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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7

An efficient SAC-OCDMA system using three different codes with two different detection techniques for maximum allowable users

In this paper, three codes spectral amplitude coding optical code division multiple access (SAC-OCDMA) are proposed and compared in terms of system performance including bit error rate (BER), number of active users, high achievable data rate, high signal to noise ratio (SNR) and the minimum received power that the OCDMA system supports to achieve a minimum BER value. The proposed codes are diagonal double weight (DDW) codes, modified double weight (MDW) codes and enhanced double weight (EDW). Different detection as AND subtraction detection technique and single photodiode detection (SPD) are investigated to reduce the effect of both the multiple access interference and phase induced intensity noise. The obtained results show that SAC-OCDMA using EDW code with SPD detection can achieve large number users with better BER (~ 10{sup −9}), SNR (> 20 dB), and minimum received power (~ − 20 dBm) relative to the other codes with other detection techniques.

42 ENGINEERING↗

Effects of microwave and ultrasound exposure to microsphere particles made out of different classes of inorganic and organic materials

In this study polymer, metal oxide and polymer-PZT composite microsphere materials were prepared by either hydrothermal or microwave assisted methods. Materials were subjected to microwave and ultrasound irradiation under specific conditions in order to understand their mechanical stability and morphological changes in dimensions. Scanning electron microscopy imaging was carried out before and after each irradiation and clear differences were observed depending on irradiation method and sample composition.

36 MATERIALS SCIENCE↗

Enabling AC electroluminescence in quasi-2D perovskites by uniformly arranging different-n-value nanoplates to allow bidirectional charge transport

Perovskite light-emitting diodes (LEDs) are normally operated under forward direct current (DC) to realize electron/hole injection at cathode/anode surfaces. In this work, we demonstrate an alternating current (AC) driven LED enabled by bi-directionally allowed charge transport in quasi-2D perovskite (PEA 2 MA n-1 PbnI 3n+1 ) film. Essentially, the bi-directional charge transport is realized by uniformly arranging different-n-value 2D nanoplates together with symmetrically designed anode/cathode interfaces, which can allow injected electrons and holes to form light-emitting states under both forward and reverse biases, leading to an AC electroluminescence (EL) with the device architecture of ITO/PEI/PEDOT:PSS/PEA 2 MA n-1 PbnI 3n+1 /P3HT/PEI/Ag. The high AC EL performance was achieved with the radiance = 24 W Sr -1 m -2 and 18.3 W Sr -1 m -2 and EQE = 12.5% and 3.7% under forward and reverse biases. Furthermore, the device-operational stability was largely improved with the half-intensity time of T 50 = 11.0 h under AC bias (+2 V/-2 V, 50 Hz) as compared to T 50 = 3.9 h under forward bias (+2 V/0 V, 50 Hz).

36 MATERIALS SCIENCE↗

Comparison of the Forward and Reverse Photocycle Dynamics of Two Highly Similar Canonical Red/Green Cyanobacteriochromes Reveals Unexpected Differences

Cyanobacteriochromes (CBCRs) are cyanobacterial photoreceptors that exhibit photochromism between two states: a thermally stable dark-adapted state and a metastable light-adapted state with bound linear tetrapyrrole (bilin) chromophores possessing 15Z and 15E configurations, respectively. The photodynamics of canonical red/green CBCRs have been extensively studied; however, the time scales of their excited-state lifetimes and subsequent ground-state evolution rates widely differ and, at present, remain difficult to predict. Here, we compare the photodynamics of two closely related red/green CBCRs that have substantial sequence identity (~68%) and similar chromophore environments: AnPixJg2 from Anabaena sp. PCC 7120 and NpR6012g4 from Nostoc punctiforme. Using broadband transient absorption spectroscopy on the primary (125 fs to 7 ns) and secondary (7 ns to 10 ms) time scales together with global analysis modeling, our studies revealed that AnPixJg2 and NpR6012g4 have comparable quantum yields for initiating the forward ( 15Z P r → 15E P g ) and reverse ( 15E P g → 15Z P r ) reactions, which proceed through monotonic and nonmonotonic mechanisms, respectively. In addition to small discrepancies in the kinetics, the secondary reverse dynamics resolved unique features for each domain: intermediate shunts in NpR6012g4 and a Meta-Gf intermediate red-shifted from the 15Z P r photoproduct in AnPixJg2. Altogether, this study supports the conclusion that sequence similarity is a useful criterion for predicting pathways of the light-induced evolution and quantum yield of generating primary intermediate Φ p within subfamilies of CBCRs, but more studies are still needed to develop a comprehensive molecular level understanding of these processes.

