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At least 127 records · Page 7

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NASA NTRS1987

Ketimine modifications as a route to novel amorphous and derived semicrystalline poly(arylene ether ketone) homo- and copolymers

A series of amine terminal amorphous poly(arylene ether ketone) oligomers of controlled molecular weights (2-15 K) were synthesized. These oligomers have been found to undergo 'self-crosslinking' reactions upon heating above 220 C, via the reaction of the terminal amine groups with the in-chain keto carbonyl functionalities. The resulting networks are ductile, chemically resistant, and nonporous. The networks obtained via generated ketimine functionality were characterized by solid state NMR. They have also been found to be remarkably stable toward hydrolysis. Ketimine functional bishalide monomers have also been synthesized. Such monomers have been utilized to synthesize a wide variety of amorphous poly(arylene ether) ketimine polymers. A high molecular weight hydroquinone functional poly(arylene ether) ketimine has been acid treated to regenerate a poly(arylene ether ketone) backbone in solution. This novel procedure thus allows for the synthesis of important matrix resins under relatively mild conditions.

Mohanty, D. K.↗

NASA NTRS1988

Novel technique to measure the microwave response of high T(c) superconductors between 4.2 and 200 K

This paper describes a novel technique for measurements of the complex surface impedance Z(s) of high-T(c) superconductors over an extremely wide range of temperature, from 4.2 K and at least 200 K. The technique uses a superconducting Pb-plated Cu high-Q-cavity resonator operated at an ambient temperature of 4.2 K, with the sample (typically a 3-mm-diam x 1-mm-thick disk) mounted on a sapphire rod in the center of cavity, at a high B-field and thermally insulated from the cavity walls, making it possible to control the sample temperature externally. Since the cavity characteristics are dominated by the sample properties (the contribution of the Pb-covered walls maintained at 4.2 K is negligible), measurement of the cavity Q and resonant frequency makes it possible to measure Zs as a function of the sample temperature. The Z(s) values for bulk Y1Ba2Cu3O(y) and La(1.85)Sr(0.15)CuO4 were measured over a temperature range 4.2-100 K.

Sridhar, S.↗

NASA NTRS1987

Novel optoelectronic devices; Proceedings of the Meeting, The Hague, Netherlands, Mar. 31-Apr. 2, 1987

The present conference on novel optoelectronics discusses topics in the state-of-the-art in this field in the Netherlands, quantum wells, integrated optics, nonlinear optical devices and fiber-optic-based devices, ultrafast optics, and nonlinear optics and optical bistability. Attention is given to the production of fiber-optics for telecommunications by means of PCVD, lifetime broadening in quantum wells, nonlinear multiple quantum well waveguide devices, tunable single-wavelength lasers, an Si integrated waveguiding polarimeter, and an electrooptic light modulator using long-range surface plasmons. Also discussed are backward-wave couplers and reflectors, a wavelength-selective all-fiber switching matrix, the impact of ultrafast optics in high-speed electronics, the physics of low energy optical switching, and all-optical logical elements for optical processing.

Adams, Michael J.↗

NASA NTRS1989

A novel multistage estimation of the signal parameters of a possibly data-modulated sinusoid under very high dynamics

A novel multistage estimation scheme is presented for estimating the parameters of a received carrier signal possibly phase-modulated by unknown data, and experiencing very high Doppler, Doppler rate, etc. Such a situation arises, for example, in the case of Global Positioning Systems (GPS) where the signal parameters are directly related to the position, velocity, acceleration and jerk of the GPS receiver. In the proposed multistage scheme, the first stage estimator operates as a coarse estimator resulting in higher rms estimation errors but with a relatively small probability of the frequency estimation error exceeding one-half of the sampling frequency (an event termed cycle slip). The second state of the estimator operates on the error signal available from the first stage, refining the overall estimates, and in the process also reduces the number of cycle slips. The first stage algorithm is selected to be a modified least squares algorithm operating upon the differential signal model and referred to as differential least squares. This estimation stage provides relatively coarse estimates of the frequency and its derivatives. The second algorithm is simply an extended Kalman filter which also yields the estimate of the phase along with a more refined estimate of frequency as well. A major advantage of the proposed algorithm is a reduction in the threshold on received carrier power-to-noise power spectral density ratio as compared to the threshold achievable by either of these algorithms alone. In fact, it appears from the simulations that for the case of an unmodulated carrier, the proposed scheme achieves the same threshold as for an almost exact and computationally intensive implementation of the maximum likelihood estimator.

Kumar, Rajendra↗

NASA NTRS1988

Novel tether-connected two-dimensional structures for low earth orbits

This paper proposes novel tether-connected two-dimensional structures with a size of several hundred square kilometers for low earth orbits. The attitude of these structures is gravitationally stabilized with respect to an earth-oriented reference frame. A stable shape is obtained by utilizing environmental forces such as differential air drag or electrodynamic forces which stiffen the system. Configurations which differ in geometry and in the number of connecting tethers are presented in the paper. The static stability of each configuration is analyzed as a function of design and orbital parameters. A brief discussion of the applications of such tethered systems is provided at the end of the paper.

