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Primary Objective Grating Astronomical Telescope

It has been 370 years since a seventeenth century French mathematician, Mersenne, presciently sketched out an astronomical telescope based on dual parabolic reflectors. Since that time the concept of the primary objective has been virtually unchanged. Now a new class of astronomical telescope with a primary objective grating (POG) has been studied as an alternative. The POG competes with mirrors, in part, because diffraction gratings provide the very chromatic dispersion that mirrors defeat. The resulting telescope deals effectively with long-standing restrictions on multiple object spectroscopy (MOS). Other potential benefits include unprecedented apertures and collection areas. The new design also favors space deployment as a gossamer membrane. The inventor, Tom Ditto, first discovered that higher-order diffraction images contain hidden depth cues, for which he was granted a seminal range finding patent in 1987. Subsequently, he invented and patented 3D localizers, profilometers and microscopes using POGs. The POG telescope was placed in the public domain to expedite research. The function of a telescopes primary objective is to collect flux and to deliver images. Both functions dictate that size matters, and bigger is better. For that reason, there has been a steady push over the past century to ramp up the size of the primary mirror. However, for every doubling of mirror diameter, the elapsed time between initial effort and first light has also doubled. Meanwhile, costs escalated beyond the mirror alone, because larger instruments required larger enclosures and better pointing mechanisms. One key catalog of observation, spectrographic data, is far more difficult to amass than two-dimensional imagery. While the number of observable objects has increased with mirror size, the capacity to take spectra has not increased proportionately. In the best of circumstances, spectrograms are available for one per cent of the all objects surveyed. Spectroscopy was a historical afterthought introduced in the nineteenth century shortly after the invention of the diffraction grating and over a century after Newtons 1670 telescope. Spectroscopy is generally accomplished using a diffraction grating as the disperser in the secondary. The light being delivered to the spectrograph is first captured by a primary mirror which provides no chromatic magnification by itself. Sizeable spectrographs could not be deployed while diffraction gratings were rare commodities scribed using mechanical ruling engines that produced one grating line at a time. Today diffraction gratings are commonplace. Their recent availability is a product of both the invention of holography and the mass replication of surface microstructures. Holography permits all lines in a grating to be made simultaneously in a single photographic exposure. Holograms can then be reproduced by embossing processes. The improvement in replication is analogous to how Gutenberg changed the availability of books. The masters may be expensive, but the copies are not. Computer science is another technology that emerged in the second half of the twentieth century without which our proposed spectrographic instrument could not function due to the complexity of image processing required in data reduction. The employment of very large diffraction gratings as primary objectives for astronomical telescopes requires a novel

spectroscopy

On the global circulation and the hurricane system of the Jovian atmosphere

An argument is made to support the proposal that Jupiter's red spot and the white and brown ovals are hurricanes or cyclones. Against the background of a convectively unstable troposphere, the general condition exists for the formation of hurricanes. The energy Jupiter emits must be transported upwards through the troposphere. If that transport is accelerated by the prevailing upward motions in the solar driven multicellular meridional circulation, eastward jets develop such as observed in the l region. But if that vertical transport is impeded by the prevailing downward motions in the meridional circulation, the atmosphere reacts and tends to maintain the process through the development of hurricanes. Dynamically induced by solar differential heating, an ordered latitudinal structure with alternating stability and instability is impressed on the troposphere to form alternating zonal strata where hurricanes are forbidden and permitted, respectively.

Mayr, H. G.

Information theory analysis of sensor-array imaging systems for computer vision

Information theory is used to assess the performance of sensor-array imaging systems, with emphasis on the performance obtained with image-plane signal processing. By electronically controlling the spatial response of the imaging system, as suggested by the mechanism of human vision, it is possible to trade-off edge enhancement for sensitivity, increase dynamic range, and reduce data transmission. Computational results show that: signal information density varies little with large variations in the statistical properties of random radiance fields; most information (generally about 85 to 95 percent) is contained in the signal intensity transitions rather than levels; and performance is optimized when the OTF of the imaging system is nearly limited to the sampling passband to minimize aliasing at the cost of blurring, and the SNR is very high to permit the retrieval of small spatial detail from the extensively blurred signal. Shading the lens aperture transmittance to increase depth of field and using a regular hexagonal sensor-array instead of square lattice to decrease sensitivity to edge orientation also improves the signal information density up to about 30 percent at high SNRs.

