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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Source:sink imbalance detected with leaf and canopy-level spectroscopy in a field-grown crop

The finely-tuned balance between sources and sinks determines plant resource partitioning and regulates growth and development. Understanding and measuring metabolic indicators of source or sink limitation forms a vital part of global efforts to increase crop yield for future food security. Here, we measured metabolic profiles of Cucurbita pepo (zucchini) grown in the field under carbon sink limitation and control conditions. We demonstrate that these profiles can be measured non-destructively using hyperspectral reflectance at both leaf and canopy scales. Total non-structural carbohydrates (TNC) increased 82% in sink-limited plants; leaf mass per unit area (LMA) increased 38%; free amino acids increased 22%. Partial least-squares regression models link these measured functional traits with reflectance data, enabling high-throughput estimation of traits comprising the sink limitation response. Leaf- and canopy-scale models for TNC had R 2 values of 0.93 and 0.64 and %RMSE of 13% and 38% respectively. For LMA, R 2 values were 0.91 and 0.60 and %RMSE 7% and 14%; for free amino acids, R 2 was 0.53 and 0.21 with %RMSE 20% and 26%. Remote sensing can enable accurate, rapid detection of sink limitation in the field at the leaf and canopy scale, greatly expanding our ability to understand and measure metabolic responses to stress.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Spectroscopic pressure investigation of a novel high energy system

This work here combines a novel multimodal spectroscopic technique, O–PTIR and Raman spectroscopy, which allows for the simultaneous collection of infrared and Raman spectra, with traditional diamond anvil cell techniques to explore pressure induced phase transitions in a high energy material. Two phase transitions are revealed, with the first transition emerging below 0.23 GPa, to a higher order phase, followed by a broad transition to a lower order phase. Aside from the pressure studies, hyperspectral imaging was performed, confirming the homogeneous nature of the system.

36 MATERIALS SCIENCE↗
NASA NTRS2009

Thermal Infrared Spectral Imager for Airborne Science Applications

An airborne thermal hyperspectral imager is under development which utilizes the compact Dyson optical configuration and quantum well infrared photo detector (QWIP) focal plane array. The Dyson configuration uses a single monolithic prism-like grating design which allows for a high throughput instrument (F/1.6) with minimal ghosting, stray-light and large swath width. The configuration has the potential to be the optimal imaging spectroscopy solution for lighter-than-air (LTA) vehicles and unmanned aerial vehicles (UAV) due to its small form factor and relatively low power requirements. The planned instrument specifications are discussed as well as design trade-offs. Calibration testing results (noise equivalent temperature difference, spectral linearity and spectral bandwidth) and laboratory emissivity plots from samples are shown using an operational testbed unit which has similar specifications as the final airborne system. Field testing of the testbed unit was performed to acquire plots of apparent emissivity for various known standard minerals (such as quartz). A comparison is made using data from the ASTER spectral library.

QWIP↗
DOE OSTI2025

Using Neural Networks to Identify Mixture Components in Hyperspectral Reflectance Data

Neural networks have been employed to identify materials of interest from hyperspectral data (generally imagery) based on their unique spectral signatures. This approach assumes that there is a single material that is standing out from the rest of the spectrum to be identified. However, pixels often contain more than one material, or a material of interest may itself be a mixture of multiple materials. Neural networks are only as good as the data used to train them, and it takes a great deal of work in the laboratory to identify, make, and measure all potential mixtures of interest. Thus, researchers often calculate synthetic spectra using algorithms with varying degrees of fidelity to the physics that govern the interactions between light and multiple materials. In this work, we have (1) adapted a neural network designed to identify mixture components from Raman spectroscopy to work with visible to near‐infrared reflectance data and (2) tested three common mixture algorithms to determine the most accurate and least computationally expensive method to build synthetic training datasets. With our initial test dataset, we have achieved accuracies of > 90% and found that the synthetic training dataset produced using the Hapke mixture model provides the best results.

