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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Processing and characterization of the homologous Zr x Ta 2 O 2x+5 series

In this study, Zr x Ta 2 O 2x+5 (ZTOx) was systematically studied to determine ideal solid-state synthesis and pressureless sintering conditions. For Zr 6 Ta 2 O 17 (ZTO6) and other compositions with values of x in ZTOx the optimal synthesis temperature of 1100 °C with 1 h dwell time was optimal. XRD phase analysis of the homologous series indicated that for ZTOx, x = 5, 6, 7, and 8 were within the phase stability field while x = 4 and x = 9 were outside the phase stability field. Unit cell lattice parameters changed anisotropically with Zr:Ta ratio with an overall <0.1% change in unit cell volume across the solid solution. Some Raman modes red shifted while others blue shifted, indicating competing tensile and compressive strains. Sintering of ZTOx required a progressively higher temperature as Zr-content increased despite the same starting powder grain sizes and synthesis temperature. Higher Vickers hardness for Zr-rich (12.7–12.8 GPa) than Ta-rich Zr x Ta 2 O 2x+5 (11.6–11.7 GPa) disappeared when accounting for different sintering temperatures. Indentation toughness was similar for all compositions (1.2–1.4 MPa m 1/2 ). Properties of Zr x Ta 2 O 2x+5 series indicate tunability of Zr:Ta composition ratio while maintaining the structure and room temperature mechanical properties comparable to Hf 6 Ta 2 O 17 and 8 mol% yttria stabilized zirconia ceramics.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Fourier-based methods for removing mesh anomalies from angle resolved photoemission spectra

Recent improvements to spatial resolution in angle-resolved photo-emission spectroscopy (ARPES) have made it common to perform measurements with a very brief dwell time, for the purpose of mapping the spectral function over large surface regions. However, rapid measurement modalities can suffer a grid-like intensity modulation due to a wire mesh that is typically placed in front of the ARPES detector to block stray electrons. Here, we explore Fourier-based methods that can effectively remove this artifact, and improve the quality of ARPES images obtained in rapid scanning modes. In conclusion, an open source software package is provided containing implementations of demonstrated algorithms.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2024

Surface exsolving perovskite ceramics as catalyst for microwave methane pyrolysis to co-generate hydrogen and carbon nanotube

In this study, we have successfully developed a novel surface exsolving perovskite ceramic, which demonstrates the ability to simultaneously generate CO x -free hydrogen and carbon nanotubes (CNTs) through methane pyrolysis under the influence of microwave irradiation. We conducted an extensive survey and optimization of various perovskite materials specifically tailored for microwave applications. Among the materials investigated, nickel-doped strontium titanium oxide (STON) emerged as the most promising candidate, exhibiting both a satisfactory methane conversion rate and excellent responsiveness to microwave irradiation. Refinement of STON was carried out by fine-tuning the Ni content, optimizing the reduction dwell time, and adjusting the reduction temperature. Notably, SrTiNi 0.08 O 3 (STON8), demonstrated an impressive initial methane conversion rate of up to 40%. Transmission Electron Microscopy (TEM) provided visual evidence of the correlation between Ni content and reduction temperature, with respect to the exsolved Ni metal particle size. This finding highlights the immense potential of surface exsolving perovskite ceramics as a highly effective catalyst for the simultaneous production of CNTs and COx-free hydrogen via methane pyrolysis under microwave irradiation. Furthermore, it represents a step forward in the field of catalytic materials and microwave-driven processes.

08 HYDROGEN↗
DOE OSTI2025

Direct ink writing of aqueous-based Gadolinium (III) oxide slurries

Gadolinium (III) oxide (gadolinia, Gd 2 O 3 ) has recently been identified as an intriguing material for applications in the medical, solid oxide fuel cell, and nuclear industries. This interest drives the need for developing and understanding manufacturing techniques that can produce dense Gd 2 O 3 structures. Direct ink writing (DIW), an extrusion-based additive manufacturing method, has also garnered interest because of its capability to produce dense ceramic parts with increased complexity in an economical manner. In this study, DIW was explored as a manufacturing technique for Gd 2 O 3 . Experiments were performed to develop Gd 2 O 3 bearing inks capable of being processed via DIW. Ink solids loading and sintering temperatures were varied to assess their impact on the final density and microstructure. Optimum sintering conditions are proposed and were experimentally verified at a dwell temperature of 1500°C. Gd 2 O 3 samples were successfully manufactured using DIW, achieving densities greater than 96 % of the theoretical density.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Proton-detected solid-state NMR spectroscopy of spin-1/2 nuclei with large chemical shift anisotropy

