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NASA NTRS1981

Formation of pyrophosphate, tripolyphosphate, and phosphorylimidazole with the thioester, N, S-diacetylcysteamine, as the condensing agent

The formation of pyrophosphate, tripolyphosphate and phosphorylimidazole from orthophosphate in the presence of the thioester N, S-diacetylcysteamine is reported. Reactions performed with 0.20 M orthophosphate and 0.20 M N, S-diacetylcysteamine in 0.40 M imidazole under drying conditions at 50 C yielded pyrophosphate and tripolyphosphate after six days in the presence and absence of divalent metal ions. Reactions carried out at ambient temperature yielded phosphorylimidazole in the presence or absence of 0.05 M MgCl2, phosphorylimidazole and pyrophosphate in the presence of 0.05 M CaCl2, and pyrophosphate and tripolyphosphate in the presence of 0.15 M CaCl2. Such reactions represent potential pathways for the formation of energy-rich compounds providing free energy for use in prebiotic biopolymer synthesis.

Weber, A. L.↗

NASA NTRSDate not supplied

Remote Pilot Handoffs in Large UAS Multi-Vehicle Operations: Best Practices and Supportive Technologies

In response to pilot shortages and increasing air cargo demands, NASA's Pathfinding for Airspace with Autonomous Vehicles (PAAV) sub-project conducted the fourth in a series of tabletop studies investigating scalable solutions for integrating large Uncrewed Aircraft Systems (UAS) into the National Airspace System (NAS). This study solicited subject matter expertise to identify solutions to potential challenges for a further term vision, guiding participants through scenario-based discussions where the remote pilot (RP)-to-vehicle ratio has been scaled from 1:1 to m:N. Of those challenges, remote pilot handoffs were found throughout all phases of flight, both in nominal and non-nominal scenarios. The current paper details participant-suggested procedural and technological solutions for overcoming the handoff challenge, including determining the accepting RP, which aircraft to release, the location and timing of the transition, and options for supporting personnel, tools, and automation that could facilitate safe and efficient handoffs.

unmanned aircraft systems (UAS)↗

NASA NTRSDate not supplied

Remote Pilot Handoffs in Large UAS Multi-Vehicle Operations: Best Practices and Supportive Technologies

uncrewed aircraft systems↗

NASA NTRSDate not supplied

Streamlining Tactical Operator Handoffs During Multi-Vehicle Operations

Increased automation has shifted the operator control paradigm from a single operator controlling a single vehicle, to multiple operators collaborating to control multiple vehicles; this paradigm is known as m:N. Many questions remain unanswered in this new operational paradigm about the division of assets as workload for individual operators varies over time. This paper explores the management of workload by enabling operators to temporarily handoff vehicles among each other. A study was conducted to explore both a manual and assisted method for performing handoffs during manipulated contingency scenarios. The assisted handoff method allowed subjects to easily choose and group nominal and/or contingency vehicles. The number of contingencies was also manipulated to determine the effect workload had on how pilots utilized the ability to handoff vehicles. Results show subjects performed handoffs more often when there were more contingencies and when the assisted handoff tool was available. In addition, the assisted tool made subjects feel more comfortable, enabling them to feel like they could take longer to resolve contingency situations. Lastly, even during contingencies, subjects were able to successfully complete secondary tasks.

m:N operations↗

NASA NTRS1988

Robust design of distributed controllers for large flexible space structures

Independent Modal Space Control (IMSC) method avoids control spillover generated by conventional control schemes such as Coupled Modal Control by decoupling the large flexible space structure into independent subsystems of second order and controlling each mode independently. The IMSC implementation requires that the number of actuators be equal to that of modeled modes, which is in general very huge. Consequently the number of required actuators is unrealizable. Two methods are proposed for the implementation of IMSC with reduced number of actuators. In the first method, the first m modes are optimized, leaving the last (n-m) modes unchanged. In the second method, generalized inverse matrices are employed to design the feedback controller so that the control scheme is suboptimal with respect to IMSC. The performance of the proposed methods is tested by performing computer simulation on a simply support beam. Simulation results are presented and discussed.