99 GENERAL AND MISCELLANEOUS↗
NASA NTRS2012

The HYSPIRI Decadal Survey Mission: Update on the Mission Concept and Science Objectives for Global Imaging Spectroscopy and Multi-Spectral Thermal Measurements

The NASA HyspIRI mission is planned to provide global solar reflected energy spectroscopic measurement of the terrestrial and shallow water regions of the Earth every 19 days will all measurements downlinked. In addition, HyspIRI will provide multi-spectral thermal measurements with a single band in the 4 micron region and seven bands in the 8 to 12 micron region with 5 day day/night coverage. A direct broadcast capability for measurement subsets is also planned. This HyspIRI mission is one of those designated in the 2007 National Research Council (NRC) Decadal Survey: Earth Science and Applications from Space. In the Decadal Survey, HyspIRI was recognized as relevant to a range of Earth science and science applications, including climate: "A hyperspectral sensor (e.g., FLORA) combined with a multispectral thermal sensor (e.g., SAVII) in low Earth orbit (LEO) is part of an integrated mission concept [described in Parts I and II] that is relevant to several panels, especially the climate variability panel." The HyspIRI science study group was formed in 2008 to evaluate and refine the mission concept. This group has developed a series of HyspIRI science objectives: (1) Climate: Ecosystem biochemistry, condition & feedback; spectral albedo; carbon/dust on snow/ice; biomass burning; evapotranspiration (2) Ecosystems: Global plant functional types, physiological condition, and biochemistry including agricultural lands (3) Fires: Fuel status, fire frequency, severity, emissions, and patterns of recovery globally (4) Coral reef and coastal habitats: Global composition and status (5) Volcanoes: Eruptions, emissions, regional and global impact (6) Geology and resources: Global distributions of surface mineral resources and improved understanding of geology and related hazards These objectives are achieved with the following measurement capabilities. The HyspIRI imaging spectrometer provides: full spectral coverage from 380 to 2500 at 10 nm sampling; 60 m spatial sampling with a 150 km swath; and fully downlinked coverage of the Earth's terrestrial and shallow water regions every 19 days to provide seasonal cloud-free coverage of the terrestrial surface. The HyspIRI Multi-Spectral Thermal instrument provides: 8 spectral bands from 4 to 12 microns; 60 m spatial sampling with a 600 km swath; and fully downlinked coverage of the Earth's terrestrial shallow water regions every 5 days (day/night) to provide nominally cloud-free monthly coverage. The HyspIRI mission also includes an on-board processing and direct broadcast capability, referred to as the Intelligent Payload Module (IPM), which will allow users with the appropriate antenna to download a subset of the HyspIRI data stream to a local ground station. These science and science application objectives are critical today and uniquely addressed by the combined imaging spectroscopy, thermal infrared measurements, and IPM direct broadcast capability of HyspIRI. Two key objectives are: (1) The global HyspIRI spectroscopic measurements of the terrestrial biosphere including vegetation composition and function to constrain and reduce the uncertainty in climate-carbon interactions and terrestrial biosphere feedback. (2) The global 8 band thermal measurements to provide improved constraint of fire related emissions. In this paper the current HyspIRI mission concept that has been reviewed and refined to its current level of maturity with a Data Products Symposium, Science Workshop and NASA HWorkshop is presented including traceability between the measurements and the science and science application objectives.

Green, Robert O.↗
DOE OSTI2022

Integrating very-high-resolution UAS data and airborne imaging spectroscopy to map the fractional composition of Arctic plant functional types in Western Alaska