Constant-time (CT) dipolar heteronuclear multiple quantum coherence (D-HMQC) has previously been demonstrated as a method for proton detection of high-resolution wideline NMR spectra of spin-1/2 nuclei with large chemical shift anisotropy (CSA). However, 1 H transverse relaxation and t 1 -noise often reduce the sensitivity of D-HMQC experiments, preventing the theoretical gains in sensitivity provided by 1 H detection from being realized. In this paper, we demonstrate a series of improved pulse sequences for 1 H detection of spin-1/2 nuclei under fast MAS, with 195 Pt SSNMR experiments on cisplatin as an example. First, a t 1 -incrementation protocol for D-HMQC dubbed Arbitrary Indirect Dwell (AID) is demonstrated. AID allows the use of arbitrary, rotor asynchronous t 1 -increments, but removes the constant time period from CT D-HMQC, resulting in improved sensitivity by reducing transverse relaxation losses. Next, we show that short high-power adiabatic pulses (SHAPs), which efficiently invert broad MAS sideband manifolds, can be effectively incorporated into 1 H detected symmetry-based resonance echo double resonance (S-REDOR) and t 1 -noise eliminated (TONE) D-HMQC experiments. The S-REDOR experiments with SHAPs provide approximately double the dipolar dephasing, as compared to experiments with rectangular inversion pulses. We lastly show that sensitivity and resolution can be further enhanced with the use of swept excitation pulses as well as adiabatic magic angle turning (aMAT).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Semi-empirical simulation of in-motion radiation detection systems

The Replicative Assessment of Spectroscopic Equipment (RASE) is an open-source software that uses experimental data as the basis to simulate the response of commercial radiation detectors to sources in various situations, particularly in the context of nuclear security and safeguards applications. Dynamic RASE introduces the capability to simulate scenarios where sources and detector are in relative motion. Position-dependent experimentally acquired gamma spectra are ingested by Dynamic RASE to build maps that describe the detector response over all space. These response maps are used to replicate the time-dependent energy spectra collected as sources move on a path near the detector. Here, a Gaussian process is used to build each map, incorporating a novel kernel adapted to the special case of radiation detection. The approach has been validated against experimental data acquired using a NaI-based detector for 137 Cs and 54 Mn sources. The capability to create accurate simulations using either long-dwell static measurements or dynamic pass-by measurements as source data has been demonstrated. Quantitative relative performance, benefits, and shortcomings are discussed.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2020

Self-welding of Inconel 617 under high-pressure-high-temperature conditions for nuclear reactors

In response to continuously declining availability of fossil fuels, nuclear power has become an important alternative source of power generation. Growing application of nuclear power has relieved the shortage of electricity. However, it is also accompanied with new drawbacks, such as radioactive waste, and potential catastrophic consequences in case of major accidents. For nuclear power plants, severe accidents mostly originate from the reactor, making the reliability of the reactor of paramount importance to the overall safety of a nuclear power plant. Massive heat generation through nuclear fission/fusion and heat exchange render the whole reactor operating at extremely high temperatures (i.e., 900–1000 °C), which, in conjunction with large load from subsystems/ components made of special heavy alloys, renders the reactor under the risk of self-welding, a phenomenon that could lead to strong bonding between components and paralyze the operability of the nuclear reactor. This paper investigates the self-welding behavior of Inconel 617, a primary candidate nickel alloy for key components of the next generation gas cooled nuclear plant, inside a controlled atmospheric furnace with preset static load, simulating the high-pressure high-temperature conditions inside nuclear reactors. Therefore, test results show that Inconel 617 experiences self-welding through common oxide zone at the interface, and it has remarkable bonding strength, requiring 4114 N (57.15 MPa) and 4338 N (60.25 MPa) to break apart a mated sample pair, under an apparent contact pressure of 0.341 MPa after 50-h aging, in helium and air atmospheres, respectively. The higher oxygen presence in air results in slightly stronger oxide bond at the interface, compared to helium, and the bond strength increases with dwell time.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2023

