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NASA NTRS1994

Climate Change on Mars

Today, Mars is cold and dry. With a 7 mbar mean surface pressure, its thin predominantly CO2 atmosphere is not capable of raising global mean surface temperatures significantly above its 217K effective radiating temperature, and the amount of water vapor in the atmosphere is equivalent to a global ocean only 10 microns deep. Has Mars always been in such a deep freeze? There are several lines of evidence that suggest it has not. First, there are the valley networks which are found throughout the heavily cratered terrains. These features are old (3.8 Gyr) and appear to require liquid water to form. A warm climate early in Mars' history has often been invoked to explain them, but the precise conditions required to achieve this have yet to be determined. Second, some of the features seen in orbiter images of the surface have been interpreted in terms of glacial activity associated with an active hydrological cycle some several billion years ago. This interpretation is controversial as it requires the release of enormous quantities of ground water and enough greenhouse warming to raise temperatures to the melting point. Finally, there are the layered terrains that characterize both polar regions. These terrains are geologically young (10 Myr) and are believed to have formed by the slow and steady deposition of dust and water ice from the atmosphere. The individual layers result from the modulation of the deposition rate which is driven by changes in Mars' orbital parameters. The ongoing research into each of these areas of Martian climate change will be reviewed, and similarities to the Earth's climate system will be noted.

Haberle, R. M.↗
NASA NTRS1997

A blast of gas in the latest Paleocene: simulating first-order effects of massive dissociation of oceanic methane hydrate

Carbonate and organic matter deposited during the latest Paleocene thermal maximum is characterized by a remarkable -2.5% excursion in delta 13C that occurred over approximately 10(4) yr and returned to near initial values in an exponential pattern over approximately 2 x 10(5) yr. It has been hypothesized that this excursion signifies transfer of 1.4 to 2.8 x 10(18) g of CH4 from oceanic hydrates to the combined ocean-atmosphere inorganic carbon reservoir. A scenario with 1.12 x 10(18) g of CH4 is numerically simulated here within the framework of the present-day global carbon cycle to test the plausibility of the hypothesis. We find that (1) the delta 13C of the deep ocean, shallow ocean, and atmosphere decreases by -2.3% over 10(4) yr and returns to initial values in an exponential pattern over approximately 2 x 10(5) yr; (2) the depth of the lysocline shoals by up to 400 m over 10(4) yr, and this rise is most pronounced in one ocean region; and (3) global surface temperature increases by approximately 2 degrees C over 10(4) yr and returns to initial values over approximately 2 x 10(6) yr. The first effect is quantitatively consistent with the geologic record; the latter two effects are qualitatively consistent with observations. Thus, significant CH4 release from oceanic hydrates is a plausible explanation for observed carbon cycle perturbations during the thermal maximum. This conclusion is of broad interest because the flux of CH4 invoked during the maximum is of similar magnitude to that released to the atmosphere from present-day anthropogenic CH4 sources.

Non-NASA Center↗
NASA NTRS2013

Modeling and Evaluation of the Global Sea-Salt Aerosol Distribution: Sensitivity to Emission Schemes and Resolution Effects at Coastal/Orographic Sites

One of the major sources of uncertainty in model estimates of the global sea-salt aerosol distribution is the emission parameterization. We evaluate a new sea-salt aerosol life cycle module coupled to the online multi-scale chemical transport model NMMB/BSC-CTM. We compare 5 year global simulations using five state-of-the-art sea-salt open-ocean emission schemes with monthly averaged coarse aerosol optical depth (AOD) from selected AERONET sun photometers, surface concentration measurements from the University of Miami's Ocean Aerosol Network, and measurements from two NOAA/PMEL cruises (AEROINDOEX and ACE1). Model results are highly sensitive to the introduction of sea-surface-temperature (SST)-dependent emissions and to the accounting of spume particles production. Emission ranges from 3888 teragrams per year to 8114 teragrams per year, lifetime varies between 7.3 hours and 11.3 hours, and the average column mass load is between 5.0 teragrams and 7.2 teragrams. Coarse AOD is reproduced with an overall correlation of around 0.5 and with normalized biases ranging from +8.8 percent to +38.8 percent. Surface concentration is simulated with normalized biases ranging from minus 9.5 percent to plus 28 percent and the overall correlation is around 0.5. Our results indicate that SST-dependent emission schemes improve the overall model performance in reproducing surface concentrations. On the other hand, they lead to an overestimation of the coarse AOD at tropical latitudes, although it may be affected by uncertainties in the comparison due to the use of all-sky model AOD, the treatment of water uptake, deposition and optical properties in the model and/or an inaccurate size distribution at emission.