Huck, F. O.

A proposed research program in information processing

The goal of the Formalized Software Development (FSD) project was to demonstrate improvements productivity of software development and maintenance through the use of a new software lifecycle paradigm. The paradigm calls for the mechanical, but human-guided, derivation of software implementations from formal specifications of the desired software behavior. It relies on altering a system's specification and rederiving its implementation as the standard technology for software maintenance. A system definition for this paradigm is composed of a behavioral specification together with a body of annotations that control the derivation of executable code from the specification. Annotations generally achieve the selection of certain data representations and/or algorithms that are consistent with, but not mandated by, the behavioral specification. In doing this, they may yield systems which exhibit only certain behaviors among multiple alternatives permitted by the behavioral specification. The FSD project proposed to construct a testbed in which to explore the realization of this new paradigm. The testbed was to provide operational support environment for software design, implementation, and maintenance. The testbed was proposed to provide highly automated support for individual programmers ('programming in the small'), but not to address the additional needs of programming teams ('programming in the large'). The testbed proposed to focus on supporting rapid construction and evolution of useful prototypes of software systems, as opposed to focusing on the problems of achieving production quality performance of systems.

Schorr, Herbert

Spaceflight Operations Services Grid (SOSG)

In an effort to adapt existing space flight operations services to new emerging Grid technologies we are developing a Grid-based prototype space flight operations Grid. This prototype is based on the operational services being provided to the International Space Station's Payload operations located at the Marshall Space Flight Center, Alabama. The prototype services will be Grid or Web enabled and provided to four user communities through portal technology. Users will have the opportunity to assess the value and feasibility of Grid technologies to their specific areas or disciplines. In this presentation descriptions of the prototype development, User-based services, Grid-based services and status of the project will be presented. Expected benefits, findings and observations (if any) to date will also be discussed. The focus of the presentation will be on the project in general, status to date and future plans. The End-use services to be included in the prototype are voice, video, telemetry, commanding, collaboration tools and visualization among others. Security is addressed throughout the project and is being designed into the Grid technologies and standards development. The project is divided into three phases. Phase One establishes the baseline User-based services required for space flight operations listed above. Phase Two involves applying Gridlweb technologies to the User-based services and development of portals for access by users. Phase Three will allow NASA and end users to evaluate the services and determine the future of the technology as applied to space flight operational services. Although, Phase One, which includes the development of the quasi-operational User-based services of the prototype, development will be completed by March 2004, the application of Grid technologies to these services will have just begun. We will provide status of the Grid technologies to the individual User-based services. This effort will result in an extensible environment that incorporates existing and new spaceflight services into a standards-based framework providing current and future NASA programs with cost savings and new and evolvable methods to conduct science. This project will demonstrate how the use of new programming paradigms such as web and grid services can provide three significant benefits to the cost-effective delivery of spaceflight services. They will enable applications to operate more efficiently by being able to utilize pooled resources. They will also permit the reuse of common services to rapidly construct new and more powerful applications. Finally they will permit easy and secure access to services via a combination of grid and portal technology by a distributed user community consisting of NASA operations centers, scientists, the educational community and even the general population as outreach. The approach will be to deploy existing mission support applications such as the Telescience Resource Kit (TReK) and new applications under development, such as the Grid Video Distribution System (GViDS), together with existing grid applications and services such as high-performance computing and visualization services provided by NASA s Information Power Grid (IPG) in the MSFC s Payload Operations Integration Center (POIC) HOSC Annex. Once the initial applications have been moved to the grid, a process will begin to apply the new programming paradigms to integrate them where possible. For example, with GViDS, instead of viewing the Distribution service as an application that must run on a single node, the new approach is to build it such that it can be dispatched across a pool of resources in response to dynamic loads. To make this a reality, reusable services will be critical, such as a brokering service to locate appropriate resource within the pool. This brokering service can then be used by other applications such as the TReK. To expand further, if the GViDS application is constructed using a services-based mel, then other applications such as the Video Auditorium can then use GViDS as a service to easily incorporate these video streams into a collaborative conference. Finally, as these applications are re-factored into this new services-based paradigm, the construction of portals to integrate them will be a simple process. As a result, portals can be tailored to meet the requirements of specific user communities.

