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At least 127 records · Page 7

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NASA NTRS1992

Endogenous production, exogenous delivery and impact-shock synthesis of organic molecules - An inventory for the origins of life

The contribution of organic-rich comets, carbonaceous asteroids, and interplanetary dust particles and of impact shock-synthesized organics in the atmosphere to the origin of life on earth is studied and quantitatively compared with the principal non-heavy-bombardment sources of prebiotic organics. The results suggest that heavy bombardment before 3.5 Gyr ago either produced or delivered quantities of organics comparable to those produced by other energy sources.

Chyba, Christopher↗

NASA NTRS1992

Exobiology science objectives at a lunar base

Five general categories of experimentation on the moon are reviewed which would provide important scientific information about chemical evolution and the origin and early evolution of life. Attention is given to: (1) chemical analyses of samples for products of prebiotic evolution, (2) analysis of crater records and understanding the implications for the origin and evolution of life on earth, (3) exposure of microbes and organics to the space environment, (4) collection of cosmic dust particles and analysis of volatiles and organics, and (5) observations of planetary environments and the interstellar medium to determine the nature and extent of chemical evolution.

Devincenzi, Donald L.↗

NASA NTRS2006

Application of Aerosol Hygroscopicity Measured at the Atmospheric Radiation Measurement Program's Southern Great Plains Site to Examine Composition and Evolution

A Differential Mobility Analyzer/Tandem Differential Mobility Analyzer (DMA/TDMA) was used to measure submicron aerosol size distributions, hygroscopicity, and occasionally volatility during the May 2003 Aerosol Intensive Operational Period (IOP) at the Central Facility of the Atmospheric Radiation Measurement Program's Southern Great Plains (ARM SGP) site. Hygroscopic growth factor distributions for particles at eight dry diameters ranging from 0.012 micrometers to 0.600 micrometers were measured throughout the study. For a subset of particle sizes, more detailed measurements were occasionally made in which the relative humidity or temperature to which the aerosol was exposed was varied over a wide range. These measurements, in conjunction with backtrajectory clustering, were used to infer aerosol composition and to gain insight into the processes responsible for evolution. The hygroscopic growth of both the smallest and largest particles analyzed was typically less than that of particles with dry diameters of about 0.100 micrometers. It is speculated that condensation of secondary organic aerosol on nucleation mode particles is largely responsible for the minimal hygroscopic growth observed at the smallest sizes considered. Growth factor distributions of the largest particles characterized typically contained a nonhygroscopic mode believed to be composed primarily of dust. A model was developed to characterize the hygroscopic properties of particles within a size distribution mode through analysis of the fixed size hygroscopic growth measurements. The performance of this model was quantified through comparison of the measured fixed size hygroscopic growth factor distributions with those simulated through convolution of the size-resolved concentration contributed by each of the size modes and the mode-resolved hygroscopicity. This transformation from sizeresolved hygroscopicity to mode-resolved hygroscopicity facilitated examination of changes in the hygroscopic properties of particles within a size distribution mode that accompanied changes in the sizes of those particles. This model was used to examine three specific cases in which the sampled aerosol evolved slowly over a period of hours or days.

Gasparini, Roberto↗

NASA NTRS2001

Solubility of methanol in low-temperature aqueous sulfuric acid and implications for atmospheric particle composition

Using traditional Knudsen cell techniques, we find well-behaved Henry's law uptake of methanol in aqueous 45 - 70 wt% H2SO4 solutions at temperatures between 197 and 231 K. Solubility of methanol increases with decreasing temperature and increasing acidity, with an effective Henry's law coefficient ranging from 10(exp 5) - 10(exp 8) M/atm. Equilibrium uptake of methanol into sulfuric acid aerosol particles in the upper troposphere and lower stratosphere will not appreciably alter gas-phase concentrations of methanol. The observed room temperature reaction between methanol and sulfuric acid is too slow to provide a sink for gaseous methanol at the temperatures of the upper troposphere and lower stratosphere. It is also too slow to produce sufficient quantities of soluble reaction products to explain the large amount of unidentified organic material seen in particles of the upper troposphere.