Bias↗
NASA NTRS1986

A comparison of the regional slope characteristics of Venus and earth - Implications for geologic processes on Venus

The range of 3 degree by 3 degree regional slopes of the Earth and Venus is similar (approximately 0.0-2.4 degrees), although the surface distribution of these values differs significantly. On earth, cratonic and abyssal plains form extensive regions of 0.0 degree slope. Within these regions a variety of features (mid-ocean ridges, volcanic island chains, subduction zones, and floded mountains) have regional slope characteristics influenced by seafloor spreading and plate recycling, as well as an active weathering regime. The plains provinces of Venus are much more rugged than earth's plains and are marked by numerous closely spaced circular and linear features (0.1-0.2 degree regional slope) concentrated into broad linear zones of global extent. Although Venus highlands are bounded by narrow zones of relatively steep slope, the margins of Aphrodite Terra and Beta Regio are not as steep as earth's continental margins and appear to be best developed parallel to the trends of major chasmata within these regions. Ishtar Terra's margins are significantly steeper and more continuous than other highland margins and are comparable to passive margins on earth. The Venus highlands do not contain appreciable smooth, flat interior regions, implying that highland topography is not significantly modified by erosion or deposition.

Sharpton, V. L.↗
NASA NTRS1998

Site Selection for Mars Exopaleontology in 2001

The microbial fossil record encompasses a wide range of information, including cellular remains, stromatolites, biofabrics, trace fossils, biominerals and chemofossils. The preservation of fossils is strongly influenced by the physical, chemical and biological factors of the environment which, acting together, ultimately determine the types of information that will be captured and retained in the rock record. The critical factor in assessing the suitability of a site for a microbial fossil record is the paleoenvironment. The reconstruction of ancient sedimentary environments usually requires the integration of a wide variety of geological information, including the shape, geometry and internal structure of sedimentary deposits, their mineralogy, and geochemistry. For Mars, much of our knowledge about past environments is based on orbital imaging of geomorphic features. This evidence provides an important context and starting point for site selection. However, our knowledge of the martian surface is quite limited, and a major goal of the upcoming exploration effort is to reconstruct the history of Martian volatiles, climate, and hydrology as a context for the exploration for past or present life. Mineralogical mapping from orbit will be an important key in this effort. In exploring for evidence of past life, terrestrial experience suggests that the long-term preservation of biological information as fossils occurs under a fairly narrow range of geological conditions that are well known to paleontologists (1). In detrital sedimentary systems, microbial fossilization is favored by rapid burial in fine-grained, clay-rich sediments. In chemical sedimentary systems, preservation is enhanced by rapid entombment in fine-grained chemical precipitates. For long term preservation, host rocks must be composed of stable minerals that resist chemical weathering, and which form an impermeable matrix and closed chemical system that can protect biosignatures from alteration during subsequent diagenetic change or metamorphism. In this context, host rocks composed of highly ordered, chemically-stable mineral phases, like silica (forming cherts) or phosphate (forming phosphorites), are especially favored. Such lithologies tend to have very long crustal residence times and (along with carbonates and shales), are the most common host rocks for the Precambrian microfossil record on Earth. If we assume that a subsurface hydrosphere has been present throughout martian history, then life could have originated there at any time, perhaps emerging at the surface periodically when climate changes, induced by external forcing or endogenous processes (e.g. volcanism), allowed liquid water to exist at the surface. The recent discovery of subsurface chemolithoautotrophic organisms which are capable of synthesizing organic substrates from C02 and H2 liberated from the aqueous weathering of basalt, is especially. relevant as a model for martian life. While a subsurface habitable zone may yet exist on Mars, access to such environments will likely require drilling to depths of several kilometers. Given the technological challenge of deep drilling, this is unlikely to occur prior to human missions. So, even if there is extant life on Mars today in subsurface habitats, it may be much easier to find its fossil counterparts in ancient deposits exposed at the surface. In exploring for a fossil record in subsurface environments on Mars there are several geological situations that may provide access to the appropriate materials. These include 1) ejecta from impact craters, 2) talus slopes, debris flows or alluvial fans developed below the walls of deep canyons, and 3) the deposits of outflood channels. Examples of aqueous mineral deposits of formed in subsurface environments that could harbor a microbial fossil record include such things as cements in detrital sedimentary rocks, low temperature diagenetic minerals deposited in veins, or filling vesicles in volcanic rocks, and hydrothermal deposits formed below the upper temperature limit for life (about 160 degrees C). There are many sites within the present latitudinal constraints for the 2001 mission (15 deg S to 30 deg N) that meet these requirements. But the practical problem with these kinds of deposits is that they tend to be disseminated, making up only a small percentage of a host rock. Even with mineralogical information provided by the Thermal Emission Spectrometer (TES) presently in orbit around Mars, predicting their occurrence ahead of time may be quite difficult. The deposits of surficial aqueous sedimentary systems are likely to provide the largest targets for site selection in 2001. Of these, the deposits of hydrothermal systems (subaerial and subaqueous thermal springs) have been discussed previously. It is likely that hydrothermal systems were widespread on Mars early in its history and a number of common geo-tectonic settings on Mars are likely to have hosted hydrothermal activity. Most of these are represented within the latitudinal constraints presently identified for 2001. However, the deposits of surface spring systems are likely to be difficult to find as well. On Earth, exposure areas for hydrothermal spring mounds are typically a few square kms, less than a single TES pixel. But such deposits may be quite abundant within some volcanic terrains, It is estimated, for example, that between 15-20% of the floor of Yellowstone caldera is covered by thermal spring deposits. In such abundances, subaerial sinters could well be detected by TES. Where exposed, the shallow subsurface portions of these systems may be quite a lot larger (perhaps tens of square kms), although (as noted above) mineralization may be finely disseminated in the basement rock, making remote detection more difficult. Paleolake Basins. There are a large number of potential paleolake basins on Mars (inclusive of impact craters and volcanic calderas) that have been previously identified using Viking images. Most of these lie in the southern highlands beyond the l5 deg S constraint for 2001. However, deposits of paleolakes may offer the largest and most easily identified exopaleontological targets from orbit. Based on a variety of arguments, some workers have suggested that there was once an ancient ocean on the northern plains, and some sites of interest (potential shoreline terraces) fall within the 30 deg N constraint. From a paleontological standpoint the most interesting places of this type are terminal paleolake basins which are likely to have been both saline and alkaline. Models by Schaefer suggest such environments could be widespread on Mars. The conditions in terminal lake basin settings favor widespread chemical sedimentation, an important condition for microbial fossilization. Important lithological targets for a microbial fossil record in terminal lake basins include spring-deposited carbonates, shoreline cements, a wide variety of evaporite minerals and fine-grained detrital sediments including shales, marls, and water-lain volcanic ash deposits. In developing a strategy to explore for ancient hydrothermal deposits on Mars, we can learn from the methods that have been developed by explorationists to explore for economic mineral deposits on Earth. Due to their simple mineralogy, hydrothermal deposits can often be detected using remote sensing methods. Common thermal spring mineral assemblages include silica, carbonate, and various metallic oxides and sulfides. But there are also a number of diagnostic silicate minerals, including clays, formed by the hydrothermal alteration of country rocks. These hydrothermal minerals have characteristic spectral signatures that could be detected from Mars orbit using high resolution infrared remote sensing methods. In playa lake settings, evaporite deposits often form a predictable "bull's eye" pattern with carbonates being deposited in marginal basin areas, and sulfates and halides occurring progressively more basinward. The floors of some impact craters on Mars, such as "White Rock" and Bequeral Crater (see Oxia Palus NE, Site 148), have floor deposits that could be evaporites, inclusive of carbonates. Evaporite minerals possess characteristic spectral signatures in the infrared and could similarly be identified from Mars orbit using high resolution remote sensing methods. Clearly, utilization of TES data will be important for optimizing site selection for Exopaleontology, and every effort should be made to benefit from that data before a final decision is made.

