High-performance anthraquinone with potentially low cost for aqueous redox flow batteries
Alkaline anthraquinone flow battery with active species exhibiting long lifetime and potentially low mass-production cost.
Wu, Min↗
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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Q1 2023 U.S. Solar Photovoltaic System and Energy Storage Cost Benchmarks With Minimum Sustainable Price Analysis Data File
The U.S. Department of Energy's (DOE's) Solar Energy Technologies Office (SETO) aims to accelerate the advancement and deployment of solar technology in support of an equitable transition to a decarbonized economy no later than 2050, starting with a decarbonized power sector by 2035. Its approach to achieving this goal includes driving innovations in technology, hardware, and soft cost reductions to make solar affordable and accessible for all. As part of this effort, SETO must track solar cost trends so it can focus its research and development (R&D) on the highest-impact activities. The benchmarks in this report are bottom-up cost estimates of all major inputs to PV and energy storage system installations. Bottom-up costs are based on national averages and do not necessarily represent typical costs in all local markets. Like last year's report, this year's report includes two distinct sets of benchmarks: minimum sustainable price (MSP) benchmarks and modeled market price (MMP) benchmarks. MSP benchmarks can be interpreted as the minimum price a company needs to charge to remain financially solvent in the long term based on the minimum sustainable prices of all inputs including minimum sustainable profit margins. MMP benchmarks can be interpreted as the actual cash sales price a company charges in the given benchmark period. These simplified estimates are useful for tracking technological progress, but they do not reflect all experiences. In fact, no individual estimate under any approach can reflect the diversity of the PV and storage manufacturing and installation industries.
14 SOLAR ENERGY↗
Designing electrolytes with high solubility of sulfides/disulfides for high-energy-density and low-cost K-Na/S batteries
Alkaline metal sulfur (AMS) batteries offer a promising solution for grid-level energy storage due to their low cost and long cycle life. However, the formation of solid compounds such as M 2 S 2 and M 2 S (M = Na, K) during cycling limits their performance. Here we unveil intermediate-temperature K-Na/S batteries utilizing advanced electrolytes that dissolve all polysulfides and sulfides (K 2 S x , x = 1–8), significantly enhancing reaction kinetics, specific capacity, and energy density. These batteries achieve near-theoretical capacity (1655 mAh g -1 sulfur) at 75 °C with a 1 M sulfur concentration. At a 4 M sulfur concentration, they deliver 830 mAh g -1 at 2 mA cm -2 , retaining 71% capacity after 1000 cycles. This new K-Na/S battery with specific energy of 150-250 Wh kg -1 only employs earth-abundant elements, making it attractive for long-duration energy storage.
36 MATERIALS SCIENCE↗
Analysis of degradation in residential battery energy storage systems for rate-based use-cases
This article examines the impact of residential battery energy storage (BES) systems' operational modes on the life (i.e. usable energy capacity) of the battery under several climatic conditions and battery chemistries. The sharp increase in residential BES installations has been a result of decreasing costs of batteries, increase in rate structures motivated applications such as solar self-consumption and time-of-use energy management, and customers purchasing these systems for backup power. While these different modes of operations provide a combination of increased bill savings, reliability of supply, and energy sustainability to the customer, their operational characteristics vary significantly between use-cases. Functional life of BES systems is known to be strongly dependent on their operating conditions. In this article, we analyze the operation of residential BES systems under different rate-based use-cases, for different battery chemistries and cell designs, and under different environmental conditions. This is conducted by simulating the control of BES operations using rate-based cycling algorithms and analyzing the prognosis of multiple battery lifetime models that consider complex nonlinear dependencies of operational stress factors such as state-of-charge, depth-of-discharge, and temperature on degradation. Significant variations in battery life are observed owing to the differences in characteristics of the uses-cases coupled with environmental conditions and battery chemistries. Such differences lead to the conclusion that choice of residential BES technologies and chemistries should account for their intended use-cases.
25 ENERGY STORAGE↗
Intercalated water in aqueous batteries
The unprecedentedly growing demand for energy storage devices in recent years calls for diversified chemistries with unique advantages. When it comes to safety and cost, aqueous battery systems have attracted tremendous attention. Being a universal solvent, water can solvate the cations with rather high dehydration energy due to the hydrogen bonding environment, relatively small size and high polarity. Such properties make solvent co-intercalation, which is seen in a few of the non-aqueous systems, more likely to happen in aqueous batteries. Hydrated cations show drastically different behaviors from naked cations during intercalation/de-intercalation processes and hence enable many reactions that are otherwise difficult to proceed. This review summarizes the roles of co-intercalated water in aqueous batteries from how water molecules coordinate with cations to examples of water-mediated reactions in different types of host materials.