Iraci, Laura T.↗

NASA NTRS2010

Simulation of Earth-Moon-Mars Environments for the Assessment of Organ Doses

Space radiation environments for historically large solar particle events (SPE) and galactic cosmic rays (GCR) at solar minimum and solar maximum are simulated in order to characterize exposures to radio-sensitive organs for missions to low-Earth orbit (LEO), moon, and Mars. Primary and secondary particles for SPE and GCR are transported through the respective atmosphere of Earth or Mars, space vehicle, and astronaut s body tissues using the HZETRN/QMSFRG computer code. In LEO, exposures are reduced compared to deep space because particles are deflected by the Earth s magnetic field and absorbed by the solid body of the Earth. Geomagnetic transmission function as a function of altitude was applied for the particle flux of charged particles, and the shift or the organ exposures to higher velocity or lower stopping powers compared to those in deep space were analyzed. In the transport through Mars atmosphere, a vertical distribution of atmospheric thickness was calculated from the temperature and pressure data of Mars Global Surveyor, and the directional cosine distribution was implemented to describe the spherically distributed atmospheric distance along the slant path at each altitude. The resultant directional shielding by Mars atmosphere at solar minimum and solar maximum was used for the particle flux simulation at various altitudes on the Martian surface. Finally, atmospheric shielding was coupled with vehicle and body shielding for organ dose estimates. We made predictions of radiation dose equivalents and evaluated acute symptoms at LEO, moon, and Mars at solar minimum and solar maximum.

Kim, Myung-Hee↗

NASA NTRS2017

Refractory Organics in Comet 67P Churyumov-Gerasimenko: Additional Evidence for Large-scale Mixing in the Primitive Solar Nebula?

The COSIMA instrument onboard the Rosetta spacecraft collected and analyzed samples of individual particles from the coma of Comet67P/ Churyumov-Gerasimenko. Initial results of the analysis of several particles have been presented elsewhere while analyses of the organic component of the dust particles has been shown to compare favor ably to laboratory spectra of IOM extracted from the Orguil and Murchison meteorites. Here we will compare the spectra of the same two particles to laboratory spectra of organic grain coatings produced via Surface Mediated Reactions of CO, H2 and N2 on amorphous iron silicate grains.

Refractory Organics↗

NASA NTRS2003

Uptake of Organic Vapors by Sulfate Aerosols: Physical and Chemical Processes

While it is known that upper tropospheric sulfate particles contain a significant amount of organic matter, both the source of the organic fraction and its form in solution are unknown. These studies explore how the chemical characteristics of the molecules and surfaces in question affect heterogeneous interactions. The solubilities of acetaldehyde [CH3CHO] and ethanol [CH3CH20H] in cold, aqueous sulfuric acid solutions have been measured by Knudsen cell studies. Henry's law solubility coefficients range from 10(exp 2) to 10(exp 5) M/atm for acetaldehyde, and from 10(exp 4) to 10(exp 9) M/atm for ethanol under upper tropospheric conditions (210-240 K, 40-80 wt. % H2S04). The multiple solvation pathways (protonation, enolization, etc.) available to these compounds in acidic aqueous environments will be discussed. Preliminary results from the interaction of acetaldehyde with solutions of formaldehyde in sulfuric acid will be presented as well. The physical and chemical processes that affect organic uptake by aqueous aerosols will be explored, with the aim of evaluating organic species not yet studied in low temperature aqueous sulfuric acid.

Michelsen, R. R.↗

NASA NTRS1982

An intense, quasi-steady thunderstorm over mountainous terrain. II - Doppler radar observations of the storm morphological structure

The morphological characteristics of mean storm-scale airflow patterns of an intense quasi-steady storm formed in South Park, Colorado are described. Vertical transport of northerly low-level momentum within the updraft imparted a significant blocking on mid-level flow with southerly momentum. The blocking affected the movement and characteristics of adjacent, less organized storms, and additional storm-environment interactions produced an organized recirculation of precipitation particles from the mid-level updraft to the low-level updraft. The steadiness of the storm is found to have depended on the introduction of low-level flow directed opposite to mid-level flow, and on the formation of persistent downdrafts of sufficient magnitude to sustain an active gust front.

