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DOE OSTI2025

Kelvin probe force microscopy under ambient conditions

Kelvin probe force microscopy (KPFM) is a technique derived from atomic force microscopy that provides maps of surface potential or work function differences across material systems, with nanometre-scale resolution. KPFM is a useful tool for investigating electrical phenomena such as dipole orientation, interfacial charge transfer, charge accumulation, band bending and doping levels. This Primer aims to provide an overview of typical ambient-condition KPFM measurements, covering their underlying principles, experimental implementations and wide-ranging applications. Key KPFM variants, including amplitude and frequency modulation, heterodyne detection schemes and innovative open loop and pulsed force techniques, are discussed, with practical guidance on optimizing signal acquisition and reducing errors. Specialized approaches, such as time-resolved KPFM and multimodal KPFM, are discussed for their ability to capture dynamic charge processes and chemical information, respectively. Here, we highlight recent advances in KPFM applications, spanning metal alloys, soft matter, ferroelectrics, photovoltaics and 2D materials, showcasing its versatility across research domains. By addressing current limitations and identifying future opportunities, this Primer underscores the transformative potential of KPFM in advancing the understanding of nanoscale electrical phenomena.

Zahmatkeshsaredorahi, Amirhossein [Lehigh Univ., B↗

NASA NTRS1989

The Li-7 and Be-7 deexcitation lines: Probes for accelerated particle transport models in solar flares

The photon energy spectrum of a spectral feature composed of the 429 and 478 keV gamma-ray lines from Li-7 and Be-7 (produced by interactions of flare-accelerated alpha particles with ambient He in the solar atmosphere) depends on the angular distribution of the interacting accelerated particles. This spectrum is calculated for limb and disc-centered flares using a loop model for the transport of the ions. In this model, the flux tube magnetic field is constant in the corona and converges in the chromosphere to the photosphere. Magnetic mirroring and MHD pitch-angle scattering are both taken into account. Comparison of these results with data from other experiments is presented.

Murphy, Ronald J.↗

DOE OSTI2025

Comparative analysis of thermal management systems in electric vehicles at extreme weather conditions: Case study on Nissan Leaf 2019 Plus, Chevrolet Bolt 2020 and Tesla Model 3 2020

With the surge in electric vehicle (EV) adoption and the need for extended driving ranges, optimizing energy efficiency, particularly through thermal management, is critical, especially in extreme weather. Managing the substantial energy needed for cabin climate control and battery temperature regulation can increase energy demands by over 50 %, severely limiting range. This study conducts a comparative analysis of thermal management systems (TMS) in three popular EV vehicles, 2020 Chevrolet Bolt, 2019 Nissan Leaf Plus, and 2020 Tesla Model 3, evaluating their distinct TMS configurations and performance under varied weather conditions. Using both numerical simulations and experimental data collected on a controlled test bench at Argonne National Laboratory, we assess how TMS architecture and operational modes influence energy consumption and range. A comprehensive TMS model was developed, integrating cabin and battery thermal sub-models in the Autonomie software platform, to simulate temperature fluctuations and range impacts. Cabin climate was modeled using a mono-zonal approach, while battery cell temperature distribution was estimated through a 2D nodal structure. Each vehicle's distinct TMS setup was evaluated: the Chevrolet Bolt and Tesla Model 3 use a dual evaporator vapor compression cycle with a PTC heater for the cabin and a coolant loop for battery thermal management; the Nissan Leaf Plus employs a heat pump with a PTC heater for the cabin and air-cooling for the battery. Tests conducted at ambient temperatures of 35°C, 22°C, -7°C, and -18°C reveal significant differences in energy use and range reduction across both configurations and conditions. At 35°C, the Tesla Model 3, Chevrolet Bolt, and Nissan Leaf Plus have a range reduction of 8%, 9%, and 13%, respectively, due to air conditioning. In winter, heating technology is paramount; at -7°C, the Nissan Leaf's heat pump configuration achieves a lower range reduction (19.3%) compared to the Tesla and Chevrolet Bolt PTC heaters, which reduce range by 28.3% and 31%, respectively. Further, this study provides valuable insights for automotive engineers, EV technology researchers, and thermal management system designers aiming to enhance electric vehicle performance by understanding how different weather conditions and TMS architectures impact energy consumption and driving range.

