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At least 127 records · Page 7

Coevolution of Machine Learning and Process-Based Modelling to Revolutionize Earth and Environmental Sciences: A Perspective

Machine learning (ML) applications in Earth and environmental sciences (EES) have gained incredible momentum in recent years. However, these ML applications have largely evolved in ‘isolation’ from the mechanistic, process-based modelling (PBM) paradigms, which have historically been the cornerstone of scientific discovery and policy support. In this perspective, we assert that the cultural barriers between the ML and PBM communities limit the potential of ML, and even its ‘hybridization’ with PBM, for EES applications. Fundamental, but often ignored, differences between ML and PBM are discussed as well as their strengths and weaknesses in light of three overarching modelling objectives in EES, (1) nowcasting and prediction, (2) scenario analysis, and (3) diagnostic learning. The paper ponders over a ‘coevolutionary’ approach to model building, shifting away from a borrowing to a co-creation culture, to develop a generation of models that leverage the unique strengths of ML such as scalability to big data and high-dimensional mapping, while remaining faithful to process-based knowledge base and principles of model explainability and interpretability, and therefore, falsifiability.

Saman Razavi↗

Effect of space flight on interferon production - mechanistic studies

Ground-based models were studied for the effects of space flight on immune responses. Most time was spent on the model for the antiorthostatic, hypokinetic, hypodynamic suspension model for rats. Results indicate that suspension is useful for modeling the effects of spaceflight on functional immune responses, such as interferon and interleukin production. It does not appear to be useful for modeling shifts in leukocyte sub-populations. Calcium and 1,25-dihydroxyvitamin D sub 3 appear to play a pivitol role in regulating shifts in immune responses due to suspension. The macrophage appears to be an important target cell for the effects of suspension on immune responses.

Sonnenfeld, Gerald↗

The use of plasma ashers and Monte Carlo modeling for the projection of atomic oxygen durability of protected polymers in low Earth orbit

The results of ground laboratory and in-space exposure of polymeric materials to atomic oxygen has enabled the development of a Monte Carlo computational model which simulates the oxidation processes of both environments. The cost effective projection of long-term low-Earth-orbital durability of protected polymeric materials such as SiO(x)-coated polyimide Kapton photovoltaic array blankets will require ground-based testing to assure power system reliability. Although silicon dioxide thin film protective coatings can greatly extend the useful life of polymeric materials in ground-based testing, the projection of in-space durability based on these results can be made more reliable through the use of modeling which simulates the mechanistic properties of atomic oxygen interaction, and replicates test results in both environments. Techniques to project long-term performance of protected materials, such as the Space Station Freedom solar array blankets, are developed based on ground laboratory experiments, in-space experiments, and computational modeling.

Banks, Bruce A.↗

The role of Ekman flow and planetary waves in the oceanic cross-equatorial heat transport

A numerical model is used to mechanistically simulate the oceans' seasonal cross-equatorial heat transport. The basic process of Ekman pumping and drift is able to account for a large amount of the cross-equatorial flux. Increased easterly wind stress in the winter hemisphere causes Ekman surface drift poleward, while decreased easterly stress allows a reduction in the poleward drift in the summer hemisphere. The addition of planetary and gravity waves to this model does not alter the net cross-equatorial flow, although the planetary waves are clearly seen. On comparison with Oort and Vonder Haar (1976), this adiabatic advective redistribution of heat is seen to be plausible up to 10-20 deg N, beyond which other dynamics and thermodynamics are indicated.

