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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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118 records · Page 7

We Must Stop Fossil Fuel Emissions to Protect Permafrost Ecosystems

Climate change is an existential threat to the vast global permafrost domain. The diverse human cultures, ecological communities, and biogeochemical cycles of this tenth of the planet depend on the persistence of frozen conditions. The complexity, immensity, and remoteness of permafrost ecosystems make it difficult to grasp how quickly things are changing and what can be done about it. Here, we summarize terrestrial and marine changes in the permafrost domain with an eye toward global policy. While many questions remain, we know that continued fossil fuel burning is incompatible with the continued existence of the permafrost domain as we know it. If we fail to protect permafrost ecosystems, the consequences for human rights, biosphere integrity, and global climate will be severe. The policy implications are clear: the faster we reduce human emissions and draw down atmospheric CO 2 , the more of the permafrost domain we can save. Emissions reduction targets must be strengthened and accompanied by support for local peoples to protect intact ecological communities and natural carbon sinks within the permafrost domain. Some proposed geoengineering interventions such as solar shading, surface albedo modification, and vegetation manipulations are unproven and may exacerbate environmental injustice without providing lasting protection. Conversely, astounding advances in renewable energy have reopened viable pathways to halve human greenhouse gas emissions by 2030 and effectively stop them well before 2050. We call on leaders, corporations, researchers, and citizens everywhere to acknowledge the global importance of the permafrost domain and work towards climate restoration and empowerment of Indigenous and immigrant communities in these regions.

54 ENVIRONMENTAL SCIENCES↗

An Asymmetric Dust Ring around a Very Low Mass Star ZZ Tau IRS

We present Atacama Large Millimeter/submillimeter Array (ALMA) gas and dust observations at band 7 (339 GHz: 0.89 mm) of the protoplanetary disk around a very low mass star ZZ Tau IRS with a spatial resolution of 025. The {sup 12}CO J = 3 → 2 position–velocity diagram suggests a dynamical mass of ZZ Tau IRS of ∼0.1–0.3 M {sub ☉}. The disk has a total flux density of 273.9 mJy, corresponding to an estimated mass of 24–50 M {sub ⊕} in dust. The dust emission map shows a ring at r = 58 au and an azimuthal asymmetry at r = 45 au with a position angle of 135°. The properties of the asymmetry, including radial width, aspect ratio, contrast, and contribution to the total flux, were found to be similar to the asymmetries around intermediate mass stars (∼2 M {sub ☉}) such as MWC 758 and IRS 48. This implies that the asymmetry in the ZZ Tau IRS disk shares a similar origin with others, despite the star being ∼10 times less massive. Our observations also suggest that the inner and outer parts of the disk may be misaligned. Overall, the ZZ Tau IRS disk shows evidence of giant planet formation on a ∼10 au scale at a few megayears. If confirmed, it will challenge existing core accretion models in which such planets have been predicted to be extremely hard to form around very low mass stars.

74 ATOMIC AND MOLECULAR PHYSICS↗

A Combined Crossed Molecular Beam and Theoretical Investigation of the Elementary Reaction of Tricarbon (C 3 (X 1 Σ g + )) with Diacetylene (C 4 H 2 (X 1 Σ g + )): Gas Phase Formation of the Heptatriynylidyne Radical ( l -C 7 H(X 2 Π))

An elucidation of the underlying formation pathways to acyclic hydrocarbons such as polyynes (C n H 2 ), cumulenes (C n H 2 ), and linear resonantly stabilized linear radicals (l-C n H) is indispensable to understand the hydrocarbon chemistry in extreme low and high temperature environments. In this study, we exploited the crossed molecular beam technique to investigate the reaction of tricarbon C 3 (X 1 Σ g + ) with diacetylene (butadiyne; HCCCCH; X 1 Σ g + ) at a collision energy of 47 ± 1 kJ mol ⁻1 . The experimental data were merged with ab initio calculations of the singlet C 7 H 2 potential energy surface (PES) revealing that the reaction is initiated via the formation of an initial van der Waals reactant complex in the entrance channel. Subsequent rearrangements lead to various carbene-type and cyclic intermediates via ring-opening, ring-closure, and hydrogen migration processes eventually forming acyclic C 7 H 2 isomers prior to their barrierless unimolecular decomposition to the most stable linear isomer, heptatriynylidyne (C 7 H, X 2 Π) in an overall endoergic reaction (+57 kJ mol ⁻1 ). The reaction exhibits strong similarities to the tricarbon – acetylene (C 3 – C 2 H 2 ). Furthermore, the significant energy threshold suggests that the tricarbon reaction with (poly)acetylenes forming resonantly stabilized linear radicals are open in high-temperature environments such as combustion flames and circumstellar envelopes of carbon stars and planetary nebulae as their descendants; however, these reactions are closed in low-temperature environments as in cold molecular clouds and hydrocarbon-rich atmospheres of planets and their moons such as in Titan.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Reaction between Hydrogen and Ferrous/Ferric Oxides at High Pressures and High Temperatures—Implications for Sub-Neptunes and Super-Earths