33 ADVANCED PROPULSION SYSTEMS↗

DOE OSTI2023

A Propane Hydronic Heat Pump with Energy Storage

Propane is an environment-friendly refrigerant, having a 20-year GWP (global warming potential) of 0.072 and a 100-year GWP of 0.02, as compared to R-410A having a GWP > 2000. It has superior thermodynamic cycle performance and heat transfer characteristics. However, propane is classified as a A3 refrigerant, which is highly flammable, and not allowed to be used indoor if the system charge is higher than 150 grams. It is a challenge to use propane in residential applications requiring a rated capacity larger than 10 k Watts. A hydronic heat pump, i.e., containing propane in an outdoor unit and distributing the cooling and heating capacity through a hydronic coil to the indoor space addresses the flammability issue, while maintaining a high efficiency. We developed a hydronic heat pump with propane, it uses a two-stage compressor, a brazed plate indoor heat exchanger, and a microchannel outdoor heat exchanger. It achieves a rated cooling capacity larger than 10 k Watts, and a cooling SEER (cooling seasonal energy efficiency rating) > 16.0 (cooling seasonal COP > 4.7) and a heating HSPF (heating seasonal performance factor) > 9.5 (heating seasonal COP > 2.78), while requiring a system charge < 1200 grams. Additionally, the hydronic heat pump was evaluated in a laboratory water heating loop to heat a 50-gallon water tank in a full condensing mode. Experiments of heating the tank water from 58F(14.4°C) to 150F(65.6°C) were conducted under ambient temperatures from 17F(-8.3°C) to 75F(23.9°C), at the compressor high and low stages.

Shen, Bo↗

NASA NTRS1989

High temperature skin friction measurement

Skin friction measurement in the NASA Langley hypersonic propulsion facility is described. The sensor configuration utilized an existing balance, modified to provide thermal isolation and an increased standoff distance. For test run times of about 20 sec and ambient-air cooling of the test section and balance, the modified balance performed satisfactorily, even when it was subjected to acoustic and structural vibration. The balance is an inertially balanced closed-loop servo system where the current to a moving-coil motor needed to restore or null the output from the position sensor is a measure of the force or skin friction tending to displace the moving element. The accuracy of the sensor is directly affected by the position sensor in the feedback loop, in this case a linear-variable differential transformer which has proven to be influenced by temperature gradients.

Tcheng, Ping↗

NASA NTRSDate not supplied

Particle Loading Tests on HEPA Flat Sheet Media at Sub-Ambient Pressures Using a Lunar Dust Simulant

When humans return to the moon under the NASA Artemis program, their activities on the lunar surface will inevitably lead to the intrusion of some level of lunar dust into the lander cabin. Therein the crew would be exposed to the potential hazards of lunar dust and the possibility of subsequent transfer into orbiting segments after docking. The spacecraft’s cabin filtration system will need to be effective at removing the airborne lunar dust to properly purify the breathable cabin air and minimize the spreading of the dust throughout the vehicle and orbital segments through the mission duration. The fine nature of the lunar dust will require high efficiency filtration, such as HEPA. A series of tests were performed in a specially designed recirculating sealed flow loop, for testing filter media and filter elements at the NASA Glenn Research Center. The flow loop was used to assess the performance and capacity of flat sheet filter media at representative cabin pressures using JSC-1AF lunar dust simulant and at high rates of particle loading. The pressure drop across the filter media was measured as a function of accumulated particle mass load at ambient pressure and at two sub-ambient pressures, 0.0703MPa and 0.0565MPa, and at a media velocity that was scaled relative to its pleated configuration. The challenge particle flows were generated by a custom designed particle generator that introduces dispersed particles of the lunar simulant at high concentrations. An optical particle counting instrument provided filter efficiency measurements within the sealed environment. The pressure drop was found to increase linearly with the amount of dust load on the media, for all test conditions, while the starting pressure drop was found to be lower at the lowest sub-ambient pressure case. High filter efficiency was maintained after high particle loads on the media.

