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At least 127 records · Page 7

A medium-range structure motif linking amorphous and crystalline states

Amorphous materials have no long-range order, but there are ordered structures at short range (2–5 Å), medium range (5–20 Å) and even longer length scales. While regular and semiregular polyhedra are often found as short-range ordering in amorphous materials, the nature of medium-range order has remained elusive. Consequently, it is difficult to determine whether there exists any structural link at medium range or longer length scales between the amorphous material and its crystalline counterparts. Moreover, an amorphous material often crystallizes into a phase of different composition, with very different underlying structural building blocks, further compounding the issue. Here, we capture an intermediate crystalline cubic phase in a Pd-Ni-P amorphous alloy and reveal the structure of the medium-range order, a six-membered tricapped trigonal prism cluster (6M-TTP) with a length scale of 12.5 Å. We find that the 6M-TTP can pack periodically to several tens of nanometres to form the cube phase. Our experimental observations provide evidence of a structural link between the amorphous and crystalline phases in a Pd-Ni-P alloy at the medium-range length scale and suggest that it is the connectivity of the 6M-TTP clusters that distinguishes the crystalline and amorphous phases. These findings will shed light on the structure of amorphous materials at extended length scales beyond that of short-range order.

36 MATERIALS SCIENCE↗

A Medium Voltage Testbed for the Performance and Function Tests of a 13.8 kV Power Conditioning System Converter

Medium voltage SiC devices facilitate the development of medium voltage grid-connected power electronics converters. However, it is difficult to test these converters directly on the real medium voltage grid, especially considering abnormal grid conditions, such as grid voltage and frequency variation, and different converter operation modes, such as grid-connected mode and islanded mode. This paper introduces the design and implementation of a medium voltage testbed, which supports tests of medium voltage converters in both grid-connected and islanded mode tests. In the grid-connected mode, the testbed can provide up to 13.8 kV grid voltage, can support the four-quadrant operation, and can emulate different grid conditions, such as voltage and frequency variation. In the islanded mode, the converter under test works as a voltage source and the testbed emulates a three-phase balanced or unbalanced load. Experiment test results are provided to validate the design and capability of the testbed.

Li, Haiguo↗

Collisions of Single-Cycle and Subcycle Attosecond Light Pulses in a Nonlinear Resonant Medium

By numerically solving the system of Maxwell–Bloch equations, we have examined theoretically collisions of extremely short single-cycle and unipolar subcycle pulses in a nonlinear resonant medium under conditions that the light interacts coherently with the medium. The dynamics of the electric field of structures of light-induced polarization and inversion difference has been considered in the situation in which pulses are overlapped in the medium. We show that the states of the medium (to the right and to the left of the overlap region of the pulses) may differ. In particular, we show that polarization waves with different characteristics can exist in the regions of the medium that are located on opposite sides of the overlap region of the pulses. These waves travel in different directions and have different spatial frequencies.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Vehicle Technologies and Fuel Cell Technologies Office Research and Development Programs: Prospective Benefits Assessment for Medium- and Heavy-duty Vehicles