Nguyen, Charles C.↗

NASA NTRS2002

Laboratory Anion Chemistry: Implications for the DIBs, and a Potential Formation Mechanism for a Known Interstellar Molecule

Due to recent interest in molecular anions as possible interstellar species, we have carried out several laboratory studies of anion chemistry. The reactions of the series C(sub n)(sup -); and C(sub n)H(sup -) with H and H2 were studied to address the viability of such species in the diffuse interstellar medium and to address their ability to be carriers of the diffuse interstellar bands (DIBs). These same molecules were also reacted with N and O to show possible heteroatomic products. C(sub m)N(sup - was a particularly stable product from the reaction of C(sub n)(sup -) + N. C3N(sup -) was further reacted with H to study chemistry that could produce HC3N, a known interstellar species. The reactions were done in a flowing afterglow selected ion flow tube apparatus (FA-SIFT). The anions were generated in an electron impact or cold cathode discharge source and the anion of interest was then selected by a quadrupole mass filter. The selected ion was then reacted with the atomic or molecular species in the flow tube and products were detected by another quadrupole. While the C(sub n)(sup -) species do not appear to be viable DIB carriers, their possible presence could provide a mechanism for the formation of known heteroatomic neutral molecules detected in the interstellar medium (ISM).

Eichelberger, B.↗

NASA NTRS2005

Dynamic Harris current sheet thickness from Cluster current density and plasma measurements

We use the first accurate measurements of current densities in the plasma sheet to calculate the half-thickness and position of the current sheet as a function of time. Our technique assumes a Harris current sheet model, which is parameterized by lobe magnetic field B(o), current sheet half-thickness h, and current sheet position z(sub o). Cluster measurements of magnetic field, current density, and plasma pressure are used to infer the three parameters as a function of time. We find that most long timescale (6-12 hours) current sheet crossings observed by Cluster cannot be described by a static Harris current sheet with a single set of parameters B(sub o), h, and z(sub o). Noting the presence of high-frequency fluctuations that appear to be superimposed on lower frequency variations, we average over running 6-min intervals and use the smoothed data to infer the parameters h(t) and z(sub o)(t), constrained by the pressure balance lobe magnetic field B(sub o)(t). Whereas this approach has been used in previous studies, the spatial gnuhen& now provided by the Cluster magnetometers were unavailable or not well constrained in earlier studies. We place the calculated hdf&cknessa in a magnetospheric context by examining the change in thickness with substorm phase for three case study events and 21 events in a superposed epoch analysis. We find that the inferred half-thickness in many cases reflects the nominal changes experienced by the plasma sheet during substorms (i.e., thinning during growth phase, thickening following substorm onset). We conclude with an analysis of the relative contribution of (Delta)B(sub z)/(Delta)X to the cross-tail current density during substorms. We find that (Delta)B(sub z)/(Delta)X can contribute a significant portion of the cross-tail c m n t around substorm onset.

Thompson, S. M.↗

NASA NTRS1973

A computer program to calculate zeroes, extrema, and interval integrals for the associated Legendre functions

A computer program is described for the calculation of the zeroes of the associated Legendre functions, Pnm, and their derivatives, for the calculation of the extrema of Pnm and also the integral between pairs of successive zeroes. The program has been run for all n,m from (0,0) to (20,20) and selected cases beyond that for n up to 40. Up to (20,20), the program (written in double precision) retains nearly full accuracy, and indications are that up to (40,40) there is still sufficient precision (4-5 decimal digits for a 54-bit mantissa) for estimation of various bounds and errors involved in geopotential modelling, the purpose for which the program was written.