Schopf, P. S.↗

Fracture-tough, corrosion-resistant bearing steels

The fundamental principles allowing design of stainless bearing steels with enhanced toughness and stress corrosion resistance has involved both investigation of basic phenomena in model alloys and evaluation of a prototype bearing steel based on a conceptual design exercise. Progress in model studies has included a scanning Auger microprobe (SAM) study of the kinetics of interfacial segregation of embrittling impurities which compete with the kinetics of alloy carbide precipitation in secondary hardening steels. These results can define minimum allowable carbide precipitation rates and/or maximum allowable free impurity contents in these ultrahigh strength steels. Characterization of the prototype bearing steel designed to combine precipitated austenite transformation toughening with secondary hardening shows good agreement between predicted and observed solution treatment response including the nature of the high temperature carbides. An approximate equilibrium constraint applied in the preliminary design calculations to maintain a high martensitic temperature proved inadequate, and the solution treated alloy remained fully austenitic down to liquid nitrogen temperature rather than transforming above 200 C. The alloy can be martensitically transformed by cryogenic deformation, and material so processed will be studied further to test predicted carbide and austenite precipitation behavior. A mechanistically-based martensitic kinetic model was developed and parameters are being evaluated from available kinetic data to allow precise control of martensitic temperatures of high alloy steels in future designs. Preliminary calculations incorporating the prototype stability results suggest that the transformation-toughened secondary-hardening martensitic-stainless design concept is still viable, but may require lowering Cr content to 9 wt. pct. and adding 0.5 to 1.0 wt. pct. Al. An alternative design approach based on strain-induced martensitic transformation during cryogenic forming, thus removing the high martensitic constraint, may permit alloy compositions offering higher fracture roughness.

Olson, Gregory B.↗

Characteristics of 3-D transport simulations of the stratosphere and mesosphere

A 3D mechanistic, primitive-equation model of the stratosphere and mesosphere is coupled to an offline spectral transport model. The dynamics model is initialized with and forced by observations so that the coupled models may be used to study specific episodes. Results are compared with those obtained by transport online in the dynamics model. Although some differences are apparent, the results suggest that coupling of the models to a comprehensive photochemical package will provide a useful tool for studying the evolution of constituents in the middle atmosphere during specific episodes.

Fairlie, T. D. A.↗

Modeling Creep Effects in Advanced SiC/SiC Composites

Because advanced SiC/SiC composites are projected to be used for aerospace components with large thermal gradients at high temperatures, efforts are on-going at NASA Glenn to develop approaches for modeling the anticipated creep behavior of these materials and its subsequent effects on such key composite properties as internal residual stress, proportional limit stress, ultimate tensile strength, and rupture life. Based primarily on in-plane creep data for 2D panels, this presentation describes initial modeling progress at applied composite stresses below matrix cracking for some high performance SiC/SiC composite systems recently developed at NASA. Studies are described to develop creep and rupture models using empirical, mechanical analog, and mechanistic approaches, and to implement them into finite element codes for improved component design and life modeling

Lang, Jerry↗

Development of thermomechanical life prediction models for thermal barrier coatings

Thermal barrier coatings (TBCs) for turbine airfoils in high-performance engines represent an advanced materials technology with both performance and durability benefits. The foremost TBC benefit is the reduction of heat transferred into air-cooled components. To achieve these benefits, however, the TBC system must be reliable. Mechanistic thermomechanical and thermochemical life models and statistically significant design data are therefore required for the reliable exploitation of TBC benefits on gas turbine airfoils. Garrett's NASA-HOST Program (NAS3-23945) is designed to fulfill these requirements. This program focuses on predicting the lives of two types of strain-tolerant and oxidation-resistant TBC systems that are produced by commercial coating suppliers to the gas turbine industry. The plasma-sprayed TBC system, composed of a low-pressure plasma-spray (LPPS) applied oxidation resistant NiCrAlY bond coating, and an air-plasma-sprayed yttria partially stabilized zirconia insulated layer is applied by both Chromalloy and Klock. The second type of TBC is applied by the electron beam-physical vapor deposition process by Temescal. Thermomechanical life models are being tailored to predict TBC strain tolerance in terms of materials, engine, and mission parameters. Continuum and fracture mechanics approaches and statistical methods are being evaluated to develop tensile and compressive strain functions required to drive a mission analysis capable thermomechanical life model for TBCs. Results of initial testing to calibrate these life models will be presented.