Bradford, Robert N.

Development of the GEOS-MIT gcm Atmosphere-Ocean Model for Coupled Data Assimilation

During the last two plus decades, The Goddard Earth Observing System (GEOS) and Massachusetts Institute of Technology (MIT) modeling groups have developed, respectively, atmosphere-only and ocean-only global general circulation models. These two models (GEOS and MIT-GCM (General Circulation Model)) have demonstrated their data assimilation capabilities with the recent releases of the Modern Era Reanalysis for Research Applications, Version 2 (MERRA-2) atmospheric reanalysis and the Estimating the Circulation and Climate of the Ocean, Version 4 (ECCO-v4) ocean (and sea ice) state estimate. Independently, the two modeling groups have also produced global atmosphere-only and ocean-only simulations with km-scale grid spacing which proved invaluable for process studies and for the development of satellite and in-situ sampling strategies. Recently, a new effort has been made to couple these two models and to leverage their data-assimilation and high resolution capabilities (i.e., eddy-permitting ocean, cloud-permitting atmosphere). The focus in the model development is put on sub-seasonal to decadal time scales. In this talk, I discuss the new coupled model and present some first coupled simulation results. This will include a high-resolution coupled GEOS-MIT simulation, whereby we have coupled a cubed-sphere-720 (approximately 1/8 degrees) configuration of the GEOS atmosphere to a latitude-longitude-cap-1080 (approximately 1/12 degrees) configuration of the MIT ocean. We compare near-surface diagnostics of this fully coupled ocean-atmosphere set-up to equivalent atmosphere-only and ocean-only simulations. In the comparisons we focus in particular on the differences in air-sea interactions between sea surface temperature (SST) and wind for the coupled and uncoupled simulations.

Strobach, Ehud

The Development of the New GEOS-MITgcm Atmosphere-Ocean Model for Coupled Data Assimilation System

During the last two plus decades, The Goddard Earth Observing System (GEOS) and Massachusetts Institute of Technology (MIT) modeling groups have developed, respectively, atmosphere-only and ocean-only global general circulation models. These two models (GEOS and MITgcm) have demonstrated their data assimilation capabilities with the recent releases of the Modern Era Reanalysis for Research Applications, Version 2 (MERRA-2) atmospheric reanalysis and the Estimating the Circulation and Climate of the Ocean, Version 4 (ECCO-v4) ocean (and sea ice) state estimate. Independently, the two modeling groups have also produced global atmosphere-only and ocean-only simulations with km-scale grid spacing which proved invaluable for process studies and for the development of satellite and in-situ sampling strategies.Recently, a new effort has been made to couple these two models and to leverage their data-assimilation and high resolution capabilities (i.e., eddy-permitting ocean, cloud-permitting atmosphere). The focus in the model development is put on sub-seasonal to decadal time scales. In this talk, I discuss the new coupled model and present some first coupled simulation results. This will include a high-resolution coupled GEOS-MIT simulation, whereby we have coupled a cubed-sphere-720 (~ 1/8 deg) configuration of the GEOS atmosphere to a lat-lon-cap-1080 (~ 1/12 deg) configuration of the MIT ocean. We compare near-surface diagnostics of this fully coupled ocean-atmosphere set-up to equivalent atmosphere-only and ocean-only simulations. In the comparisons we focus in particular on the differences in air-sea interactions between sea surface temperature (SST) and wind for the coupled and uncoupled simulations.