Payne, M. H.↗

NASA NTRS1989

Non-noble electrocatalysts for alkaline fuel cells

Carbons activated with macrocyclics have attracted increasing attention as alternative electrocatalysts for oxygen reduction. Initial activity of these catalysts is good, but performance declines rapidly. Pyrolyzing the macrocyclic on the carbon support leads to enhanced stability and the catalysts retain good activity. The approach described is designed to develop bulk doped catalysts with similar structures to pyrolyzed macrocyclic catalysts. The transition metal and coordinated ligands are dispersed throughout the bulk of the conductive carbon skeleton. Two approaches to realizing this concept are being pursued, both involving the doping of carbon precursors. In one approach, the precursor is a solid phase carbon-containing ion-exchange resin. The precursor is doped with a transition metal and/or nitrogen, and the resulting mixture is pyrolyzed. In the other approach, the precursor is a gas-phase hydrocarbon. This is introduced with a transition metal species and nitrogen species into a reactor and pyrolyzed. Several studies have been conducted to determine if there is a synergistic effect between the transition metal and nitrogen and the effect of different methods of introducing the metal-nitrogen (M-N) coordination on performance. One approach was to introduce the metal and nitrogen separately, for example, by sequentially doping FeCl3 and NH4OH into the resin. Catalysts were prepared from an undoped ion-exchange resin, a resin doped only with N, a resin doped only with Fe, and a resin doped with both Fe and N. Introduction of nitrogen alone has no beneficial effect on the performance of the catalysts. The introduction of the Fe alone significantly improves the performance in both the high and low current density regions. When both Fe and N are introduced, the performance at lower current densities (catalytic activity) is increased beyond that of the Fe-doped carbon, but the performance at higher current densities is similar to the carbon containing only Fe. Catalysts prepared from resins-Fe(bipy)3SO4 precursors have performance that is only slightly less then CoTMPP adsorbed and pyroloyzed on Vulcan XC-72. Their performance is much better than carbons which have had the N and Fe introduced separately.

Sarangapani, S.↗

NASA NTRS1992

Pressurized Lunar Rover

The pressurized lunar rover (PLR) consists of a 7 m long, 3 m diameter cylindrical main vehicle and a trailer which houses the power and heat rejection systems. The main vehicle carries the astronauts, life support systems, navigation and communication systems, directional lighting, cameras, and equipment for exploratory experiments. The PLR shell is constructed of a layered carbon-fiber/foam composite. The rover has six 1.5 m diameter wheels on the main body and two 1.5 m diameter wheels on the trailer. The wheels are constructed of composites and flex to increase traction and shock absorption. The wheels are each attached to a double A-arm aluminum suspension, which allows each wheel 1 m of vertical motion. In conjunction with a 0.75 m ground clearance, the suspension aids the rover in negotiating the uneven lunar terrain. The 15 N-m torque brushless electric motors are mounted with harmonic drive units inside each of the wheels. The rover is steered by electrically varying the speeds of the wheels on either side of the rover. The PLR trailer contains a radiosotope thermoelectric generator providing 6.7 kW. A secondary back-up energy storage system for short-term high-power needs is provided by a bank of batteries. The trailer can be detached to facilitate docking of the main body with the lunar base via an airlock located in the rear of the PLR. The airlock is also used for EVA operation during missions. Life support is a partly regenerative system with air and hygiene water being recycled. A layer of water inside the composite shell surrounds the command center. The water absorbs any damaging radiation, allowing the command center to be used as a safe haven during solar flares. Guidance, navigation, and control are supplied by a strapdown inertial measurement unit that works with the on-board computer. Star mappers provide periodic error correction. The PLR is capable of voice, video, and data transmission. It is equipped with two 5 W X-band transponder, allowing simultaneous transmission and reception. An S-band transponder is used to communicate with the crew during EVA. The PLR has a total mass of 6197 kg. It has a nominal speed of 10 km/hr and a top speed of 18 km/hr. The rover is capable of towing 3 metric tons (in addition to the RTG trailer).

Creel, Kenneth↗

NASA NTRS2002

Autonomous Reconfigurable Control Allocation (ARCA) for Reusable Launch Vehicles

The role of control allocation (CA) in modern aerospace vehicles is to compute a command vector delta(sub c) is a member of IR(sup n(sub a)) that corresponding to commanded or desired body-frame torques (moments) tou(sub c) = [L M N](sup T) to the vehicle, compensating for and/or responding to inaccuracies in off-line nominal control allocation calculations, actuator failures and/or degradations (reduced effectiveness), or actuator limitations (rate/position saturation). The command vector delta(sub c) may govern the behavior of, e.g., acrosurfaces, reaction thrusters, engine gimbals and/or thrust vectoring. Typically, the individual moments generated in response to each of the n(sub a) commands does not lie strictly in the roll, pitch, or yaw axes, and so a common practice is to group or gang actuators so that a one-to-one mapping from torque commands tau(sub c) actuator commands delta(sub c) may be achieved in an off-line computed CA function.