Lorenzini, Enrico C.↗

NASA NTRS1989

Novel photovoltaic delta-doped GaAs superlattice structure

An asymmetric delta-doped GaAs structure is described which exhibits novel photovoltaic effects and low-intensity nonlinear optics. Of particular interest in this kind of structure is the ability to design the electrooptical and nonlinear optical properties and the material response time over a wide range by appropriate design of the doping profile.

Glass, A. M.↗

NASA NTRS1990

A novel multireceiver communications system configuration based on optimal estimation theory

A multireceiver configuration for the purpose of carrier arraying and/or signal arraying is presented. Such a problem arises for example, in the NASA Deep Space Network where the same data-modulated signal from a spacecraft is received by a number of geographically separated antennas and the data detection must be efficiently performed on the basis of the various received signals. The proposed configuration is arrived at by formulating the carrier and/or signal arraying problem as an optimal estimation problem. Two specific solutions are proposed. The first solution is to simultaneously and optimally estimate the various phase processes received at different receivers with coupled phase locked loops (PLLs) wherein the individual PLLs acquire and track their respective receivers' phase processes, but are aided by each other in an optimal manner. However, when the phase processes are relatively weakly correlated, and for the case of relatively high values of symbol energy-to-noise spectral density ratio, a novel configuration for combining the data modulated, loop-output signals is proposed. The scheme can be extended to the case of low symbol energy-to-noise case by performing the combining/detection process over a multisymbol period. Such a configuration results in the minimization of the effective radio loss at the combiner output, and thus a maximization of energy per bit to noise-power spectral density ration is achieved.

Kumar, R.↗

NASA NTRS1990

Novel laser gain and time-resolved FTIR studies of photochemistry

Several techniques are discussed which can be used to explore laboratory photochemical processes and kinetics relevant to planetary atmospheres; these include time-resolved laser gain-versus-absorption spectroscopy and time-resolved Fourier transform infrared (FTIR) emission studies. The laser gain-versus-absorption method employed tunable diode and F-center lasers to determine the yields of excited photofragments and their kinetics. The time-resolved FTIR technique synchronizes the sweep of a commercial FTIR with a pulsed source of light to obtain emission spectra of novel transient species in the infrared. These methods are presently being employed to investigate molecular photodissociation, the yields of excited states of fragments, their subsequent reaction kinetics, Doppler velocity distributions, and velocity-changing collisions of translationally fast atoms. Such techniques may be employed in future investigations of planetary atmospheres, for example to study polycyclic aromatic hydrocarbons related to cometary emissions, to analyze acetylene decomposition products and reactions, and to determine spectral features in the near infrared and infrared wavelength regions for planetary molecules and clusters.

Leone, Stephen R.↗

NASA NTRS1989

Novel fabrication technique for improving the figure-of-merit of thermoelectric materials

Reduction of the thermal conductivity of thermoelectric materials in order to improve the figure of merit and, hence, the conversion efficiency is discussed. A novel fabrication technique that reduces the thermal conductivity without too adverse an effect on the electrical properties is reported. This is achieved by producing an oxygen-free, very-fine-grain SiGe alloy with very small (on the order of 50 A) precipitates.

Beaty, J. S.↗

NASA NTRS1990

A novel sample-positioning system for microgravity application

This paper proposes a novel method for sample positioning in containerless processing at microgravity, using a system based on pulsed lasers. The method has two attributes. First, by generating beams that cancel out vectorially, the suspended material can be heated without being accelerated, a feature that can be used in melting and heat-treatment applications. Second, the specimen can be positioned within a fairly large work space. It is emphasized that this method can service a regime unfulfilled by the other levitation methods, such as electromagnetic levitation, active magnetic suspension, acoustic levitation, of electrostatic suspension.

Sridharan, G.↗

NASA NTRS1990

Novel Si(1-x)Ge(x)/Si heterojunction internal photoemission long-wavelength infrared detectors

The feasibility of a novel p(+)-Si(1-x)Ge(x)-p-Si heterojunction internal photoemission (HIP) IR detector is demonstrated. A degenerately doped p(x)-Si(1-x)Ge(x) layer is required for strong IR absorption to generate photoexcited holes. The Si(1-x)Ge(x) layers are grown by molecular beam epitaxy, with boron concentrations up to 10 to the 20th/cu cm achieved by using an HBO2 source. Photoresponse at wavelengths ranging from 2 to 10 microns has been obtained with quantum efficiencies above 1 percent. The tailorable cutoff wavelength of the HIP detector has been demonstrated by varying the Ge composition ratio in the Si(1-x)Ge(x) layers.