Farmer, Jack↗
NASA NTRS1993

Transport and residence times of tropospheric aerosols inferred from a global three-dimensional simulation of Pb-210

A global three-dimensional model is used to investigate the transport and tropospheric residence time of Pb-210, an aerosol tracer produced in the atmosphere by radioactive decay of Rn-222 emitted from soils. The model uses meteorological input with 4 deg x 5 deg horizontal resolution and 4-hour temporal resolution from the Goddard Institute for Space Studies general circulation model (GCM). It computes aerosol scavenging by convective precipitation as part of the wet convective mass transport operator in order to capture the coupling between vertical transport and rainout. Scavenging in convective precipitation accounts for 74% of the global Pb-210 sink in the model; scavenging in large-scale precipitation accounts for 12%, and scavenging in dry deposition accounts for 14%. The model captures 63% of the variance of yearly mean Pb-210 concentrations measured at 85 sites around the world with negligible mean bias, lending support to the computation of aerosol scavenging. There are, however, a number of regional and seasonal discrepancies that reflect in part anomalies in GCM precipitation. Computed residence times with respect to deposition for Pb-210 aerosol in the tropospheric column are about 5 days at southern midlatitudes and 10-15 days in the tropics; values at northern midlatitudes vary from about 5 days in winter to 10 days in summer. The residence time of Pb-210 produced in the lowest 0.5 km of atmosphere is on average four times shorter than that of Pb-210 produced in the upper atmosphere. Both model and observations indicate a weaker decrease of Pb-210 concentrations between the continental mixed layer and the free troposphere than is observed for total aerosol concentrations; an explanation is that Rn-222 is transported to high altitudes in wet convective updrafts, while aerosols and soluble precursors of aerosols are scavenged by precipitation in the updrafts. Thus Pb-210 is not simply a tracer of aerosols produced in the continental boundary layer, but also of aerosols derived from insoluble precursors emitted from the surface of continents. One may draw an analogy between Pb-210 and nitrate, whose precursor NO(sub x) is sparingly soluble, and explain in this manner the strong correlation observed between nitrate and Pb-210 concentrations over the oceans.