Hodel, A. S.↗

NASA NTRS1998

Lunar and Solar Torques on the Oceanic Tides

Brosche and Seiler recently suggested that direct lunar and solar tidal torques on the oceanic tides play a significant role in the earth's short-period angular momentum balance ("short-period" here meaning daily and sub-daily). We reexamine that suggestion here, concentrating on axial torques and hence on variations in rotation rate. Only those spherical harmonic components of the ocean tide having the same degree and order as the tidal potential induce nonzero torques. Prograde components (those moving in the same direction as the tide-generating body) produce the familiar secular braking of the earth's rotation. Retrograde components, however, produce rapid variations in UTI at twice the tidal frequency. There also exist interaction torques between tidal constituents, e.g. solar torques on lunar tides. They generate UTI variations at frequencies equal to the sums and differences of the original tidal frequencies. We give estimates of the torques and angular momentum variations for each of the important regimes, secular to quarter-diurnal. For the M(sub 2) potential acting on the M(sub 2) ocean tide, we find an associated angular momentum variation of amplitude 3 x 10(exp 19) N m. This is 5 to 6 orders of magnitude smaller than the angular momentum variations associated with tidal currents. We conclude that these torques do not play a significant role in the short-period angular momentum balance.

Ray, Richard D.↗

NASA NTRS1980

Cosmological tests of the Hoyle-Narlikar conformal gravity

For the first time the Hoyle-Narlikar theory with creation of matter and a variable gravitational constant G, is subjected to the following cosmological tests: (1) the magnitude versus z relation, (2) the N(m) versus m relation for quasars, (3) the metric angular diameters versus z relation, (4) the isophotal angles versus z relation, (5) the log N-log S radio source count, and finally (6) the 3 K radiation. It is shown that the theory passes all these tests just as well as the standard cosmology, with the additional advantage that the geometry of the universe is uniquely determined, with a curvature parameter equal to zero. It is also interesting to note that the variability of G affects the log N-log S curve in a way similar to the density evolution introduced in standard cosmologies. The agreement with the data is therefore achieved without recourse to an ad hoc density evolution.

Canuto, V. M.↗

NASA NTRS1981

Analysis and simulation of a magnetic bearing suspension system for a laboratory model annular momentum control device

A linear analysis and the results of a nonlinear simulation of a magnetic bearing suspension system which uses permanent magnet flux biasing are presented. The magnetic bearing suspension is part of a 4068 N-m-s (3000 lb-ft-sec) laboratory model annular momentum control device (AMCD). The simulation includes rigid body rim dynamics, linear and nonlinear axial actuators, linear radial actuators, axial and radial rim warp, and power supply and power driver current limits.

Groom, N. J.↗

NASA NTRS1979

Scale covariance and G-varying cosmology. III - The /m, z/, /theta sub m, z/, /theta sub i, z/, and /N/m/, m/ tests

The Einstein gravitational equations in atomic units are fully solved for a matter-dominated universe in the context of a recently proposed scale-covariant cosmology. The magnitude-redshift relation for elliptical galaxies is studied, the evolutionary parameter used in such a study is derived, and the relation between isophotal angular diameters and redshifts is investigated, along with the relation between metric angular diameters and redshifts, the N(m)-magnitude relation for QSOs, and the magnitude-redshift relation for QSOs. Results are presented for four gauges (i.e., relations between G and the scale function beta (t)), and no contradictions are found between the proposed theory and the observational data. It is shown that only an open universe can fit the data if certain gauges suggested by a recent analysis of the time variation of the moon's period are selected and that observations made with atomic instruments do not necessarily yield geometrical parameters unless specific assumptions are made regarding the relation between atomic and gravitational dynamics.