Lin, T. L.↗

NASA NTRS1989

Viscosity measurements at high temperature and high pressure: A novel technique

The extensive numerical modelling of transport phenomena was performed for the melt growth of mercury cadmium telluride. To increase the fidelity of modelling the kinematic viscosity of liquid Hg(1-x)Cd(x)Te was determined at various compositions in the range of x between 0 and 0.2 and at temperatures around and below the respective melting point. The phase diagram of Hg(1-x)Cd(x)Te shows that for this range the melting point varies from 670 C for pure HgTe to 790 C at x=0.2. The vapor pressure above the melt varies correspondingly from 15 to about 40 atm. Hence, the measurement of viscosities in this system requires a technique that allows for combinations of high temperatures and pressures. In addition, a closed isothermal system is required. The high pressure melt container must also be inert to molten Hg(1-x)Cd(x)Te to avoid possible errors from contamination of the liquid. A novel technique that largely circumvents the above experimental problems is described. Its theory is also presented.

Jin, Wei-Qing↗

NASA NTRS1991

A novel method of testing the shear strength of thick honeycomb composites

Sandwich composites of aluminum and glass/phenolic honeycomb core were tested for shear strength before and after impact damage. The assessment of shear strength was performed in two ways; by four point bend testing of sandwich beams and by a novel double lap shear (DLS) test. This testing technique was developed so smaller specimens could be used, thus making the use of common lab scale fabrication and testing possible. The two techniques yielded similar data. The DLS test gave slightly lower shear strength values of the two methods but were closer to the supplier's values for shear strength.

Hodge, A. J.↗

NASA NTRS1990

Time-dependent treatment of scattering. II - Novel integral equation approach to quantum wave packets

The novel wave-packet propagation scheme presented is based on the time-dependent form of the Lippman-Schwinger integral equation and does not require extensive matrix inversions, thereby facilitating application to systems in which some degrees of freedom express the potential in a basis expansion. The matrix to be inverted is a function of the kinetic energy operator, and is accordingly diagonal in a Bessel function basis set. Transition amplitudes for various orbital angular momentum quantum numbers are obtainable via either Fourier transform of the amplitude density from the time to the energy domain, or the direct analysis of the scattered wave packet.

Sharafeddin, Omar A.↗

NASA NTRS1991

A novel boundary layer sensor utilizing domain switching in ferroelectric liquid crystals

This paper describes the design and the principles of operation of a novel sensor for the optical detection of a shear stress field induced by air or gas flow on a rigid surface. The detection relies on the effects of shear-induced optical switching in ferroelectric liquid crystals. It is shown that the method overcomes many of the limitations of similar measuring techniques including those using cholesteric liquid crystals. The present method offers a preferred alternative for flow visualization and skin friction measurements in wind-tunnel experiments on laminar boundary layer transition investigations. A theoretical model for the optical response to shear stress is presented together with a schematic diagram of the experimental setup.

Parmar, D. S.↗

NASA NTRS1990

Application of a novel multi-stage signal parameter estimator to high dynamic GPS receivers

The performance of a novel multistage estimator when applied to the estimation of the position, velocity, and acceleration of high dynamic Global Positioning System (GPS) receivers is discussed. For the present application, a two-stage specialization of the more general estimation scheme is considered, wherein the first-stage algorithm is selected to be a modified least-squares algorithm operating upon the differential signal model and referred to as differential least-squares (DLS) and the second stage is simply an extended Kalman filter (EKF). In terms of the threshold on received carrier power-to-noise power spectral density ratio (CNR), when compared to the single-stage EKF algorithm, the DLS-EKF algorithm is about 1.5-2.0 dB better in terms of threshold and outperforms the crossproduct AFC (automatic frequency control) loop by 2-5 dB. For the case when data modulation is present, the proposed scheme provides an improvement of about 6 dB in terms of CNR compared to an earlier approximate MLE (maximum likelihood estimation) scheme. There are also very significant improvements in terms of other performance measures.

Kumar, R.↗

NASA NTRS1990

Novel computational strategies for solution of large-scale structural problems

Novel computational strategies are presented for the analysis of large and complex structures. The strategies are based on generating the response of the complex structure using large perturbations from that of a simpler model, associated with a simpler structure (or a simpler mathematical/discrete model of the original structure). Numerical examples are presented to demonstrate the effectiveness of the strategies developed.

Noor, Ahmed K.↗

NASA NTRS1991

Theoretical performance of novel multipliers at millimeter and submillimeter wavelengths

A theoretical comparison of various low and high order multipliers for 200 GHz and 1 THz has been carried out. Novel diodes including single barrier varactors, barrier-intrinsic-n(+)diodes and high electron mobility varactors are shown to have excellent theoretical performance, comparable or better than the conventional Schottky varactors for single and double diode frequency multipliers at millimeter and submillimeter wavelengths, whereas quantum well diodes, since they suffer from high resistive losses, are shown to be less attractive. In comparison to the conventional Schottky varactor, these new diodes have some potential advantages in their characteristics such as a stronger nonlinearity or a special symmetry. For future optimization some general comments on these advantages as well as other factors affecting multiplication are given.

Tolmunen, Timo J.↗