Abstract Sub-Neptune exoplanets may have thick hydrogen envelopes and therefore develop a high-pressure interface between hydrogen and the underlying silicates/metals. Some sub-Neptunes may convert to super-Earths via massive gas loss. If hydrogen chemically reacts with oxides and metals at high pressures and temperatures ( P − T ), it could impact the structure and composition of the cores and atmospheres of sub-Neptunes and super-Earths. While H 2 gas is a strong reducing agent at low pressures, the behavior of hydrogen is unknown at the P − T expected for sub-Neptunes’ interiors, where hydrogen is a dense supercritical fluid. Here we report experimental results of reactions between ferrous/ferric oxides and hydrogen at 20–40 GPa and 1000–4000 K utilizing the pulsed laser-heated diamond-anvil cell combined with synchrotron X-ray diffraction. Under these conditions, hydrogen spontaneously strips iron off the oxides, forming Fe-H alloys and releasing oxygen to the hydrogen medium. In a planetary context where this reaction may occur, the Fe-H alloy may sink to the metallic part of the core, while released oxygen may stabilize as water in the silicate layer, providing a mechanism to ingas hydrogen to the deep interiors of sub-Neptunes. Water produced from the redox reaction can also partition to the atmosphere of sub-Neptunes, which has important implications for understanding the composition of their atmospheres. In addition, super-Earths converted from sub-Neptunes may contain a large amount of hydrogen and water in their interiors (at least a few wt% H 2 O). This is distinct from smaller rocky planets, which were formed relatively dry (likely a few hundredths wt% H 2 O).

58 GEOSCIENCES↗

Deconstructing the Soil Microbiome into Reduced-Complexity Functional Modules

The soil microbiome is an invaluable component of the biosphere and critical for ecosystem functions, including biogeochemical cycling, soil-atmosphere gas exchange, degradation of toxic compounds, and promotion of plant growth and stress resistance/resilience. An improved understanding of the soil microbiome will help with predicting how these processes respond to external perturbations, and with harnessing beneficial aspects of the soil microbiome for agronomic applications such as crop amendments. However, the extensive taxonomic and functional diversity inherent within the soil microbiome hinders efficient analysis of this system. Microbial biodiversity in soils is orders of magnitude greater than other commonly studied systems such as the human gut microbiome (Blum, Zechmeister-Boltenstern, and Keiblinger 2019; Berendsen, Pieterse, and Bakker 2012). Thousands of microbial taxa may be found in a single gram of soil (Roesch et al. 2007), and high rates of gene flow and mutation further promote microbial diversification (Sergaki et al. 2018). Concomitantly, functional diversity in soil is similarly extensive. Soil is a heterogeneous mixture of microenvironments with defined physical and chemical attributes (Bach et al. 2018), within which numerous microbial guilds of distinct life-strategies and metabolic capacities can be found (Perez-Garcia, Lear, and Singhal 2016; H.-S. Song et al. 2014). Furthermore, the soil microbiome harbors a significant fraction of rare and/or quiescent members (Blagodatskaya and Kuzyakov 2013) that exist below the threshold of detection of current technologies. Such rare taxa may make significant contributions to process rates (Shade and Gilbert 2015; Dawson et al. 2017), but their scarcity complicates their identification and analysis. Finally, the vast amounts of information generated through holistic analyses of soil communities represent an intense computational burden (Scholz, Lo, and Chain 2012; Prosser 2015) that precludes assessment of the complete functional and taxonomic diversity contained in this ecosystem.

