Search NASA⌕ Search

SEARCH · Search NASA

Results for “hydrogen detection”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 127 records · Page 7

Near-infrared observations of the proto-planetary nebula AFGL 618

Near-IR images and spectroscopy of the bipolar protoplanetary nebula AFGL 618 are presented. Emission from molecular hydrogen is detected in the 0.90-1.34-micron spectrum. A visual extinction of 3.4 +4.0/-2.0 mag to the H2-emitting region is derived from molecular hydrogen line ratios. Models of collisionally excited and fluorescent H2 emission are compared with the data: the near-IR H2 spectrum is found to be dominated by emission from collisionally excited molecules at Tex of about 2000 K, but a component of fluorescent emission is also present. It is shown that this type of near-IR spectrum is an excellent tool for discriminating relatively low levels of fluorescent H2 emission from a strong collisionally excited component. Images in the H- and K-bandpasses are analyzed using models which assume single scattering of photons from the central objects. The models indicate that the bipolar axis is inclined to the plane of the sky by about 45 deg. The emission in the H- and K-bands is found to be consistent with single scattering of photons by dust with a distribution such that the dust density increases with increasing stellar latitude and is nearly zero at the poles.

Latter, William B.↗

Detection of interstellar pick-up hydrogen in the solar system

Interstellar hydrogen ionized primarily by the solar wind has been detected by the Solar Wind Ion Composition Spectrometer instrument on the Ulysses spacecraft at a distance of 4.8 AUs from the sun. This 'pick-up' hydrogen is identified by its distinct velocity distribution function, which drops abruptly at twice the local solar wind speed. From the measured fluxes of pick-up protons and singly charged helium, the number densities of neutral hydrogen and helium in the distant regions of the solar system are estimated to be 0.077 +/- 0.015 and 0.013 +/- 0.003 per cu cm, respectively.

Gloeckler, G.↗

Molecular hydrogen in H II region transition zones

Model calculations are performed which demonstrate that H II - H I transition zones with densities between 10 and 100 per cu cm may contain molecular-hydrogen column densities of the order of 10 to the 13th power to 10 to the 15th power per sq cm. Observational data for several stars are presented which confirm the theoretical values. It is concluded that all detectable molecular hydrogen is not necessarily located in cold regions of space.

Hill, J. K.↗

The Development of Silicon Carbide Based Hydrogen and Hydrocarbon Sensors

Silicon carbide is a high temperature electronic material. Its potential for development of chemical sensors in a high temperature environment has not been explored. The objective of this study is to use silicon carbide as the substrate material for the construction of chemical sensors for high temperature applications. Sensors for the detection of hydrogen and hydrocarbon are developed in this program under the auspices of Lewis Research Center, NASA. Metal-semiconductor or metal-insulator-semiconductor structures are used in this development. Specifically, using palladium-silicon carbide Schottky diodes as gas sensors in the temperature range of 100 to 400 C are designed, fabricated and assessed. The effect of heat treatment on the Pd-SiC Schottky diode is examined. Operation of the sensors at 400 C demonstrate sensitivity of the sensor to hydrogen and hydrocarbons. Substantial progress has been made in this study and we believe that the Pd-SiC Schottky diode has potential as a hydrogen and hydrocarbon sensor over a wide range of temperatures. However, the long term stability and operational life of the sensor need to be assessed. This aspect is an important part of our future continuing investigation.

Liu, Chung-Chiun↗

Type IA Supernovae

Spectral calculations show that a model based on the thermonuclear explosion of a degenerate carbon/oxygen white dwarf provides excellent agreement with observations of Type Ia supernovae. Identification of suitable evolutionary progenitors remains a severe problem. General problems with estimation of supernova rates are outlined and the origin of Type Ia supernovae from double degenerate systems are discussed in the context of new rates of explosion per H band luminosity, the lack of observed candidates, and the likely presence of H in the vicinity of some SN Ia events. Re-examination of the problems of triggering Type Ia by accretion of hydrogen from a companion shows that there may be an avenue involving cataclysmic variables, especially if extreme hibernation occurs. Novae may channel accreting white dwarfs to a unique locus in accretion rate/mass space. Systems that undergo secular evolution to higher mass transfer rates could lead to just the conditions necessary for a Type Ia explosion. Tests involving fluorescence or absorption in a surrounding circumstellar medium and the detection of hydrogen stripped from a companion, which should appear at low velocity inside the white dwarf ejecta, are suggested. Possible observational confirmation of the former is described.