25 ENERGY STORAGE↗
Well-to-Wheels Analysis of Zero-Emission Plug-In Battery Electric Vehicle Technology for Medium- and Heavy-Duty Trucks
Conventional diesel medium- and heavy-duty vehicles (MHDVs) create large amount of air emissions. With the advancement in technology and reduction in the cost of batteries, plug-in battery electric vehicles (BEVs) are increasingly attractive options for improving energy efficiency and reducing air emissions of MHDVs. In this paper, we compared the well-to-wheels (WTW) greenhouse gases (GHGs) and criteria air pollutant emissions of MHD BEVs with their conventional diesel counterparts across weight classes and vocations. We expanded the Greenhouse gases, Regulated Emissions, and Energy use in Technologies (GREET) model to conduct the WTW analysis of MHDVs. The fuel economy for a wide range of MHDV weight classes and vocations, over various driving cycles, was evaluated using a high-fidelity vehicle dynamic simulation software (Autonomie). The environmental impacts of MHD BEVs are sensitive to the source of electricity used to recharge their batteries. The WTW results show that MHD BEVs significantly improve environmental sustainability of MHDVs by providing deep reductions in WTW GHGs, nitrogen oxides, volatile organic compounds, and carbon monoxide emissions, compared to conventional diesel counterparts. Increasing shares of renewable and natural gas technologies in future national and regional electricity generation are expected to reduce WTW particulate matters and sulfur oxide emissions for further improvement of the environmental performance of MHD BEVs.
33 ADVANCED PROPULSION SYSTEMS↗
Low-Cost All-Temperature Zinc-Pulp Battery for Stationary Storage
WH-Power Final Technical Report — Low-Cost All-Temperature Zinc-Pulp Battery This is the final scientific/technical report for ARPA-E CREATE program award DE-AR0001796, covering work from September 2023 through September 2025. The WHP–UMD–Yale team set out to develop a safe, low-cost, wide-temperature zinc battery for grid-scale stationary storage. What was built: A zinc-pulp (Zn/CNF) battery system pairing an aqueous high-entropy electrolyte (HEE) with a cellulose-derived ion-conducting membrane.
25 ENERGY STORAGE↗
Storage Futures Study: Storage Technology Modeling Input Data Report
The Storage Futures Study (SFS) is a multiyear research project to explore the role and impact of energy storage in the evolving electricity sector of the United States. The SFS is designed to examine the potential impact of energy storage technology advancement on the deployment of utility-scale storage and the adoption of distributed storage, and the implications for future power system infrastructure investment and operations. This specific report synthesizes current and projected cost performance assumptions along with location availability for storage technologies through 2050 that will be used in scenario analysis for the SFS at both the bulk power and distribution system scales. For comparison and context, this report also presents a synthesis of current cost and performance characteristics of energy storage technologies for storage durations ranging from minutes to months and including mechanical, thermal, and electrochemical storage technologies for the electricity sector. This information is intended to cover a broad range of storage technologies that are currently receiving significant attention from the investment community as well as in the media. In the report, we emphasize that energy storage technologies must be described in terms of both their power (kilowatts [kW]) capacity and energy (kilowatt-hours [kWh]) capacity to assess their costs and potential use cases.
24 POWER TRANSMISSION AND DISTRIBUTION↗
Screening Li-Ion Batteries for Internal Shorts
The extremely high cost of aerospace battery failures due to internal shorts makes it essential that their occurrence be very rare, if not eliminated altogether. With Li-ion cells/batteries, the potentially catastrophic safety hazard that some internal shorts present adds additional incentive for prevention. Prevention can be achieved by design, manufacturing measures, and testing. Specifically for NASA s spacesuit application, a Li-ion polymer pouch cell battery design is in its final stages of production. One of the 20 flight batteries fabricated and tested developed a cell internal short, which did not present a safety hazard, but has required revisiting the entire manufacturing and testing process. Herein are the details of the failure investigation that followed to get to root cause of the internal short and the corrective actions that will be taken. The resulting lessons learned are applicable to most Li-ion battery applications.
