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At least 127 records · Page 7

On the initiation of melt fracture.

Discussion of a problem encountered in the processing of viscoelastic materials that is caused by the presence of a hydrodynamic instability in the extrusion of polymer melts. The importance of the so-called Weissenberg number in determining the onset of the melt fracture is examined using classical linearized hydrodynamic stability analysis. It is shown that the simple shearing flow of a viscoelastic fluid becomes unstable at a critical value of the Weissenberg number. Implications for the extrusion processing of polymers are reviewed.

Mcintire, L. V.↗

Nonlinear Viscoelastic Mechanics of Cross-linked Rubbers

The paper develops a general theory for finite rubber viscoelasticity, and specifies it in the form, convenient for solving problems important for rubber, tire and space industries. Based on the quasi-linear approach of non-equilibrium thermodynamics, a general nonlinear theory has been developed for arbitrary nonisothermal deformations of viscoelastic solids. In this theory, the constitutive equations are presented as the sum of known equilibrium (rubber elastic) and non-equilibrium (liquid polymer viscoelastic) terms. These equations are then simplified using several modeling arguments. Stability constraints for the proposed constitutive equations are also discussed. It is shown that only strong ellipticity criteria are applicable for assessing stability of the equations governing viscoelastic solids.

Freed, Alan D.↗

Viscoelastic cationic polymers containing the urethane linkage

A method for the synthesis and manufacturing of elastomeric compositions and articles containing quaternary nitrogen centers and condensation residues along the polymeric backbone of the centers is presented. Linear and cross-linked straight chain and block polymers having a wide damping temperature range were synthesized. Formulae for the viscoelastic cationic polymers are presented.

Rembaum, A.↗

The Considere Condition and Rapid Stretching of Linear and Branched Polymer Melts

We analyze the onset of "necking" and subsequent filament failure during the transient uniaxial elongation of viscoelastic fluid samples in extensional rheometers. In the limit of rapid elongation (such that no molecular relaxation occurs), the external work applied is all stored elastically and the Considere criterion originally developed in solid mechanics can be used to quantitatively predict the critical Hencky strain to failure. By comparing the predictions of the Doi-Edwards model for linear homopolymer melts with those of the "Pom-Pom" model for prototypical branched melts we show that the critical strain to failure in rapid elongation of a rubbery material is intimately linked to the molecular topology of the chain, especially the degree of chain branching. The onset of necking instability is monotonically shifted to larger Hencky strains as the number of branches is increased. Numerical computations at finite Deborah numbers also show that there is an optimal range of deformation rates over which homogeneous extensions can be maintained to large strain. We also consider other rapid homogeneous stretching deformations, such as biaxial and planar stretching, and show that the degree of stabilization afforded by inclusion of material with long-chain branching is a sensitive function of the imposed mode of deformation.

McKinley, Gareth H.↗

Numerical and laboratory simulation of fault motion and earthquake occurrence

Simple linear rheologies were used with elastic forces driving the main events and viscoelastic forces being important for aftershock and creep occurrence. Friction and its dependence on velocity, stress, and displacement also plays a key role in determining how, when, and where fault motion occurs. The discussion of the qualitative behavior of the simulators focuses on the manner in which energy was stored in the system and released by the unstable and stable sliding processes. The numerical results emphasize the statistics of earthquake occurrence and the correlations among source parameters.

Cohen, S. C.↗

Numerical and laboratory simulation of fault motion and earthquake occurrence

This paper reviews the simulation of earthquake occurrence by numerical and laboratory mechanical block models. Simple linear rheological elements are used with elastic forces driving the main events and viscoelastic forces being important for aftershock and creep occurrence. Friction and its dependence on velocity, stress, and displacement also play a key role in determining how, when, and where fault motion occurs. The discussion of the qualitative behavior of the simulators focuses on the manner in which energy is stored in the system and released by the unstable and stable sliding processes. The numerical results emphasize the statistics of earthquake occurrence and the correlations among source parameters.