Balkanski, Yves J.↗
NASA NTRS1994

Exobiology site priorities for Mars Pathfinder

The fact that life developed on the Earth within the first billion years of its history makes it quite plausible that life may have also developed on Mars. If life did develop on Mars, it undoubtedly left behind a fossil record. Such a fossil record is likely to be more accessible than either subsurface environments that may harbor life, or scattered 'oases' that may be present at the surface. Consequently, the post-Viking approach of Mars exobiology has shifted focus to search for evidence of an ancient martian biosphere. This has led to the emergence of a new subdiscipline of paleontology, herein termed 'exopaleontology', which deals with the exploration for fossils on other planets and whose core concepts derive from Earth-based Precambrian paleontology, microbial ecology, and sedimentology. Potential targets on Mars for subaqueous spring deposits, sedimentary cements, and evaporites are ancient terminal lake basins where hydrological systems could have endured for some time under arid conditions. Potential targets for the Mars Pathfinder mission include channeled impact craters and areas of deranged drainage associated with outflows in northwest Arabia and Xanthe Terra, where water may have ponded temporarily to form lakes. The major uncertainty of such targets is their comparatively younger age and the potentially short duration of hydrological activity compared to older paleolake basins found in the southern hemisphere. However, it has been suggested that cycles of catastrophic flooding associated with Tharsis volcanism may have sustained a large body of water, Oceanus Borealis, in the northern plains area until quite late in martian history. Although problematic, the shoreline areas of the proposed northern ocean provide potential targets for a Mars Pathfinder mission aimed at exploring for carbonates or other potentially fossiliferous marine deposits. Carbonates and evaporites possess characteristic spectra signatures in the near-infrared and should be detectable using rover-based spectroscopy and other methods for in situ mineralogical analysis.

Farmer, Jack D.↗
NASA NTRS2002

Iridium and Spherules in Late Eocene Impact Deposits

We have been independently examining the Ir (FTK) and spherule (SL) contents of recently discovered late Eocene impact deposits from the south Atlantic and western Indian oceans. These include ODP Sites 1090 [14,15], 709 [lo], and 699 [Liu in prep.]. Iridium abundances at these sites are within the typical range reported for late Eocene deposits, with peak concentrations between 100 and 1000 pg/g. In Table 1 we present estimated net Ir fluences (in ng Ir/cm ) for these and nine other sites. Although there are fewer sites than the K/T boundary, the average of 9 ng Ir/cm2 is probably a good estimate of the late Eocene global flux. This is enough Ir for a 6 km comet (assuming 250 ng/g Ir, p=1.5), is sufficient to produce the Popigai or Chesapeake Bay structures, and is 16% of the flux estimated for the K/T boundary (55 ng/cm2 [ 161). Figure 1 shows the relative abundances of Ir, glassy microtektites and cpx-bearing spherules in sediments from Sites 699 and 1090, which are separated by only 3100 km. Although these two sites have similar Ir anomalies, the abundances of spherules are quite different. Site 1090 has well-defined peaks for both types of spherules, with a peak of 562 cpx spheruledg, while Site 699 contains only a few glassy microtektites and no cpx spherules. While the different abundances of spherules may reflect a heterogeneous distribution of spherules on the Earth s surface, an equally likely cause of this difference may be differential preservation of spherules in the sediment. recovered are only a trace residue of the initial impact deposit. Earlier work found 0.22 ng/g Ir in glassy microtektites from Site 689 [17], an insufficient concentration to support 0.16 ng/g in the bulk sediment at this site. We measured 15 ng/g Ir in a group of 95 cpx spherules from Site 1090 with sizes from 63 to -200 pm, a set typical of the size distribution at this site. Although this is a significant concentration it also cannot support the Ir peak. We presently lack quantitative data on the mass concentration of cpx spherules in Site 1090 sediments, but it is certainly <1 mg/g in The impact record in the late Eocene is very different from that at the Cretaceous-Tertiary In contrast, the late Eocene probably experienced multiple impact events.

Kyte, F. T.↗
NASA NTRS1997

Searching for Biogeochemical Cycles on Mars

The search for life on Mars clearly benefits from a rigorous, yet broad, definition of life that compels us to consider all possible lines of evidence for a martian biosphere. Recent studies in microbial ecology illustrate that the classic definition of life should be expanded beyond the traditional definition of a living cell. The traditional defining characteristics of life are threefold. First, life is capable of metabolism, that is, it performs chemical reactions that utilize energy and also synthesize its cellular constituents. Second, life is capable of self-replication. Third, life can evolve in order to adapt to environmental changes. An expanded, ecological definition of life also recognizes that life is a community of organisms that must interact with their nonliving environment through processes called biogeochemical cycles. This regenerative processing maintains, in an aqueous conditions, a dependable supply of nutrients and energy for growth. In turn, life can significantly affect those processes that control the exchange of materials between the atmosphere, ocean, and upper crust. Because metabolic processes interact directly with the environment, they can alter their surroundings and thus leave behind evidence of life. For example, organic matter is produced from single-carbon-atom precursors for the biosynthesis of cellular constituents. This leads to a reservoir of reduced carbon in sediments that, in turn, can affect the oxidation state of the atmosphere. The harvesting of chemical energy for metabolism often employs oxidation-reduction reactions that can alter the chemistry and oxidation state of the redox-sensitive elements carbon, sulfur, nitrogen, iron, and manganese. Have there ever been biogeochemical cycles on Mars? Certain key planetary processes can offer clues. Active volcanism provides reduced chemical species that biota can use for organic synthesis. Volcanic carbon dioxide and methane can serve as greenhouse gases. Thus the persistence of volcanism on Mars may well have influenced the persistence of a martian biosphere. The geologic processing of the crust can affect the availability of nutrients and also control the deposition of minerals that could have served as a medium for the preservation of fossil information. Finally, the activity of liquid water is crucial to life. Was there ever an Earth-like hydrologic cycle with rainfall? Has aqueous activity instead been restricted principally to hydrothermal activity below the surface? To what extent did the inorganic chemistry driven by sunlight and hydrothermal activity influence organic chemistry (prebiotic chemical evolution)? This paper addresses these and other key questions.