Transportation and electricity systems integration via electric vehicle charging-as-a-service: A review of techno-economic and societal benefits

Here, in support of global decarbonization efforts, the adoption of electric vehicles is proceeding rapidly across transportation sectors, population groups, and regions. However, access to electric vehicle charging infrastructure remains sparse and inequitable, and technical, economic, and procedural challenges have encumbered its expansion. Charging-as-a-service, which can mitigate cost and effort risks of charging equipment ownership, adds a means of meeting many of these challenges. As charging-as-a-service has not been analyzed or addressed in the scholarly literature, we synthesize media, marketing, and analogous scholarly publications to categorize and describe the functions asserted by existing charging-as-a-service vendors. We demonstrate and quantify the benefits of many of these functions via four example business cases, sited at a detached residence, a multi-unit dwelling, a consumer-facing business, and a commercial fleet depot. Outcomes show that savings and revenues realized via charging-as-a-service can reduce charging costs, beneficially shape grid loads, and make charging installation economical where it otherwise would not be. Discussion highlights the need to deploy charging-as-a-service in cooperation with initiatives promoting societal benefits, including charging access equity.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2022

Charging needs for electric semi-trailer trucks

Battery-electric vehicles provide a pathway to decarbonize heavy-duty trucking, but the market for heavy-duty battery-electric semi-trailer trucks is nascent, and specific charging requirements remain uncertain. We leverage large-scale vehicle telematics data (>205 million miles of driving) to estimate the charging behaviors and infrastructure requirements for U.S. battery-electric semi-trailer trucks within three operating segments: local, regional, and long-haul. We model two types of charging - mid-shift (fast) and off-shift (slow) - and show that off-shift charging at speeds compatible with current light-duty charging infrastructure (i.e., =350 kW) can supply 35% to 77% of total energy demand for local and regional trucks with =300-mile range. Megawatt-level speeds are required for mid-shift charging, which make up 44% to 57% of energy demand for long-haul trucks with =500-mile range. However, demand shifts from mid-shift to off-shift charging as the range for battery-electric trucks increases and when off-shift charging is widely available. Finally, we observe geographic trends in charging demand, finding that local trucks have greater demand within urban areas, whereas long-haul trucks have more demand along rural interstate corridors. As the range for battery-electric trucks increases, we show that charging demand shifts from rural to urban locations due to observed vehicle dwell tendencies.

33 ADVANCED PROPULSION SYSTEMS↗
DOE OSTI2023

Deployment priority of public charging speeds for increasing battery electric vehicle usability

To inform charger deployment decisions, this paper aims to understand the potential utilization and deployment priority for public charging infrastructure. A data-driven Cumulative Public Recharging (CPR) model is developed to explore the travel patterns by using 2017 National Household Travel Survey data. Given the daily trip sequence, trip distance, and dwell times, the study examines the daily expected driving range and BEV feasibility under different charging speeds, battery capacity, and charging behaviors. The results suggest that more advanced public chargers increase the daily expected driving range. Home charging is sufficient for most daily short-distance trips while public chargers are still needed for medium- and long-distance trips. Extreme fast charging (xFC) may not be necessary for people with home charging but could be more useful for people without home charging and for urgent charging. In conclusion, xFC becomes even less important to drivers with longer BEV ranges, a finding that contradicts conventional thinking.