Wheeler, J. Craig↗

Using silicon diodes for detecting the liquid-vapor interface in hydrogen

Tests were performed using commercially available silicon diode temperature sensors to detect the location of the liquid-vapor interface in hydrogen during ground test programs. Results show that by increasing the current into the sensor, silicon diodes can be used as liquid level point sensors. After cycling the sensors from liquid to vapor several times, it was found that with a 30 mA (milliamps) input current, the sensors respond within 2 seconds by measuring a large voltage difference when transitioning from liquid to vapor across the interface. Nearly instantaneous response resulted during a transition form vapor to liquid. Detailed here are test procedures, experimental results, and guidelines for applying this information to other test facilities.

Dempsey, Paula J.↗

Using silicon diodes for detecting the liquid-vapor interface in hydrogen

Tests were performed using commercially available silicon diode temperature sensors to detect the location of the liquid-vapor interface in hydrogen during ground test programs. Results show that by increasing the current into the sensor, silicon diodes can be used as liquid level point sensors. After cycling the sensors from liquid to vapor several times, it was found that with a 30 mA (milliamps) input current, the sensors respond within 2 seconds by measuring a large voltage difference when transitioning from liquid to vapor across the interface. Nearly instantaneous response resulted during a transition from vapor to liquid. Detailed here are test procedures, experimental results, and guidelines for applying this information to other test facilities.

Dempsey, Paula J.↗

The use of the ion probe mass spectrometer in the measurement of hydrogen concentration gradients in Monel K 500

The ion probe mass spectrometer was used to measure hydrogen concentration gradients in cathodically charged Monel K 500. Initial work with the ion probe involved the calibration of the instrument and the establishment of a suitable experimental procedure for this application. Samples of Monel K 500 were cathodically charged in a weak sulfuric acid solution. By varying the current density, different levels of hydrogen were introduced into the samples. Hydrogen concentration gradients were taken by ion sputtering on the surface of these samples and monitoring the behavior of the hydrogen mass peak as a function of time. An attempt was made to determine the relative amounts of hydrogen in the bulk and grain boundaries by analyzing a fresh fracture surface with a higher proportion of grain boundary area. It was found that substantially more hydrogen was detected in the grain boundaries than in the bulk, confirming the predictions of previous workers. A sputter rate determination was made in order to establish the rate of erosion.

Truhan, J. J., Jr.↗

Mass-dependent channel electron multiplier operation

The absolute counting efficiency and pulse height distributions of a continuous-channel electron multiplier used in the detection of hydrogen, argon and xenon ions are assessed. The assessment technique, which involves the post-acceleration of 8-eV ion beams to energies from 100 to 4000 eV, provides information on counting efficiency versus post-acceleration voltage characteristics over a wide range of ion mass. The charge pulse height distributions for H2 (+), A (+) and Xe (+) were measured by operating the experimental apparatus in a marginally gain-saturated mode. It was found that gain saturation occurs at lower channel multiplier operating voltages for light ions such as H2 (+) than for the heavier ions A (+) and Xe (+), suggesting that the technique may be used to discriminate between these two classes of ions in electrostatic analyzers.

Fields, S. A.↗

High-resolution X-ray spectroscopy of M87 with the Einstein observatory - The detection of an O VIII emission line

The paper deals with high-resolution X-ray spectroscopy performed to study the extended source surrounding the giant elliptical galaxy, M87, in the Virgo cluster. From observations carried out with a focal plane crystal spectrometer, L-alpha emission was detected from hydrogenic oxygen (O VIII). Upper limits could be set on lines from intermediate ionization states of iron. The presence of a quantity of cooler matter surrounding M87 was revealed, which has important implications for cluster models and favors a radiatively controlled accretion mechanism.