DesMarais, David J.↗
NASA NTRS2015

Land Boundary Conditions for the Goddard Earth Observing System Model Version 5 (GEOS-5) Climate Modeling System: Recent Updates and Data File Descriptions

The Earths land surface boundary conditions in the Goddard Earth Observing System version 5 (GEOS-5) modeling system were updated using recent high spatial and temporal resolution global data products. The updates include: (i) construction of a global 10-arcsec land-ocean lakes-ice mask; (ii) incorporation of a 10-arcsec Globcover 2009 land cover dataset; (iii) implementation of Level 12 Pfafstetter hydrologic catchments; (iv) use of hybridized SRTM global topography data; (v) construction of the HWSDv1.21-STATSGO2 merged global 30 arc second soil mineral and carbon data in conjunction with a highly-refined soil classification system; (vi) production of diffuse visible and near-infrared 8-day MODIS albedo climatologies at 30-arcsec from the period 2001-2011; and (vii) production of the GEOLAND2 and MODIS merged 8-day LAI climatology at 30-arcsec for GEOS-5. The global data sets were preprocessed and used to construct global raster data files for the software (mkCatchParam) that computes parameters on catchment-tiles for various atmospheric grids. The updates also include a few bug fixes in mkCatchParam, as well as changes (improvements in algorithms, etc.) to mkCatchParam that allow it to produce tile-space parameters efficiently for high resolution AGCM grids. The update process also includes the construction of data files describing the vegetation type fractions, soil background albedo, nitrogen deposition and mean annual 2m air temperature to be used with the future Catchment CN model and the global stream channel network to be used with the future global runoff routing model. This report provides detailed descriptions of the data production process and data file format of each updated data set.

GEOS-5↗
NASA NTRS2020

Impact-driven mobilization of deep crustal brines on dwarf planet Ceres

Ceres, the only dwarf planet in the inner Solar System, appears to be a relict ocean world. Data collected by NASA's Dawn spacecraft provided evidence that global aqueous alteration within Ceres resulted in a chemically evolved body that remains volatile-rich(1). Recent emplacement of bright deposits sourced from brines attests to Ceres being a persistently geologically active world(2,3), but the surprising longevity of this activity at the 92-km Occator crater has yet to be explained. Here, we use new high-resolution Dawn gravity data to study the subsurface architecture of the region surrounding Occator crater, which hosts extensive young bright carbonate deposits (faculae). Gravity data and thermal modelling imply an extensive deep brine reservoir beneath Occator, which we argue could have been mobilized by the heating and deep fracturing associated with the Occator impact, leading to long-lived extrusion of brines and formation of the faculae. Moreover, we find that pre-existing tectonic cracks may provide pathways for deep brines to migrate within the crust, extending the regions affected by impacts and creating compositional heterogeneity. The long-lived hydrological system resulting from the impact might also occur for large impacts in icy moons, with implications for creation of transient habitable niches over time.High-resolution data of Ceres's bright spots (faculae), obtained by Dawn's second extended mission, suggest the existence of a deep brine-rich reservoir that emerged to the surface through long-lived cryovolcanic activity as a consequence of the impact that created Occator crater.

C. A. Raymond↗
NASA NTRS2024

Organic Products of Fatty Acid and Magnesium Sulfate Mixtures after Gamma Radiolysis: Implications for Missions to Europa