Strangman, T. E.↗

Patterns and Variability in Global Ocean Chlorophyll: Satellite Observations and Modeling

Recent analyses of SeaWiFS data have shown that global ocean chlorophyll has increased more than 4% since 1998. The North Pacific ocean basin has increased nearly 19%. These trend analyses follow earlier results showing decadal declines in global ocean chlorophyll and primary production. To understand the causes of these changes and trends we have applied the newly developed NASA Ocean Biogeochemical Assimilation Model (OBAM), which is driven in mechanistic fashion by surface winds, sea surface temperature, atmospheric iron deposition, sea ice, and surface irradiance. The model utilizes chlorophyll from SeaWiFS in a daily assimilation. The model has in place many of the climatic variables that can be expected to produce the changes observed in SeaWiFS data. This enables us to diagnose the model performance, the assimilation performance, and possible causes for the increase in chlorophyll. A full discussion of the changes and trends, possible causes, modeling approaches, and data assimilation will be the focus of the seminar.

Gregg, Watson↗

Connecting Paleo and Modern Oceanographic Data to Understand Atlantic Meridional Overturning Circulation Over Decades to Centuries

Modeling is an important tool for understanding AMOC on all timescales. Mechanistic studies of modern AMOC variability have been hampered by a lack of consistency between free-running models and the sensitivity of AMOC to resolution and parameterization. Recent work within the framework of the phase two Coordinated Ocean- Reference Experiments (CORE-II) addresses this issue head on, looking at model differences of AMOC mean state and interannual variability. One consistent feature across the models is that AMOC mean transport is related to mixed layer depths and Labrador Sea salt content, whereas interannual variability is primarily associated with Labrador Sea temperature anomalies. This is consistent with the hypothesized importance of salt balance for AMOC variability on geological timescales. The simulated relationships between AMOC and subsurface temperature anomalies in fully coupled climate models reveal subsurface AMOC fingerprints that could be used to reconstruct historical AMOC variations at low frequency.With the lack of long-term AMOC observations, models of ocean state that assimilate observational data have been explored as a way to reconstruct AMOC, but comparisons between models indicate they are quite variable in their AMOC representations. Karspeck et al. (2015) found that historical reconstructions of AMOC in such models are sensitive to the details of the data assimilation procedure. The ocean data assimilation community continues to address these issues through improved models and methods for estimating and representing error information.Two objectives of paleoclimate modeling are 1) to provide mechanistic information for interpretation of paleoclimate observations, and 2) to test the ability of predictive models to simulate Earth's climate under different background forcing states. In a good example of the first objective, Schmittner and Lund (2015) and Menviel et al. (2014) provided key information about the proxy signals expected under freshwater disturbance of AMOC, which were used to support the paleoclimate observations made by Henry et al. (2016). In an example of the second objective, Muglia and Schmittner (2015) analyzed Third Paleoclimate Modeling Intercomparison Project (PMIP3) models of the Last Glacial Maximum (LGM) and found consistently more intense and deeper AMOC transports relative to preindustrial simulations, counter to the paleoclimate consensus of LGM conditions, indicating that some processes are not well represented in the PMIP3 models. One challenge is to find adequate paleo observations against which to test these models. PMIP is now in phase 4 (part of CMIP6), which includes experiments covering five periods in Earth's history: the last millennium, last glacial maximum, last interglacial, and the mid-Pliocene. Newly compiled paleoclimate datasets from the PAGES2k project, more transient simulations, and participation of isotope enabled models planned for CMIP6PMIP4 will enable richer paleo data-model comparisons in the near future.

Kilbourne, Hali↗

Recent Trends in Global Ocean Chlorophyll

Recent analyses of SeaWiFS data have shown that global ocean chlorophyll has increased more than 5% since 1998. The North Pacific ocean basin has increased nearly 19%. To understand the causes of these trends we have applied the newly developed NASA Ocean Biogeochemical Assimilation Model (OBAM), which is driven in mechanistic fashion by surface winds, sea surface temperature, atmospheric iron deposition, sea ice, and surface irradiance. The mode1 utilizes chlorophyll from SeaWiFS in a daily assimilation. The model has in place many of the climatic variables that can be expected to produce the changes observed in SeaWiFS data. Th~s enables us to diagnose the model performance, the assimilation performance, and possible causes for the increase in chlorophyll.