Widespread changes in vegetation cover and composition are driving strong impacts on Arctic ecosystem functioning and global climate feedbacks. An accurate characterization of tundra vegetation composition is required to understand how the Arctic will respond to future climate change. However, quantifying tundra vegetation composition over large areas is challenging as commonly-used satellite observations are too coarse, spatially and spectrally, to differentiate low-lying tundra vegetation types. Recent airborne and spaceborne imaging spectroscopy platforms provide better data to characterize vegetation composition. Yet, our ability to characterize vegetation composition with imaging spectroscopy remains largely unexplored in the Arctic, particularly due to a lack of ground observations needed to train and test classification models. To address this problem, we collected very-high-resolution (VHR, ~5 cm) unoccupied aerial system (UAS) imagery at three low-Arctic tundra sites located on the Seward Peninsula, western Alaska. In this paper, we examine the feasibility of integrating imagery from the UAS and the hyperspectral Airborne Visible/Infrared Imaging Spectrometer, Next Generation (AVIRIS-NG) airborne instrument to map the fractional composition of 12 key Arctic plant functional types (PFTs). To this end, we first mapped the 12 PFTs from our VHR UAS imagery using random forest classification. We then used these UAS-derived PFT maps as ground truth to develop partial least squares regression (PLSR) models to predict the fractional cover (FCover) of each PFT from AVIRIS-NG imagery. Further, we evaluated the performance of our PLSR models using reserved UAS samples, as well as by mapping PFT FCover and dominant PFT for large tundra landscapes. Our results show that 1) Arctic PFTs can be effectively mapped using VHR UAS imagery, with overall accuracy between 86% and 92%, 2) when the UAS mapped PFTs were used to inform PLSR scaling models, the FCover of the 12 PFTs could be effectively estimated from AVIRIS-NG imagery with a mean absolute error (MAE) <0.13, and 3) our PLSR models outperformed traditional, fully constrained least-squares (FCLS) linear mixture analysis and produced high-quality, spatially contiguous PFT FCover and PFT maps that captured vegetation spatial patterns with similar accuracy to those developed from UAS imagery. The developed PLSR models have the potential to be broadly applied for quantifying vegetation composition with AVIRIS-NG images to help monitor tundra vegetation dynamics and improve process-based modeling of tundra ecosystems.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

Nano-spectroscopy of excitons in atomically thin transition metal dichalcogenides

Abstract Excitons play a dominant role in the optoelectronic properties of atomically thin van der Waals (vdW) semiconductors. These excitons are amenable to on-demand engineering with diverse control knobs, including dielectric screening, interlayer hybridization, and moiré potentials. However, external stimuli frequently yield heterogeneous excitonic responses at the nano- and meso-scales, making their spatial characterization with conventional diffraction-limited optics a formidable task. Here, we use a scattering-type scanning near-field optical microscope (s-SNOM) to acquire exciton spectra in atomically thin transition metal dichalcogenide microcrystals with previously unattainable 20 nm resolution. Our nano-optical data revealed material- and stacking-dependent exciton spectra of MoSe 2 , WSe 2 , and their heterostructures. Furthermore, we extracted the complex dielectric function of these prototypical vdW semiconductors. s-SNOM hyperspectral images uncovered how the dielectric screening modifies excitons at length scales as short as few nanometers. This work paves the way towards understanding and manipulation of excitons in atomically thin layers at the nanoscale.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
NASA NTRS2022

Mapping invasive alien species in grassland ecosystems using airborne imaging spectroscopy and remotely observable vegetation functional traits

Lespedeza cuneata (sericea lespedeza; hereafter “sericea”) is an invasive species brought to the U.S. from East Asia in the 1890s to be used as forage. However, it has now become a growing ecological and economic threat in grasslands of several states in the U.S. southern Great Plains including Oklahoma, Kansas, Missouri, and Nebraska. Here, we demonstrate the capability of airborne imaging spectroscopy to map sericea in a large natural grassland within the Tallgrass Prairie Preserve, the largest protected tallgrass prairie in the world, located in northeastern Oklahoma. Through this research, we investigated which remotely observable vegetation functional traits (referring to biochemical, physiological, and structural traits) contribute to distinguishing sericea from cooccurring native species and whether we can detect sericea remotely through quantifying these functional traits using imaging spectroscopic data (also known as hyperspectral data). To achieve these objectives, full-range airborne hyperspectral data with spatial resolution of 1 m were collected from the study area in August 2020. In addition, a total of 12 vegetation functional traits were measured through field sampling for model development. We first identified functional traits that contributed to separating sericea from other species, and then used them in a classification model to detect sericea in our study site. We found total carotenoids (sum of neoxanthin, violaxanthin, antheraxanthin, zeaxanthin, and lutein), chlorophyll a + b (sum of chlorophyll a and chlorophyll b), total nitrogen, canopy height, potassium, and magnesium as the main functional traits contributing to the detection of sericea; an overall classification accuracy of approximately 94% was reported. However, the proposed approach overestimated sericea cover in species-rich plant communities. Overall, our findings demonstrated an essential role for airborne remote sensing in 1) direct mapping of invasive plants and 2) quantifying functional traits associated with success strategies of invasive species. Eventually, experiments like ours can aid in developing large-scale and science-driven management practices to both identify the current extent, and to control the spread of invasive species in grasslands and similar short-stature environments. This will not only improve management practices but will have major societal and economic benefits.