Sub-ambient↗

NASA NTRSDate not supplied

Particle Loading Tests on HEPA Flat Sheet Media at Sub-Ambient Pressures Using a Lunar Dust Simulant

When humans return to the moon under the NASA Artemis program, their activities on the lunar surface will inevitably lead to the intrusion of some level of lunar dust into the lander cabin. Therein the crew would be exposed to the potential hazards of lunar dust and the possibility of subsequent transfer into orbiting segments after docking. The spacecraft’s cabin filtration system will need to be effective at removing the airborne lunar dust to properly purify the breathable cabin air and minimize the spreading of the dust throughout the vehicle and orbital segments through the mission duration. The fine nature of the lunar dust will require high efficiency filtration, such as HEPA. A series of tests were performed in a specially designed recirculating sealed flow loop, for testing filter media and filter elements at the NASA Glenn Research Center. The flow loop was used to assess the performance and capacity of flat sheet filter media at representative cabin pressures using JSC-1AF lunar he filter media was measured as a function of accumulated particle mdust simulant and at high rates of particle loading. The pressure drop across tass load at ambient pressure and at two sub-ambient pressures, 0.0703MPa and 0.0565MPa, and at a media velocity that was scaled relative to its pleated configuration. The challenge particle flows were generated by a custom designed particle generator that introduces dispersed particles of the lunar simulant at high concentrations. An optical particle counting instrument provided filter efficiency measurements within the sealed environment. The pressure drop was found to increase linearly with the amount of dust load on the media, for all test conditions, while the starting pressure drop was found to be lower at the lowest sub-ambient pressure case. High filter efficiency was maintained after high particle loads on the media

Sub-ambient↗

NASA NTRS1994

Particle-in-cell simulations of the critical ionization velocity effect in finite size clouds

The critical ionization velocity (CIV) mechanism in a finite size cloud is studied with a series of electrostatic particle-in-cell simulations. It is observed that an initial seed ionization, produced by non-CIV mechanisms, generates a cross-field ion beam which excites a modified beam-plasma instability (MBPI) with frequency in the range of the lower hybrid frequency. The excited waves accelerate electrons along the magnetic field up to the ion drift energy that exceeds the ionization energy of the neutral atoms. The heated electrons in turn enhance the ion beam by electron-neutral impact ionization, which establishes a positive feedback loop in maintaining the CIV process. It is also found that the efficiency of the CIV mechanism depends on the finite size of the gas cloud in the following ways: (1) Along the ambient magnetic field the finite size of the cloud, L (sub parallel), restricts the growth of the fastest growing mode, with a wavelength lambda (sub m parallel), of the MBPI. The parallel electron heating at wave saturation scales approximately as (L (sub parallel)/lambda (sub m parallel)) (exp 1/2); (2) Momentum coupling between the cloud and the ambient plasma via the Alfven waves occurs as a result of the finite size of the cloud in the direction perpendicular to both the ambient magnetic field and the neutral drift. This reduces exponentially with time the relative drift between the ambient plasma and the neutrals. The timescale is inversely proportional to the Alfven velocity. (3) The transvers e charge separation field across the cloud was found to result in the modulation of the beam velocity which reduces the parallel heating of electrons and increases the transverse acceleration of electrons. (4) Some energetic electrons are lost from the cloud along the magnetic field at a rate characterized by the acoustic velocity, instead of the electron thermal velocity. The loss of energetic electrons from the cloud seems to be larger in the direction of plasma drift relative to the neutrals, where the loss rate is characterized by the neutral drift velocity. It is also shown that a factor of 4 increase in the ambient plasma density, increases the CIV ionization yield by almost 2 orders of magnitude at the end of a typical run. It is concluded that a larger ambient plasma density can result in a larger CIV yield because of (1) larger seed ion production by non-CIV mechanisms, (2) smaller Alfven velocity and hence weak momentum coupling, and (3) smaller ratio of the ion beam density to the ambient ion density, and therefore a weaker modulation of the beam velocity. The simulation results are used to interpret various chemical release experiments in space.