Through a diverse set of programs, the Vehicle Technologies and Fuel Cell Technologies Offices of the U.S. Department of Energy’s Office of Energy Efficiency and Renewable Energy (EERE) invest in early-stage vehicle and fuel cell research. The Vehicle Technologies Office (VTO) and the Fuel Cell Technologies Office (FCTO) are two offices that are encompassed within EERE’s Sustainable Transportation pillar. VTO conducts research and development (R&D) to provide low-cost, reliable, and efficient energy for the transportation of goods and people across America. FCTO has a comprehensive portfolio of activities that address the barriers facing the development and implementation of hydrogen and fuel cells, with the ultimate goals of decreasing our dependence on oil, reducing greenhouse gas (GHG) emissions, and enabling clean, reliable power generation through both transportation and stationary uses of hydrogen. This report quantifies the vehicle-level and national-level benefits of successful VTO and FCTO R&D applied to medium- and heavy-duty vehicles. The benefits estimated include reductions in energy use and GHG emissions from and changes in expenditures on medium- and heavy-duty vehicles on the road in the United States through the year 2050. The potential future benefits of successfully developing and implementing these technologies were analyzed by comparing a “Program Success” case to a base case (the “No Program” case). The Program Success case represents the future with successful implementation of VTO and FCTO technologies. The No Program case represents a future in which VTO or FCTO do not contribute to these technologies after Fiscal Year (FY) 2019. Three side cases were analyzed to assess the sensitivity of the projections of market adoption to future electricity prices (including infrastructure costs), the availability of electricity and hydrogen at public stations, and fuel cell system efficiency. Advanced vehicle technologies supported by VTO and FCTO programs can greatly increase the fuel economy of medium- and heavy-duty vehicles. As a result of EERE-supported technologies, the sales-weighted average fuel economy of the fleet of all new Class 7 and 8 trucks in the Program Success case is projected to be 1.2 times that of the trucks in the No Program case in 2035 and 1.3 times the baseline in 2050. These technologies in Classes 4–6 increase fuel economy by a factor of 1.46 in 2035 and 1.78 in 2050. The fuel economy of the entire on-road medium- and heavy-duty vehicle fleet, including all fuel types, is projected to be higher by 10%, reaching 9.1 mpgde in 2035, and by 25%, reaching 11.0 mpgde in 2050. The resulting petroleum savings in 2050 were estimated to be 0.75 million barrels per day, and reductions in GHG emissions in 2050 were estimated to 110 million metric tons of carbon dioxide equivalent (CO 2 -eq) per year. Such petroleum reductions result in significant reductions in fuel expenditure for medium- and heavy-duty vehicles, totaling approximately $37 billion annually by 2035. Figure ES-1 shows the difference in projected consumption of diesel fuel, electricity, and hydrogen in the No Program and Program Success cases. Negative values show the reduction in the Program Success case, relative to the No Program case.

33 ADVANCED PROPULSION SYSTEMS↗

Analysis of operational requirements for medium density air transportation. Volume 1: Summary

The medium density air travel market was studied to determine the aircraft design and operational requirements. The impact of operational characteristics on the air travel system and the economic viability of the study aircraft were also evaluated. Medium density is defined in terms of numbers of people transported (20 to 500 passengers per day on round trip routes), and frequency of service ( a minumium of two and maximum of eight round trips per day) for 10 regional carriers. The operational characteristics of aircraft best suited to serve the medium density air transportation market are determined and a basepoint aircraft is designed from which tradeoff studies and parametric variations could be conducted. The impact of selected aircraft on the medium density market, economics, and operations is ascertained. Research and technology objectives for future programs in medium density air transportation are identified and ranked.

Source record↗

An experimental test of the homogeneity of the interstellar medium

Observations of nonthermal continuum radio emission at 750 MHz and hydrogen-line emission at 1420 MHz have been compared in order to test the extent to which cosmic-ray electrons, magnetic fields, and hydrogen gas coexist in the interstellar medium. If the interstellar medium is homogeneous in the sense that its constituents are mixed together and can interact, then regions of line and continuum emission should be spatially correlated. The measurements indicate that at most 28% of continuum emission in the Galaxy comes from such a homogeneous medium. The remaining nonthermal emission agrees in magnitude with the residual emission found by Berkhuijsen after subtraction of the polarized component of nonthermal emission. In addition, the data discussed here show that the major filamentary structures found in the two forms of emission rarely coincide spatially. Consequently, both the average and the exceptional structure in the medium indicate that the synchrotron-radiating magnetoplasma and the neutral hydrogen gas are not closely interacting in the present state of the medium.

Baker, P. L.↗

Some interhemispheric comparisons of medium-scale waves in the lower stratosphere

Remarkable domination of the summer Southern Hemisphere (SH) circulation by medium-scale features (zonal waves 4-7) has been reported. More recently, it has been shown that these features derive their energy from baroclinic instabilities of the mean state. As one aspect of attempting to further explain the unusual spectral peak and phase-time continuity of the SH waves, the same microwave satellite instrument is used to compare characteristics of medium-scale lower stratospheric temperature waves in the Northern Hemisphere (NH) and SH summertimes. Data from the Tiros-N Microwave Sounding Unit from August 1979 are analyzed here and compared with previous analyses for January 1979 reported by Yu et al. (1983) and others. The interhemispheric comparison reveals that summertime medium-scale waves in the NH do not exhibit the striking phase-time continuity of their SH summer counterparts. In addition, winter NH medium-scale waves are also found to have less phase-time continuity than those in the SH winter. The reason for the interhemispheric difference in maintenance of the medium-scale waves, especially in summertime, remains to be explained.