Darcy, Eric↗
Ghostbusters for Batteries
End-of-life lithium-ion batteries are Class 9 hazardous materials due to flammability of electrolyte and lithium. It is why the transportation cost ranges from $2.49/kg - $7.20/kg for civilian and defense disposition, that is over 50% of the cost of recycling. Damaged batteries have many times greater transportation cost. Dead batteries require costly bunker-storage that occupies real estate and personnel that could be used for productive purposes. Insurance is expensive and accidents are almost assured even with relatively low volumes of waste. Tipping fees on top of this adds an unpredictable, inflated cost for the EV industry, which is very cost sensitive for survival. Transforming lithium-ion into a class of non-hazardous material reduces transportation cost to $0.10/kg, providing a value opportunity of ~$2/kg to ~$6/kg for civilian and defense disposition respectively. OnTo can eliminate the risk of thermal runaway with a brief, non-toxic treatment to eliminate flammability and toxic risks in most any battery, except Pb, which is inherently toxic. With the service, OnTo also can provide rigorous certainty that cells are rendered inert. OnTo’s patented and patent pending deactivation technology improves the cost and safety for disposition of end-of-life lithium-ion battery packs and cells. Deactivation uses non-toxic chemical processing to remove inherent risks in lithium-ion and other primary and secondary chemistries. The technology has been demonstrated and developed through DOE contract with OnTo Technology LLC (EE0008475).
25 ENERGY STORAGE↗
Improved, low cost inorganic-organic separators for rechargeable silver-zinc batteries
Several flexible, low-cost inorganic-organic separators with performance characteristics and cycle life equal to, or better than, the Lewis Research Center Astropower separator were developed. These new separators can be made on continuous-production equipment at about one-fourth the cost of the Astropower separator produced the same way. In test cells, these new separators demonstrate cycle life improvement, acceptable operating characteristics, and uniform current density. The various separator formulas, test cell construction, and data analysis are described.
Sheibley, D. W.↗
Design analysis of a particle-based thermal energy storage system for concentrating solar power or grid energy storage
Energy storage is becoming indispensable for expanding renewable energy integration, and it is critical to the future low-carbon energy supply. Large-capacity, grid scale energy storage can support the integration of solar and wind power and support grid resilience with the diminishing capacity of baseload fossil power plants. With the development of thermal energy storage (TES) for concentrating solar power systems, standalone TES for grid integration becomes attractive due to the declining renewable generation cost and an increasing need for energy storage. The standalone TES system introduced in this paper can play a big role in the carbon-free energy future with capacity larger than batteries and cost likely lower than other energy storage methods such as pumped storage hydropower and compressed air energy storage, both of which also have geological limitations. To this end, we describe a TES system that uses stable, inexpensive solid particles as a TES media to provide scalable, low cost energy storage. The particle-based TES has the ability to drive various thermal power cycles including conventional steam-Rankine, air Brayton turbine with combined-cycle ability, or the emerging supercritical carbon dioxide Brayton power cycle. This work describes the containment design method including a concrete silo and an internal-insulation layer for the particle-TES system. The economic analysis shows significantly low storage cost when the particle-TES is integrated with Brayton combined-cycle power generation. The paper shows the design approach of the particle-TES system and its economic potential for bulk energy storage. The advantage of the particle-TES system as a promising bulk energy storage method is its ability to economically support dispatchable renewable grid penetration for larger capacity and longer discharging hours than current battery storage technologies.
25 ENERGY STORAGE↗
Advancing Mn-Based Li-Ion Battery Cathodes via a Partially Cation-Disordered Zigzag-Type Li–Nb–Mn–O Framework
Mn-based Li-ion battery cathodes encompass a great variety of materials structures. Decades of research effort have proven that developing a Mn-based structure featuring a high redox activity, stable cycling, and cost-effectiveness is a longstanding challenge. Motivated by such a need and inspired by the structural diversity of Mn-based cathodes, we develop a partially cation-disordered lithium niobium manganese oxide with a zigzag structure, filling the knowledge gap between zigzag-ordered and fully disordered Li-Mn-based oxides. Electrochemically, the partially disordered cathode greatly unlocks the redox activity of the zigzag lattice and maintains the cycling stability. Mechanism-wise, the partial disordering suppresses the disproportionation reaction of Mn(III) and facilitates a disordered λ-MnO 2 -tetragonal cation-disordered rock salt structural transformation. Furthermore, the work suggests the substantial opportunity of using partial disordering as the key strategy to revive locked-up redox activities and realize new energy storage mechanisms, for the pursuit of high-performance cost-effective battery materials.
25 ENERGY STORAGE↗
Where and When Does Solar Plus Storage Make Sense for Commercial Buildings?