Naylor, Dan T.↗

Initial Characterization of Active Transitioning Centaur, P/2019 LD{sub 2} (ATLAS), Using Hubble, Spitzer, ZTF, Keck, Apache Point Observatory, and GROWTH Visible and Infrared Imaging and Spectroscopy

We present visible and mid-infrared imagery and photometry of temporary Jovian co-orbital comet P/2019 LD{sub 2} taken with Hubble Space Telescope/Wide Field Camera 3 (HST/WFC3), Spitzer Space Telescope/Infrared Array Camera (Spitzer/IRAC), and the GROWTH telescope network, visible spectroscopy from Keck/Low-Resolution Imaging Spectrometer (LRIS), and archival Zwicky Transient Facility observations taken between 2019 April and 2020 August. Our observations indicate that the nucleus of LD{sub 2} has a radius between 0.2 and 1.8 km assuming a 0.08 albedo and a coma dominated by ∼100 μm-scale dust ejected at ∼1 m s{sup −1} speeds with a ∼1′ jet pointing in the southwest direction. LD{sub 2} experienced a total dust mass loss of ∼10{sup 8} kg at a loss rate of ∼6 kg s{sup −1} with Afρ/cross section varying between ∼85 cm/125 km{sup 2} and ∼200 cm/310 km{sup 2} from 2019 April 9 to 2019 November 8. If the increase in Afρ/cross section remained constant, it implies LD{sub 2}'s activity began ∼2018 November when within 4.8 au of the Sun, implying the onset of H{sub 2}O sublimation. We measure CO/CO{sub 2} gas production of ≲10{sup 27} mol s{sup −1}/≲10{sup 26} mol s{sup −1} from our 4.5 μm Spitzer observations; g–r = 0.59 ± 0.03, r–i = 0.18 ± 0.05, and i–z = 0.01 ± 0.07 from GROWTH observations; and H{sub 2}O gas production of ≲80 kg s{sup −1} scaling from our estimated C {sub 2} production of Q{sub C{sub 2}}≲7.5×10{sup 24} mol s{sup −1} from Keck/LRIS spectroscopy. We determine that the long-term orbit of LD{sub 2} is similar to Jupiter-family comets having close encounters with Jupiter within ∼0.5 Hill radius in the last ∼3 y and within 0.8 Hill radius in ∼9 y. Additionally, 78.8% of our orbital clones are ejected from the solar system within 1 × 10{sup 6} yr, having a dynamical half-life of 3.4 × 10{sup 5} yr.

47 OTHER INSTRUMENTATION↗

Modeling the Enceladus dust plume based on in situ measurements performed with the Cassini Cosmic Dust Analyzer

We analyzed data recorded by the Cosmic Dust Analyzer on board the Cassini spacecraft during Enceladus dust plume traversals. Our focus was on profiles of relative abundances of grains of different compositional types derived from mass spectra recorded with the Dust Analyzer subsystem during the Cassini flybys E5 and E17. The E5 profile, corresponding to a steep and fast traversal of the plume, has already been analyzed. In this paper, we included a second profile from the E17 flyby involving a nearly horizontal traversal of the south polar terrain at a significantly lower velocity. Additionally, we incorporated dust detection rates from the High Rate Detector subsystem during flybys E7 and E21. We derived grain size ranges in the different observational data sets and used these data to constrain parameters for a new dust plume model. This model was constructed using a mathematical description of dust ejection implemented in the software package DUDI. Further constraints included published velocities of gas ejection, positions of gas and dust jets, and the mass production rate of the plume. Our model employs two different types of sources: diffuse sources of dust ejected with a lower velocity and jets with a faster and more colimated emission. From our model, we derived dust mass production rates for different compositional grain types, amounting to at least 28 kg s –1 . Previously, salt-rich dust was believed to dominate the plume mass based on E5 data alone. The E17 profile shows a dominance of organic-enriched grains over the south polar terrain, a region not well constrained by E5 data. By including both E5 and E17 profiles, we find the salt-rich dust contribution to be at most 1% by mass. This revision also results from an improved understanding of grain masses of various compositional types that implies smaller sizes for salt-rich grains. Our new model can predict grain numbers and masses for future mission detectors during plume traversals.