Yu, W.-B.↗

Radiation characteristics of a source in a thin substrate mounted over a dielectric medium

The radiation pattern of a line source is calculated for the case in which the source is lying on the top or the bottom surface of a lossless dielectric substrate that is mounted on the top of semiinfinite dielectric medium. It is found that in both cases the pattern along the interfaces has a null; that the pattern in the upper semiinfinite medium has a single lobe; and that the pattern in the lower semiinfinite medium has many lobes, the number of which varies with the substrate thickness. In both cases, the power radiated into the lower medium is more than that radiated into the upper medium. Applications of this calculation to remote sensing, microstrip antenna technology, and antenna arrays are discussed.

Engheta, Nader↗

Non-invasive optical detection of glucose in cell culture nutrient medium

The objective of the proposed research was to begin the development of a non-invasive optical sensor for measuring glucose concentration in the output medium of cell cultures grown in a unique NASA bioreactor referred to as an integrated rotating-wall vessel (IRWV). The input, a bovine serum based nutrient media, has a known glucose concentration. The cells within the bioreactor digest a portion of the glucose. Thus, the non-invasive optical sensor is needed to monitor the decrease in glucose due to cellular consumption since the critical parameters for sustained cellular productivity are glucose and pH. Previous glucose sensing techniques have used chemical reactions to quantify the glucose concentration. Chemical reactions, however, cannot provide for continuous, real time, non-invasive measurement as is required in this application. Our effort while in the fellowship program was focused on the design, optical setup, and testing of one bench top prototype non-invasive optical sensor using a mid-infrared absorption spectroscopy technique. Glucose has a fundamental vibrational absorption peak in the mid-infrared wavelength range at 9.6 micron. Preliminary absorption data using a CO2 laser were collected at this wavelength for water based glucose solutions at different concentrations and one bovine serum based nutrient medium (GTSF) with added glucose. The results showed near linear absorption responses for the glucose-in-water data with resolutions as high at 108 mg/dl and as low as 10 mg/dl. The nutrient medium had a resolution of 291 mg/dl. The variability of the results was due mainly to thermal and polarization drifts of the laser while the decrease in sensitivity to glucose in the nutrient medium was expected due to the increase in the number of confounders present in the nutrient medium. A multispectral approach needs to be used to compensate for these confounders. The CO2 laser used for these studies was wavelength tunable (9.2 to 10.8 micrometers), however, it was to unstable across wavelengths to test the multispectral approach. From this research, further NASA support was obtained to continue the work throughout the year in which a more stable light source will be used at smaller, near-infrared, wavelengths. It is anticipated that a more compact, non-invasive, optical glucose sensor will be realized which can be used with a bioreactor on future space shuttle missions. It is also anticipated that a multispectral optical sensor may be used to determine the concentration of other molecules needed within the NASA bioreactor, such as fructose and galactose.

Cote, Gerald L.↗

Inherent and Apparent Scattering Properties of Coated or Uncoated Spheres Embedded in an Absorbing Host Medium

The conventional Lorenz-Mie formalism is extended to the scattering process associated with a coated sphere embedded in an absorbing medium. It is shown that apparent and inherent scattering cross sections of a scattering particle, which are identical in the case of transparent host medium, are different if the host medium is absorptive. Here the inherent single-scattering properties are derived from the near-field information whereas the corresponding apparent counterparts are derived from the far-field asymptotic form of the scattered wave with scaling of host absorption that is assumed to be in an exponential form. The formality extinction and scattering efficiencies defined in the same manner as in the conventional sense can be unbounded. For a nonabsorptive particle embedded in an absorbing medium, the effect of host absorption on the phase matrix elements associated with polarization is significant. This effect, however, is largely reduced for strongly absorptive particles such as soot. For soot particles coated with water, the impurity can substantially reduce the single-scattering albedo of the particle if the size parameter is small. For water-coating soot and hollow ice spheres, it is shown that the phase matrix elements -P(sub 12)/P(sub 11) and P(sub 33)/P(sub 11) are unique if the shell is thin, as compared with the case for thick shell. Furthermore, the radiative transfer equation regarding a multidisperse particle system in an absorbing medium is discussed. It is illustrated that the conventional computation algorithms can be applied to solve the multiple scattering process if the scaled apparent single-scattering properties are applied.

