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Results for “correlated electron systems”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
NASA NTRS1994

Hubble Space Telescope Goddard high-resolution spectrograph H2 rotational spectra of Jupiter's aurora

We have observed the emission spectrum from Jupiter's north auroral atmosphere with 0.57 A spectral resolution over 1204-1241 A. Bright emissions have been detected from 50 deg to 60 deg latitude at locations consistent with 6 to 30 R (sub J) auroral ovals, with much fainter emissions away form the auroral ovals. The emission spectrum is well fitted by both laboratory spectra and theoretical models of optically thin electron excited H2, with added Doppler-broadened Lyman Alpha emission. The observed Lyman Alpha emission wings extend more than 1 A from line center and appear correlated in strength with the H2 brightness. Individual rotational lines in the H2 Werner band system are resolved, allowing a determination of the H2 rotational temperature at the altitude of the emission. We derive best-fit temperatures from 400-450 to 700-750 K, with the auroral emission layer temperature changing either across the auroral oval or over several days' time. These observations demonstrate for the first time the ability to measure the observed rapid H2 temperature variations across Jupiter's auroral atmosphere.

Clarke, John T.↗
NASA NTRS1975

A variable conductance heat pipe flight experiment - Performance in space

The Ames Heat Pipe Experiment (AHPE) is a variable conductance heat pipe/radiator system which was launched aboard the OAO-C spacecraft in August, 1972. All available flight data was reviewed and those from a few orbits were selected for correlation with predictions from an analytical model of the system. The principal conclusion of this study is that gas controlled variable conductance heat pipes can perform reliably for long time periods in the space environment and can effectively provide temperature stabilization for spacecraft electronics. Furthermore, the performance of such systems can be adequately predicted using existing analysis tools.

Wanous, D. J.↗
NASA NTRS1977

The composition of carbonaceous chondrite matrix

Matrix compositions of 32 of the approximately 40 known carbonaceous chondrites were analyzed using an electron probe defocussed-beam technique. Except in those chondrites that show evidence of metamorphism, matrices are compositionally similar and have correlation coefficients of +0.96 or greater. The implications of these analyses for the chemistry of individual matrix phases and for primitive solar system material are discussed.

Mcsween, H. Y., Jr.↗
NASA NTRS1987

Positive ions of the first- and second-row transition metal hydrides

Theoretical dissociation energies for the first- and second-row transition metal hydride positive ions are critically compared against recent experimental values obtained from ion beam reactive scattering methods. Theoretical spectroscopic parameters and dipole moments are presented for the ground and several low-lying excited states. The calculations employ large Gaussian basis sets and account for electron correlation using the single-reference single- and double-excitation configuration interaction and coupled-pair-functional methods. The Darwin and mass-velocity contributions to the relativistic energy are included in the all-electron calculations on the first-row systems using first-order perturbation theory, and in the second-row systems using the Hay and Wadt relativistic effective core potentials. The theoretical D(0) values for the second-row transition metal hydride positive ions should provide a critical measure of the experimental values, which are not as refined as many of those in the first transition row.

Pettersson, Lars G. M.↗
NASA NTRS1993

Monitoring damage growth in titanium matrix composites using acoustic emission

The application of the acoustic emission (AE) technique to locate and monitor damage growth in titanium matrix composites (TMC) was investigated. Damage growth was studied using several optical techniques including a long focal length, high magnification microscope system with image acquisition capabilities. Fracture surface examinations were conducted using a scanning electron microscope (SEM). The AE technique was used to locate damage based on the arrival times of AE events between two sensors. Using model specimens exhibiting a dominant failure mechanism, correlations were established between the observed damage growth mechanisms and the AE results in terms of the events amplitude. These correlations were used to monitor the damage growth process in laminates exhibiting multiple modes of damage. Results revealed that the AE technique is a viable and effective tool to monitor damage growth in TMC.