Canuto, V. M.↗

NASA NTRS2007

Strain Dependence of Photoluminescense of Individual Carbon Nanotubes

We have investigated strain dependence of photoluminescense (PL) spectra of single wall carbon nanotubes (SWNT). Nanotubes were sparsely dispersed in a thin PMMA film applied to acrylic bar, and strained in both compression and extension by bending this bar in either direction in a homebuilt four-point bending rig. The average surface strain was measured with high accuracy by a resistive strain gage applied on top of the film. The near infrared imaging and spectroscopy were performed on the inverted microscope equipped with high numerical aperture reflective objective lens and InGaAs CCD cameras. PL was excited with a diode laser at either 658, 730 or 785 nm, linearly polarized in the direction of the strain. We were able to measure (n,m) types and orientation of individual nanotubes with respect to strain direction and strain dependence of their PL maxima. It was found that PL peak shifts with respect to the values measured in SDS micelles are a sum of three components. First, a small environmental shift due to difference in the dielectric constant of the surrounding media, that is constant and independent of the nanotube type. Second, shift due to isotropic compression of the film during drying. Third, shifts produced by the uniaxial loading of the film in the experiment. Second and third shifts follow expression based on the first-order expansion of the TB hamiltonian. Their magnitude is proportional to the nanotube chiral angle and strain, and direction is determined by the nanotube quantum number. PL strain dependence measured for a number of various nanotube types allows to estimate TB carbon-carbon transfer integral.

Nikolaev, Pavel N.↗

NASA NTRS1993

Deep imaging of high redshift QSO fields below the Lyman limit. II - Number counts and colors of field galaxies

We present an analysis of the number counts and colors of faint galaxies to about 26.5 mag in the fields of two high Galactic latitude, very-high-redshift QSOs. We concentrate on the general properties of the field galaxies at faint magnitudes. In particular, we readdress the faint galaxy number counts and colors as a function of apparent magnitude and we reexamine the possible contribution of very-high-redshift galaxies to the faint samples. We find that the number counts to R = 26 are well fitted by the relation log N(m) = 0.31R + C. The G-band counts for the same galaxies are consistent with the same slope fainter than G about 23.5, but exhibit a much steeper slope at brighter magnitudes. At R = 25.5, the differential number counts have reached about 1.2 x 10 exp 5/sq deg; the same surface density of galaxies is reached at G = 26.5. We confirm the existence of a gradual 'blueing' trend of the field galaxies toward fainter apparent magnitude; however, the blueing trend appears to extend only as faint as G about 24, fainter than which both the (G-R) and (U sub n-G) colors appear to level off. The mean colors of faint galaxies are considerably redder than flat spectrum. There are essentially no objects to R = 26 which have spectral energy distributions which are bluer than flat spectrum. The potential contribution of very-high-redshift galaxies may have been underestimated in previous analyses; the current data are consistent with the same population of relatively luminous galaxies at z about 3 as exist at z about 0.7.

Steidel, Charles C.↗

NASA NTRS2012

Rates of Dinitrogen Fixation and the Abundance of Diazotrophs in North American Coastal Waters Between Cape Hatteras and Georges Bank

We coupled dinitrogen (N2) fixation rate estimates with molecular biological methods to determine the activity and abundance of diazotrophs in coastal waters along the temperate North American Mid-Atlantic continental shelf during multiple seasons and cruises. Volumetric rates of N2 fixation were as high as 49.8 nmol N L(sup -1) d(sup -1) and areal rates as high as 837.9 micromol N m(sup -2) d(sup -1) in our study area. Our results suggest that N2 fixation occurs at high rates in coastal shelf waters that were previously thought to be unimportant sites of N2 fixation and so were excluded from calculations of pelagic marine N2 fixation. Unicellular N2-fixing group A cyanobacteria were the most abundant diazotrophs in the Atlantic coastal waters and their abundance was comparable to, or higher than, that measured in oceanic regimes where they were discovered. High rates of N2 fixation and the high abundance of diazotrophs along the North American Mid-Atlantic continental shelf highlight the need to revise marine N budgets to include coastal N2 fixation. Integrating areal rates of N2 fixation over the continental shelf area between Cape Hatteras and Nova Scotia, the estimated N2 fixation in this temperate shelf system is about 0.02 Tmol N yr(sup -1), the amount previously calculated for the entire North Atlantic continental shelf. Additional studies should provide spatially, temporally, and seasonally resolved rate estimates from coastal systems to better constrain N inputs via N2 fixation from the neritic zone.

Middle Atlantic Bight↗