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At least 127 records · Page 7

Direct measurements of the ionization profile in krypton helicon plasmas

Helicons are efficient plasma sources, capable of producing plasma densities of 10{sup 19} m{sup -3} with only 100 s W of input rf power. There are often steep density gradients in both the neutral density and plasma density, resulting in a fully ionized core a few cm wide surrounded by a weakly ionized plasma. The ionization profile is usually not well known because the neutral density is typically inferred from indirect spectroscopic measurements or from edge pressure gauge measurements. We have developed a two photon absorption laser induced fluorescence (TALIF) diagnostic capable of directly measuring the neutral density profile. We use TALIF in conjunction with a Langmuir probe to measure the ionization fraction profile as a function of driving frequency, magnetic field, and input power. It is found that when the frequency of the driving wave is greater than a critical frequency, f{sub c} Almost-Equal-To 3f{sub lh}, where f{sub lh} is the lower hybrid frequency at the antenna, the ionization fraction is small (0.1%) and the plasma density low (10{sup 17} m{sup -3}). As the axial magnetic field is increased, or, equivalently, the driving frequency decreased, a transition is observed. The plasma density increases by a factor of 10 or more, the plasma density profile becomes strongly peaked, the neutral density profile becomes strongly hollow, and the ionization fraction in the core approaches 100%. Neutral depletion in the core can be caused by a number of mechanisms. We find that in these experiments the depletion is due primarily to plasma pressure and neutral pumping.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

An atom trap trace analysis system for measuring krypton contamination in xenon dark matter detectors

We have developed an atom trap trace analysis (ATTA) system to measure Kr in Xe at the part per trillion (ppt) level, a prerequisite for the sensitivity achievable with liquid xenon dark matter detectors beyond the current generation. Since Ar and Kr have similar laser cooling wavelengths, the apparatus has been tested with Ar to avoid contamination prior to measuring Xe samples. A radio-frequency plasma discharge generates a beam of metastable atoms which is optically collimated, slowed, and trapped using standard magneto-optical techniques. Based on the measured overall system efficiency of 1.2 × 10{sup −8} (detection mode), we expect the ATTA system to reach the design goal sensitivity to ppt concentrations of Kr in Xe in <2 h.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Liquid xenon purification, de-radonation (and de-kryptonation)

Liquid xenon detectors are at the forefront of rare event physics, including searches for neutrino-less double beta decay and WIMP dark matter. The xenon for these experiments needs to be purified from chemical impurities such as electronegative atoms and molecules, which absorb ionization electrons, and VUV (178 nm) scintillation light-absorbing chemical species. In addition, superb purification from radioactive impurities is required. Particularly challenging are radioactive noble isotopes ({sup 85}Kr,{sup 39,42}Ar,{sup 220,222}Rn). Radon is a particularly universal problem, due to the extended decay sequence of its daughters and its ubiquitous presence in detector materials. Purification and de-radonation of liquid xenon are addressed with particular focus on the experience gained with the EXO-200 neutrino-less double beta decay detector.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Characteristics of a nanosecond-barrier-discharge-pumped multiwave UV – VUV lamp on a mixture of argon, krypton and vapours of freon

We present the results of investigation of the characteristics of a nanosecond-barrier-discharge-pumped multiwave lamp based on a gas mixture of Ar – Kr – CCl{sub 4}, which emits in the spectral range of 170 – 260 nm. The main emission bands in the lamp spectrum are ArCl (B → X) near 175 nm, KrCl (B → X) near 222 nm and Cl{sub 2} (D' → A') near 258 nm. The lamp intensity with respect to pressure, working mixture composition and pump regime is optimised. (uv - vuv emitters)