Cohen, S. C.↗

A Thermodynamic Theory of Solid Viscoelasticity: Nonlinear Thermo-viscoelasticity - Part II:

This paper, second in the series of three papers, develops a general, nonlinear, non-isothermal, compressible theory for finite rubber viscoelasticity and specifies it in a form convenient for solving problems important to the rubber, tire, automobile, and air-space industries, among others. Based on the quasi-linear approach of non-equilibrium thermodynamics, a general nonlinear theory of differential type has been developed for arbitrary non-isothermal deformations of viscoelastic solids. In this theory, the constitutive equations were presented as the sum of a rubber elastic (equilibrium) and a liquid type viscoelastic (non-equilibrium) terms. These equations have then been simplified using several modeling and simplicity arguments.

Freed, Alan D.↗

Interlaminar R-Curve Effects in Thermoplastic Composites: Experiments and Model Correlations

The interlaminar fracture behavior of thermoplastic composites under Mode-I and Mode-II static loading is investigated in this research. The material system under consideration is a carbon fiber reinforced low melt semi-crystalline resin TC1225 LMPAEK T700G (T700/LMPAEK)†. Characterization experiments were conducted to measure the load-displacement response, peak load, and propagation of delamination from a pre-implanted Kapton® insert. The Mode-I response was characterized using a double cantilever beam (DCB) test according to the ASTM D5528-22 standard. It was observed that the propagation exhibited significant resistance to delamination growth, i.e., an R-Curve effect. The test data indicated that the steady-state fracture toughness, G SS I , was approximately twice the mean initiation fracture toughness, G Ic . The Mode-II response of an end notch flexure (ENF) specimen tested according to the ASTM D7905-19 standard exhibited an unexpected stable behavior upon attaining peak load. Prior to attaining peak load, the Mode-II response exhibited some non-linearity, which may be attributed to nonlinear bulk material response, e.g., hyper-elasticity, viscoelasticity, plasticity, etc., and potentially friction at the load/support rollers and R-Curve effects. Finite element models based on the Cohesive Zone Method (CZM) and the Virtual Crack Closure Technique (VCCT) were used to predict the DCB and ENF specimen responses. DCB analysis results obtained using G SS I predicted propagation consistent with experimental data. However, results obtained with the as characterized G Ic were inaccurate in predicting delamination growth onset and peak load. ENF analysis results obtained with the as-characterized Mode-II fracture toughness, G IIc , were inaccurate in predicting the peak load and propagation. Hence, R-Curve effects were included in both DCB and ENF simulations, which enabled improved predictions. The experimentally determined Mode-I R-Curve was used for the DCB simulations, whereas an R-Curve was derived for Mode-II assuming that the change in compliance of the specimen was associated with crack growth only.

Prabhakar M Rao↗

Interlaminar R-Curve Effects in Thermoplastic Composites: Experiments and Model Correlations

The interlaminar fracture behavior of thermoplastic composites under Mode-I and Mode-II static loading is investigated in this research. The material system under consideration is a carbon fiber reinforced low melt semi-crystalline resin TC1225 LMPAEK T700G (T700/LMPAEK)†. Characterization experiments were conducted to measure the load-displacement response, peak load, and propagation of delamination from a pre-implanted Kapton® insert. The Mode-I response was characterized using a double cantilever beam (DCB) test according to the ASTM D5528-22 standard. It was observed that the propagation exhibited significant resistance to delamination growth, i.e., an R-Curve effect. The test data indicated that the steady-state fracture toughness, G SS I , was approximately twice the mean initiation fracture toughness, G Ic . The Mode-II response of an end notch flexure (ENF) specimen tested according to the ASTM D7905-19 standard exhibited an unexpected stable behavior upon attaining peak load. Prior to attaining peak load, the Mode-II response exhibited some non-linearity, which may be attributed to nonlinear bulk material response, e.g., hyper-elasticity, viscoelasticity, plasticity, etc., and potentially friction at the load/support rollers and R-Curve effects. Finite element models based on the Cohesive Zone Method (CZM) and the Virtual Crack Closure Technique (VCCT) were used to predict the DCB and ENF specimen responses. DCB analysis results obtained using G SS I predicted propagation consistent with experimental data. However, results obtained with the as characterized G Ic were inaccurate in predicting delamination growth onset and peak load. ENF analysis results obtained with the as-characterized Mode-II fracture toughness, G IIc , were inaccurate in predicting the peak load and propagation. Hence, R-Curve effects were included in both DCB and ENF simulations, which enabled improved predictions. The experimentally determined Mode-I R-Curve was used for the DCB simulations, whereas an R-Curve was derived for Mode-II assuming that the change in compliance of the specimen was associated with crack growth only.