33 ADVANCED PROPULSION SYSTEMS↗
DOE OSTI2024

Coupled management of electric vehicle workplace charging and office building loads

Significant building energy savings are realized through heating, ventilation, and air conditioning (HVAC) setpoint adjustment and daylighting control. Workplace charging (WPC) enables colocation of electric vehicles (EVs) with office building loads. We proposed managing energy use of workplace EV charging and the office building and determined the number of EVs that building energy savings can facilitate charging. We simulated building energy savings in typical medium offices in Chicago IL, Baltimore MD, and Houston TX, spanning three US climate regions. Considering the EV hosting capacity of the saved building energy and travel patterns of roundtrip commuting, we minimized EV charging costs under time-of-use electricity pricing. Managed WPC can reduce charging electricity bills compared to first-come, first-served charging. The ratio of EVs to chargers, the coincident period of commuters’ dwell time and lower electricity prices, and the number of EVs in the office impacted the economic benefits achieved through charging management.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2025

Electrifying education: Exploring the electrification potential of U.S. School bus fleets

We analyze the operations of 270 diesel school buses across the United States to assess their electrification potential and evaluate the impact of various charging strategies on electricity demand. We find that school buses typically follow a two-route schedule on weekdays, featuring extended dwell times between morning and evening trips. Weekday trip distances average 25 miles, while weekend trips average 42 miles. Charging simulations indicate over 90% of the U.S. school bus fleet could be electrified using current technologies (300-mile range at 1.21 kWh/mile with 19.2-kW depot charging) without modifying existing operating patterns. Depot charging is a key enabler of school bus electrification, however, the strategic placement of charging stations at other locations (e.g., schools) can further increase electrification potential. Additionally, we find electric school bus charging to be highly flexible, with charge management capable of reducing peak charging loads at depots by up to 77%.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2026

Time Matters: A Survival Analysis of Public Electric Vehicle Charging Infrastructure Utilization

The rapid adoption of plug-in electric vehicles (PEVs) places significant demands on public charging infrastructure, making it critical to understand and optimize charger utilization. This study provides one of the most comprehensive analyses of charging behavior to date by applying a survival analysis to a dataset of nearly 16 million level 2 (L2) and direct current (DC) fast charger sessions across the United States from 2017 to 2022. Using Kaplan-Meier curves and log rank tests, our analysis reveals statistically significant and distinct duration patterns influenced by charger type, time of day, and day of the week. We find that L2 charging sessions exhibit high variability tied to venue type, whereas DC sessions are more uniform, typically lasting 30-45 min. This study introduces the operational efficiency score (OES), a metric for standardizing the performance evaluation of charging stations. Our findings offer actionable insights for optimizing charger deployment, developing dynamic pricing strategies to reduce vehicle dwell time, and improving load management for grid operators, ultimately enhancing the efficiency and availability of public charging infrastructure.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2021

A Facile, One-Step Synthesis for Core–Shell Perovskite Materials via Molten Salt

Core–shell La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3 (LSCF)–La 0.8 Sr 0.2 MnO 3 (LSM) heterostructure crystalline materials have been synthesized in a simple, one-step feeding method via a KNO 3 molten salt solvent. Two-phase perovskite composites can be synthesized in times as short as 10 minutes and is demonstrated for the first time in a molten salt. Further, a combination of X-ray diffraction and S/TEM energy dispersive X-ray spectroscopy has been utilized to confirm the formation of an LSM shell on LSCF cores in all samples when adjusting dwell time, core size, weight ratio between core and shell precursors, and weight ratio of powder to salt. Specifically, decreasing the LSCF core size increases core–shell yield. Smaller cores introduce a greater density of facets on the crystal surface and provide more favorable sites for LSM heterogeneous nucleation.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Rapid Identification of Synthetic Routes to Functional Metastable Phases Using X-ray Probed Laser Anneal Mapping (XPLAM) Time-Temperature Quench Maps

Many material systems have known or predicted functional phases that are metastable at standard temperature and pressure. While substantial advances have been made in the high-throughput and combinatorial synthesis of materials with a range of stoichiometries, investigation of thermal processing remains largely the domain of iterative uniform anneals or static gradients. Here we develop X-ray probed laser anneal mapping (XPLAM), a high throughput technique coupling spatially resolved X-ray diffraction with microsecond to millisecond laser gradient anneals to produce temperature–dwell–transformation (TDT) diagrams of the phase as a function of quench time and temperature. In addition to showing regimes where specific metastable phases form preferentially, TDT diagrams provide insight into the submillisecond kinetics of solid–solid phase transitions. This is a unique tool for mapping reaction pathways for metastable phases. As a first demonstration of XPLAM, we study Bi2O3, which has a rich set of polytypes, including the d-phase with an exceptionally high oxygen ion conductivity. We demonstrate the first annealing-driven synthesis of room temperature d-Bi2O3. We expect XPLAM to prove a powerful technique for rapid identification of synthetic routes to metastable phases and to generate the exhaustive data sets required for machine learning-guided exploration of materials processing.