If ocean-derived materials are present at Europa’s surface, they would represent accessible records of ocean chemistry and habitability, but such materials would be further processed by the moon’s harsh radiation environment. In this study, saturated fatty acids were precipitated onto a Europa-relevant hydrated magnesium sulfate and exposed to gamma radiation doses up to 2 MGy at -196° C. Alkane chains, with carbon numbers one less than those of the starting fatty acids, were the most abundant radiolysis products in solvent and thermal extracts analyzed by gas chromatography mass spectrometry. Detections of monounsaturated fatty acids and combined radiolysis products were attributed to the experiment’s Europa-like parameters. Additionally, elevated concentrations of shorter-chain saturated fatty acids suggest that gamma radiation induced charge remote fragmentation of the alkyl chains of some starting fatty acids under these experimental conditions. Quantitation of fatty acid concentrations in the irradiated samples enabled the calculation of a radiolysis constant that indicated exposure to a 5 MGy dose of gamma radiation would have resulted in a ~90% loss of the initial fatty acid population. The samples were further studied by Raman spectroscopy and laser desorption and ionization mass spectrometry, which characterized the distribution of fatty acids and their radiolysis products on sulfate surfaces. The substantial loss of starting fatty acids typically seen with increasing radiation dose, along with the remarkable diversity of radiolysis products identified, suggest that the detection of fatty acids in irradiated sulfate deposits on Europa will be challenged by rapid destruction of any initial fatty acid populations and scrambling of their residual signals by a myriad of organic radiolysis products. If missions to Europa encounter sulfate deposits, targeting minimally irradiated units may still enable the detection of surviving fatty acid signatures that could inform about Europa’s subsurface chemistry and habitability.

James M T Lewis↗
NASA NTRSDate not supplied

Microstructural Characterization of Felsite Fragments From the Apollo Next Generation Sample Analysis (ANGSA) Double Drive Tube 73001/73002

While the Moon’s surface is dominated by mafic igneous products formed through the crystallization of the lunar magma ocean, and the subsequent eruption of mare basalts – felsic magmatic fragments (variably referred to as felsites, granites, rhyolites or granophyres) have been identified from a number of Apollo samples (e.g. 12013[1], 14321[2], 15405[3] and 73215[4]). Magmatic edifices like the Gruithuisen Domes – silicic constructs sometimes found proximal to the basaltic mare provinces filling nearside basins, may represent a petrogenetic origin. However, this is, is complicated by the fact that they apparently predate mare volcanism (e.g. [5]). Additionally, crater-counting indicates that these silicic surface features also postdate radiogenic ages of Apollo felsites [6]. Various modes of felsic magmatism have been invoked to explain the presence of felsic lithologies on the Moon, including: 1) fractional crystallization and silicate liquid immiscibility; 2) partial melting of lunar crust through basaltic underplating; and 3) fractional crystallization of the mare parent magmas. Although these models are plausible, based on known Apollo samples and lunar meteorites, they are complicated by the lack of sample lithologies with intermediate composition between basaltic magmas and the felsic components, and the fact that partial melting of many crustal rock types on the Moon (e.g., anorthosite, troctolites) are unlikely to form granites. Along with other unique magmatic lithologies, new felsites have been identified within the < 1 mm size fractions of the ANGSA double drive core tube (73001/73002) from Apollo 17 station 3, sampling the light mantle landslide deposit from the South Massif [7]. These additional examples of lunar felsite will help us to better constrain the processes that lead to the formation of these evolved lithologies. To do this, we have employed a gambit of high-resolution scanning electron microscopy (SEM) and scanning transmission electron microscopy (TEM) analytical techniques, including electron backscatter diffraction (EBSD), cathodoluminescence and high-angle annular dark field (HAADF) imaging. These data provide unique insights into the felsite mineralogy and microstructures including the coexistence of quartz and tridymite in many of the fragments. In addition, these analyses provide petrological context and assist targeted in situ secondary ion mass spectrometry (SIMS) measurements of the U-Pb systematics of accessory minerals, and the volatile abundances and D/H ratios of apatite grains identified within the clasts.

lunar↗
NASA NTRS2015

Environmental Consequences of Big Nasty Impacts on the Early Earth

The geological record of the Archean Earth is spattered with impact spherules from a dozen or so major cosmic collisions involving Earth and asteroids or comets (Lowe, Byerly 1986, 2015). Extrapolation of the documented deposits suggests that most of these impacts were as big or bigger than the Chicxulub event that famously ended the reign of the thunder lizards. As the Archean impacts were greater, the environmental effects were also greater. The number and magnitude of the impacts is bounded by the lunar record. There are no lunar craters bigger than Chicxulub that date to Earth's mid-to-late Archean. Chance dictates that Earth experienced no more than approximately 10 impacts bigger than Chicxulub between 2.5 billion years and 3.5 2.5 billion years, the biggest of which were approximately30-100 times more energetic, comparable to the Orientale impact on the Moon (1x10 (sup 26) joules). To quantify the thermal consequences of big impacts on old Earth, we model the global flow of energy from the impact into the environment. The model presumes that a significant fraction of the impact energy goes into ejecta that interact with the atmosphere. Much of this energy is initially in rock vapor, melt, and high speed particles. (i) The upper atmosphere is heated by ejecta as they reenter the atmosphere. The mix of hot air, rock vapor, and hot silicates cools by thermal radiation. Rock raindrops fall out as the upper atmosphere cools. (ii) The energy balance of the lower atmosphere is set by radiative exchange with the upper atmosphere and with the surface, and by evaporation of seawater. Susequent cooling is governed by condensation of water vapor. (iii) The oceans are heated by thermal radiation and rock rain and cooled by evaporation. Surface waters become hot and salty; if a deep ocean remains it is relatively cool. Subsequently water vapor condenses to replenish the oceans with hot fresh water (how fresh depending on continental weathering, which might be rather rapid under the circumstances). (iv) The surface temperature of dry land is presumed to be the same as the lower atmosphere. A thermal wave propagates into the land at a rate set by conduction. Impacts not greatly larger than Chicxulub can raise the surface temperature by tens, hundreds, or even thousands of degrees, and evaporate meters to hundreds of meters of water. The biggest should have vitrified exposed dry land. More results are for the talk, as here we have run out of space.