Strobach, Ehud

A New Atmosphere-Ocean Model for Studying Air-Sea Interactions and Coupled Data Assimilation

During the last two plus decades, The Goddard Earth Observing System (GEOS) and Massachusetts Institute of Technology (MIT) modeling groups have developed, respectively, atmosphere-only and ocean-only global general circulation models. These two models (GEOS and MITgcm) have demonstrated their data assimilation capabilities with the recent releases of the Modern Era Reanalysis for Research Applications, Version 2 (MERRA-2) atmospheric reanalysis and the Estimating the Circulation and Climate of the Ocean, Version 4 (ECCO-v4) ocean (and sea ice) state estimate. Independently, the two modeling groups have also produced global atmosphere-only and ocean-only simulations with km-scale grid spacing which proved invaluable for process studies and for the development of satellite and in-situ sampling strategies.Recently, a new effort has been made to couple these two models and to leverage their data-assimilation and high resolution capabilities (i.e., eddy-permitting ocean, cloud-permitting atmosphere). The focus in the model development is put on sub-seasonal to decadal time scales. In this talk, I discuss the new coupled model and present some first coupled simulation results. This will include a high-resolution coupled GEOS-MIT simulation, whereby we have coupled a cubed-sphere-720 (~ 1/8°) configuration of the GEOS atmosphere to a lat-lon-cap-1080 (~ 1/12°) configuration of the MIT ocean. We compare near-surface diagnostics of this fully coupled ocean-atmosphere set-up to equivalent atmosphere-only and ocean-only simulations. In the comparisons we focus in particular on the differences in air-sea interactions between sea surface temperature (SST) and wind for the coupled and uncoupled simulations.

Strobach, Ehud

The Development of the New GEOS-MITgcm Atmosphere-Ocean Model for Coupled Data Assimilation System

During the last two plus decades, The Goddard Earth Observing System (GEOS) and Massachusetts Institute of Technology (MIT) modeling groups have developed, respectively, atmosphere-only and ocean-only global general circulation models. These two models (GEOS and MITgcm) have demonstrated their data assimilation capabilities with the recent releases of the Modern Era Reanalysis for Research Applications, Version 2 (MERRA-2) atmospheric reanalysis and the Estimating the Circulation and Climate of the Ocean, Version 4 (ECCO-v4) ocean (and sea ice) state estimate. Independently, the two modeling groups have also produced global atmosphere-only and ocean-only simulations with km-scale grid spacing which proved invaluable for process studies and for the development of satellite and in-situ sampling strategies.Recently, a new effort has been made to couple these two models and to leverage their data-assimilation and high resolution capabilities (i.e., eddy-permitting ocean, cloud-permitting atmosphere). The focus in the model development is put on sub-seasonal to decadal time scales. In this talk, I discuss the new coupled model and present some first coupled simulation results. This will include a high-resolution coupled GEOS-MIT simulation, whereby we have coupled a cubed-sphere-720 (~ 1/8°) configuration of the GEOS atmosphere to a lat-lon-cap-1080 (~ 1/12°) configuration of the MIT ocean. We compare near-surface diagnostics of this fully coupled ocean-atmosphere set-up to equivalent atmosphere-only and ocean-only simulations. In the comparisons we focus in particular on the differences in air-sea interactions between sea surface temperature (SST) and wind for the coupled and uncoupled simulations.