Yang, P.↗

Release of somatic embryogenic potential from excised zygotic embryos of carrot and maintenance of proembryonic cultures in hormone-free medium

Excised zygotic embryos, mericarps ("seeds") and hypocotyls of seedlings of cultivated carrot Daucus carota cv. Scarlet Nantes were evaluated for their ability to generate somatic embryos on a semisolid hormone-free nutrient medium. Neither intact zygotic embryos nor hypocotyls ever produced somatic embryos. However, mericarps and broken zygotic embryos were excellent sources for somatic embryo production (response levels as high as 86%). Somatic embryo formation was highest from cotyledons, but was also observed on isolated hypocotyls and root tips of mature zygotic embryos. On media containing unreduced nitrogen, somatic embryo formation led to the generation of vigorous cultures comprised entirely of somatic embryos at various stages of development which in turn proliferated still other somatic embryos. However, a medium was devised which when 1-5 mM NH4+ was the sole nitrogen source, led only to a proliferation of globular proembryos. Sustained subculturing of these proembryos at 2-3 week intervals enabled establishment of highly uniform cultures in which no further development into more mature stages of embryonic development occurred. These have been maintained, without decline, as morphogenetically competent proembryonic globules for over ten months. A basal medium containing from 1-5 mM NH4+ as the sole nitrogen source appears not to be inductive to somatic proembryo formation. Instead, such a medium is best thought of as permissive to the expression of embryogenically determined cells within zygotic embryos. By excising and breaking or wounding zygotic embryos, constituent cells are probably released from positional or chemical restraints and thus are able to express their innate embryogenic potential. Once a proembryonic culture is established, this medium containing 1-5 mM NH4+ as the sole nitrogen source provides a nonpermissive environment to the development and growth of later embryonic stages, but it does allow the continued formation and multiplication of globular somatic proembryos. The sequence of events leading from excised broken zygotic embryos to the formation of somatic embryos and the maintenance of somatic proembryos are demonstrated by scanning electron microscopy and histological preparations. Germination levels from intact zygotic embryos on media with varying levels and ratios of unreduced vs. reduced inorganic nitrogen were determined as well and provided baseline or control data on the type of response obtained from nonwounded material.

Non-NASA Center↗

Somatic proembryo production from excised, wounded zygotic carrot embryos on hormone-free medium: evaluation of the effects of pH, ethylene and activated charcoal

Wounded zygotic embryos of cultivated carrot produce somatic proembryos on hormone-free nutrient medium containing 1 mM NH4+ as the sole nitrogen source. Continued maintenance of proembryos on this medium leads to a "pure" culture of preglobular stage proembryos (PGSPs). Ethylene had no effect on this process. Also, somatic embryo production was not affected by growing cultures on activated charcoal-impregnated filter papers. However, somatic proembyros initiated on activated charcoal papers were not maintainable as PGSPs and developed into later embryo stages. Normally, medium pH dropped from 5.7 to 4 during each subculture period, but when using activated charcoal papers the pH endpoint was around 6 - 7 due to a leachable substance(s) within the filter papers. When powdered, activated charcoal was used in the medium as an adsorbent of products potentially released after wounding, pH dropped at the normal rate and to the expected levels; proembryos did not mature into later embryo stages and were maintainable exclusively as PGSPs. Low pH (approximately 4) is detrimental to proembyro production, but is essential to maintaining PGSPs on hormone-free nutrient medium, whereas a sustained pH > or = 5.7 allows continued development of PGSPs into later embryo stages.