asteroids↗
NASA NTRS2015

Environmental Consequences of Big Nasty Impacts on the Early Earth

The geological record of the Archean Earth is spattered with impact spherules from a dozen or so major cosmic collisions involving Earth and asteroids or comets (Lowe, Byerly 1986, 2015). Extrapolation of the documented deposits suggests that most of these impacts were as big or bigger than the Chicxulub event that famously ended the reign of the thunder lizards. As the Archean impacts were greater, the environmental effects were also greater. The number and magnitude of the impacts is bounded by the lunar record. There are no lunar craters bigger than Chicxulub that date to Earth's mid-to-late Archean. Chance dictates that Earth experienced no more than approximately 10 impacts bigger than Chicxulub between 2.5 billion years and 3.5 billion years, the biggest of which were approximately 30-100 times more energetic, comparable to the Orientale impact on the Moon (1x10 (sup 26) joules). To quantify the thermal consequences of big impacts on old Earth, we model the global flow of energy from the impact into the environment. The model presumes that a significant fraction of the impact energy goes into ejecta that interact with the atmosphere. Much of this energy is initially in rock vapor, melt, and high speed particles. (i) The upper atmosphere is heated by ejecta as they reenter the atmosphere. The mix of hot air, rock vapor, and hot silicates cools by thermal radiation. Rock raindrops fall out as the upper atmosphere cools. (ii) The energy balance of the lower atmosphere is set by radiative exchange with the upper atmosphere and with the surface, and by evaporation of seawater. Susequent cooling is governed by condensation of water vapor. (iii) The oceans are heated by thermal radiation and rock rain and cooled by evaporation. Surface waters become hot and salty; if a deep ocean remains it is relatively cool. Subsequently water vapor condenses to replenish the oceans with hot fresh water (how fresh depending on continental weathering, which might be rather rapid under the circumstances). (iv) The surface temperature of dry land is presumed to be the same as the lower atmosphere. A thermal wave propagates into the land at a rate set by conduction. Impacts not greatly larger than Chicxulub can raise the surface temperature by tens, hundreds, or even thousands of degrees, and evaporate meters to hundreds of meters of water. The biggest should have vitrified exposed dry land. More results are for the talk, as here we have run out of space.

Archean Earth↗
NASA NTRS2015

Characterization of the Temporal-Spatial Variability of Trans-Atlantic Dust Transport Based on CALIPSO Lidar Measurements

The trans-Atlantic dust transport has important implications for human and ecosystem health, the terrestrial and oceanic biogeochemical cycle, weather systems, and climate. A reliable assessment of these influences requires the characterization of dust distributions in three dimensions and over long time periods. We provide an observation-based multiyear estimate of trans-Atlantic dust transport by using a 7-year (2007 - 2013) lidar record from the Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) in both cloud-free and above-cloud conditions. We estimate that on a basis of the 7-year average and integration over 10S - 30N, 182 Tg a-1 dust leaves the coast of North Africa at 15W, of which 132 Tg a-1 and 43 Tg a-1 reaches 35W and 75W, respectively. These flux estimates have an overall known uncertainty of (45 - 70). The 7-year average of dust deposition into the Amazon Basin is estimated to be 28 (8 - 48) Tg a-1 or 29 (8 - 50) kg ha-1 a-1. This imported dust could provide about 0.022 (0.006 - 0.037) Tg P of phosphorus per year, equivalent to 23 (7 - 39) g P ha-1 a-1 to fertilize the Amazon rainforest, which is comparable to the loss of phosphorus to rainfall. Significant seasonal variations are observed in both the magnitude of total dust transport and its meridional and vertical distributions. The observed large interannual variability of annual dust transport is highly anti-correlated with the prior-year Sahel Precipitation Index. Comparisons of CALIPSO measurements with surface-based observations and model simulations will also be discussed.