Hamed Gholizadeh↗
NASA NTRS1996

Spectral imaging applications: Remote sensing, environmental monitoring, medicine, military operations, factory automation and manufacturing

This paper reviews the activities at OKSI related to imaging spectroscopy presenting current and future applications of the technology. The authors discuss the development of several systems including hardware, signal processing, data classification algorithms and benchmarking techniques to determine algorithm performance. Signal processing for each application is tailored by incorporating the phenomenology appropriate to the process, into the algorithms. Pixel signatures are classified using techniques such as principal component analyses, generalized eigenvalue analysis and novel very fast neural network methods. The major hyperspectral imaging systems developed at OKSI include the Intelligent Missile Seeker (IMS) demonstration project for real-time target/decoy discrimination, and the Thermal InfraRed Imaging Spectrometer (TIRIS) for detection and tracking of toxic plumes and gases. In addition, systems for applications in medical photodiagnosis, manufacturing technology, and for crop monitoring are also under development.

National Defense↗
NASA NTRS2018

Characterization of Firefly, an Imaging Spectrometer Designed for Airborne Measurements of Solar-Induced Fluorescence

FIREFLY (Fluorescence Imaging of REd and Far-red Light Yield) is a compact, fine-resolution imaging spectrometer that was designed and assembled by Headwall Photonics (Fitchburg, MA, USA) in collaboration with NASA scientists for airborne measurements of Solar-Induced Fluorescence (SIF). FIREFLY is integrated into the next generation of NASA Goddard’s Lidar, Hyperspectral and Thermal airborne imager (G-LiHT; www.gliht.nasa.gov), providing a complete system for measuring, interpreting and scaling SIF emissions. Characterization of FIREFLY was performed here to evaluate its performance and suitability for retrieving SIF.

Imaging Spectroscopy↗
NASA NTRS2016

Mid and Thermal Infrared Remote Sensing at the Jet Propulsion Laboratory

The mid and thermal infrared (MTIR) for the Earth surface is defined between 3 and 14µm. In the outer solar system, objects are colder and their Planck response shifts towards longer wavelengths. Hence for these objects (e.g. icy moons, polar caps, comets, Europa), the thermal IR definition usually stretches out to 50µm and beyond. Spectroscopy has been a key part of this scientific exploration because of its ability to remotely determine elemental and mineralogical composition. Many key gas species such as methane, ammonia, sulfur, etc. also have vibrational bands which show up in the thermal infrared spectrum above the background response. Over the past few decades, the Jet Propulsion Laboratory has been building up a portfolio of technology to capture the MTIR for various scientific applications. Three recent sensors are briefly reviewed: The airborne Hyperspectral thermal emission spectrometer (HyTES), the ECOsystem Spaceborne Thermal Radiometer Experiment on Space Station (ECOSTRESS) and Mars Climate Sounder (MCS)/DIVINER. Each of these sensors utilize a different technology to provide a remote sensing product based on MTIR science. For example, HyTES is a push-brooming hyperspectral imager which utilizes a large format quantum well infrared photodetector (QWIP). The goal is to transition this to a new complementary barrier infrared photodetector (CBIRD) with a similar long wave cut-off and increased sensitivity. ECOSTRESS is a push-whisk Mercury Cadmium Telluride (MCT) based high speed, multi-band, imager which will eventually observe and characterize plant/vegetation functionality and stress index from the International Space Station (ISS) across the contiguous United States (CONUS). MCS/DIVINER utilizes thermopile technology to capture the thermal emission from the polar caps and shadow regions of the moon. Each sensor utilizes specific JPL technology to capture unique science. similar long wave cut-off and increased sensitivity. ECOSTRESS is a push-whisk Mercury Cadmium Telluride (MCT) based high speed, multi-band, imager which will eventually observe and characterize plant/vegetation functionality and stress index from the International Space Station (ISS) across the contiguous United States (CONUS). MCS/DIVINER utilizes thermopile technology to capture the thermal emission from the polar caps and shadow regions of the moon. Each sensor utilizes specific JPL technology to capture unique science.

