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At least 127 records · Page 7

Implications of smaller concentrations of stratospheric OH - A two-dimensional model study of ozone perturbations

There is growing observational evidence that stratospheric OH concentrations are smaller than models have been predicting. Using very recent HOx reaction rate coefficient measurements in a two-dimensional photochemical model, results which support these observations are obtained. As a consequence of smaller OH concentrations, we show that perturbations of stratospheric ozone by NOx (SST emissions and nitrogen fertilizers) may be larger than expected, while perturbations due to added water vapor and chlorine (SSTs and chlorofluoromethanes, respectively) may be smaller.

Whitten, R. C.↗

Photochemical trajectory modelling studies of the 1987 Antarctic spring vortex

Simulations of Antarctic ozone photochemistry performed using a photochemical model integrated along air parcel trajectories are described. This type of model has a major advantage at high latitudes of being able to simulate correctly the complex interaction between photolysis and temperature fields, which, because of the polar night cannot be represented accurately in a zonally averaged framework. Isentropic air parcel trajectories were computed using Meteorological Office global model analyses and forecast fields from positions along the ER-2 flight paths during the Airborne Antarctic Ozone Experiment in Austral Spring 1987. A photochemical model is integrated along these trajectories using the aircraft observations to initialize constituent concentrations. The model includes additional reactions of the ClO dimer and also bromine reactions, which are thought to play a significant role in Antarctica. The model also includes heterogeneous reactions which are invoked when the air parcel passes through a polar stratospheric cloud (PSC). The existence of a PSC is determined throughout the course of the model integration from the parcel temperature and the saturated vapour pressure of water over an assumed H2O/HNO3 mixture. The air parcel temperature is used to determine the saturated vapor pressure of HNO3 over the same mixture. Mixing ratios which exceed saturation result in condensation of the excess in the model and hence lead to a reduction of the amount of gas phase NO2 available for chemical reaction.

Austin, J.↗

Lagrangian photochemical modeling studies of the 1987 Antarctic spring vortex. I - Comparison with AAOE observations

Results from the Lagrangian photochemical model integrated along computed air parcel trajectories intersected by the ER-2 aircraft are presented and compared with AAOE observations. According to the model, the BrO observations made from the ER-2 within the dehydrated denitrified region are consistent with there being approximately 5 parts per trillion by volume of BrO(y) at 428 K in spring. Within the high ClO region, ozone destruction rates are expected to exceed 2 percent/d with approximately 80 percent due to the ClO dimer mechanism.

Jones, R. L.↗

Experimental and Modeling Studies of the Combustion Characteristics of Conventional and Alternative Jet Fuels. Final Report

The objectives of this project have been to develop a comprehensive set of fundamental data regarding the combustion behavior of jet fuels and appropriately associated model fuels. Based on the fundamental study results, an auxiliary objective was to identify differentiating characteristics of molecular fuel components that can be used to explain different fuel behavior and that may ultimately be used in the planning and design of optimal fuel-production processes. The fuels studied in this project were Fischer-Tropsch (F-T) fuels and biomass-derived jet fuels that meet certain specifications of currently used jet propulsion applications. Prior to this project, there were no systematic experimental flame data available for such fuels. One of the key goals has been to generate such data, and to use this data in developing and verifying effective kinetic models. The models have then been reduced through automated means to enable multidimensional simulation of the combustion characteristics of such fuels in real combustors. Such reliable kinetic models, validated against fundamental data derived from laminar flames using idealized flow models, are key to the development and design of optimal combustors and fuels. The models provide direct information about the relative contribution of different molecular constituents to the fuel performance and can be used to assess both combustion and emissions characteristics.

Meeks, Ellen↗

Three-Dimensional Tracer Model Study of Atmospheric CO2 - Response to Seasonal Exchanges with the Terrestrial Biosphere

A three-dimensional tracer transport model is used to investigate the annual cycle of atmospheric CO2 concentration produced by seasonal exchanges with the terrestrial biosphere. The tracer model uses winds generated by a global general circulation model to advect and convect CO2; no explicit diffusion coefficients are employed. A biospheric exchange function constructed from a map of net primary productivity, and Azevedo's (1982) seasonality of CO2 uptake and release closely simulates the annual cycles at coastal stations. The results show that zonal homogeneity in surface CO2 concentrations can never be achieved at mid-latitudes where the time scale for zonal mixing is longer than the time scale for biospheric exchange. Analysis of the zonal mean balance in the lower troposphere reveals that atmospheric transport processes may alter the CO2 response to local biospheric exchanges by 50% or more. Hence year-to-year variation of the annual CO2 cycle may result from the natural variability of the atmospheric circulation as well as from changes in the sources and sinks.