Strobach, Ehud

The composite classification problem in optical information processing

Optical pattern recognition allows objects to be recognized from their images and permits their positional parameters to be estimated accurately in real time. The guiding principle behind optical pattern recognition is that a lens focusing a beam of coherent light modulated with an image produces the two-dimensinal Fourier transform of that image. When the resulting output is further transformed by the matched filter corresponding to the original image, one obtains the autocorrelation function of the original image, which has a peak at the origin. Such a device is called an optical correlator and may be used to recognize the locate the image for which it is designed. (From a practical perspective, an approximation to the matched filter must be used since the spatial light modulator (SLM) on which the filter is implemented usually does not allow one to independently control both the magnitude and phase of the filter.) Generally, one is not just concerned with recognizing a single image but is interested in recognizing a variety of rotated and scaled views of a particular image. In order to recognize these different views using an optical correlator, one may select a subset of these views (whose elements are called training images) and then use a composite filter that is designed to produce a correlation peak for each training image. Presumably, these peaks should be sharp and easily distinguishable from the surrounding correlation plane values. In this report we consider two areas of research regarding composite optical correlators. First, we consider the question of how best to choose the training images that are used to design the composite filter. With regard to quantity, the number of training images should be large enough to adequately represent all possible views of the targeted object yet small enough to ensure that the resolution of the filter is not exhausted. As for the images themselves, they should be distinct enough to avoid numerical difficulties yet similar enough to avoid gaps in which certain views of the target will be unrecognized. One method that we introduce to study this problem is called probing and involves the creation of the artificial imagery. The second problem we consider involves the clasification of the composite filter's correlation plane data. In particular, we would like to determine not only whether or not we are viewing a training image, but, in the former case, we would like to determine which training image is being viewed. This second problem is investigated using traditional M-ary hypothesis testing techniques.

Hall, Eric B.

The ground processing simulator - A tool for mission model analysis and planning from a launch site perspective

The Ground Processing Simulator (GPS) is a computer-assisted planning tool designed and developed for Space Shuttle launch site application. Utilizing two programming languages, General Purpose Simulation System and FORTRAN, GPS provides the capability to analyze proposed Shuttle mission models via computer simulation. NASA-developed mission models which specify Shuttle launch rates, mission durations, cargo elements, and designated launch site are tested for feasibility by the simulator. GPS produces facility utilization schedules (including the identification of conflicts), launch data options, cargo element requirement dates, ground support equipment inventory requirements, and other data necessary to assess both the programmatic and launch site resources required to support proposed mission models. The purpose of this computer-assisted analysis is to determine methods which will permit the launching of the maximum number of cargoes per year on schedule, and in the sequence desired, with the minimum expenditure of resources.

Ralph, J. A.

Magnetic Damping of Solid Solution Semiconductor Alloys

The objective of this study is to: (1) experimentally test the validity of the modeling predictions applicable to the magnetic damping of convective flows in electrically conductive melts as this applies to the bulk growth of solid solution semiconducting materials; and (2) assess the effectiveness of steady magnetic fields in reducing the fluid flows occurring in these materials during processing. To achieve the objectives of this investigation, we are carrying out a comprehensive program in the Bridgman and floating-zone configurations using the solid solution alloy system Ge-Si. This alloy system has been studied extensively in environments that have not simultaneously included both low gravity and an applied magnetic field. Also, all compositions have a high electrical conductivity, and the materials parameters permit reasonable growth rates. An important supporting investigation is determining the role, if any, that thermoelectromagnetic convection (TEMC) plays during growth of these materials in a magnetic field. TEMC has significant implications for the deployment of a Magnetic Damping Furnace in space. This effect will be especially important in solid solutions where the growth interface is, in general, neither isothermal nor isoconcentrational. It could be important in single melting point materials, also, if faceting takes place producing a non-isothermal interface. In conclusion, magnetic fields up to 5 Tesla are sufficient to eliminate time-dependent convection in silicon floating zones and possibly Bridgman growth of Ge-Si alloys. In both cases, steady convection appears to be more significant for mass transport than diffusion, even at 5 Tesla in the geometries used here. These results are corroborated in both growth configurations by calculations.

Szofran, Frank R.

