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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Assembled peptoid crystalline nanomaterials as carbonic anhydrase mimics for promoted hydration and sequestration of CO 2

Carbonic anhydrase (CA) mimics have received significant attention due to their promising applications in the enhanced hydration and sequestration of CO 2 . Herein, we report the assembly of sequence-defined peptoids into crystalline nanomaterials with controlled microenvironment of active sites as CA mimics for promoted hydration and sequestration of CO 2 . By incorporating specific ligands into self-assembling peptoids and coordinating these ligands with metal cations, we synthesize a variety of crystalline nanosheets and nanotubes as efficient CA mimics comparable to natural bovine CA. Molecular dynamics simulations reveal the critical roles of peptoid-Zn 2+ binding energy and the active site local microenvironment on the catalytic performance of these CA mimics. CO 2 precipitation results show that these CA mimics promote the hydration and sequestration of CO 2 while retaining high thermal and chemical stabilities. This study offers essential guidance for the future design of high-performance CA-mimics suitable for applications in CO 2 capture and sequestration.

Chakma, Progyateg [Pacific Northwest National Labo↗
DOE OSTI2026

Multifunctional electrochemical memory stabilized by phase coexistence

Our growing computing needs, especially in applications that heavily rely on artificial intelligence (AI), motivate a search for new components that could substantially augment the performance of general-purpose digital computers. Beyond ON/OFF switching, new components with linear multistate analog resistive tuning, nonlinear volatile switching, spiking, oscillatory, stochastic and other complex functionalities could enable highly efficient neuromorphic computing schemes for AI information processing. Compared to the extreme multifunctionality of biological neurons, realizing all the above characteristics in a single, scalable analog component remains a grand challenge. Here we investigate electrochemical gating combined with localized thermal activation to program and switch a single, vertically integrated and dimensionally scaled electrothermal chemical random access memory (ETCRAM) with a channel and reservoir composed of phase-separated vanadium oxide. Closely related to electrochemical RAM (ECRAM), ETCRAM uses an integrated gate-heater electrode to overcome kinetic barriers that help retain states at ambient temperatures. In addition to synapse-like stable and programmable analog resistance states arising from redox-tunable phase coexistence, a single component exhibits neuron-like nonlinear conductance switching with a tunable threshold and self-driven dynamics owing to the thermally driven metal-insulator phase transition in vanadium dioxide. More broadly, we demonstrate that electrochemically stabilized phase coexistence could unlock analog electronics with novel functionality, stability, reconfigurability, and scalability.

Oh, Sangheon [Sandia National Lab. (SNL-CA), Liver↗
NASA NTRS1972

Observations of fast auroral waves.

Results of simultaneous observation of a fast wave event from the Ester Dome Observatory (EDO) near College, Alaska, the Poker Flat Rocket Launching Facility (PKR), and Fort Yukon, Alaska (FYU). The display occurred on Mar. 27, 1971, and the general morphology is described and discussed. It is suggested that fast auroral waves occur when a preceding substorm has enhanced the particle population in the region of the magnetosphere near L = 6 in the midnight sector; then transverse hydromagnetic waves, associated with the onset of further local substorm activity, become visible through their action on this enhanced particle population as they propagate inwards in the equatorial region.

Boyd, J. S.↗
NASA NTRS1973

Observations of Mare Serenitatis from lunar orbit and their interpretation

Visual observations are investigated of color differences of Serenitatis mare materials from orbit complement photography and other remotely sensed data. The light tan gray inner fill of the Serenitatis basin is younger than the dark blue gray annulus; the latter continues into and appears to be contemporaneous with the fill of Mare Tranquillitatis. Mare ridges occur in both the inner basin fill and the dark annulus of Serenitatis. Ridges are interpreted as the result of structural deformation and up-doming after the solidification of the basaltic lavas. On the southeastern rim of the Serenitatis basin is the darkes blue gray unit within which Apollo 17 landed. Highland massifs surrounding this unit have unstable slopes which are believed to be the result of localized tectonic activity. On the southwest rim of the basin are the dark tan to brown gray mantling materials of the Sulpicius Gallus Formation. Farther west on the rim are dark blue grap patches which resemble the mare material of the Serenitatis dark annulus.