Gregg, Watson↗

Mesoscale density variability in the mesosphere and thermosphere: Effects of vertical flow accelerations

A mechanistic one dimensional numerical (iteration) model was developed which can be used to simulate specific types of mesoscale atmospheric density (and pressure) variability in the mesosphere and the thermosphere, namely those due to waves and those due to vertical flow accelerations. The model was developed with the idea that it could be used as a supplement to the TGCMs (thermospheric general circulation models) since such models have a very limited ability to model phenomena on small spatial scales. The simplest case to consider was the integration upward through a time averaged, height independent, horizontally divergent flow field. Vertical winds were initialized at the lower boundary using the Ekman pumping theory over flat terrain. The results of the computations are summarized.

Revelle, D. O.↗

Kinetics and Mechanism of the Reaction of Hydoxyl Radicals with Acetonitrile under Atmospheric Conditions

The pulsed laser photolysis-pulsed laser induced fluorescence technique has been employed to determine absolute rate coefficients for the reaction OH + CH3CN (1) and its isotopic variants, OH + CD3CN (2), OD + CH3CN (3), and OD + CD3CN (4). Reactions 1 and 2 were studied as a function of pressure and temperature in N2, N2/O2, and He buffer gases. In the absence of O2 all four reactions displayed well-behaved kinetics with exponential OH decays and pseudo-first rate constants which were proportional to substrate concentration. Data obtained in N2 over the range 50-700 Torr at 298 K are consistent with k(sub 1), showing a small pressure dependence. The Arrhenius expression obtained by averaging data at all pressures in k(sub 1)(T) = (1.1(sup +0.5)/(sub -0.3)) x 10(exp -12) exp[(-1130 +/- 90)/T] cu cm /(molecule s). The kinetics of reaction 2 are found to be pressure dependent with k(sub 2) (298 K) increasing from (1.21 +/- 0.12) x 10(exp -14) to (2.16 +/- 0.11) x 10(exp -14) cm(exp 3)/ (molecule s) over the pressure range 50-700 Torr of N2 at 298 K. Data at pressures greater than 600 Torr give k(sub 2)(T) = (9.4((sup +13.4)(sub -5.0))) x 10(exp -13) exp[(-1180 +/- 250)/T] cu cm/(molecule s). The rates of reactions 3 and 4 are found to be independent of pressure over the range 50-700 Torr of N2 with 298 K rate coefficient given by k(sub 3) =(3.18 +/- 0.40) x 10(exp -14) cu cm/(molecule s) and k(sub 4) = (2.25 +/-0.28) x 10(exp -14) cu cm/(molecule s). In the presence of O2 each reaction shows complex (non-pseudo-first-order) kinetic behavior and/or an apparent decrease in the observed rate constant with increasing [O2], indicating the presence of significant OH or OD regeneration. Observation of regeneration of OH in (2) and OD in (3) is indicative of a reaction channel which proceeds via addition followed by reaction of the adduct, or one of its decomposition products, with O2. The observed OH and OD decay profiles have been modeled by using a simple mechanistic scheme to extract kinetic information about the adduct reations with O2 and branching ratios for OH regeneration. A plausible mechanism for OH regeneration in (2) involves OH addition to the nitrogen atom followed by O2 addition to the cyano carbon atom, isomeriazation and decomposition to D2CO + DOCN + OH. Our results suggest that the OH + CH3CN reaction occurs via a complex mechanism involving both bimolecular and termolecular pathways, analogous to the mechanisms for the the important atmospheric reactions of OH with CO and HNO3.

Hynes, A. J.↗

Terrestrial Models and Global Change: Challenges for the Future

A wide variety of models have illustrated the potential importance of terrestrial biological feedbacks on climate and climate change, yet our ability to make precise predictions is severely limited, due to a high degree of uncertainty. In this paper, after briefly reviewing current models, we present challenges for new terrestrial models and introduce a simple mechanistic approach that may complement existing approaches.

Hurtt, George C.↗

Airborne Dust Plumes Lofted by Dislodged Ice Blocks at Russell Crater, Mars

Linear dune gullies on poleward-facing Martian slopes are enigmatic. Formation by CO2-ice block or snow cornice falls has been proposed based on optical imagery of bright, high-albedo features inside gully channels. Because these features often resemble patchy frost residue rather than three-dimensional blocks, more evidence is needed to support the ice-block formation mechanism. Satellite imagery captured two simultaneous airborne plumes with in-channel sources at the Russell crater megadune, thrust up, and dispersed outward along the path of linear dune gullies. We use spectral data analyses, climatic analyses of bolometric temperatures, and thermal modeling to further develop the mechanistic framework for linear dune gully development. Basal sublimation and CO2 gas venting likely cause CO2-ice-block detachment and falls from gully alcoves in southern early spring, accompanied by ice-block off-gassing and saltation of sands and coarse silts that are redeposited around gully channels, and lofting of sublimation lag (coarse dust/silt) into airborne plumes.

