of uranium carbide, making additional carbon available for reaction with the tungsten. Reaction layers were formed both by vapor phase reaction and by physical contact, producing either or both UWC2 and W2C, dependent upon the phases present in the starting fuel alloy. Formation of UWC2 results in slow growth of the reaction layer with time, while W2C reaction layers grow rapidly, allowing equilibrium to be reached in less than 2500 hours at 1800 C. The presence of a thermal gradient had no effect on the reactions observed nor did the presence of thoria in the tungsten clad.

Phillips, W. M.↗

Compatibility of buffered uranium carbides with tungsten.

Results of compatibility tests between tungsten and hyperstoichiometric uranium carbide alloys run at 1800 C for 1000 and 2500 hours. These tests compared tungsten-buffered uranium carbide with tungsten-buffered uranium-zirconium carbide. The zirconium carbide addition appeared to widen the homogeneity range of the uranium carbide, making additional carbon available for reaction. Reaction layers could be formed by either of two diffusion paths, one producing UWC2, while the second resulted in the formation of W2C. UWC2 acts as a diffusion barrier for carbon and slows the growth of the reaction layer with time, while carbon diffusion is relatively rapid in W2C, allowing equilibrium to be reached in less than 2500 hours at a temperature of 1800 C.

Phillips, W. M.↗

Some observations on uranium carbide alloy/tungsten compatibility.

Results of chemical compatibility tests between both pure tungsten and thoriated tungsten run at 1800 C for up to 3300 hours with uranium carbide alloys. Alloying with zirconium carbide appeared to widen the homogeneity range of uranium carbide, making additional carbon available for reaction with the tungsten. Reaction layers were formed both by vapor phase reaction and by physical contact, producing either or both UWC2 and W2C, depending upon the phases present in the starting fuel alloy. Formation of UWC2 results in slow growth of the reaction layer with time, while W2C reaction layers grow rapidly, allowing equilibrium to be reached in less than 2500 hours at 1800 C. Neither the presence of a thermal gradient nor the presence of thoria in the tungsten clad affect the reactions observed.

Phillips, W. M.↗

The O I /5577-A wavelength/ airglow - Observations and excitation mechanisms

Analysis of the O I /5577-A wavelength/ airglow observations conducted on board the Atmosphere Explorer C satellite yields the following results when combined with simultaneous measurements of ion and neutral composition. A volume emission rate profile derived after sunset requires the production of an O(1S) atom in 8% of the O2(+) recombinations. Photoelectric impact on atomic oxygen and the dissociative recombination of O2(+) are important sources of O(1S) in the dayglow; however, the airglow measurements require a large additional production of O(1S) below 200 km in addition to these. The reaction N + O2(+) yielding NO(+) + O(1S) can provide the missing O(1S) source if the rate coefficient is near 2.5 times 10 to the minus 11th cu cm per sec.

Frederick, J. E.↗

On the radiative damping of atmospheric waves

General expressions for computing time constants for radiative decay of harmonic temperature perturbations in planetary atmospheres are developed. Four spatial scales are shown to be generally important: the scale height of the atmospheric absorber, the absorption mean free path for thermal radiation, the altitude above the planetary surface, and the wavelength of the temperature perturbation. Atmospheric inhomogeneity is particularly important when the radiation mean free path and the vertical wavelength divided by 2 pi both exceed the absorber scale height. The surface is very important for wave decay at altitudes less than a few radiation mean free paths, and its effect depends on a comparison of the surface response time and the lifetime of the atmospheric perturbation. The surface response time depends on the conducting and emitting properties of the surface material and on the strength of turbulence in the planetary boundary layer. The additional influence of chemical reactions and phase changes on radiative damping is discussed, and several assumptions inherent in the development of the general expressions for time constants are evaluated. Terrestrial examples are used for purposes of illustration, but the development is kept sufficiently general so that the results remain applicable to most situations on other planets.

Prinn, R. G.↗

Development of a model and computer code to describe solar grade silicon production processes

Mathematical models, and computer codes based on these models were developed which allow prediction of the product distribution in chemical reactors in which gaseous silicon compounds are converted to condensed phase silicon. The reactors to be modeled are flow reactors in which silane or one of the halogenated silanes is thermally decomposed or reacted with an alkali metal, H2 or H atoms. Because the product of interest is particulate silicon, processes which must be modeled, in addition to mixing and reaction of gas-phase reactants, include the nucleation and growth of condensed Si via coagulation, condensation, and heterogeneous reaction.