Bakuckas, J. G., Jr.↗
NASA NTRS1995

Methods of video and shearography inspection

The goal of this research effort was to study methods of video image correlation and electronic shearography for nondestructive evaluation of aerospace components. Methods of physical load application must be developed before interrogations with these methods may be used to qualify hardware. To that end, inspection procedures were developed for a variety of aerospace components and material systems. Experiments were also conducted from which the relationship between the control settings of the electronic shearography apparatus may be related to flaw detectability. A short feasibility study was conducted to determine the applicability of electronic shearography to the determination of the stress intensity factor of a Mode 1 crack tip by measurement of the localized zone of three dimensional plasticity

Lansing, Matthew D.↗
NASA NTRS1978

Limb Infrared Monitor of the Stratosphere /LIMS/ experiment

The Limb Infrared Monitor of the Stratosphere (LIMS) radiometer is a satellite-borne six-channel multispectral scanning radiometer using a two-stage methane and ammonia solid-cryogen cooler to cool the (Hg, Cd)Te focal plane to 65 K. The LIMS experiment employs thermal IR limb sounding to provide vertical-profile measurement of temperature and of concentrations of O3, NO3, and H2O in the stratosphere on a global scale. The goals of the experiment and the expected accuracies of the measurements are outlined, and the radiance measured by the radiometer is analyzed. A program of correlative measurements designed for verification and augmentation of the LIMS data is discussed. Detailed descriptions are given of the LIMS components and optics, the detector capsule assembly, the solid-cryogen cooler, the four operational modes of the LIMS system, and the data-processor electronics. It is noted that prelaunch acceptance testing thus far completed indicates that the LIMS specification design requirements have been met, and the experiment's performance goals can be achieved.

Drozewski, R. W.↗
NASA NTRS1979

Voyager 1 Planetary Radio Astronomy Observations Near Jupiter

Results are reported from the first low frequency radio receiver to be transported into the Jupiter magnetosphere. Dramatic new information was obtained both because Voyager was near or in Jupiter's radio emission sources and also because it was outside the relatively dense solar wind plasma of the inner solar system. Extensive radio arcs, from above 30 MHz to about 1 MHz, occurred in patterns correlated with planetary longitude. A newly discovered kilometric wavelength radio source may relate to the plasma torus near Io's orbit. In situ wave resonances near closest approach define an electron density profile along the Voyager trajectory and form the basis for a map of the torus. Studies in progress are outlined briefly.

Warwick, J. W.↗
NASA NTRS1979

Voyager 1 planetary radio astronomy observations near Jupiter

Results from the first low-frequency radio receiver to be transported into the Jupiter magnetosphere are reported. Dramatic new information was obtained, both because Voyager was near or in Jupiter's radio emission sources and because it was outside the relatively dense solar wind plasma of the inner solar system. Extensive radio spectral arcs, from above 30 to about 1 MHz, occurred in patterns correlated with planetary longitude. A newly discovered kilometric wavelength radio source may relate to the plasma torus near Io's orbit. In situ wave resonances near closest approach define an electron density profile along the Voyager trajectory and form the basis for a map of the torus. Detailed studies are in progress and are outlined briefly.

Warwick, J. W.↗
NASA NTRS1988

Ocean topography experiment (TOPEX) radar altimeter

A spaceflight qualified Radar Altimeter capable of achieving the TOPEX Mission measurement precision requirement of 2-centimeters, is provided and its performance (Engineering Assessment) will be evaluated after launch and continuously during its 3-year mission operational period. Information will be provided to JPL about the calibration of the TOPEX Radar Altimeter. The specifications for the required data processing algorithms which will be necessary to convert the Radar Altimeter mission telemetry data into the geophysical data will also be provided. The stringent 2 cm precision requirement for ocean topography determination from space necessitated examining existing Radar Altimeter designs for their applicability towards TOPEX. As a result, a system configuration evolved using some flight proven designs in conjunction with needed improvements which include: (1) a second frequency or channel to remove the range delay or apparent height bias caused by the electron content of the ionosphere; (2) higher transmit pulse repetition frequencies for correlation benefits at higher sea states to maintain precision; and (3) a faster microprocessor to accommodate two channels of altimetry data. Additionally, examination of past altimeter programs associated data processing algorithms was accomplished to establish the TOPEX-class Radar Altimeter data processing algorithms, and the necessary direction was outlined to begin to generate these for the TOPEX Mission.

Rossi, L. C.↗
NASA NTRS1984

Plasma variables and tribological properties of coatings in low pressure (0.1 - 10.0 torr) plasma systems

A detailed treatment is presented of the dialog known as plasma surface interactions (PSI) with respect to the coating process and its tribological behavior. Adsorption, morphological changes, defect formation, sputtering, chemical etching, and secondary electron emission are all discussed as promoting and enhancing the surface chemistry, thus influencing the tribological properties of the deposited flux. Phenomenological correlations of rate of deposition, flux composition, microhardness, and wear with the plasma layer variables give an insight to the formation of chemical bonding between the deposited flux and the substrate surface.