74 ATOMIC AND MOLECULAR PHYSICS↗

Analysis of Krypton-85 Legacy Waste Forms: Part I

In 2010, five samples were reclaimed at the Idaho National Laboratory (INL). These samples were generated by R&D performed in the 1970’s relating to the long-term storage of 85 Kr and presented a unique opportunity to study a potential 85 Kr waste form after over three half-lives have elapsed. The container material of two of the reclaimed 85 Kr legacy waste form samples was examined by optical microscopy and by SEM-EDS. Substantial corrosion was observed throughout each sample container. The bulk of the container material was identified as carbon steel, while stainless steel was identified as the weld material used in container manufacture and/or sealing. The material used for Kr encapsulation was found adhered to the walls of each container and had a chemical composition consistent with zeolite minerals. Kr was found coincident with the adhered material, demonstrating that the encapsulation method used in the original experiments was effective in the long-term retention of Kr. In conclusion, the sectioning, mounting, and initial analysis of these legacy samples is an important step in the study of all five legacy 85 Kr waste forms and the information gained from the analysis of Samples 2 and 5 will be used to guide future efforts on these remaining samples.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Level-energy-dependent mean velocities of excited tungsten atoms sputtered by krypton-ion bombardment

Visible emission spectra were acquired from neutral atoms sputtered by 35–60 keV Kr{sup +} ions from a polycrystalline tungsten surface. Mean velocities of excited tungsten atoms in seven different 6p states were also obtained via the dependence of photon intensities on the distance from the surface. The average velocities parallel to the surface normal varied by factors of 2–4 for atoms in the different 6p energy levels. However, they were almost independent of the incident ion kinetic energy. The 6p-level energy dependence indicated that the velocities of the excited atoms were determined by inelastic processes that involve resonant charge exchange.

42 ENGINEERING↗

Adsorption Isotherms for Xenon and Krypton using INL HZ-PAN and AgZ-PAN Sorbents

The generation of adsorption isotherms compliments the scale-up of off-gas processes used to control the emission of encapsulated radioactive volatile fission and activation products released during Used Nuclear Fuel (UNF) reprocessing activities. A series of experiments were conducted to obtain capacity results for varying Kr and Xe gas concentrations using HZ-PAN and AgZ-PAN engineered form sorbents. Gas compositions for Kr ranged from 150-40,000 ppmv and 250-5020 ppmv for Xe in a helium balance. The experiments were all performed at 220 K at a flowrate of 50 sccm. Acquired capacities were then respectively fit to the Langmuir equation using the Langmuir linear regression method to obtain the equilibrium parameters Qmax and Keq. Generated experimental adsorption isotherms were then plotted with the Langmuir predicted isotherms to illustrate agreement between the two. The Langmuir parameters were provided for input into the OSPREY model to predict breakthrough of single component adsorption of Kr and Xe on HZ-PAN and AgZ-PAN sorbents at the experimental conditions tested. Kr and Xe capacities resulting from model breakthrough predictions were then compared to experimental capacities for model validation.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Transmission Electron Microscopy Investigation of Krypton Bubbles in Polycrystalline CeO2

To gain an understanding of gas bubble transport in oxide nuclear fuel, this paper uses polycrystalline CeO2, composed of both nanograins and micrograins, as a surrogate material for UO2. The CeO2 was implanted with 150-keV Kr ions up to a dose of 1 x 1016 ions/cm2 at 600 degrees C. Transmission electron microscopy characterizations of small Kr bubbles in nanograin and micrograin regions were compared. The grain boundary acted as an efficient defect sink, as evidenced by smaller bubbles and a lower bubble density in the nanograin region as compared to the micrograin region.

99 GENERAL AND MISCELLANEOUS↗

Multicomponent adsorption of radioactive iodine and krypton using ETS-10 supported carbon nano-polyhedrons

Over 13% of the world's energy demand is supplied by nuclear power plants in 31 countries. This demand is growing; by 2030 the IAEA predicts a 100% increase in the demand for nuclear energy. The increase in nuclear energy production imposes a growing strain on the uranium fuel supply. At current consumption rates the world's supply of uranium is projected to last ∼100 years. Following the IAEA's prediction for increased nuclear energy, uranium supplies will dwindle even more quickly. However, this consequence can be limited as ∼95% of uranium is left in used nuclear fuel (UNF). Reprocessing of UNF will utilize this remaining uranium and extend the lifetime of the world's uranium supply. One of the concerns with nuclear reprocessing is that it frees radionuclides created by the fission of uranium to be released into the atmosphere through off-gas. The major constituents of off-gas include: {sup 85}Kr, {sup 129}I, {sup 14}C, {sup 3}H, and various Xe isotopes. {sup 85}Kr and {sup 129}I present the largest threat due to their harmful environmental effects and abundance. They are the most practical contaminants to be removed to meet requirements for radionuclide release. Removal of these contaminants has been a challenge since the 1950's, and several methods including cryogenic distillation, fluorocarbon absorption, wet scrubbing, and adsorption have been employed. Currently, adsorption on porous solid sorbents shows the most promising results. Until now, several sorbents such as silver impregnated mordenite, silver Engelhard titanosilicate 10, chalcogen based aerogels, and metal organic framework, MOFs have been investigated for this purpose. Despite these advances, development of economical and highly active sorbents for complete removal and immobilization of volatile radioactive gases remains a key challenge in realizing advanced fuel cycles. This work is focused on the multicomponent of {sup 85}Kr and {sup 129}I from a simulated off-gas with an Engelhard titanosilicate 10 (ETS-10) supported carbon nano-polyhedron sorbent. Adsorption studies were performed to determine iodine sorption capacity as a function of temperature and iodine inlet concentration. (authors)