Johnson, William R.↗
DOE OSTI2025

High-throughput micro-scale bandgap mapping for perovskite-inspired materials with complex composition space

Abstract To realize the full promise of high-throughput experimental workflows, the rate of sample synthesis must be matched by that of characterization. Of growing interest are contactless optical techniques that can rapidly measure material homogeneity and properties. Here, we present a hyperspectral imaging method to measure local optical bandgap distributions within samples, utilizing spatially-resolved reflectance spectra coupled with automated data analysis. We collect approximately one million optical bandgap data across the compositional space of Cs 3 (Bi x Sb 1-x ) 2 (Br y I 1-y ) 9 perovskite-inspired materials. Our results show non-monotonic bandgap variations (i.e., bandgap bowing) along six composition gradient sequences, in addition to identifying samples with multiple bandgaps in statistics. High-throughput transient absorption spectroscopy reveals that within these compositions, the depletion of the ground state carriers to excited states occurred at discrete energy levels with independent carrier dynamics, consistent with the bandgap observation and indicative of phase separation. This work demonstrates the potential for rapid optical measurements to assess material quality and homogeneity in a high-throughput experimental setting, supporting screening and recipe optimization of optoelectronic material candidates with desired carrier dynamics and optical properties.

Science & Technology - Other Topics↗
DOE OSTI2020

Temperature Measurement of Laser-Irradiated Metals Using Hyperspectral Imaging

Accurate noncontact surface-temperature measurements during laser-based materials processing remain challenging due to the difficulty of establishing reliable emissivity values as a function of temperature and wavelength. Direct measurement of emissivity is difficult, as the emissivity may be changing constantly in the laser-material interaction region, where the temperature gradients are extreme and surface displacement can complicate the measurement. Here, we present a hyperspectral imaging method using a multiwavelength camera to capture the spectral radiance in eight different bands and fit the wavelength-dependent radiance to Planck’s law. Time-resolved temperature measurements during microsecond pulsed-laser irradiation of a metal plate made of the titanium alloy Ti -6 Al -4 V provide temperature information about the irradiated surface with an estimated accuracy of ± 10 % . The extracted wavelength-dependent emissivity slope compares well with reported results for macroscale titanium melts obtained using IR spectroscopy, which measure temperature without any built-in assumptions about the emissivity. The results are directly applicable to temperature monitoring during welding, additive manufacturing, and semiconductor growth.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2023

Selective Detection in Impulsive Low-Frequency Raman Imaging Using Shaped Probe Pulses

Impulsive stimulated Raman scattering (ISRS) using a single short femtosecond pump pulse to excite molecular vibrations offers an elegant pump-probe approach to perform vibrational imaging below 200 cm –1 . One shortcoming of ISRS is its inability to offer vibrational selectivity as all the vibrational bonds whose frequencies lie within the short pump-pulse bandwidth are excited. To date, several coherent control techniques have been explored to address this issue and selectively excite a specific molecular vibration by shaping the pump pulse. There has not been any systematic work that reports an analogous shaping of the probe pulse to implement preferential detection. In this work, we focus on vibrational imaging and report vibrational selective detection by shaping the probe pulse in time. Here, we demonstrate numerically and experimentally two pulse-shaping strategies with one functioning as a vibrational notch filter and the other functioning as a vibrational low-pass filter. This enables fast (25 μs/pixel) and selective hyperspectral imaging in the low-frequency regime (< 200 cm –1 ).