36 MATERIALS SCIENCE↗
DOE OSTI2021

In Situ Methods for Metal-Flux Synthesis in Inert Environments

Flux growth synthesis is an advantageous synthetic method as it allows for the growth of single crystals of both congruently melting and metastable phases. The determination of synthetic parameters for the flux growth of new crystalline phases is complex as many factors and parameters need to be considered, such as purity and morphology of starting material and heating profile variables including maximum temperature, dwell time, cooling rate and flux removal temperature. In situ monitoring of crystallite growth can lead to elucidation of reaction intermediates and growth mechanisms. The determination of pivotal reaction parameters can revolutionize the way growth parameters are selected. In this work, we report a new sample environment and furnace apparatus for synchrotron in situ synthesis of crystalline materials, including flux grown intermetallics.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Evaluating Brightness and Stability of Cathodoluminescence from Colloidal Semiconductor Nanocrystals

Cathodoluminescence offers promise as a technique for correlation of atomic structure with electronic structure at the level of individual nanoparticles or even defects, with the ability to analyze complex nanostructures at length-scales far below those typically available to optical spectroscopy. Unlike other forms of electron microscopy, cathodoluminescence offers direct insights into the electronic structure of the visualized sample. Despite reports more than 10 years ago of individual nanoparticle cathodoluminescence, effective cathodoluminescence collection from colloidal semiconductor materials is relatively rare and remains challenging due to the instability of materials under the conditions of electron beam irradiation. In this work, to clarify the roadblocks for cathodoluminescence analysis of colloidal nanocrystals, we attempt a comprehensive study of the cathodoluminescence properties of semiconductor quantum shells, which have a thin concentric CdSe shell surrounding CdS nanoparticles, then surrounded by a further concentric CdS shell. These same materials were recently demonstrated to show promising scintillation performance in radioluminescence measurements, including high brightness (up to 100 ph/keV) and excellent durability. Comparative quantum yield measurements are designed to assess the brightness of semiconductor nanocrystal films, which show that the quantum shells are much less bright under electron irradiation compared to X-ray photons. Instability of CL emission is assigned to charging effects on the samples—and not thermal effects—through a series of voltage, current, dwell time, and atmospheric pressure experiments.

cathodoluminescence↗
DOE OSTI2022

CO 2 Laser Sintering of Garnet-Type Solid-State Electrolytes

We report the processing of garnet-type solid-state electrolytes remains challenging as densification conventionally requires high sintering temperatures and long processing times, which can result in severe Li loss, the formation of secondary phases, and thus high porosity and low ionic conductivity. Here, we report an ultrafast sintering method based on CO 2 laser scanning with the assistance of a heating stage. We demonstrate the rapid densification of low-packing-density Li 6.4 La 3 Zr 1.4 Ta 0.6 O 12 (LLZTO) films, which are difficult to densify by conventional furnace sintering methods. This unique approach has three fingerprint characteristics: (1) mitigation of Li loss through ultrafast sintering (dwelling time $\ll$1 s); (2) a unique anisotropic shrinkage behavior that greatly reduces film thickness; (3) wave-like surface topology from point scanning strategy that enables 3D interfacial contacts with electrode materials. Herein, highly dense (95.68%) and highly conductive (0.26 mS·cm –1 at 25 °C) LLZTO films are obtained through CO2 laser sintering. This work provides a unique, scalable, and widely applicable ultrarapid laser sintering technique to overcome the difficulties associated with classic methods for the integration of SSEs for practical all-solid-state Li-metal battery applications.

36 MATERIALS SCIENCE↗