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The properties of the large molecular cloud complexes in the solar vicinity and in the inner Galaxy are summarized. Particular attention is paid to the stability of the clouds against the tidal field of the Galaxy, associated clouds of warm atomic hydrogen gas and star formation in the clouds. The linewidth-size relation is discussed and the possibility that it is an artifact of the blending of unrelated clouds at different distances is raised.
A combined physical and chemical modeling of the halos around molecular clouds is presented, with special emphasis on the H-to-H2 transition. On the basis of H I 21 cm observations, it is shown that the halos are extended. A physical model is employed in conjunction with a chemistry code to provide a self-consistent description of the gas. The radiative transfer code provides a check with H I, CO, and OH observations. It is concluded that the warm neutral halos are not gravitationally bound to the underlying molecular clouds and are isobaric. It is inferred from the observed extent of the H I envelopes and the large observed abundance of OH in them that the generally accepted rate for H2 information on grains is too large by a factor of two to three.
We report on the gamma-ray observations of giant molecular clouds Orion A and B with the Large Area Telescope (LAT) on board the Fermi Gamma-ray Space Telescope. The gamma-ray emission in the energy band between approx 100 MeV and approx 100 GeV is predicted to trace the gas mass distribution in the clouds through nuclear interactions between the Galactic cosmic rays (CRs) and interstellar gas. The gamma-ray production cross-section for the nuclear interaction is known to approx 10% precision which makes the LAT a powerful tool to measure the gas mass column density distribution of molecular clouds for a known CR intensity. We present here such distributions for Orion A and B, and correlate them with those of the velocity-integrated CO intensity (W(sub CO)) at a 1 deg 1 deg pixel level. The correlation is found to be linear over a W(sub CO) range of approx 10-fold when divided in three regions, suggesting penetration of nuclear CRs to most of the cloud volumes. The W(sub CO)-to-mass conversion factor, X(sub CO), is found to be approx 2.3 10(exp 20) / sq cm (K km/s)(exp -1) for the high-longitude part of Orion A (l > 212 deg), approx 1.7 times higher than approx 1.3 10(exp 20) found for the rest of Orion A and B. We interpret the apparent high X(sub CO) in the high-longitude region of Orion A in the light of recent works proposing a nonlinear relation between H2 and CO densities in the diffuse molecular gas.W(sub CO) decreases faster than the H2 column density in the region making the gas "darker" to W(sub CO).
The synthetic pathways to aromatic molecules inside photon-shielded dense molecular clouds remain a fundamental, unsolved enigma in astrochemistry and astrophysics, with low-temperature molecular growth routes involving aromatic radicals, such as prototype bicyclic naphthyl (C 10 H 7 • ), implicated as key sources. Here, exploiting crossed molecular beam experiments augmented by electronic structure calculations, unexpected pathways are exposed leading to the gas-phase formation of 1- and 2-naphthyl via barrierless bimolecular reactions of atomic carbon (C) with indene (C 9 H 8 ) and of dicarbon (C 2 ) with styrene (C 8 H 8 ) accompanied by ring expansion and cyclization together with aromatization. These facile routes challenge conventional wisdom that aromatic radicals are formed in deep space solely via “bright” gas-phase photochemistry of their closed-shell polycyclic aromatic hydrocarbon (PAH) precursors. A hitherto disregarded “dark” aromatic radical chemistry with aromatic radicals synthesized via gas-phase reactions offers new concepts on the chemical evolution of the chemistry of dark molecular clouds eventually culminating in the rapid formation of aromatics, fullerenes, and carbonaceous nanostructures.
Faint emission in the CO(1-0) and CO(2-1) spectral lines at mm wavelengths has been discovered from dark dust clouds in the inner disk of M31. These dust clouds are located in regions of the galaxy where there is little evidence of star-forming activity. The CO emission from these clouds is resolved, and comes from roughly the same area covered by the dust clouds. The line profile widths and cloud sizes imply cloud masses typical for giant molecular clouds (GMCs) in the Galaxy, but the observed surface brightnesses are only a few tenths of a K, and the typical CO(1-0) luminosities are a factor of about 10 smaller than those of Galactic GMCs of the same size and velocity line width. The CO(2-1)/CO(1-0) line ratios are very low, suggesting subthermal excitation, and precluding use of this ratio alone to determine the kinetic temperature. However, there are indications that the kinetic temperatures are significantly lower than the values of 10-30 K typical for Galactic GMCs, and may be close to the 2.7 K cosmic background.
The preliminary results are reported of a survey of every EINSTEIN image which overlaps any high-latitude molecular cloud in a search for X-ray emitting pre-main sequence stars. This survey, together with complementary KPNO and IRAS data, will allow the determination of how prevalent low mass star formation is in these clouds in general and, particularly, in the translucent molecular clouds.