Modeling Oxidative Dehydrogenation of Propane with Supported Vanadia Catalysts Using Multireference Methods

The oxidative dehydrogenation of propane over supported vanadium oxide catalysts poses significant computational challenges due to complex electronic structure changes along the reaction coordinate, driven primarily by changes in the oxidation states of vanadium. To address these challenges, we systematically test quantum chemical methods, including multireference (MR) approaches, domain-based local pair natural orbital coupled cluster theory (DLPNO-CCSD(T)), and density functional theory (DFT). The initial C–H bond-breaking transition state requires MR treatment due to its multireference character, while subsequent steps permit efficient single-reference calculations. For the rate-limiting C–H activation step mediated by the vanadyl moiety, complete 1 active space second-order perturbation theory (CASPT2) yields an apparent activation barrier (E app 600K ) of 138 kJ/mol, consistent with experimental values (134 ± 4 kJ/mol; Gruene et al. Catal. Today 2010, 157, 137). In contrast, DLPNO-CCSD(T) overestimates this barrier (198 kJ/mol), whereas DFT predictions span 125–150 kJ/mol, depending on the functional. Our multireference investigation of this transition metal oxide-catalyzed process demonstrates that an active space that incorporates the C–H σ and V=O σ/π bonding orbitals, oxygen lone pairs, and their antibonding counterparts adequately captures electronic structure changes along the chemical transformation. Furthermore, these findings provide a general strategy for active space selection in transition metal oxide-catalyzed C/O–H bond activation reactions. The reference dataset from this work, which includes MR calculations with manually selected active spaces for all intermediates and transition states in the propane ODH reaction network, will serve as a benchmark for automating active space selection in similar systems.

Catalysts

Investigating Extreme Events in the NASA GEOS Multiscale Modeling System

Advances in computing capabilities and scientific development have come together to evolve general circulation models into multi-scale Earth system modeling tools. The Goddard Earth Observing System (GEOS) model is one such example of this evolution. The GEOS model is driven by the finite-volume cubed-sphere (FV3) non-hydrostatic dynamical core. Surrounding FV3 is a scale-aware physics package and data assimilation capability permitting multi-scale application of GEOS for sub-seasonal to seasonal climate prediction, medium range weather prediction, and global mesoscale modeling at convection allowing resolutions. GEOS also includes a comprehensive chemistry package representing a range of capabilities from basic chemistry and interactve aerosols and gaseous species, to carbon emissions and uptake, and complex ozone photochemistry. In this study, we apply the GEOS model to study the fidelity of these processes with increasing horizontal resolution and scale-aware processes in GEOS on extreme events. The GEOS model is run for 40-days beginning in August 2016 at three uniform global resolutions of 13-km (c768), 6-km (c1536) and 3-km (c3072) with 72 vertical levels up to 0.01mb. The model physics use the Grell-Freitas scale-aware convection scheme to dynamically reduce the role of parameterized deep convection as resolved scale processes in the model take over at higher resolutions. We will include high-resolution global emissions and fluxes of aerosols and carbon downscaled from recent satellite observations. We will compare these simulations with reanalyses and observations, focusing on rainfall, clouds and radiative forcing at hourly to monthly timescales. We will closely examine the probability distribution of precipitation intensities and radiative properties of clouds on a daily time scale. In addition, we will focus on extreme events, in particular the diurnal cycle of convection over the US and the frequency and physical nature of organized convection and heavy rain events across the globe.