Fung, I.↗

A general circulation model study of atmospheric carbon monoxide

The carbon monoxide cycle is studied by incorporating the known and hypothetical sources and sinks in a tracer model that uses the winds generated by a general circulation model. Photochemical production and loss terms, which depend on OH radical concentrations, are calculated in an interactive fashion. The computed global distribution and seasonal variations of CO are compared with observations to obtain constraints on the distribution and magnitude of the sources and sinks of CO, and on the tropospheric abundance of OH. The simplest model that accounts for available observations requires a low latitude plant source of about 1.3 x 10 to the 15th g/yr, in addition to sources from incomplete combustion of fossil fuels and oxidation of methane. The globally averaged OH concentration calculated in the model is 750,000/cu cm. Models that calculate globally averaged OH concentrations much lower than this nominal value are not consistent with the observed variability of CO. Such models are also inconsistent with measurements of CO isotopic abundances, which imply the existence of plant sources.

Pinto, J. P.↗

Scale-model studies for the improvement of flow patterns of a low-speed tunnel

Parameters affecting the performance of a scale model V/STOL wind tunnel were measured. These included: (1) static pressure variation around the closed tunnel circuit as affected by the application of various screens; (2) pressure rise and radial distribution of flow through the fan; (3) variation of screen parameters and screen location affecting the flow; and (4) effects of multiple screens on the velocity distribution in the fourth diffuser. In these tests the fan was driven through a long shaft by an externally situated 11,190-W (15-HP) motor equipped to turn at 4 speeds.

Barna, P. S.↗

A model study of the effects of intermittent loss on odd nitrogen concentrations in the lower troposphere

A time-dependent box model of the lower troposphere which includes a description of photochemical and physical processes has been developed. This model has been applied to the calculation of nitric acid and NO(x)(NO + NO2) concentrations over a diurnal cycle which includes precipitation. Nitric acid concentrations and the HNO3/NO(x) ratio are found to be highly variable under the assumptions regarding the frequency, duration, and intensity of precipitation employed in this model. The chemistry of odd nitrogen compounds during the night is potentially important in establishing the level of nitric acid in the lower troposphere. These calculations also indicate that relatively large errors may occur when the continuity equation describing nitric acid variations is averaged over a diurnal cycle which includes precipitation. Interpretation of simultaneous measurements of HNO3 and NO(x) will require some knowledge of the history of the observed air mass and may require an improved understanding of nighttime odd nitrogen chemistry.

Stewart, R. W.↗

A Model Study of Zonal Forcing in the Equatorial Stratosphere by Convectively Induced Gravity Waves

A two-dimensional cloud-resolving model is used to examine the possible role of gravity waves generated by a simulated tropical squall line in forcing the quasi-biennial oscillation (QBO) of the zonal winds in the equatorial stratosphere. A simulation with constant background stratospheric winds is compared to simulations with background winds characteristic of the westerly and easterly QBO phases, respectively. In all three cases a broad spectrum of both eastward and westward propagating gravity waves is excited. In the constant background wind case the vertical momentum flux is nearly constant with height in the stratosphere, after correction for waves leaving the model domain. In the easterly and westerly shear cases, however, westward and eastward propagating waves, respectively, are strongly damped as they approach their critical levels, owing to the strongly scale-dependent vertical diffusion in the model. The profiles of zonal forcing induced by this wave damping are similar to profiles given by critical level absorption, but displaced slightly downward. The magnitude of the zonal forcing is of order 5 m/s/day. It is estimated that if 2% of the area of the Tropics were occupied by storms of similar magnitude, mesoscale gravity waves could provide nearly 1/4 of the zonal forcing required for the QBO.