Moghaddam-Taaheri, E.↗

NASA NTRS1975

Development of a solar-powered residential air conditioner: Screening analysis

Screening analysis aimed at the definition of an optimum configuration of a Rankine cycle solar-powered air conditioner designed for residential application were conducted. Initial studies revealed that system performance and cost were extremely sensitive to condensing temperature and to the type of condenser used in the system. Consequently, the screening analyses were concerned with the generation of parametric design data for different condenser approaches; i. e., (1) an ambient air condenser, (2) a humidified ambient air condenser (3) an evaporative condenser, and (4) a water condenser (with a cooling tower). All systems feature a high performance turbocompressor and a single refrigerant (R-11) for the power and refrigeration loops. Data were obtained by computerized methods developed to permit system characterization over a broad range of operating and design conditions. The criteria used for comparison of the candidate system approaches were (1) overall system COP (refrigeration effect/solar heat input), (2) auxiliary electric power for fans and pumps, and (3) system installed cost or cost to the user.

Source record↗

NASA NTRS2003

Low Frequency High Amplitude Temperature Oscillations in Loop Heat Pipe Operation

This paper presents a theory that explains low frequency, high amplitude temperature oscillations in loop heat pipe (LHP) operation. Oscillations of the CC temperature with amplitudes on the order of tens of degrees Kelvin and periods on the order of hours have been observed in some LHPs during ambient testing. There are presently no satisfactory explanations for such a phenomenon in the literature. It is well-known that the operating temperature of an LHP with a single evaporator is governed by the compensation chamber (CC) temperature, which in turn is a function of the evaporator heat load, sink temperature, and ambient temperature. As the operating condition changes, the CC temperature will change during the transient but eventually reach a new steady temperature. Under certain conditions, however, the LHP never really reaches a true steady state, but instead displays an oscillatory behavior. The proposed new theory describes why low frequency, high amplitude oscillations may occur when the LHP has a low evaporator power, a low heat sink temperature (below ambient temperature), and a large thermal mass attached to the evaporator. When this condition prevails, there are some complex interactions between the CC, condenser, thermal mass and ambient. The temperature oscillation is a result of the large movement of the vapor front inside the condenser, which is caused by a change in the net evaporator power modulated by the large thermal mass through its interaction with the sink and CC. The theory agrees very well with previously published test data. Effects of various parameters on the amplitude and frequency of the temperature oscillation are also discussed.

Ku, Jentung↗

DOE OSTI2022

Thermal storage system with coupled tanks

Methods and apparatus are disclosed for high-efficiency thermal storage with a fluid-filled “battery” tank positioned within a fluid-filled “reservoir” tank. Fluid loops couple the tanks to a heat pump and a building. The heat pump can charge the battery tank or deliver thermal energy (cold or heat) to a building, using the reservoir tank or ambient air as a thermal energy source. The battery tank can discharge energy to the building jointly with the heat pump or, at periods of peak electricity usage, with the heat pump switched off. Operating modes allow significant savings in electricity usage and mitigate the “duck curve.” Low duty cycle usage of the reservoir enables efficient underground thermal storage with less digging than conventional geothermal technologies. Additional efficiency is achieved with phase change materials installed inside a tank or in a tank wall, providing temperature regulation. Control methods are disclosed.