Srivastava, R.↗

Catalytic processes in the atmospheres of earth and Venus

Photochemical processes in planetary atmospheres are strongly influenced by catalytic effects of minor constituents. Catalytic cycles in the atmospheres of Earth and Venus are closely related. For example, chlorine oxides (ClOx) act as catalysts in the two atmospheres. On earth, they serve to convert odd oxygen (atomic oxygen and ozone) to molecular oxygen. On Venus they have a similar effect, but in addition they accelerate the reactions of atomic and molecular oxygen with carbon monoxide. The latter process occurs by a unique combination of ClOx catalysis and sulful dioxide photosensitization. The mechanism provides an explanation for the very low extent of carbon dioxide decomposition by sunlight in the Venus atmosphere.

Demore, W. B.↗

Canonical solutions for unsteady flow fields

The initial value problem of one-dimensional gas-dynamics involving discontinuous, nonuniform initial data is discussed. Canonical solutions which are valid in a small x, t region aroung a discontinuity, and which include the first order effects of nonuniformities in the data, are derived explicitly. The theory is derived by considering a group of elementary piston problems. Solutions with a shock or with a centered expansion wave are worked out individually in order to relate initial flow properties and their gradients to the speed and acceleration of the discontinuity waves. They are then combined to represent the solution of a general initial value problem by regarding the piston path as a contact line. In addition, problems with chemical reaction are discussed in terms of elementary piston problems which involve strong detonation waves, Chapman-Jouguet detonation waves, and deflagration waves.

Liu, G. C.↗

Response of GAS payload (G345 and G347) temperatures to various orbiter flight attitudes

At the beginning of the Get-Away Special (GAS) flight program, the GAS Project flew a Flight Verification Payload on STS-3 to make measurements of the vibrations, acoustic and magnetic environments of the canister, and to obtain thermal profiles of internal and external components of the GAS system. These data were used to verify pre-flight thermal models of the GAS system and results have been published in a GSFC Technical Note, X-732-83-8 (Butler, 1983). On somewhat later flights of the Orbiter, STS-7 and STS-8, the Naval Research Laboratory and the Goddard Space Flight Center jointly developed and flew a GAS payload whose primary objective was to evaluate the performance of ultraviolet-sensitive (Schumann) photographic emulsions in the Orbiter environment, including pre-flight integration, on-orbit exposure to the ambient environment of the Orbiter bay and post-flight conditions before removal of the experiment from the vehicle. These emulsions, used in spectrographs to record solar radiations with wavelengths between 100 A and 2000 A, have low gelatin content and no protective gelatin overcoating in order to maximize their UV sensitivity. Consequently, they are extremely sensitive to environmental conditions. Furthermore, they are exposed directly to space during the observations because any intervening protective window or lense would completely absorb the radiations to be studied. which was prepared at the Naval Research Laboratory under the direction of Robert Kreplin (Kreplin et al., 1984 a) also included two thermal sensors, whose output was recorded once an hour with a precision of 0.7O C. The experiment operated nominally on both missions and provided important data confirming that W - sensitive emulsions could tolerate integration and flight on the Shuttle with relatively little deterioration. The results of these studies have already been reported (Kreplin et al, 1984 b). The temperature measurements also were recorded successfully and are the basis for this paper. They are a useful complement to the thermal observations made on STS-3 and provide additional insight into the reaction of a payload to typical thermal environments that GAS experiments are subject to. Our GAS experiment and the circumstances of its flights were particularly useful in terms of modeling the thermal response of the GAS canister and our instrument. The Orbiter was held (except for interruptions for star tracker alignment, satellite deployments, etc., in specific attitudes for sufficiently long periods of time that the thermal response of the instrument to each attitude was well measured. Two types of GAS canister end cap, one, the insulated end cap and the other a silverized teflon covered end-cap, were used on the two flights so that a direct comparison of the thermal performance of the two types was obtained. This report is an attempt to compare these observations with a simple thermal model of the instrument in the GAS canister in order to assess whether such simple models can be useful to experimenters in predicting the thermal response of their payloads.

Werner M. Neuper↗

Acetylene-Terminated Polyimide Siloxanes

Siloxane-containing addition polyimides yield toughened high-temperature adhesives and matrix resins. Addition polyimide made by reaction of aromatic tetracarboxylic acid dianhydride with aromatic diamine in presence of ethynyl-substituted aromatic monoamine. Acetylene-terminated siloxane imide cured by heating to yield acetylene-terminated polyimide siloxane.

St. Clair, Terry L.↗

Efficient near ultraviolet light induced formation of hydrogen by ferrous hydroxide

A possible origin of early hydrogen by UV-induced photoreduction of ferrous ions was investigated by measuring the rate of H2 formation from irradiated FeSO4 solutions as a function of pH and the range of UV sources. It was found that, in addition to the known reaction in acid solution which decreases in yield with increasing pH and requires far-UV light, there is an efficient reaction occurring between pH 6 and 9 which utilizes near-UV light (of a 200-W mercury arc lamp). This latter reaction is a linear function of both the concentration of Fe(2+) and the light intensity. These results support the suggestion of Braterman et al. (1983) that the near-UV-driven photooxidation of ferrous ions may be responsible for the origin of the banded iron formations on the early earth. The efficient photoreaction could also explain the source of reducing equivalents for CO2 reduction.