El-Baz, F.↗
NASA NTRS1973

Observations of Mare Serenitatis from lunar orbit and their interpretation

Visual observations of color differences of Serenitatis mare materials from orbit complement photography and other remotely sensed data. The light tan gray inner fill of the Serenitatis Basin is younger than the dark blue gray annulus; the latter continues into and appears to be contemporaneous with the fill of Mare Tranquillitatis. Mare ridges occur in both the inner basin fill and the dark annulus of Serenitatis. Ridges are interpreted as the result of structural deformation and up-doming after the solidification of the basaltic lavas. On the southeastern rim of the Serenitatis Basin is the darkest blue gray unit within which Apollo 17 landed. Highland massifs surrounding this unit have unstable slopes which are believed to be the result of localized tectonic activity. On the southwest rim of the basin are the dark tan to brown gray mantling materials of the Sulpicius Gallus Formation.

El-Baz, F.↗
NASA NTRS1975

A preliminary investigation of the potential applicability of the IPAD system to non-aerospace industry

A study of the applicability of the planned Integrated Programs for Aerospace-Vehicle Design (IPAD) system to the design activities of non-aerospace industries was carried out. It was determined that IPAD could be of significant benefit to a number of industries, with the most likely users being the heavy construction and automotive industries. Two additional short studies were initiated to investigate the possible impact of IPAD on a national energy program and on urban and regional planning activities of local and state governments. These initial studies indicated the possibility of significant payoff in these areas and the need for further investigations. It was also determined that utilization of IPAD by non-aerospace industries will probably involve a long stepwise process, since these industries maintain a policy of gradual introduction of new technology.

Hulbert, L. E.↗
NASA NTRS1976

Automatic noise limiter-blanker

A blanker system that may be used with audio noise limiters or automatic noise limiters was described. The system employs a pair of silicon diodes and two RC filters connected across the feedback impedance of an operational amplifier so as to counteract impulse noise interference caused by local spherics activity or 60 Hz harmonics radiated from ac motor control systems. The following information is given: circuit diagram and description, operating details, evaluation, discussion of other noise blanking methods.

Burhans, R. W.↗
NASA NTRS1977

Dust storms on Mars: Considerations and simulations

Aeolian processes are important in modifying the surface of Mars at present, and appear to have been significant in the geological past. Aeolian activity includes local and global dust storms, the formation of erosional features such as yardangs and depositional features such as sand dunes, and the erosion of rock and soil. As a means of understanding aeolian processes on Mars, an investigation is in progress that includes laboratory simulations, field studies of earth analogs, and interpretation of spacecraft data. This report describes the Martian Surface Wind Tunnel, an experimental facility established at NASA-Ames Research Center, and presents some results of the general investigation. Experiments dealing with wind speeds and other conditions required for the initiation of particle movement on Mars are described and considerations are given to the resulting effectiveness of aeolian erosion.

Greeley, R.↗
NASA NTRS1981

Spectral investigations of Mars from Viking

In connection with the Viking mission, spectral and photometric data of Mars were obtained with the aid of camera systems located either on the planetary surface (Lander I and II) or in Martian orbit (Orbiter I and II). Operations from Lander I are scheduled to continue through 1990. Comparisons made of the surface and atmospheric spectral and photometric properties at various times throughout the Mission were probably the most important studies conducted by the Lander cameras. The variations in atmospheric optical density due to clouds, dust storm activity (both local and global), and even a partial eclipse of the sun by the small satellite Phobos, were observed by the Lander imaging systems. Using Viking Orbiter II images, the surface materials of the equatorial region have been classified and mapped on the basis of spectral reflectance properties. Attention is also given to some details regarding the characteristics of the Viking imaging systems.

Evans, N.↗
NASA NTRS1987

History and morphology of faulting in the Noctis Labyrinthus-Claritas Fossae Region of Mars

The topographically high areas cut by Noctis Labyrinthus, Noctis Fossae, and Claritas Fossae were subjected to only minor resurfacing during and following local tectonic activity. Principal resurfacing materials consist of lava flows from Syria Planum and Tharsis Montes. Thus, these areas preserve much of the fault record produced by tectonism in this region. Although recent geologic maps of the area have been produced from Viking images, the only detailed fault histories available until now were described from Mariner 9 images. Much of the faulting in the Tharsis tectonic province was centered in Syria Planum; therefore, understanding the fault history in this region is critical to understanding the stress history and tectonism of Tharsis as a whole.