15 GEOTHERMAL ENERGY↗

NASA NTRS1988

Antimisting kerosene: Low temperature degradation and blending

The inline filtration characteristics of freshly blended and degraded antimisting fuels (AMK) at low temperature are examined. A needle valve degrader was modified to include partial recirculation of degraded fuel and heat addition in the bypass loop. A pressure drop across the needle valve of up to 4,000 psi was used. The pressure drop across a 325 mesh filter screen placed inline with the degrader and directly downstream of the needle valve was measured as a function of time for different values of pressure drop across the needle valve. A volume flux of 1 gpm/sq in was employed based on the frontal area of the screen. It was found that, at ambient temperatures, freshly blended AMK fuel could be degraded using a single pass degradation at 4,000 psi pressure drop across the needle valve to give acceptable filterability performance. At fuel temperatures below -20 C, degradation becomes increasingly difficult and a single pass technique results in unacceptable filtration performance. Recirculation of a fraction of the degraded fuel and heat addition in the bypass loop improved low temperature degradation performance. The problem is addressed of blending the AMK additive with Jet A at various base fuel temperatures.

Yavrouian, A.↗

NASA NTRS1991

A numerical simulation of magnetic reconnection and radiative cooling in line-tied current sheets

Radiative MHD equations are used for an optically thin plasma to carry out a numerical experiment related to the formation of 'postflare' loops. The numerical experiment starts with a current sheet that is in mechanical and thermal equilibrium but is unstable to both tearing-mode and thermal-condensation instabilities. The current sheet is line-tied at one end to a photospheric-like boundary and evolves asymmetrically. The effects of thermal conduction, resistivity variation, and gravity are ignored. In general, reconnection in the nonlinear stage of the tearing-mode instability can strongly affect the onset of condensations unless the radiative-cooling time scale is much smaller than the tearing-mode time scale. When the ambient plasma is less than 0.2, the reconnection enters a regime where the outflow from the reconnection region is supermagnetosonic with respect to the fast-mode wave speed. In the supermagnetosonic regime the most rapidly condensing regions occur downstream of a fast-mode shock that forms where the outflow impinges on closed loops attached to the photospheric-like boundary. A similar shock-induced condensation might occur during the formation of 'postflare' loops.

Forbes, T. G.↗

NASA NTRS1973

Preliminary analysis of NASA optical data obtained in barium ion cloud experiment of September 21, 1971.

This paper reviews the optical data obtained by NASA in the joint NASA-MPE experiment conducted on September 21, 1971, involving the release of a barium cloud at an altitude of about 31,500 km over Colombia, South America. The data indicated an anomalously high rate of elongation and an unexpectedly large rate of deceleration of the main core of the ion cloud. The outermost striational features achieved a steady velocity within a few minutes, thus indicating that they had acquired the velocity of the ambient plasma. From the observed drift of these striations, one deduces an electric field that, when referred to a coordinate system rotating with the earth, has a meridional component directed toward the interior of the magnetic loop of 0.14 mV/m and a component perpendicular to the meridional plane of 0.15 mV/m directed to the west.

Adamson, D.↗

NASA NTRS1990

Modeling solar flare conduction fronts. I - Homogeneous plasmas and ion-acoustic turbulence. II - Inhomogeneous plasmas and ambipolar electric fields

A one-dimensional, electrostatic, particle-in-cell simulation is used here to model the expansion of a heated electron population in a coronal loop during a solar flare and the characteristics of the associated X-ray emissions. The hot electrons expand outward from the localized region, creating an ambipolar electric field which accelerates a return current of cooler, ambient electrons. Ion-acoustic waves are generated by the return currents as proposed by Brown et al. (1979), but they play little or no role in containing energetic electrons and the conduction front proposed by Brown et al. does not form. The X-ray emission efficiency of the electrons is too low in the corona for them to be the source of hard X-ray bursts. The particle dynamics changes dramatically if the heated plasma is at low altitudes and expands upward into the more tenuous plasma at higher altitudes. Two important applications of this finding are the radio-frequency heating of the corona and the collisional heating of the chromosphere by precipitating energetic electrons. In both cases, the overlying plasma has a density that is too low to supply a balancing return current to the expanding hot electrons. As a result, an ambipolar electric field develops that tends to confine the energetic electrons behind a front that propagate outward at about the speed of sound.