A baseline model of the composition and abundances of grains and gases in molecular cloud cores and accretion disks around young stars is defined by employing: a wide range of astronomical data and theory; the composition of primitive bodies in the solar system; and solar elemental abundances. It is proposed that in the coldest portions of these objects the major grain species include amorphous olivine, amorphous orthopyroxene, volatile and refractory organics, water ice, troilite, and metallic iron. Using a combination of laboratory measurements of optical constants and asymptotic theory, values of the real and imaginary indices of refraction of these grain species over a wavelength range that runs from the vacuum UV to the radio domain are derived. Auxiliary information for these grain species, such as their vaporization temperatures bulk densities, and their fractional abundances by mass. The above information on grain properties in molecular cloud cores and accretion disks is used to estimate the Rosseland mean opacity of the grains in both environments and the IR and microwave opacity of grains in accretion disks.
Attention is given to a fairly homogeneous and nearly complete inventory of the molecular clouds in Orion and Monoceros, to a peak CO intensity of 0.5 K and a velocity resolution of 0.6 km/sec, from which a contour map of velocity-intergrated CO intensity is derived and presented with a schematic key. It is noted that, with the exception of Mon R2, the main areas of star formation in this survey lie on the forward surface of a large blunt cone or wedge of molecular clouds pointing towards the center of Barnard's Loop and the older subassociations of OB stars in Orion. This is a region which the present negative CO results, 21-cm observations, and galaxy counts, despite the currently low density, show to have once contained the dense molecular gas from which older OB stars formed.
A simple model of tidal encounters has been applied to the problem of an open cluster in a clumpy molecular cloud. The parameters of the clumps are taken from the Blitz, Stark, and Long (1988) catalog of clumps in the Rosette molecular cloud. Encounters are modeled as impulsive, rectilinear collisions between Plummer spheres, but the tidal approximation is not invoked. Mass and binding energy changes during an encounter are computed by considering the velocity impulses given to individual stars in a random realization of a Plummer sphere. Mean rates of mass and binding energy loss are then computed by integrating over many encounters. Self-similar evolutionary calculations using these rates indicate that the disruption process is most sensitive to the cluster radius and relatively insensitive to cluster mass. The calculations indicate that clusters which are born in a cloud similar to the Rosette with a cluster radius greater than about 2.5 pc will not survive long enough to leave the cloud. The majority of clusters, however, have smaller radii and will survive the passage through their parent cloud.
The stellar content and physical properties of the molecular clouds associated with 21 bright far-IR sources in the outer Galaxy have been determined through C-12O, C-13O, 6-cm radio continuum, and IRAS observations. The molecular cloud masses range from 200 to about 10,000 solar masses. The far-IR luminosity-to-mass ratio for these clouds has a mean value of 6.8 solar luminosity/solar masses and shows no correlation with the cloud mass, a result similar to that found for more massive clouds in the inner Galaxy. The radio continuum survey of the 21 bright far-IR sources indicates that most of these regions probably have a single, massive star providing most of the ionization. The cloud masses derived from virial and LTE analyses are in agreement, supporting the assumptions commonly made in their calculations, and a tight, near-linear correlation is found between the C-12O luminosity and the cloud mass. The H2 column density and integrated C-12O intensity are also correlated on a point-by-point basis, although the scatter is larger than the C-12O luminosity-cloud mass relation.
Observations at the 2.6 mm line of CO reveal the presence of a large number of molecular clouds at high galactic latitude. If the velocity dispersion of the clouds is a measure of their scale height, the mean distance of the ensemble detected is 100 pc. The clouds are unusual in that either they are not gravitationally bound or they are very deficient in CO relative to molecular hydrogen. These clouds represent a heretofore unrecognized component of the local interstellar medium. If they are pervasive in the Milky Way, they probably represent the small molecular cloud component of the interstellar medium.
In an attempt to determine the distances to four high-latitude molecular clouds (HLCs), echelle spectra near the Na I D lines, accurate MK spectral types, and photoelectric photometry for 25 nearby stars have been obtained. Fairly firm distance limits may be placed on MBM 40 (d smaller than or equal to 140 pc) and MBM 53 (d greater than or equal to 110 pc and less than or equal to 155 pc), based on the presence or absence of strong interstellar Na I absorption towards stars projected on or near those HLCs. Weak interstellar absorption lines observed toward many of the stars located near MBM 54 and 55 make the distances to those clouds less certain (about 265 pc for both). Interstellar CH absorption at 4300 A was detected in the spectrum of HD 218662, located behind MBM 53 with a CH column density of 2.1 x 10 to the 13th per sq cm, thus implying a CH abundance comparable to that observed in other molecular clouds. Morphological and velocity agreement among CO emission, the Na I absorption, the 100 micron infrared cirrus emission, and the 21 cm H I emission near these HLCs suggest a close association of the interstellar material responsible for those phenomena.
From a new survey of the 2.6 mm line of CO in the southern Milky Way, 37 molecular clouds were identified along the Carina arm from l = 282 deg to 336 deg with masses generally greater than 10 to the 5th solar mass. The clouds lie approximately every 700 pc along a spiral segment that is nearly 25 kpc long and has a pitch of about 10 deg. The total mass of these clouds is 40 x 10 to the 6th solar mass, or rougly 1 x 10 to the 6th solar mass each on average. The abrupt tangent point in molecular clouds at l = 280 deg and the characteristic loop structure in the l-v diagram are unmistakable evidence of a CO spiral arm in Carina. This arm apparently connects with the northern hemisphere Sagittarius arm to form a single 10 deg spiral which extends more than two-thirds of the way around the Galaxy.