Tanaka, Kenneth L.↗
NASA NTRS1989

Low level remote sensing: The Doppler Radar wind profiler

Mesoscale phenomena such as thunderstorm and sea breeze frontal circulations are being investigated using a 50 MHz Doppler wind profiler at the Kennedy Space Center. The profiler installation will begin October 1, 1988 and will be completed by February 17, 1989. The focus of current research and plans for next year include: examination of vertical velocities associated with local thunderstorm activity and sea breeze frontal circulations and compare the vertical velocities to conceptual mesoscale models; implementation of space-time conversion analysis techniques to blend profiler data with National Meteorological Center's model output and other wind data such as jimsphere, windsonde and rawinsonde for mesoscale analysis; development of suggestions for use of wind profiler data in mesoscale analysis and forecasting at Kennedy Space Center; and problems detection in the quality of the profiler data during this research project. Researchers will work closely with MSFC to identify and solve the data quality problems.

Forbes, Gregory S.↗
NASA NTRS1990

Coronae of Mnemosyne Regio - Morphology and origin

The Mnemosine Regio area of Venus contains seven of the circular-to-elliptical structures, characterized by an annulus of concentric ridges, that are known as 'coronae'. Several corona-origin models are presently considered, and it is found that the processes associated with diapirism or hot-spots, and the gravitational relaxation of high topography, are most consistent with the topography and morphology of these coronae. The sequence of the formation and evolution of the coronae proceeds from regional volcanic and tectonic activity, through localized uplift and volcanism, to annulus and trough formation related to gravitational relaxation, and finally local volcanic flooding of the corona, annulus, and trough.

Stofan, Ellen R.↗
NASA NTRS1991

Physical processes in comets

Post-Halley comets are known to be irregular objects with most nucleus activity very localized and with the dust coma capable of fragmentation and apparently being a source of gas. Older, 1-D strategies which assume steady isotropic outflow of material can give poor time-and-space averaged results, at best. With 2-D data, images through interference filters, it is hoped that: dust structures can be seen that give evidence of the proper geometry for data reduction; gradients along the axes of symmetry and evidence of fragmentation can be studied; and that evidence for gas abundance gradients associated with the dust can be found. High quality data from brighter comets can then be used to suggest improved data reduction procedures for fainter ones. To obtain such data, large image-quality interference filters were procured for use with a charge coupled device (CCD) camera at Lick Observatory, where the scale of the 1 m Nickel reflector is ideal for brighter comets. Whenever possible, data is taken simultaneously with other telescopes and equipment, especially spectroscopy at the Lick 3 m or infrared photometry at the Infrared Telescope Facility (IRTF) on Mauna Kea.

Newburn, Ray L., Jr.↗
NASA NTRS1992

Design of a pressurized lunar rover

A pressurized lunar rover is necessary for future long-term habitation of the moon. The rover must be able to safely perform many tasks, ranging from transportation and reconnaissance to exploration and rescue missions. Numerous designs were considered in an effort to maintain a low overall mass and good mobility characteristics. The configuration adopted consists of two cylindrical pressure hulls passively connected by a pressurized flexible passageway. The vehicle has an overall length of 11 meters and a total mass of seven metric tons. The rover is driven by eight independently powered two meter diameter wheels. The dual-cylinder concept allows a combination of articulated frame and double Ackermann steering for executing turns. In an emergency, the individual drive motors allow the option of skid steering as well. Two wheels are connected to either side of each cylinder through a pinned bar which allows constant ground contact. Together, these systems allow the rover to easily meet its mobility requirements. A dynamic isotope power system (DIPS), in conjunction with a closed Brayton cycle, supplied the rover with a continuous supply of 8.5 kW. The occupants are all protected from the DIPS system's radiation by a shield of tantalum. The large amount of heat produced by the DIPS and other rover systems is rejected by thermal radiators. The thermal radiators and solar collectors are located on the top of the rear cylinder. The solar collectors are used to recharge batteries for peak power periods. The rover's shell is made of graphite-epoxy coated with multi-layer insulation (MLI). The graphite-epoxy provides strength while the thermally resistant MLI gives protection from the lunar environment. An elastomer separates the two materials to compensate for the thermal mismatch. The communications system allows for communication with the lunar base with an option for direct communication with earth via a lunar satellite link. The various links are combined into one signal broadcast in the S-band at 2.3 GHz. The rover is fitted with a parabolic reflector disk for S-band transmission, and an omnidirectional antenna for local extravehicular activity (EVA) communication. The rover's guidance, navigation, and control subsystem consists of an inertial guidance system, an orbiting lunar satellite, and an obstacle avoidance system. In addition, the rover is equipped with a number of external fixtures including two telerobotic arms, lights, cameras, EVA storage, manlocks, a docking fixture, solar panels, thermal radiators, and a scientific airlock. In conclusion, this rover meets all of the design requirements and clearly surpasses them in the areas of mobility and maneuverability.