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Krypton-xenon separation properties of SAPO-34 zeolite materials and membranes

Separation of the radioisotope 85 Kr from 136 Xe is an important target during used nuclear fuel recycling. In this paper, we report a detailed study on the Kr and Xe adsorption, diffusion, and membrane permeation properties of the silicoaluminophosphate zeolite SAPO-34. Adsorption and diffusion measurements on SAPO-34 crystals indicate their potential for use in Kr-Xe separation membranes, but also highlight competing effects of adsorption and diffusion selectivity. SAPO-34 membranes are synthesized on α$-$alumina disk and tubular substrates via steam assisted conversion seeding and hydrothermal growth, and are characterized in detail. Membrane transport measurements reveal that SAPO-34 membranes can separate Kr from Xe by molecular sieving, with Kr permeabilities around 50 Barrer and mixture selectivity of 25–30 for Kr at ambient or slight sub-ambient conditions. Finally, the membrane transport characteristics are modeled by the Maxwell-Stefan equations, whose predictions are in very good agreement with experiment and confirm the minimal competing effects of adsorption and diffusion.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Krypton-81 in groundwater of the Culebra Dolomite near the Waste Isolation Pilot Plant, New Mexico

TheWaste Isolation Pilot Plant (WIPP) in New Mexico is the first geologic repository for disposal of transuranic nuclear waste fromdefense-related programs of the US Department of Energy. It is constructed within halite beds of the Permian-age Salado Formation. The Culebra Dolomite, confined within Rustler Formation evaporites overlying the Salado Formation, is a potential pathway for radionuclide transport from the repository to the accessible environment in the human-disturbed repository scenario. Although extensive subsurface characterization and numerical flow modeling of groundwater has been done in the vicinity of theWIPP, few studies have used natural isotopic tracers to validate the flow models and to better understand solute transport at this site. The advent of Atom-Trap Trace Analysis (ATTA) has enabled routine measurement of cosmogenic 81Kr (half-life 229,000 yr), a near-ideal tracer for long-term groundwater transport. We measured 81Kr in saline groundwater sampled from two Culebra Dolomite monitoring wells near the WIPP site, and compared 81Kr model ages with reverse particle-tracking results of well-calibrated flow models. The 81Kr model ages are ~130,000 and ~330,000 yr for high-transmissivity and low-transmissivity portions of the formation, respectively. Compared with flow model results which indicate a relatively young mean hydraulic age (~32,000 yr), the 81Kr model ages imply substantial physical attenuation of conservative solutes in the Culebra Dolomite and provide limits on the effective diffusivity of contaminants into the confining aquitards.

Sturchio, Neil C.↗

Impact of krypton irradiation on a single crystal tungsten: Multi-modal X-ray imaging study

Understanding microstructural and strain evolutions induced by noble gas production in the nuclear fuel matrix or plasma-facing materials is crucial for designing next generation nuclear reactors, as they are responsible for volumetric swelling and catastrophic failure. In this paper we describe a multimodal approach combining synchrotron-based nanoscale X-ray imaging techniques with atomic-scale electron microscopy techniques for mapping chemical composition, morphology and lattice distortion in a single crystal W induced by Kr irradiation. We report that Kr-irradiated single crystal W undergoes surface deformation, forming Kr containing cavities. Furthermore, positive strain fields are observed in Kr-irradiated regions, which lead to compression of underlying W matrix.

36 MATERIALS SCIENCE↗