Putman, William

A Quantitative Study of Oxygen as a Metabolic Regulator

An acute reduction in oxygen (O2) delivery to a tissue is generally associated with a decrease in phosphocreatine, increases in ADP, NADH/NAD, and inorganic phosphate, increased rates of glycolysis and lactate production, and reduced rates of pyruvate and fatty acid oxidation. However, given the complexity of the human bioenergetic system and its components, it is difficult to determine quantitatively how cellular metabolic processes interact to maintain ATP homeostasis during stress (e.g., hypoxia, ischemia, and exercise). Of special interest is the determination of mechanisms relating tissue oxygenation to observed metabolic responses at the tissue, organ, and whole body levels and the quantification of how changes in tissue O2 availability affect the pathways of ATP synthesis and the metabolites that control these pathways. In this study, we extend a previously developed mathematical model of human bioenergetics to provide a physicochemical framework that permits quantitative understanding of O2 as a metabolic regulator. Specifically, the enhancement permits studying the effects of variations in tissue oxygenation and in parameters controlling the rate of cellular respiration on glycolysis, lactate production, and pyruvate oxidation. The whole body is described as a bioenergetic system consisting of metabolically distinct tissue/organ subsystems that exchange materials with the blood. In order to study the dynamic response of each subsystem to stimuli, we solve the ordinary differential equations describing the temporal evolution of metabolite levels, given the initial concentrations. The solver used in the present study is the packaged code LSODE, as implemented in the NASA Lewis kinetics and sensitivity analysis code, LSENS. A major advantage of LSENS is the efficient procedures supporting systematic sensitivity analysis, which provides the basic methods for studying parameter sensitivities (i.e., changes in model behavior due to parameter variation). Sensitivity analysis establishes relationships between model predictions and problem parameters (i.e., initial concentrations, rate coefficients, etc). It helps determine the effects of uncertainties or changes in these input parameters on the predictions, which ultimately are compared with experimental observations in order to validate the model. Sensitivity analysis can identify parameters that must be determined accurately because of their large effect on the model predictions and parameters that need not be known with great precision because they have little or no effect on the solution. This capability may prove to be important in optimizing the design of experiments, thereby reducing the use of animals. This approach can be applied to study the metabolic effects of reduced oxygen delivery to cardiac muscle due to local myocardial ischemia and the effects of acute hypoxia on brain metabolism. Other important applications of sensitivity analysis include identification of quantitatively relevant pathways and biochemical species within an overall mechanism, when examining the effects of a genetic anomaly or pathological state on energetic system components and whole system behavior.

Radhakrishnan, Krishnan

The Origins and Evolution of Molecules in Icy Solids

Astronomical observations of the past few decades have revealed the existence of a variety of molecules in extraterrestrial ices. These molecules include H2O, CO, and CO2, and organics such as CH4, CH30H, and C2H6. Some ices are dominated by polar molecules, while non-polar species appear to dominate others. Observations, mainly in the radio and IR regions, have allowed the inference of other solid-phase molecules whose formation remains difficult to explain by gas-phase chemistry alone. Several laboratory research groups have reported on extensive experiments on the solid-phase reaction chemistry of icy materials, generally as initiated by either ionizing radiation or vacuum-UV photons. These experiments not only permit molecular identifications to be made from astronomical observations, but also allow predictions of yet unidentified molecules. This laboratory approach has evolved over more than 30 years with much of the earliest work focusing on complex mixtures thought to represent either cometary or interstellar ices. Although those early experiments documented a rich solid-state photo- and radiation chemistry, they revealed few details of reactions for particular molecules, partly due to the multi-component nature of the samples. Since then, model systems have been examined that allow the chemistry of individual species and specific reactions to be probed. Reactions involving most of the smaller astronomical molecules have now been studied and specific processes identified. Current laboratory work suggests that a variety of reactions occur in extraterrestrial ices, including acid-base processes, radical dimerizations, proton transfers, oxidations, reductions, and isomerizations. This workshop presentation will focus on chemical reactions relevant to solar system and interstellar ices. While most of the work will be drawn from that to which the speaker has contributed, results from other laboratories also will be included. Suggestions for future studies will be made, with an emphasis on some present deficiencies. The speaker's work has been generously supported by these NASA research programs: Cassini Data Analysis, Exobiology, Mars Fundamental Research, Outer Planets Research, Planetary Atmospheres, Planetary Geology and Geophysics, and the NASA Astrobiology Institute.

Hudson, Reggie L.