Mckean, M. E.↗

DOE OSTI2025

Fatigue Performance of an Improved Creep Strength 10%Cr Steel

The deployment of 9-12% Cr steels for elevated temperature applications up to 650 °C presents a cost-effective alternative to more expensive nickel-based alloys in steam turbine power generation. To enhance creep resistance at this temperature range, a novel ferritic-martensitic steel, designated CPJ7, was developed and fabricated at the National Energy Technology Laboratory. The alloy design aimed to mitigate the transformation of strengthening carbides into deleterious phases that degrade creep performance. Results have demonstrated that CPJ7 exhibits favorable creep and oxidation resistance at 650 °C. However, its fatigue performance remains unexplored. This study builds upon prior research by evaluating the low cycle fatigue behavior of CPJ7 and verifying that modifications beneficial to creep performance were not detrimental to the fatigue performance. The alloy was tested at both 650 °C and ambient temperature under fully reversed bending conditions (R = − 1) and a load ratio of 0.05. Furthermore, the alloy exhibits cyclic softening, a behavior consistent with other 9-10 wt.% Cr steels. Analysis of the microstructure and hysteresis loops further corroborate cyclic softening mechanisms typical of ferritic-martensitic steels. Overall, the fatigue performance of CPJ7 meets or exceeds that of P91 steel, demonstrating its potential for high-temperature structural applications.

9% Cr ferritic-martensitic steel↗

NASA NTRS1988

Collisionless shock formation and the prompt acceleration of solar flare ions

The formation mechanisms of collisionless shocks in solar flare plasmas are investigated. The priamry flare energy release is assumed to arise in the coronal portion of a flare loop as many small regions or 'hot spots' where the plasma beta locally exceeds unity. One dimensional hybrid numerical simulations show that the expansion of these 'hot spots' in a direction either perpendicular or oblique to the ambient magnetic field gives rise to collisionless shocks in a few Omega(i), where Omega(i) is the local ion cyclotron frequency. For solar parameters, this is less than 1 second. The local shocks are then subsequently able to accelerate particles to 10 MeV in less than 1 second by a combined drift-diffusive process. The formation mechanism may also give rise to energetic ions of 100 keV in the shock vicinity. The presence of these energetic ions is due either to ion heating or ion beam instabilities and they may act as a seed population for further acceleration. The prompt acceleration of ions inferred from the Gamma Ray Spectrometer on the Solar Maximum Mission can thus be explained by this mechanism.

Cargill, P. J.↗

NASA NTRS1997

Optical Design of the Developmental Cryogenic Active Telescope Testbed (DCATT)

In the summer of 1996, three Study teams developed conceptual designs and mission architectures for the Next Generation Space Telescope (NGST). Each group highlighted areas of technology development that need to be further advanced to meet the goals of the NGST mission. The most important areas for future study included: deployable structures, lightweight optics, cryogenic optics and mechanisms, passive cooling, and on-orbit closed loop wavefront sensing and control. NASA and industry are currently planning to develop a series of ground testbeds and validation flights to demonstrate many of these technologies. The Deployed Cryogenic Active Telescope Testbed (DCATT) is a system level testbed to be developed at Goddard Space Flight Center in three phases over an extended period of time. This testbed will combine an actively controlled telescope with the hardware and software elements of a closed loop wavefront sensing and control system to achieve diffraction limited imaging at 2 microns. We will present an overview of the system level requirements, a discussion of the optical design, and results of performance analyses for the Phase 1 ambient concept for DCATT,

Davila, Pam↗