Cynthia Dinwiddie↗

Dynamical Sensitivity in Response to a Wide Range of Abrupt CO 2 Forcings

An improved understanding of dynamical variability is important for projecting future changes in extratropical weather and the interaction between the extratropical troposphere and the tropics, stratosphere, cryosphere and ocean. Despite their simplicity, the abrupt 2x- and 4xCO 2 forcing simulations from the Coupled Model Intercomparison Project (CMIP) Phase 6 DECK experiments enable a mechanistic look into the forcing and feedback response characteristics of models that can be unambiguously attributed to an increase in carbon dioxide concentrations. Thus, while typically used to evaluate the climate sensitivity in models, with a primary focus on global surface temperature change, here we focus on several measures of extratropical variability, including projected changes in the storm tracks and in stratospheric polar vortex variability. Results are primarily based on simulations produced using low- and high-top versions of the NASA Goddard Institute for Space Studies Model (ModelE) but results are also presented from the larger CMIP6 multi-model ensemble. In addition to the 2x- and 4xCO 2 simulations, we also explore the linearity of the response of extratropical dynamical variability in ModelE to varying levels of CO 2 spanning the range 1/8-8xCO 2 . In particular, we show that the expansion of the jet streams varies nonlinearly with increasing CO 2 , especially in the Northern Hemisphere, and that this can be interpreted in terms of variations in ocean heat transport. The impact of composition feedbacks on changes in variability is also discussed.

dynamical variability↗

Tree Growth Enhancement Drives a Persistent Biomass Gain in Unmanaged Temperate Forests

While enhanced tree growth over the last decades has been reported in forests across the globe, it remains unclear whether it drives persistent biomass increases of forest stands, particularly in mature forests. Enhanced tree growth and stand-level biomass are often linked with a simultaneous increase in density-driven mortality and a reduction in tree longevity. Identifying empirical evidence regarding the balance between these processes is challenging due to the confounding effects of stand history, management, and environmental changes. Here, we investigate the link between growth and biomass via the negative relationship between average tree size and stand density (tree number per area). We find increasing stand density for a given mean tree size in unmanaged closed-canopy forests in Switzerland over the past six decades and a positive relationship between tree growth and stand density across forest plots—qualitatively consistent with our simulations using a mechanistic, cohort-resolving ecosystem model (BiomeE). Model simulations show that, in the absence of other disturbances, enhanced tree growth persistently increases biomass stocks despite simultaneous decreases in carbon residence time and tree longevity. However, the magnitude of simulated biomass changes for a given growth enhancement critically depends on the shape of the mortality functions. Our analyses reconcile reports of growth-induced reductions of tree longevity with model predictions of persistent biomass increases, and with our finding of trends toward denser forests in response to growth—also in mature stands.

biomass stocks↗

Comparison of kinetic models for atom recombination on high-temperature reusable surface insulation

Five kinetic models are compared for their ability to predict recombination coefficients for oxygen and nitrogen atoms over high-temperature reusable surface insulation (HRSI). Four of the models are derived using Rideal-Eley or Langmuir-Hinshelwood catalytic mechanisms to describe the reaction sequence. The fifth model is an empirical expression that offers certain features unattainable through mechanistic description. The results showed that a four-parameter model, with temperature as the only variable, works best with data currently available. The model describes recombination coefficients for oxygen and nitrogen atoms for temperatures from 300 to 1800 K. Kinetic models, with atom concentrations, demonstrate the influence of atom concentration on recombination coefficients. These models can be used for the prediction of heating rates due to catalytic recombination during re-entry or aerobraking maneuvers. The work further demonstrates a requirement for more recombination experiments in the temperature ranges of 300-1000 K, and 1500-1850 K, with deliberate concentration variation to verify model requirements.

Willey, Ronald J.↗