Alexander, M. J.↗

A Preliminary Model Study of the Large-Scale Seasonal Cycle in Bottom Pressure Over the Global Ocean

Output from the primitive equation model of Semtner and Chervin is used to examine the seasonal cycle in bottom pressure (Pb) over the global ocean. Effects of the volume-conserving formulation of the model on the calculation Of Pb are considered. The estimated seasonal, large-scale Pb signals have amplitudes ranging from less than 1 cm over most of the deep ocean to several centimeters over shallow, boundary regions. Variability generally increases toward the western sides of the basins, and is also larger in some Southern Ocean regions. An oscillation between subtropical and higher latitudes in the North Pacific is clear. Comparison with barotropic simulations indicates that, on basin scales, seasonal Pb variability is related to barotropic dynamics and the seasonal cycle in Ekman pumping, and results from a small, net residual in mass divergence from the balance between Ekman and Sverdrup flows.

Ponte, Rui M.↗

Integrated Modeling Study of the Effects of the Magnetospheric Forcing on the Jovian Ionosphere-Thermosphere System

The Jupiter Thermosphere General Circulation Model (JTGCM) calculates the global dynamical structure of Jupiter s thermosphere self-consistently with its global thermal structure and composition. The main heat source that drives the thermospheric flow is high-latitude Joule heating. A secondary source of heating is the auroral process of particle precipitation. Global simulations of Jovian thermospheric dynamics indicate strong neutral outflows from the auroral ovals with velocities up to approx.2 km/s and subsequent convergence and downwelling at the Jovian equator. Such circulation is shown to be an important process for transporting significant amounts of auroral energy t o equatorial latitudes and for regulating the global heat budget in a manner consistent with the high thermospheric temperatures observed by the Galileo probe. Adiabatic compression of the neutral atmosphere resulting from downward motion is an important source of equatorial heating (< 0.06 microbar). The adiabatic heating continues to dominate between 0.06 and 0.2 microbar, but with an addition of comparable heating due to horizontal advection induced by the meridional flow. Thermal conduction plays an important role in transporting heat down to lower altitudes (>0.2microbar) where it is balanced by the cooling associated with the wind transport processes. Interestingly, we find that radiative cooling caused by H3(+), CH4, and C2H2 emissions does not play a significant role in interpreting the Galileo temperature profile.

Bogan, Denis↗

What can we learn from relaxation measurements of a laser-perturbed atmosphere? A modeling study

The chemical kinetic aspects of a transient increase in OH and HO2 by several orders of magnitude are explored in three model tropospheres. This chemical kinetic modeling effort was undertaken to support the operation of a pump-and-probe LIDAR instrument. A powerful excimer laser pulse perturbs the troposphere after which its relaxation back to steady state is examined by remote sensing, for example by DIAL or LIF. Instead of probing ambient levels of key free radicals, a study of the relaxation kinetics in real time enables chemical mechanistic studies in situ.

Clericetti, Agostino↗

A Global Modeling Study on Carbonaceous Aerosol Microphysical Characteristics and Radiative Effects

Recently, attention has been drawn towards black carbon aerosols as a short-term climate warming mitigation candidate. However the global and regional impacts of the direct, indirect and semi-direct aerosol effects are highly uncertain, due to the complex nature of aerosol evolution and the way that mixed, aged aerosols interact with clouds and radiation. A detailed aerosol microphysical scheme, MATRIX, embedded within the GISS climate model is used in this study to present a quantitative assessment of the impact of microphysical processes involving black carbon, such as emission size distributions and optical properties on aerosol cloud activation and radiative effects. Our best estimate for net direct and indirect aerosol radiative flux change between 1750 and 2000 is -0.56 W/m2. However, the direct and indirect aerosol effects are quite sensitive to the black and organic carbon size distribution and consequential mixing state. The net radiative flux change can vary between -0.32 to -0.75 W/m2 depending on these carbonaceous particle properties at emission. Taking into account internally mixed black carbon particles let us simulate correct aerosol absorption. Absorption of black carbon aerosols is amplified by sulfate and nitrate coatings and, even more strongly, by organic coatings. Black carbon mitigation scenarios generally showed reduced radiative fluxeswhen sources with a large proportion of black carbon, such as diesel, are reduced; however reducing sources with a larger organic carbon component as well, such as bio-fuels, does not necessarily lead to a reduction in positive radiative flux.