79 ASTRONOMY AND ASTROPHYSICS↗

Observations of Disequilibrium CO Chemistry in the Coldest Brown Dwarfs

Cold brown dwarfs are excellent analogs of widely separated, gas giant exoplanets, and provide insight into the potential atmospheric chemistry and physics we may encounter in objects to be discovered by future direct imaging surveys. We present a low-resolution, R ∼ 300, M-band spectroscopic sequence of seven brown dwarfs with effective temperatures between 750 and 250 K along with Jupiter. These spectra reveal disequilibrium abundances of carbon monoxide (CO) produced by atmospheric quenching. We use the eddy diffusion coefficient (K {sub zz}) to estimate the strength of vertical mixing in each object. The K {sub zz} values of cooler gaseous objects are close to their theoretical maximum, and warmer objects show weaker mixing, likely due to less efficient convective mixing in primarily radiative layers. The CO-derived K {sub zz} values imply that disequilibrium phosphine (PH{sub 3}) should be easily observable in all of the brown dwarfs, but none as yet show any evidence for PH{sub 3} absorption. We find that ammonia is relatively insensitive to atmospheric quenching at these effective temperatures. We are able to improve the fit to WISE 0855's M-band spectrum by including both CO and water clouds in the atmospheric model.

79 ASTRONOMY AND ASTROPHYSICS↗

Thermal History of Matrix Forsterite Grains from Murchison Based on High-resolution Tomography

Protoplanetary disks are dust- and gas-rich structures surrounding protostars. Depending on the distance from the protostar, this dust is thermally processed to different degrees and accreted to form bodies of varying chemical compositions. The primordial accretion processes occurring in the early protoplanetary disk such as chondrule formation and metal segregation are not well understood. One way to constrain them is to study the morphology and composition of forsteritic grains from the matrix of carbonaceous chondrites. Here, we present high-resolution ptychographic X-ray nanotomography and multimodal chemical microtomography (X-ray diffraction and X-ray fluorescence) to reveal the early history of forsteritic grains extracted from the matrix of the Murchison CM2.5 chondrite. Here,. the 3D electron density maps revealed, at unprecedented resolution (64 nm), spherical inclusions containing Fe–Ni, very little silica-rich glass and void caps (i.e., volumes where the electron density is consistent with conditions close to vacuum) trapped in forsterite. The presence of the voids along with the overall composition, petrological textures, and shrinkage calculations is consistent with the grains experiencing one or more heating events with peak temperatures close to the melting point of forsterite (~2100 K), and subsequently cooled and contracted, in agreement with chondrule-forming conditions.

58 GEOSCIENCES↗

James Clerk Maxwell Telescope Spectral and Continuum Imaging of Hyperactive Comet 46P/Wirtanen

The Jupiter-family comet (JFC) 46P/Wirtanen passed the Earth at a distance of 0.077 au on 2018 December 16 UT, presenting a rare opportunity to study the chemical structure of its coma. With the James Clerk Maxwell Telescope we achieved a resolution of 800 km, which is smaller than the scale lengths of some distributed cometary molecules at the comet’s heliocentric distance of 1 au. Spectroscopic observations of the J = 4 - 3 transition of HCN showed generally uniform levels of outgassing activity during the observing period, 2018 December 14–20. Gas expansion velocities were ~0.6 km s{sup -1}, and the derived average HCN production rate was 7.4 × 10{sup 24} mol s{sup -1}. HCN and CH{sub 3}OH emissions were detected at least 30" (1600 km) from the nucleus, and the abundances of these species were typical for a JFC. The radial distribution of CH{sub 3}OH is consistent with an extended source of sublimation such as a population of icy grains—cometary halo ice primaries, or CHIPs—as has been invoked previously to explain hyperactivity in comets. The abundance of H{sub 2}CO is normal if it is a daughter species. HNC and CO were not detected, but a sensitive nondetection of CS implies an unusually low CS:H{sub 2}O ratio of <0.02%. The peak brightness of the 850 μm continuum emissions from icy coma dust particles of size ~1 mm fell from (52 ± 6) to (40 ± 3) mJy beam{sup -1} through the week, while the size of the dust coma remained essentially constant, with dust extending to ~1000 km from the nucleus. The total mass of those particles was ~2 × 10{sup 8} kg.

79 ASTRONOMY AND ASTROPHYSICS↗