Bhardwaj, Manoj↗
NASA NTRS1991

Thermal elastic shock and its effect on TOPEX spacecraft attitude control

Thermal elastic shock (TES) is a twice per orbit impulsive disturbance torque experienced by low-Earth orbiting spacecraft. The fundamental equations used to model the TES disturbance torque for typical spacecraft appendages (e.g., solar arrays and antenna booms) are derived in detail. In particular, the attitude-pointing performance of the TOPEX spacecraft, when subjected to the TES disturbance, is analyzed using a three-axis nonlinear time-domain simulation. Results indicate that the TOPEX spacecraft could exceed its roll-axis attitude-control requirement during penumbral transitions, and remain in violation for approximately 150 sec each orbit until the umbra collapses. A localized active-control system is proposed as a solution to minimize and/or eliminate the degrading effects of the TES disturbance.

Zimbelman, Darrell F.↗
NASA NTRS1992

Major outburst of periodic Comet Halley at a heliocentric distance of 14 AU

The properties and evolution of the major outburst experienced by Comet Halley at 14 AU during February-March 1991 are studied. It is found that the observed halo is a segment of a conical surface populated by solid particles ejected from a localized, temporarily activated region on the sunlit hemisphere of the spinning nucleus. The total mass of the ejecta was at least 10 exp 12 g and CO was probably the prime driver, accelerating the smallest grains to a terminal velocity of about 45 m/s. The mass loading of the gas flow by particulate matter is enormous, with the mass production rate exceeding the expected production rate of CO by a factor of several tens.

Sekanina, Z.↗
NASA NTRS1993

A model for tropical-extratropical transport of volcanic ash in the lower stratosphere

Large nonspherical volcanic ash particles up to 30 micrometer in size were collected between 17-19 km altitude over the Northern Hemisphere at high latitudes between October 1988 and April 1990. These particles may be derived from minor Plinian eruptions in the tropics rather than from localized volcanic activity close to the collection region. Ash particles were injected into the lower equatorial stratosphere where they entered a regime of efficient transport just above the tropopause from the tropical region towards the northern extratropical region. Transport is enhanced by stable autorotation that generates a sufficient lift force to loft nonspherical ash with a rough surface during transport, and by the gradually decreasing altitude of the tropopause from the tropics to the polar regions.

Rietmeijer, Frans J. M.↗
NASA NTRS1994

The active titration method for measuring local hydroxyl radical concentration

We are developing a method for measuring ambient OH by monitoring its rate of reaction with a chemical species. Our technique involves the local, instantaneous release of a mixture of saturated cyclic hydrocarbons (titrants) and perfluorocarbons (dispersants). These species must not normally be present in ambient air above the part per trillion concentration. We then track the mixture downwind using a real-time portable ECD tracer instrument. We collect air samples in canisters every few minutes for roughly one hour. We then return to the laboratory and analyze our air samples to determine the ratios of the titrant to dispersant concentrations. The trends in these ratios give us the ambient OH concentration from the relation: dlnR/dt = -k(OH). A successful measurement of OH requires that the trends in these ratios be measureable. We must not perturb ambient OH concentrations. The titrant to dispersant ratio must be spatially invariant. Finally, heterogeneous reactions of our titrant and dispersant species must be negligible relative to the titrant reaction with OH. We have conducted laboratory studies of our ability to measure the titrant to dispersant ratios as a function of concentration down to the few part per trillion concentration. We have subsequently used these results in a gaussian puff model to estimate our expected uncertainty in a field measurement of OH. Our results indicate that under a range of atmospheric conditions we expect to be able to measure OH with a sensitivity of 3x10(exp 5) cm(exp -3). In our most optimistic scenarios, we obtain a sensitivity of 1x10(exp 5) cm(exp -3). These sensitivity values reflect our anticipated ability to measure the ratio trends. However, because we are also using a rate constant to obtain our (OH) from this ratio trend, our accuracy cannot be better than that of the rate constant, which we expect to be about 20 percent.

Sprengnether, Michele↗