Avni, R.↗
NASA NTRS1987

Correlating east-west asymmetries in the Jovian magnetosphere and the Io sodium cloud

Three east-west intensity asymmetries in the Jupiter system that would appear to an earth observer in optical S+, extreme ultraviolet S++ and optical Na emissions are reviewed. The three asymmetries imply that some combination of the plasma torus number densities and electron temperature is, on the long-term average, larger west of Jupiter than east of Jupiter. A small east-to-west electric field, previously proposed to explain the ion intensity asymmetries, is also shown to provide a natural explanation for the sodium intensity asymmetry. A long-term average east-to-west electric field of about 3 mV/m and a corresponding west-to-east offset of about 0.16 Jupiter radii for the plasma torus at Io's orbital distance are implied. On a shorter time scale, the east-west electric field appears to be time variable and may be readily monitored from earth by observations of the sodium cloud.

Smyth, William H.↗
NASA NTRS1992

Implementation of a noise reduction circuit for spaceflight IR spectrometers

The paper discusses the implementation and analysis of a correlated triple sampling circuit using analog subtractor/integrators. The software and test setup for noise measurements are also described. The correlation circuitry is part of the signal chain for a 256-element InSb line array used in the Visible and Infrared Mapping Spectrometer. Using a focal-plane array (FPA) simulator, system noise measurements of 0.7 DN are obtained. A test setup for FPA/SPE (signal processing electronics) characterization along with noise measurements is demonstrated.

Ramirez, L.↗
NASA NTRS2006

Evolution and Control of 2219 Aluminum Microstructural Features Through Electron Beam Freeform Fabrication

The layer-additive nature of the electron beam freeform fabrication (EBF3) process results in a tortuous thermal path producing complex microstructures including: small homogeneous equiaxed grains; dendritic growth contained within larger grains; and/or pervasive dendritic formation in the interpass regions of the deposits. Several process control variables contribute to the formation of these different microstructures, including translation speed, wire feed rate, beam current and accelerating voltage. In electron beam processing, higher accelerating voltages embed the energy deeper below the surface of the substrate. Two EBF3 systems have been established at NASA Langley, one with a low-voltage (10-30kV) and the other a high-voltage (30-60 kV) electron beam gun. Aluminum alloy 2219 was processed over a range of different variables to explore the design space and correlate the resultant microstructures with the processing parameters. This report is specifically exploring the impact of accelerating voltage. Of particular interest is correlating energy to the resultant material characteristics to determine the potential of achieving microstructural control through precise management of the heat flux and cooling rates during deposition.

Taminger, Karen M.↗
NASA NTRS2006

Evolution and Control of 2219 Aluminum Microstructural Features through Electron Beam Freeform Fabrication

Electron beam freeform fabrication (EBF3) is a new layer-additive process that has been developed for near-net shape fabrication of complex structures. EBF3 uses an electron beam to create a molten pool on the surface of a substrate. Wire is fed into the molten pool and the part translated with respect to the beam to build up a 3-dimensional structure one layer at a time. Unlike many other freeform fabrication processes, the energy coupling of the electron beam is extremely well suited to processing of aluminum alloys. The layer-additive nature of the EBF3 process results in a tortuous thermal path producing complex microstructures including: small homogeneous equiaxed grains; dendritic growth contained within larger grains; and/or pervasive dendritic formation in the interpass regions of the deposits. Several process control variables contribute to the formation of these different microstructures, including translation speed, wire feed rate, beam current and accelerating voltage. In electron beam processing, higher accelerating voltages embed the energy deeper below the surface of the substrate. Two EBF3 systems have been established at NASA Langley, one with a low-voltage (10-30kV) and the other a high-voltage (30-60 kV) electron beam gun. Aluminum alloy 2219 was processed over a range of different variables to explore the design space and correlate the resultant microstructures with the processing parameters. This report is specifically exploring the impact of accelerating voltage. Of particular interest is correlating energy to the resultant material characteristics to determine the potential of achieving microstructural control through precise management of the heat flux and cooling rates during deposition.