Prabhakar Rao↗

Nonlinear viscoelastic characterization of polymer materials using a dynamic-mechanical methodology

Polymer materials retrieved from LDEF exhibit nonlinear constitutive behavior; thus the authors present a method to characterize nonlinear viscoelastic behavior using measurements from dynamic (oscillatory) mechanical tests. Frequency-derived measurements are transformed into time-domain properties providing the capability to predict long term material performance without a lengthy experimentation program. Results are presented for thin-film high-performance polymer materials used in the fabrication of high-altitude scientific balloons. Predictions based upon a linear test and analysis approach are shown to deteriorate for moderate to high stress levels expected for extended applications. Tests verify that nonlinear viscoelastic response is induced by large stresses. Hence, an approach is developed in which the stress-dependent behavior is examined in a manner analogous to modeling temperature-dependent behavior with time-temperature correspondence and superposition principles. The development leads to time-stress correspondence and superposition of measurements obtained through dynamic mechanical tests. Predictions of material behavior using measurements based upon linear and nonlinear approaches are compared with experimental results obtained from traditional creep tests. Excellent agreement is shown for the nonlinear model.

Strganac, Thomas W.↗

The response of many-storied structures under seismic actions

A seismic action which is characterized by the acceleration function of the seismic motion is analyzed. The equations of motion in the direction of the seismic action are determined for a completely rigid ground and for a ground with linear deformability characteristics (rotation deformability). The equation for the rotation motion is derived by considering elastic and viscoelastic properties of the foundation ground. The differential equations are written by treating the mechanical model of a many-storied structure as a fixed vertical beam with a uniformly distributed mass as well as with concentrated masses on each floor.

Munteanu, K.↗

Theory of rheology

The structure of the modern theory of rheology is discussed to show the assumptions and limitations. Rheology is discussed as a branch of continuum mechanics to determine the relationships between stress, strain, and strain rate which will give a closer representation of lubricant properties than the Newtonian flow equation. Rheology is also investigated as a branch of chemical physics. Consideration is limited to those theories of nonpolymeric and polymeric fluids which can represent viscoelasticity in terms of identifiable and measureable molecular characteristics. The possibility that elastic liquids may rupture in shear and linear tension analogous to the failure of solids is proposed.

Hutton, J. F.↗

The identification of a distributed parameter model for a flexible structure

A computational method is developed for the estimation of parameters in a distributed model for a flexible structure. The structure we consider (part of the RPL experiment) consists of a cantilevered beam with a thruster and linear accelerometer at the free end. The thruster is fed by a pressurized hose whose horizontal motion effects the transverse vibration of the beam. The Euler-Bernoulli theory is used to model the vibration of the beam and treat the hose-thruster assembly as a lumped or point mass-dashpot-spring system at the tip. Using measurements of linear acceleration at the tip, it is estimated that the parameters (mass, stiffness, damping) and a Voight-Kelvin viscoelastic structural damping parameter for the beam using a least squares fit to the data. Spline based approximations to the hybrid (coupled ordinary and partial differential equations) system are considered; theoretical convergence results and numerical studies with both simulation and actual experimental data obtained from the structure are presented and discussed.