59 BASIC BIOLOGICAL SCIENCES↗

Understanding the Different Diffusion Mechanisms of Hydrated Protons and Potassium Ions in Titanium Carbide MXene

The high intercalation capacitance of MXenes is attractive, but their performance as electrodes in supercapacitors is limited by mass transport when increasing the thickness and mass loading of the electrodes. Here, we report a combined experimental and computational study, through which we reveal the diffusion of hydrated ionic species at the interlayer spaces. We find that the cyclic voltammetry curves for the delaminated Ti 3 C 2 T x exhibit distinct features in acid (H 2 SO 4 ) and alkaline (KOH) electrolytes. The DFT-calculated migration profile of K + and H + , in the presence and absence of water, suggests that the intercalated water molecules stabilize the charged ions, facilitating their diffusion from two dimension to three dimension manifested by the reduced activation barriers and movement pathways. In addition, we show that the diffusion of low and high concentrations of protons is significantly different. That is, protons of high concentrations can adsorb at both sides of the interlayer spaces, and water drives frequent proton hopping between stable adsorption sites as shown in the ab initio molecular dynamics simulations. The calculations can thus explain the varied capacitance and distorted CV curves when the experiments are conducted in acid and alkaline electrolytes. Furthermore, these results can provide the guidance to improve the fast transport of ions and electrons in MXenes with high mass loading.

25 ENERGY STORAGE↗

Charge Hopping Dynamics along a Disordered Chain in Quantum Environments: Comparative Study of Different Rate Kernels

This work presents a computational study of charge hopping dynamics along a one-dimensional chain with Gaussian site energy disorder and linearly coupled quantum bath. Time dependent square displacements are calculated directly from numerical solutions of Pauli master equations, for five different rate kernels: exact Fermi golden rule (FGR) rate expression, stationary phase interpolation (SPI) approximation, semiclassical (SC) approximation, classical Marcus rate expression, and Miller-Abrahams expression. All results demonstrate diffusive behavior in the steady state limit. The results based on the FGR rate expression show that the charge transport in the quantum bath can be much more sensitive to the disorder than the prediction from the classical Marcus expression. While the SPI approximation captures this general trend reasonably well, the SC approximation tends to be unreliable at both quantitative and qualitative levels and becomes even worse than the classical Marcus expression under certain conditions. Furthermore, these results offer useful guidance in the choice of approximate rate kernels for larger-scale simulations and also demonstrate significant but fragile positive effects of quantum environments on the charge hopping dynamics.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Surface potential distribution and airflow performance of different air-exposed electrode plasma actuators at different alternating current/direct current voltages

Asymmetric surface dielectric barrier discharge (SDBD) plasma actuators have been intensely studied for a number of years due to their potential applications for aerodynamic control. In this paper, four types of actuators with different configurations of exposed electrode are proposed. The SDBD actuators investigated are driven by dual-power supply, referred to as a fixed AC high voltage and an adjustable DC bias. The effects of the electrode structures on the dielectric surface potential distribution, the electric wind velocity, and the mean thrust production are studied, and the dominative factors of airflow acceleration behavior are revealed. The results have shown that the actions of the SDBD actuator are mainly dependent on the geometry of the exposed electrode. Besides, the surface potential distribution can effectively affect the airflow acceleration behavior. With the application of an appropriate additional DC bias, the surface potential will be modified. As a result, the performance of the electric wind produced by a single SDBD can be significantly improved. In addition, the work also illustrates that the actuators with more negative surface potential present better mechanical performance.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