Taminger, Karen M.↗
NASA NTRS2012

Multi-Parameter Observation and Detection of Pre-Earthquake Signals in Seismically Active Areas

The recent large earthquakes (M9.0 Tohoku, 03/2011; M7.0 Haiti, 01/2010; M6.7 L Aquila, 04/2008; and M7.9 Wenchuan 05/2008) have renewed interest in pre-anomalous seismic signals associated with them. Recent workshops (DEMETER 2006, 2011 and VESTO 2009 ) have shown that there were precursory atmospheric /ionospheric signals observed in space prior to these events. Our initial results indicate that no single pre-earthquake observation (seismic, magnetic field, electric field, thermal infrared [TIR], or GPS/TEC) can provide a consistent and successful global scale early warning. This is most likely due to complexity and chaotic nature of earthquakes and the limitation in existing ground (temporal/spatial) and global satellite observations. In this study we analyze preseismic temporal and spatial variations (gas/radon counting rate, atmospheric temperature and humidity change, long-wave radiation transitions and ionospheric electron density/plasma variations) which we propose occur before the onset of major earthquakes:. We propose an Integrated Space -- Terrestrial Framework (ISTF), as a different approach for revealing pre-earthquake phenomena in seismically active areas. ISTF is a sensor web of a coordinated observation infrastructure employing multiple sensors that are distributed on one or more platforms; data from satellite sensors (Terra, Aqua, POES, DEMETER and others) and ground observations, e.g., Global Positioning System, Total Electron Content (GPS/TEC). As a theoretical guide we use the Lithosphere-Atmosphere-Ionosphere Coupling (LAIC) model to explain the generation of multiple earthquake precursors. Using our methodology, we evaluated retrospectively the signals preceding the most devastated earthquakes during 2005-2011. We observed a correlation between both atmospheric and ionospheric anomalies preceding most of these earthquakes. The second phase of our validation include systematic retrospective analysis for more than 100 major earthquakes (M>5.9) in Taiwan and Japan. We have found anomalous behavior before all of these events with no false negatives. Calculated false alarm ratio for the for the same month over the entire period of analysis (2003-2009) is less than 10% and was d as the earthquakes. The commonalities in detecting atmospheric/ionospheric anomalies show that they may exist over both land and sea in regions of maximum stress (i.e., along plate boundaries) Our results indicate that the ISTF model could provide a capability to observe pre-earthquake atmospheric/ionospheric signals by combining this information into a common framework.

Ouzounov, D.↗
NASA NTRS1974

Analog computation of auto and cross-correlation functions

For analysis of the data obtained from the cross beam systems it was deemed desirable to compute the auto- and cross-correlation functions by both digital and analog methods to provide a cross-check of the analysis methods and an indication as to which of the two methods would be most suitable for routine use in the analysis of such data. It is the purpose of this appendix to provide a concise description of the equipment and procedures used for the electronic analog analysis of the cross beam data. A block diagram showing the signal processing and computation set-up used for most of the analog data analysis is provided. The data obtained at the field test sites were recorded on magnetic tape using wide-band FM recording techniques. The data as recorded were band-pass filtered by electronic signal processing in the data acquisition systems.

Source record↗
NASA NTRS2003

Substitution Effects and Linear Free Energy Relationships During Reduction of 4- Benzoyl-n-(4-substituted Benzyl)pyridinium Cations

In analogy to 4-(para-substituted benzoyl)-N-methylpyridinium cations (1-X's), the title species (2-X's, -X = -OCH3, -CH3, -H, -Br, -COCH3, -NO2) undergo two reversible, well-separated (E(sub 1/2) greater than or equal to 650 mV) one-electron reductions. The effect of substitution on the reduction potentials of 2-X's is much weaker than the effect of the same substituents on 1-X's: the Hammett rho-values are 0.80 and 0.93 for the 1st- and 2nd-e reduction of 2-X's vs. 2.3 and 3.3 for the same reductions of 1-X's, respectively. Importantly, the nitro group of 2-NO2 undergoes reduction before the 2nd-e reduction of the 4-benzoylpyridinium system. These results suggest that the redox potentials of the 4-benzoylpyridinium system can be course-tuned via p-benzoyl substitution and fine-tuned via para-benzyl substitution. Introducing the recently derived substituent constant of the -NO2(sup)- group (sigma para-NO2(sup)- = -0.97) yields an excellent correlation for the 3rd-e reduction of 2- NO2 (corresponding to the reduction of the carbonyl group) with the 2nd-e reduction of the other 2-X's, and confirms the electron donating properties of -NO2(sup)-.

Leventis, Nicholas↗