Transport↗
NASA NTRS2015

Life in the Clouds of Venus? An Experimental Synthetic Biology Approach

The surface of Venus constitutes the most hellish and biologically inhospitable planetary surface in our solar system, boasting a pH of 0, blistering winds that can melt lead, and pressures of 60 atm. However, during the earlier years of the solar system, without the runaway greenhouse effect that has plagued the planet, Venus potentially housed oceans and perhaps even life. There is a possibility that microbes could have retreated into hospitable niches in the atmosphere, as suggested by Carl Sagan as early as 1967 [1]. For example, 50 km above the raging hell of the Venusian surface, exists a relatively temperate environment that might serve as reservoir for life. This astrobiology project seeks to explore life at the extremes and to theorize whether microbial communities could not only survive but also reproduce in the Venusian atmosphere. Specifically, we ask: are aerosols viable microbial environments? But before we can test for life in the clouds, we have to develop a proper reporter to visualize cell growth in situ. For this purpose, we aimed to develop cell-growth dependent reporters to serve as remote biosensors for cell growth. We developed two using the polA promoter, a DNA-replication dependent promoter, and nrd operon promoter, a cell-cycle dependent promoter. Using these cell-growth reporters, the next step is to aerosolize microbes expressing these reporters in a suspension chamber adapted from a Millikan Drop Apparatus to assay reproduction in an aerosolized environment. Better yet is to test the reproduction of microbes in a microgravity regime such as on ISS.Approach: We engineered two cell-cycle dependent genetic reporters. One was the polA promoter which codes for DNA Polymerase I, a gene active in DNA replication [2]. The other was the nrdP. The activation of ribonucleotide reductase reduces ribonucleotides into deoxyribonucleotides and is involved in the bacterial cell cycle [3]. This promoter began activation during the initiation of DNA replication and is cell-cycle dependent [4]. These promoters were fused to a GFP reporter, transformed into E. coli. The constructs were deposited in the iGEM registry as K847210: Escherichia coli DNA-replication dependent polA promoter K847211: Escherichia coli cell-division dependent nrd promoter Results: Our constructs displayed fluorescence when transformed into NEB-5alpha competent cells. While nrdP-E0840 displayed sufficient fluorescence as verified by fluorescent microscopy, the original polAP-E0840 construct (which uses mut3b GFP) exhibited low expression; while fluorescence was visible under the microscope, the signal was too weak for the camera to recognize. The polA promoter was therefore digest-ed with EcoRI and SpeI then ligated into plasmid pNCS containing a RBS, Clover, and a terminator. Clover is a highly engineered green fluorescent protein that exhibits extreme brightness [5] Fluoresence time course data demonsrated that the genes were induced in a cell cycle dependant manner [6]. Our assays via microscopy and the bulk assay shows that our promoters are functional as cell cycle reporters.Conclusions: The application of such tools are widespread and not limited to astrobiology; nrdP could be used to determine doubling times empirically and could possibly extrapolate DNA content from intensity of signals expressed by polAP. However, we are pri-marily interested in its use in astrobiology.

Escherichia↗
NASA NTRS1995

Contributions of Planetary Science to Studies of Early Biosphere Evolution

The history of impact cratering on the Moon, and extrapolations of crater chronologies to the inner planets, suggests that the late accretionary history of the Earth overlapped with other crucial events in the its history, including the origin of terrestrial life. This evidence, acquired from studies of other planetary bodies in the inner solar system, has profoundly affected how we view the early history of the Earth and evolution of the biosphere. Pre-biotic chemical evolution and the origin of life would have been delayed by the probable existence of a global magma ocean until -4.2 Ga. The early crust was largely destroyed by recycling, thus accounting for the sparse Archean record on Earth. Once life had developed, large impacts may have extinguished it several times before it finally gained a foothold. Potentially sterilizing impacts could have occurred as late as 3.7 Ga. At the very least, large impacts would have forced the biosphere through major environmental "bottlenecks" thereby canalizing its subsequent evolution. One legacy of these early events may be the structure of the present RNA-tree which indicates that extreme thermophiles are primitive within the Archaea, and may be the last common ancestors of life. By 3.5 Ga, marine sedimentary sequences contain unequivocal microbial fossils that attest to the presence of a terrestrial biosphere. The diversity of microbial forms present in these earliest fossil assemblages implies a preceding interval of evolution during which major evolutionary advances (e.g. photosynthesis) could have taken place. Evidence cited above places the origin of life within the interval 3.5 and 4.2 Ga, a period of 700 Ma. Thus, it appears that terrestrial life not only evolved rapidly, but perhaps more than once. This expands the possibilities that life may have also developed elsewhere. Of the other planets in our solar system, Mars holds the greatest chance of having developed life. But, the present surface of Mars is hostile to life. Liquid water, regarded as essential for living systems, is unstable on the surface of Mars due to the low atmospheric pressure. The results of the Viking Lander biology experiments established that organic molecules are not present in the regolith of Mars, forcing the exobiological community to consider new ways of exploring for Martian life. Older, heavily cratered terranes on Mars show geomorphic evidence for abundant water between 3.0- 4.0 Ga. It is quite possible that life developed on Mars during this time, as it did on the Earth. The present focus for Mars Exobiology lies in the search for a fossil record. Archean-aged crust, while mostly missing on Earth, appears to be widespread in ancient cratered highlands of Mars, and aqueous mineral deposits within such sequences may hold crucial fossil evidence for an early Martian biosphere.

Farmer, Jack D.↗