Borowska, Zofia K.↗

Cloned Hemoglobin Genes Enhance Growth Of Cells

Experiments show that portable deoxyribonucleic acid (DNA) sequences incorporated into host cells make them produce hemoglobins - oxygen-binding proteins essential to function of red blood cells. Method useful in several biotechnological applications. One, enhancement of growth of cells at higher densities. Another, production of hemoglobin to enhance supplies of oxygen in cells, for use in chemical reactions requiring oxygen, as additive to serum to increase transport of oxygen, and for binding and separating oxygen from mixtures of gases.

Khosla, Chaitan↗

Chlorine catalyzed destruction of ozone - Implications for ozone variability in the upper stratosphere

The annual mean and the annual amplitude of ozone have been derived from ozone measurements from the SBUV and SBUV/2 spectrometers on board the Nimbus-7 and NOAA-11 satellites. These values differ significantly from values calculated using a two-dimensional model of stratospheric photochemistry and dynamics with standard chemistry. We have found that the differences between the calculated and data-derived values are considerably improved by changing the partitioning in the Cly family to create a larger reservoir of HCl and reducing ClO. This is accomplished by including a channel for the products HCl + O2 from the reaction ClO + OH in addition to the products Cl + HO2. This partitioning also improves the agreement between the calculated and measured values of ClO/HCl ratio.

Chandra, Sushil↗

A novel approach to increasing cocaine detection confidence utilizing ion mobility spectrometry

When a positive detection of a narcotic occurs during the search of a vessel, a decision has to be made whether further intensive search is warranted. In terms of unwarranted delays of vessels and possible property damage, the accuracy of the analytical determination is very important. Analytical accuracy becomes critical when the data may be used in court actions as evidence. For this purpose, the U.S. Coast Guard has been investigating several confirmatory ion mobility spectrometry (IMS) field methods for the detection and identification of cocaine. This paper presents the findings of our investigations on the use of catalytic pyrolysis and base hydrolysis as confirmatory methods. The catalytic effects of various metals on the pyrolysis reaction are reported. In addition, the effects of several different ion mobility spectrometer sample transfer mediums and varying laboratory conditions on the base hydrolysis of the cocaine molecule are also be reported.

Jadamec, J. Richard↗

Transesophageal Echocardiographic Study of Decompression-Induced Venous Gas Emboli

Transesophageal echo-cardiography was used to evaluate venous bubbles produced in nine anesthetized dogs following decompression from 2.84 bar after 120 min at pressure. In five dogs a pulsed Doppler cuff probe was placed around the inferior vena cava for bubble grade determination. The transesophageal echo images demonstrated several novel or less defined events. In each case where the pulmonary artery was clearly visualized, the venous bubbles were seen to oscillate back and forth several times, bringing into question the effect of coincidental counting in routine bubble grade analysis using precordial Doppler. A second finding was that in all cases, extensive bubbling occurred in the portal veins with complete extraction by the liver sinusoids, with one exception where a portal-to-hepatic venous anastomosis was observed. Compression of the bowel released copious numbers of bubbles into the portal veins, sometimes more than were released into the inferior vena cava. Finally, large masses of foam were routinely observed in the non-dependent regions of the inferior vena cava that not only delayed the appearance of bubbles in the pulmonary artery but also allowed additional opportunity for further reaction with blood products and for coalescence to occur before reaching the pulmonary microcirculation. These novel observations are discussed in relation to the decompression process.

Butler, B. D.↗

Compositions of Partly Altered Olivine and Replacement Serpentine in the CM2 Chondrite QUE93005

Some phyllosilicates in CM carbonaceous chondrites formed by aqueous alteration of anhydrous precursor phases. Although broad trends in the compositions of hydrous phyllosilicates are recognized and believed to be related to trends in degree of aqueous alteration, details of the reactions that formed specific secondary minerals remain obscure. This paper reports compositional relationships between remnants of partially pseudomorphically (or alteromorphically) replaced silicates and their alteration products (serpentine) in the CM2 chondrite QUE93005 and compares it with previously published results for ALH81002. Reactants and products were characterized by optical petrography, backscattered scanning electron microscopy (BSEM), and electron microprobe. By focusing on serpentine formed from known reactants (olivines), and on only those instances in which some of the reactant silicate remains, direct compositional relationships between reactants and products, and the elemental mobility required by the reactions, can be established. Additional information is included in the original extended abstract.

Velbel, M. A.↗