Bauer, S. E.↗

A 3-D Model Study of Aerosol Composition and Radiative Forcing in the Asian-Pacific Region

The Georgia Tech/Goddard Global Ozone Chemistry Aerosol Radiation and Transport (GOCART) model will be used in analyzing the aerosol data in the ACE-Asia program. Our objectives are (1) to understand the physical, chemical, and optical properties of aerosol and the processes that control these properties over the Asian-Pacific region, (2) to determine the aerosol radiative forcing over the Asian-Pacific region, and (3) to investigate the interaction between aerosol and tropospheric chemistry. We will present the GOCART aerosol simulations of sulfate, dust, carbonaceous, and sea salt concentrations, their optical thicknesses, and their radiative effects. We will also show the comparisons of model results with data taken from previous field campaigns, ground-based sun photometer measurements, and satellite observations. Finally, we will present our plan for the ACE-Asia study.

Chin, Mian↗

A thermal scale modeling study for Apollo and Apollo applications, volume 1

The program is reported for developing and demonstrating the capabilities of thermal scale modeling as a thermal design and verification tool for Apollo and Apollo Applications Projects. The work performed for thermal scale modeling of STB; cabin atmosphere/spacecraft cabin wall thermal interface; closed loop heat rejection radiator; and docked module/spacecraft thermal interface are discussed along with the test facility requirements for thermal scale model testing of AAP spacecraft. It is concluded that thermal scale modeling can be used as an effective thermal design and verification tool to provide data early in a spacecraft development program.

Shannon, R. L.↗

Zonal winds near Venus' cloud top level - A model study of the interaction between the zonal mean circulation and the semidiurnal tide

The Holton (1982) wave-mean flow interaction model's primitive equation is presently adapted in order to clarify the interaction between the semidiurnal tide and the thermally driven mean meridional circulation near cloud top level. The model is found to produce midlatitude jets whose structure is insensitive to vertical shear of the background angular velocity, both above and below cloud top level; a sensitivity to background angular velocity at cloud top level, however, is noted. Agreement between the model tide and either the observed one or that generated by the more detailed calculations of Pechmann and Ingersoll (1984) is found to be greatest when the background angular velocity at the jet level is of the order of 30 percent larger than that which is observed.

Baker, Nancy L.↗

The GOCART Model Study of Aerosol Composition and Radiative Forcing: Present and Future

The Georgia Tech/Goddard Global Ozone Chemistry Aerosol Radiation and Transport (GOCART) model is used to simulate sulfate, dust, carbonaceous, and sea salt aerosols. The simulations are conducted using the present and future emission scenarios based on the IPCC projection. Distributions of individual aerosol components for the present day are compared with observations from field experiments, ground-based sun photometer networks, and remote sensing. Aerosol radiative forcing for the present day and the projected future will also be discussed.

Chin, Mian↗

A Modeling Study of Oceanic Response to Daily and Monthly Surface Forcing

The goal of this study is to investigate the effect of high-frequency surface forcing (wind stresses and heat fluxes) on upper-ocean response. We use the reduced-gravity quasi-isopycnal ocean model by Schopf and Loughe (1995) for this study. Two experiments are performed: one with daily and the other with monthly surface forcing. The two experiments are referred to as DD and MM, respectively. The daily surface wind stress is produced from the SSM/I wind data (Atlas et al. 1991) using the drag coefficient of Large and Pond (1982). The surface latent and sensible heat fluxes are estimated using the atmospheric mixed layer model by Seager et al. (1995) with the time-varying air temperature and specific humidity from the NCEP-NCAR reanalysis (Kalnay et al. 1996). The radiation is based on climatological shortwave radiation from the Earth Radiation Budget Experiment (ERBE) [Harrison et al. 1993] and the daily GEWEX SRB data. The ocean model domain is restricted to the Pacific Ocean with realistic land boundaries. At the southern boundary the model temperature and salinity are relaxed to the Levitus (1994) climatology. The time-mean SST distribution from MM is close to the observed SST climatology while the mean SST field from DD is about 1.5 C cooler. To identify the responsible processes, we examined the mean heat budgets and the heat balance during the first year (when the difference developed) in the two experiments. The analysis reveals that this is contributed by two factors. One is the difference in latent heat flux. The other is the difference in mixing processes. To further evaluate the responsible processes, we repeated the DD experiment by reducing the based vertical diffusion from 1e-4 to 0.5e-5. The resultant SST field becomes quite closer to the observed SST field. SST variability from the two experiments is generally similar, but the equatorial SST differences between the two experiments show interannual variations. We are investigating the possible mechanisms responsible for the different responses.

Sui, Chung-Hsiung↗