Canizares, C. R.↗

A near-infrared spectroscopic study of the starburst core of M82

Near-IR spectroscopy of the M82 starburst core is presented, including complete J, H, and K band spectra with a resolution of 0.0035-micron for the inner 60 pc of the galaxy. Also, spatial profiles along the starburst ridge are presented for Br-gamma, molecular hydrogen, and forbidden Fe II line fluxes. Emission from shocked molecular hydrogen is detected from the core of M82. The distribution of features across the starburst disk are mapped to study the relationships between spectral diagnostics. The observations are used to test the appropriateness of single-beam, aggregate models for studying the physical conditions in starbursts.

Lester, D. F.↗

Spectroscopic Evidence for Interstellar Ice in Comet Hyakutake

Volatile compounds in comets are the most pristine materials surviving from the time of formation of the Solar System, and thus potentially provide information about conditions that prevailed in the primitive solar material. Moreover, comets may have supplied a substantial fraction of the volatiles on the terrestrial planets, perhaps including organic compounds that played a role in the origin of life on Earth. Here we report the detection of hydrogen isocyanide (HNC) in comet Hyakutake. The abundance of HNC relative to hydrogen cyanide (HCN) is very similar to that observed in quiescent interstellar molecular clouds, and quite different from the equilibrium ratio expected in the outermost solar nebula, where comets are thought to form. Such a departure from equilibrium has long been considered a hallmark of gas-phase chemical processing in the interstellar medium, suggesting that interstellar gases have been incorporated into the comet's nucleus, perhaps as ices frozen onto interstellar grains. If this interpretation is correct, our results should provide constraints on the temperature of the solar nebula, and the subsequent chemical processes that occurred in the region where comets formed.

Irvine, W. M.↗

SiC-Based Gas Sensors

Electronic grade Silicon Carbide (SiC) is a ceramic material which can operate as a semiconductor at temperatures above 600 C. Recently, SiC semiconductors have been used in Schottky diode gas sensor structures. These sensors have been shown to be functional at temperatures significantly above the normal operating range of Si-based devices. SiC sensor operation at these higher temperatures allows detection of gases such as hydrocarbons which are not detectable at lower temperatures. This paper discusses the development of SiC-based Schottky diode gas sensors for the detection of hydrogen, hydrocarbons, and nitrogen oxides (NO(x)). Sensor designs for these applications are discussed. High sensitivity is observed for the hydrogen and hydrocarbon sensors using Pd on SiC Schottky diodes while the NO(x) sensors are still under development. A prototype sensor package has been fabricated which allows high temperature operation in a room temperature ambient by minimizing heat loss to that ambient. It is concluded that SiC-based gas sensors have considerable potential in a variety of gas sensing applications.

Chen, Liang-Yu↗

Volcanic Degassing of Hydrogen Compounds on Io

Thermodynamic calculations show that hydrogen, recently detected in Io's ionosphere by the Galileo spacecraft, can degas from high-temperature silicate magmas on Io in the form of H2O, H2S, HS, NaOH, H2, KOH, and HCl in order of decreasing abundance.

Zolotov, M. Yu.↗

Making Visible the Invisible

Duncan Technologies, Inc., (DTI) developed an infrared imaging system for detection of hydrogen flames in the Space Shuttle Main Engines. The product is the result of a NASA Small Business Innovation Research (SBIR) award from the Stennis Space Center.

Source record↗

Spectroscopic evidence for interstellar ices in comet Hyakutake

Volatile compounds in comets are the most pristine materials surviving from the time of formation of the Solar System, and thus potentially provide information about conditions that prevailed in the primitive solar nebula. Moreover, comets may have supplied a substantial fraction of the volatiles on the terrestrial planets, perhaps including organic compounds that played a role in the origin of life on Earth. Here we report the detection of hydrogen isocyanide (HNC) in comet Hyakutake. The abundance of HNC relative to hydrogen cyanide (HCN) is very similar to that observed in quiescent interstellar molecular clouds, and quite different from the equilibrium ratio expected in the outermost solar nebula, where comets are thought to form. Such a departure from equilibrium has long been considered a hallmark of gas-phase chemical processing in the interstellar medium, suggesting that interstellar gases have been incorporated into the comet's nucleus, perhaps as ices frozen onto interstellar grains. If this interpretation is correct, our results should provide constraints on the temperature of the solar nebula, and the subsequent chemical processes that occurred in the region where comets formed.

Non-NASA Center↗