The sulfur chemistry of (162173) Ryugu particles can be a powerful tracer of molecular cloud chemistry and small body processes, but it has not been well explored. We report identification of organosulfurs and a sulfate grain in two Ryugu particles, A0070 and A0093. The sulfate grain shows oxygen isotope ratios (δ 17 O = -11.0 ± 4.3 per mil, δ 18 O = -7.8 ± 2.3 per mil) that are akin to silicates in Ryugu but exhibit mass-independent sulfur isotopic fractionation (Δ 33 S = +5 ± 2 per mil). A methionine-like coating on the sulfate grain is isotopically anomalous (δ 15 N = +62 ± 2 per mil). Both the sulfate and organosulfurs can simultaneously form and survive during aqueous alteration within Ryugu’s parent body, under reduced conditions, low temperature, and a pH >7 in the presence of N-rich organic molecules. This work extends the heliocentric zone where anomalous sulfur, formed by selective photodissociation of H 2 S gas in the molecular cloud, is found.
The work outlined in this paper identifies 108 plausible T Tauri candidates in the regions of two high latitude translucent molecular clouds. Follow-up optical spectroscopy of these candidates is needed to resolve the question of whether or not star formation is present in these clouds. We have recently submitted a proposal to use the Kitt Peak National Observatory 2.1 meter telescope to take medium resolution spectra of the 14 PMS candidate X-ray sources in MBM 40 to determine spectral types and search for indicators of youth (strong Li absorption; H alpha emission) and we will submit a similar proposal to study the X-ray sources in MBM 55. Only spectra will provide an unambiguous determination of their pedigree. As part of an ongoing study of star formation at high galactic latitude we intend to analyze data in the ROSAT archives to investigate the possibility of star formation in all of the high latitude translucent molecular clouds observed. We believe that this project may yield a significant increase in our understanding of the star formation process for low-mass stars and of the nature of the translucent clouds.
The general lack of molecular oxygen in molecular clouds is an outstanding problem in astrochemistry. Extensive searches with the Submillimeter Astronomical Satellite, Odin, and Herschel have only produced two detections; upper limits to the O2 abundance in the remaining sources observed are about 1000 times lower than predicted by chemical models. Previous atomic oxygen observations and inferences from observations of other molecules indicated that high abundances of O atoms might be present in dense cores exhibiting large amounts of CO depletion. Theoretical arguments concerning the oxygen gas-grain interaction in cold dense cores suggested that, if O atoms could survive in the gas after most of the rest of the heavy molecular material has frozen out onto dust, then O2 could be formed efficiently in the gas. Using Herschel HIFI, we searched a small sample of four depletion cores-L1544, L694-2, L429, and Oph D-for emission in the low excitation O2 N(sub J)=3(sub 3)-1(sub 2) line at 487.249 GHz. Molecular oxygen was not detected and we derive upper limits to its abundance in the range of N(O2)/N (H2) approx. = (0.6-1.6) x10(exp -7). We discuss the absence of O2 in the light of recent laboratory and observational studies.
Over the course of this grant we used various spacecraft surveys of the Galaxy and M31 in conjunction with our extensive CO spectral line surveys to address central problems in galactic structure and the astrophysics of molecular clouds. These problems included the nature of the molecular ring and its relation to the spiral arms and central bar, the cosmic ray distribution, the origin of the diffuse X-ray background, the distribution and properties of x-ray sources and supernova remnants, and the Galactic stellar mass distribution. For many of these problems, the nearby spiral M31 provided an important complementary perspective. Our CO surveys of GMCs (Galactic Molecular Clouds) were crucial for interpreting Galactic continuum surveys from satellites such as GRO (Gamma Ray Observatory), ROSAT (Roentgen Satellite), IRAS (Infrared Astronomy Satellite), and COBE (Cosmic Background Explorer Satellite) because they provided the missing dimension of velocity or kinematic distance. GMCs are a well-defined and widespread population of objects whose velocities we could readily measure throughout the Galaxy. Through various emission and absorption mechanisms involving their gas, dust, or associated Population I objects, GMCs modulate the galactic emission in virtually every major wavelength band. Furthermore, the visibility. of GMCs at so many wavelengths provided various methods of resolving the kinematic distance ambiguity for these objects in the inner Galaxy. Summaries of our accomplishments in each of the major wavelength bands discussed in our original proposal are given
A method of mass estimation for molecular clouds is presented which is based on approximate balance in the outer cloud layers between the cloud's gravitation, the galactic tide, and internal pressure. The largest observed clouds, which have greatest linear extents of 100 pc, are found to have masses of at least 200,000 solar masses. The cloud masses cannot exceed this lower limit by more than a factor of 3, or the velocity distributions of disk stars would be more relaxed than is actually observed. This implied upper limit to cloud masses combined with the galactic tide may be related to the absence of clouds at galactocentric radii less than 4 kpc. If Sagittarius B2 is bound, its mass must be more than 50 million solar masses.