NASA Program Space Biology↗

Actinides in the Source of Cosmic Rays and the Present Interstellar Medium

The abundances of the actinide elements in the cosmic rays can provide critical constraints on the major sites of their acceleration. Using recent calculations of the r-process yields in core collapse supernovae, we have determined the actinide abundances averaged over various assumed time intervals for their supernova generation and their cosmic-ray acceleration. Using standard Galactic chemical evolution models, we have also determined the expected actinide abundances in the present interstellar medium. From these two components, we have calculated the U/Th and other actinide abundances expected in the supernova-active cores of superbubbles, as a function of their ages and mean metallicity resulting from dilution with interstellar cloud debris. Then, using observations of the fractions of Galactic supernovae that occur in superbubbles and in the rest of the interstellar medium, we calculate the expected actinide abundances in cosmic rays accelerated by Galactic supernovae. We find that the current measurements of actinide/Pt-group and preliminary estimates of the UPuCm/Th ratio in cosmic rays are all consistent with the expected values if superbubble cores have mean metallicities of around 3 times solar. Such metallicities are quite comparable to the superbubble core metallicities inferred from other cosmic-ray observations. Future, more precise measurements of these ratios with experiments such as ECCO are needed to provide a better measure of the mean source metallicity sampled by the local Galactic cosmic rays. Measurements of the cosmic- ray actinide abundances have been favorably compared with the protosolar ratio, inferred from present solar system abundances, to infer that the cosmic rays are accelerated from the general interstellar medium. We suggest, however, that such an inference is not valid because the expected actinide abundances in the present interstellar medium are very different from the protosolar values, which sampled the interstellar medium 4.5 Gyr ago and included an additional fresh ejecta component from a neighboring supernova.

Lingenfelter, R. E.↗

System and method for treatment of a medium

A system and method for treatment of a medium is disclosed. The system includes a plurality of separator zones and a plurality of heat transfer zones. Each of the separator zone and the heat transfer zone among the plurality of separator zones and heat transfer zones respectively, are disposed alternatively in a flow duct. Further, each separator zone includes an injector device for injecting a sorbent into the corresponding separator zone. Within the corresponding separator zone, the injected sorbent is reacted with a gaseous medium flowing in the flow duct, so as to generate a reacted gaseous medium and a reacted sorbent. Further, each heat transfer zone exchanges heat between the reacted gaseous medium fed from the corresponding separator zone and a heat transfer medium.

42 ENGINEERING↗

System for detecting objects in streaming 3D images formed from data acquired with a medium penetrating sensor

A detection system that detects subsurface objects within a medium and estimates various features of the objects is provided. The detection system receives a streaming sequence of image frames of the medium at various along-medium locations. An image frame contains voxel values (intensities) representing characteristics of the medium across the medium and in the depth (range) direction. The detection system depth-compensates the intensities for determining which voxels are part of an object using an unsupervised binary classifier. The detection system then connects object voxels into distinct objects and recursively estimates the features of those objects as the image frames stream based on the locations and intensities of the object voxels.

Paglieroni, David W.↗

Performance Evaluation of AG-1 FC HEPA Filters and Medium in Nuclear Complex Facilities - 20434