As the capital cost of battery energy storage systems (BESS) declines, opportunities for commercial buildings to achieve net savings through peak demand management and energy arbitrage are emerging. National Renewable Energy Laboratory researchers modeled energy storage project economics - with and without accompanying solar photovoltaic systems - using local utility rates, ASHRAE climate zones, and solar intensity data to identify regions where these systems deliver life cycle savings now and in future cost scenarios.
battery energy storage systems↗
Achieving an 80% carbon-free electricity system in China by 2035
Dramatic reductions in solar, wind, and battery storage costs create new opportunities to reduce emissions and costs in China’s electricity sector, beyond current policy goals. This study examines the cost, reliability, emissions, public health, and employment implications of increasing the share of non-fossil fuel (“carbon free”) electricity generation in China to 80% by 2035. The analysis uses state-of-the-art modeling with high resolution load, wind, and solar inputs. The study finds that achieving an 80% carbon free electricity system in China by 2035 could reduce wholesale electricity costs, relative to a current policy baseline, while maintaining high levels of reliability, reducing deaths from air pollution, and increasing employment. In our 80% scenario, wind and solar generation capacity reach 3 TW and battery storage capacity reaches 0.4 TW by 2035, implying a rapid scale up in these resources that will require changes in policy targets, markets and regulation, and land use policies.
29 ENERGY PLANNING, POLICY, AND ECONOMY↗
Development of a high fidelity CFD model for solvent evaporation and transport in porous structure during battery electrode drying
An efficient battery manufacturing process is the key to the mass production of Electric Vehicles (EV), in which drying is one of the most energy-intensive steps significantly influencing the battery cell performance. An accurate 3D CFD model for drying is essential for predicting the drying mechanism and optimizing its parameters. By optimizing the drying process, it is possible to reduce energy consumption and cost during battery manufacturing, minimize binder loading and maximize active material loading to achieve superior electrochemical performances and facilitate wider and faster public adoption of EV. This project aims to optimize the drying process during electrode manufacturing by leveraging high-fidelity, porous electrode simulations for solvent evaporation. By optimizing this process, we seek to reduce energy consumption during battery manufacturing, while minimizing binder loading and maximizing active material loading, with the overall goal of enhancing electrical vehicle performance.
Horner, Jeffrey Scott [Sandia National Laboratorie↗
Do Mandates Deliver Cost Reductions for Energy Storage?
In 2013, California implemented a mandate directing the state’s investor-owned utilities to procure 1325 MW of energy storage, to help integrate nondispatchable renewable sources of energy and assist the state in meeting its environmental goals. This paper evaluates this policy’s impact of both battery deployment, and cost, finding that as of 2019, the state was effective in spurring nearly 500 MWh of battery storage deployment over what would have been installed in absence of the policy. This additive deployment would have the effect of reducing global battery cell costs by roughly $1.00/ kWh, based on learning by doing. To support these findings, we utilize both a difference in differences estimation, and a synthetic control analysis, both of which allow us to compare battery deployment in California, to deployment in other states. To pair deployment to cost reduction, we use a learning curve analysis, which links battery shipments to cell and storage block costs. For policymakers, these results provide evidence to the effectiveness of mandates in promoting storage deployment and help explain how these policies can induce downstream effects.
Boff, Daniel S.↗
A systematic solution to quantify economic values of vehicle grid integration
We report Vehicle-Grid-Integration (VGI) supplies one of the potential benefit extensions for electric vehicles (EVs) to make use of their parking time, which enables the EVs to provide grid services while still meeting consumer driving needs. However, the costs, benefits and risks of VGI still remain unclear, which limits the development of the VGI to promote the interaction between the EV and grid. In this study, we propose an integrated framework to quantify and utilize the aggregate flexibility of the EVs to supply the grid services in electricity markets. The integrated solution includes five sub-modules that cover end-to-end functionalities from individual EV energy consumption estimation to final monetary values calculation of providing grid services. Both wholesale market and local level charging management are formulated in the optimization module. A predictive control algorithm is proposed to allocate power to individual vehicles in real time, considering uncertainties from dispatch signal and travel behavior. Simulation results from 10,000 EVs indicate that the proposed optimization methods can significantly reduce the system cost in both wholesale market and retail market. Local tariff optimization reduces the electricity cost by 24.4% compared to uncontrolled charging. Wholesale market optimization results show that $\$$691 and $\$$255 revenues can be captured by each EV in ERCOT and CAISO markets per year, although with a conservative assumption on battery throughput cost at 0.16$\$$/kWh.
29 ENERGY PLANNING, POLICY, AND ECONOMY↗