Development of Long-Lifetime Pulsed Gas Valves for Pulsed Electric Thrusters

It is advantageous for gas-fed pulsed electric thrusters to employ pulsed valves so propellant is only flowing to the device during operation. The propellant utilization of the thruster will be maximized when all the gas injected into the thruster is acted upon by the fields produced by the electrical pulse. Gas that is injected too early will diffuse away from the thruster before the electrical pulse can act to accelerate the propellant. Gas that is injected too late will miss being accelerated by the already-completed electrical pulse. As a consequence, the valve must open quickly and close equally quickly, only remaining open for a short duration. In addition, the valve must have only a small amount of volume between the sealing body and the thruster so the front and back ends of the pulse are as coincident as possible with the valve cycling, with very little latent propellant remaining in the feed lines after the valve is closed. For a real mission of interest, a pulsed thruster can be expected to pulse at least 10(exp 10) - 10(exp 11) times, setting the range for the number of times a valve must open and close. The valves described in this paper have been fabricated and tested for operation in an inductive pulsed plasma thruster (IPPT) for in-space propulsion. In general, an IPPT is an electrodeless space propulsion device where a capacitor is charged to an initial voltage and then discharged, producing a high-current pulse through a coil. The field produced by this pulse ionizes propellant, inductively driving current in a plasma located near the face of the coil. Once the plasma is formed, it can be accelerated and expelled at a high exhaust velocity by the electromagnetic Lorentz body force arising from the interaction of the induced plasma current and the magnetic field produced by the current in the coil. The valve characteristics needed for the IPPT application require a fast-acting valve capable of a minimum of 10(exp 10) valve actuation cycles. Since even 10(exp 9) cycles is well above anything demonstrated, this lower value was selected as the design point for the present work. The valve seal must remain leak-tight throughout operation, and the body must maintain a low internal leakage at relatively high operating temperatures. The full set of design requirements used for this program are summarized in Table 1. In this work, we describe two pulsed gas valves that have been fabricated to have long lifetime and demonstrate the characteristics listed above. The first is a miniaturized, conventional electromagnet-based valve while the second is a piezoelectric-based valve design. The conventional valve, shown in Fig. 1, is opened by use of a solenoid electromagnetic actuator. When current is applied to the solenoid coil, magnetic forces pull the plunger away from the valve seat, allowing fluid to flow through the valve. Removal of electrical current permits the spring and fluid pressure to seat the plunger, halting the flow of fluid. The valve body is fabricated from 304L corrosion resistant steel (CRES) and while the parts that form the magnetic circuit are fabricated from 430 CRES. This material does not have optimum magnetic properties, but its corrosion resistance permits incorporation into a design without requiring an additional plating process. A viton O-ring compound (Parker V0884-75), selected for its mechanical strength at elevated temperatures, was used for the valve seat seal. The design was based solely on the use of analytical sizing calculations, as opposed to a more rigorous finite element analysis. While this valve is small and relatively lightweight, it does not represent a design that is optimized for mass and/or a given volume envelope. The piezoelectric valve is a "puller" valve design. Applying a voltage to the piezo crystal causes it to elongate and pull a pintle off the seat, opening the valve. The valve seal consists of the pintle with an external, spherically-formed tip fabricated from Inconel 625 and the seat fabricated from Inconel 718 and possessing a spherical surface that permits the pintle to align with the valve body centerline after each cycle, maintaining the circumferential metal-on-metal seal. The contact stress on the valve pintle is expected in the worst case to be 96.5 MPa (14 ksi), which is well below the work hardening value of 413.7 MPa (60 ksi) for Inconel 615. Results presented in this work will compare the performance of each valve, both to each other and to the valve design requirements given in Table 1. In general, both valves meet all the performance envelope requirements, but the piezoelectric valve consumes considerably less power and has a faster response time over the conventional solenoid-driven valves.

Burkhardt, Wendel M.

An internal variable constitutive model for the large deformation of metals at high temperatures

The advent of large deformation finite element methodologies is beginning to permit the numerical simulation of hot working processes whose design until recently has been based on prior industrial experience. Proper application of such finite element techniques requires realistic constitutive equations which more accurately model material behavior during hot working. A simple constitutive model for hot working is the single scalar internal variable model for isotropic thermal elastoplasticity proposed by Anand. The model is recalled and the specific scalar functions, for the equivalent plastic strain rate and the evolution equation for the internal variable, presented are slight modifications of those proposed by Anand. The modified functions are better able to represent high temperature material behavior. The monotonic constant true strain rate and strain rate jump compression experiments on a 2 percent silicon iron is briefly described. The model is implemented in the general purpose finite element program ABAQUS.

Brown, Stuart