High Efficiency Particulate Air (HEPA) filters are credited as the final barrier against the release of radioactive aerosol contamination in nearly every operating U. S. Department of Energy (DOE) and National Nuclear Security Agency (NNSA) nuclear facility. The Institute for Clean Energy Technology (ICET) at Mississippi State University maintains a research program that studies various aspects of these components of containment systems and seeks to answer key questions from across the industry. This programmatic overview will include results from recent and ongoing studies, including a study on filter design and performance envelope, degradation due to aging or fatigue, fire event impact on HEPA filters, and accelerated aging of medium and component parts. ICET has completed a study helping to define the threshold for combined elevated temperature and relative humidity resistance of separator style and separator-less style HEPA filters that are used in DOE complexes. The study provides experimental data that considers elevated temperature, elevated relative humidity (RH), and target differential pressure (dP) in an attempt to gain a better understanding or more comprehensive insight into the operating envelope of different configurations of ASME (American Society for Mechanical Engineers) AG-1 Section FC filters. Test variables including air temperature ranges of 48.88 deg. C, 54.44 deg. C, or 60 deg. C (120, 130, or 140 deg. F); air RH ranges including 60-70%, 80%, or 90+% with initial filter dP of either 497.68 Pa, 746.52 Pa, or 995.36 Pa (2 inches water column (in. w. c.), 3 in. w. c., or 4 in. w. c.) included for full bracketing of each set of conditions. A study examining the effects of aging and fatigue on nuclear grade HEPA filters and medium elucidates the physical properties of media along with testing of new and aged ASME AG-1 HEPA filters. In addition to performing autopsies of the tested, aged filters to help better understand the service life of their performance, newly designed accelerated aging chambers allow new medium to undergo accelerated aging and exposure treatments. Evaluation of degradation in physical properties and functionality requires a high population of aged filters of different ages, designs, manufacturers, and operational histories. The limited availability of this population and the impropriety of looking solely at formulations and components from past years requires experimental design that will provide foresight into future filter performance. This undertaking therefore involves not only properties analysis of aged medium from different operational histories, ages, designs, and manufacturers, but also prescience in analytical goals via accelerated aging studies of newly manufactured media. A more complete understanding of the mechanisms of degradation from past formulations as well as current and future formulations is possible. Accelerated Aging of newly manufactured media utilizes exposure treatments based on the Arrhenius equation to artificially age medium and therefore glimpse into the future. Evaluation of current media properties This testing allows for the comparison of performance and durability of new filters under upset or design basis conditions with aged filters that were in service under ambient conditions and other aged filters retained in storage. Susceptibility of HEPA filters to the effects of combustion byproducts, heat, and water is also being studied in an attempt to gain understanding on the prevention of filter failures during fire events in nuclear facilities. ICET seeks to determine the effect of filter performance due to smoke loading using characterized smoke from variable fuel compositions, geometries, and loads; the smoke capacity of various filters with different burning conditions, heat release rates and transport, as well as mass transport from the air stream will be studied in low flow containment systems. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

DIISC-II: Unveiling the Connections between Star Formation and Interstellar Medium in the Extended Ultraviolet Disk of NGC 3344

We present our investigation of the extended ultraviolet (XUV) disk galaxy, NGC 3344, conducted as part of Deciphering the Interplay between the Interstellar medium, Stars, and the Circumgalactic medium survey. We use surface and aperture photometry of individual young stellar complexes to study star formation and its effect on the physical properties of the interstellar medium. We measure the specific star formation rate (sSFR) and find it to increase from 10 –10 yr –1 in the inner disk to >10 –8 yr –1 in the extended disk. This provides evidence for inside-out disk growth. If these sSFRs are maintained, the XUV disk stellar mass can double in ~0.5 Gyr, suggesting a burst of star formation. The XUV disk will continue forming stars for a long time due to the high gas depletion times (τ dep ). The stellar complexes in the XUV disk have high-Σ H I and low-Σ SFR with τ dep ~ 10 Gyr, marking the onset of a deviation from the traditional Kennicutt–Schmidt law. We find that both far-ultraviolet (FUV) and a combination of FUV and 24 μm effectively trace star formation in the XUV disk. Hα is weaker in general and prone to stochasticities in the formation of massive stars. Investigation of the circumgalactic medium at 29.5 kpc resulted in the detection of two absorbing systems with metal-line species: the stronger absorption component is consistent with gas flows around the disk, most likely tracing inflow, while the weaker component is likely tracing corotating circumgalactic gas.

79 ASTRONOMY AND ASTROPHYSICS↗

Hydrogen Embrittlement of Medium Mn Steels

Recent research efforts to develop advanced–/ultrahigh–strength medium-Mn steels have led to the development of a variety of alloying concepts, thermo-mechanical processing routes, and microstructural variants for these steel grades. However, certain grades of advanced–/ultrahigh–strength steels (A/UHSS) are known to be highly susceptible to hydrogen embrittlement, due to their high strength levels. Hydrogen embrittlement characteristics of medium–Mn steels are less understood compared to other classes of A/UHSS, such as high Mn twinning–induced plasticity steel, because of the relatively short history of the development of this steel class and the complex nature of multiphase, fine-grained microstructures that are present in medium–Mn steels. The motivation of this paper is to review the current understanding of the hydrogen embrittlement characteristics of medium or intermediate Mn (4 to 15 wt pct) multiphase steels and to address various alloying and processing strategies that are available to enhance the hydrogen-resistance of these steel grades.

36 MATERIALS SCIENCE↗