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2024

Local A-Site Phase Segregation Leads to Cs-Rich Regions Showing Accelerated Photodegradation in Mixed-Cation Perovskite Semiconductor Films

We use hyperspectral photoluminescence microscopy to study compositional heterogeneity and its influence on the stability of mixed-cation (formamindinium (FA) and cesium) FA 1-x Cs x Pb(I 0.9 Br 0.1 ) 3 lead halide perovskites with different Cs contents. We observe substantial microscale heterogeneity in the photoluminescence. By correlating photoluminescence maps with time-of-flight secondary ion mass spectrometry (ToF-SIMS) imaging, we show that the redder-photoluminescence regions of the perovskite film are associated with Cs-rich compositions. X-ray diffraction measurement and confocal Raman spectroscopy provide evidence for the presence of d-phase CsPbI x Br 3-x in these regions. Photo-aging tests show that these Cs-rich clusters undergo faster photoluminescence decay than the rest of the film. These observations highlight the importance of local heterogeneities and their influence on the stability of halide perovskite semiconductors being studied for optoelectronics.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2013

Underway Sampling of Marine Inherent Optical Properties on the Tara Oceans Expedition as a Novel Resource for Ocean Color Satellite Data Product Validation

Developing and validating data records from operational ocean color satellite instruments requires substantial volumes of high quality in situ data. In the absence of broad, institutionally supported field programs, organizations such as the NASA Ocean Biology Processing Group seek opportunistic datasets for use in their operational satellite calibration and validation activities. The publicly available, global biogeochemical dataset collected as part of the two and a half year Tara Oceans expedition provides one such opportunity. We showed how the inline measurements of hyperspectral absorption and attenuation coefficients collected onboard the R/V Tara can be used to evaluate near-surface estimates of chlorophyll-a, spectral particulate backscattering coefficients, particulate organic carbon, and particle size classes derived from the NASA Moderate Resolution Imaging Spectroradiometer onboard Aqua (MODISA). The predominant strength of such flow-through measurements is their sampling rate-the 375 days of measurements resulted in 165 viable MODISA-to-in situ match-ups, compared to 13 from discrete water sampling. While the need to apply bio-optical models to estimate biogeochemical quantities of interest from spectroscopy remains a weakness, we demonstrated how discrete samples can be used in combination with flow-through measurements to create data records of sufficient quality to conduct first order evaluations of satellite-derived data products. Given an emerging agency desire to rapidly evaluate new satellite missions, our results have significant implications on how calibration and validation teams for these missions will be constructed.

remote sensing↗
NASA NTRSDate not supplied

Reliability Test of the Actively Tunable Filter

The middle-wavelength infrared (MWIR) waveband is considered the “spectral fingerprint”for many chemical species. MWIR: 3 –10 μm wavelength range. MWIR imaging devices are important for multispectral imaging, thermography, chemical spectroscopy, surveillance, automotive safety, and astronomy. Tunable optical properties are desired to increase the amount of information that is detectable. Ge2Sb2Te5(GST) is a chalcogenide phase change material (PCM) that has the potential to be used as a compact, solid-state, fast-switching tunable optical filter.

Tunable filter↗
DOE OSTI2020

Post survey report for AOP Assignable Asset collection of Crested Butte, CO

This report contains details of the National Ecological Observatory Network Airborne Observation Platform (NEON AOP) assignable asset (AA) flight over Crested Butte, Colorado (CO). The report is being prepared for Lawrence Berkeley National Lab (LBNL), the primary clients for the flights who contracted the NEON AOP for flights during June 2018. The report includes a summary of the acquired flight lines over the planned area, results of calibration surveys, and quality assurance (QA) results of the acquired data. Detailed reports on the acquired data and processing results were also delivered with the data. LBNL contracted the AA NEON AOP flights to observe watersheds of interest at Crested Butte with remotely sensed data including high resolution LiDAR, imaging spectroscopy, and high-resolution camera imagery. The remote sensing imagery acquired by the AOP intendeds to support LBNL on an interdisciplinary project on hydrology, biogeochemistry, and ecosystem functioning in the area surrounding the Rocky Mountain Biological Laboratory (RMBL), one of the most prominent ecological study sites in the United States.

2018 NEON and 2025 CHESS Campaigns↗