Banks, H. T.↗

Tether damping in space

This paper analyzes the dynamics of a long tether connecting two spacecraft in earth orbit, one of the spacecraft having dominant mass. In particular, it considers the material damping of the tether. The nominal position of the tether is stabilized by the gravity gradient such that it is aligned with the local vertical. The tether is modeled as a viscoelastic flexible continuum. Modal frequencies are derived in an analytical approximation form. Damping ratios are estimated according to the linear model calibrated by ground measurements. The results show that, with properly chosen tether material and braiding structure, longitudinal vibrations of the tethered system are well damped.

Powell, J. David↗

A Constitutive Equation for Stratospheric Balloon Materials

The selection of a suitable material for use as a reliable stratospheric balloon gas barrier and structural component is based on a variety of properties. Due to a more desirable combination of properties, the low density polyethylene that has been used for the last half century has been replaced during the last decade by linear low density polyethylene (LLDPE). This paper describes the effort to characterize the time dependent properties of a 38 micron coextrusion of LLDPE. The nonlinear viscoelastic constitutive equation presented may be used to accurately describe the creep and/or relaxation of this film when subjected to a biaxial state of stress, such as might be required for an extended balloon flight. Recent laboratory data have been used to mod@ an existing model of LLDPE to account for differences caused by the coextrusion process. The new model will facilitate structural design optimization and reliability assessment, and may be further utilized as a predictive tool to benefit in-flight operations. Current structural analysis tech&ques based on linear elastic properties have predicted stresses in excess of those which would actually exist.

Rand, J. L.↗

Finite elements of nonlinear continua.

The finite element method is extended to a broad class of practical nonlinear problems, treating both theory and applications from a general and unifying point of view. The thermomechanical principles of continuous media and the properties of the finite element method are outlined, and are brought together to produce discrete physical models of nonlinear continua. The mathematical properties of the models are analyzed, and the numerical solution of the equations governing the discrete models is examined. The application of the models to nonlinear problems in finite elasticity, viscoelasticity, heat conduction, and thermoviscoelasticity is discussed. Other specific topics include the topological properties of finite element models, applications to linear and nonlinear boundary value problems, convergence, continuum thermodynamics, finite elasticity, solutions to nonlinear partial differential equations, and discrete models of the nonlinear thermomechanical behavior of dissipative media.

Oden, J. T.↗

The identification of a distributed parameter model for a flexible structure

A computational method is developed for the estimation of parameters in a distributed model for a flexible structure. The structure we consider (part of the RPL experiment) consists of a cantilevered beam with a thruster and linear accelerometer at the free end. The thruster is fed by a pressurized hose whose horizontal motion effects the transverse vibration of the beam. The Euler-Bernoulli theory is used to model the vibration of the beam and treat the hose thruster assembly as a lumped or point mass dashpot spring system at the tip. Measurements of linear acceleration at the tip are used to estimate the hose parameters (mass, stiffness, damping) and a Voigt-Kelvin viscoelastic structural damping parameter for the beam using a least squares fit to the data. Spline based approximations are considered to the hybrid (coupled ordinary and partial differential equations) systems; theoretical convergence results and numerical studies with both simulation and actual experimental data obtained from the structure are presented and discussed.

Banks, H. T.↗

Finite Element Prediction of Loss Factors for Structures with Frequency-dependent Damping Treatments

A finite element procedure is described for calculating the loss factors for elastic structures to which frequency-dependent viscoelastic damping treatments were applied. The frequency dependence of the viscoelastic damping material is treated by approximating its shear modulus with a second-order polynomial so that the stiffnesses associated with the constant, linear, and quadratic terms can be combined, respectively, with the stiffness, damping, and mass matrices assembled for the rest of the structure. A single complex eigenvalue analysis is then performed in which the eigenvalues are purely imaginary. The loss factor is computed by the modal strain energy (MSE) approach. In the the MSE approach, the loss factor of a composite structure vibrating in one of its natural modes may be visualized as a weighted average of the loss factors of the component parts, with the relative stored energies as weighting constants. The finite element procedure, which can treat very general geometries, is illustrated for the case of a vibrating constrained-layer damped plate.

Everstine, G. C.↗