Knupp, K. R.↗

NASA NTRS1987

Plasma instabilities in the terrestrial magnetosphere - A review of recent theoretical research

This paper reviews recent theoretical research on plasma instabilities in the terrestrial magnetosphere. This paper is organized with respect to particle free energies: electron-ion currents, electron beams, ion beams, electron anisotropies and ion anisotropies are successively considered. For each free energy, the associated instability properties are summarized, and their applications to magnetospheric physics are briefly described. Theory and simulations which have established close correlations with observations are emphasized.

Gary, S. Peter↗

NASA NTRS1999

Remote Sensing of smoke and its Direct Radiative Forcing in South America

Smoke aerosol, organic and black carbon particles suspended in the air, can absorb and reflect solar radiation to space, i.e., direct radiative forcing. Depending on the ratio of scattering to absorption, and the surface spectral properties, the net smoke effect can be warming or cooling of the climate system. Data from the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) flown on the ER-2 at altitude of 20km, and of the AERONET ground based sun/sky radiometers are used to assess the smoke aerosol optical thickness over the land and the direct radiative forcing at the top of the atmosphere and at ground level, respectively. The data are collected during the Smoke, Clouds, and Radiation - Brazil (SCAR-B) experiment. In contrast to model results of the smoke effect, we show using the AVIRIS data, that even though the surface albedo is high (0.17 - average on the solar spectrum) and the smoke single scattering albedo is low (0.88), smoke does increase the instantaneous reflectance of sunlight to space by 30-40 W/m2 for an increase in the smoke optical thickness of 0.5. The AERONET data are used to derive, simultaneously, the effect of smoke on the downward radiation. Models using spectrally averaged smoke optical properties and averaged surface reflectance, predicted very small smoke forcing. The reason is that smoke is mainly opaque in short wavelengths (e.g.<0.7 micron) while the surface is mainly bright in longer wavelengths (>0.7 micron). Modeling the effect of smoke on climate forcing cannot be done using the spectrally average properties. It requires the knowledge of the smoke and surface spectral properties.

Kaufman, Yoram J.↗

NASA NTRS1999

Remote Sensing of Smoke and its Direct Radiative Forcing in South-America

Smoke aerosol, organic and black carbon particles suspended in the air, are capable to absorb and reflect solar radiation to space - direct radiative forcing. Depending on the ratio of scattering to absorption, and on the surface spectral properties, the net smoke effect can be warming or cooling of the climate system. Data from the AVIRIS spectrometer flown on the ER-2 at altitude of 20 km, and of the AERONET ground based sun/sky radiometers are used to assess the smoke aerosol optical thickness over the land and the direct radiative forcing at the top of the atmosphere and at ground level, respectively. The data are collected during the SCAR-B experiment in Brazil. In contrast to model results of the smoke effect, we show using the AVIRIS data, that even though the surface albedo is high (0.17 - average on the solar spectrum) and the smoke single scattering albedo is low (0.88), smoke does increase the instantaneous reflectance of sunlight to space by 30-40 W/m(exp 2) for an increase in the smoke optical thickness of 0.5. The AERONET data are used to derive, simultaneously, the effect of smoke on the downward radiation. Models using spectrally averaged smoke optical properties and averaged surface reflectance, predicted very small smoke forcing. The reason is that smoke is mainly opaque in short wavelengths (e.g.< 0.7 micron) while the surface is mainly bright in longer wavelengths (> 0.7 micron). Modeling the effect of smoke on climate forcing cannot be done using the spectrally average properties. It requires the knowledge of the smoke and surface spectral properties.

Kaufman, Yoram↗

NASA NTRS2003

Radiation Protection Studies of International Space Station Extravehicular Activity Space Suits

This publication describes recent investigations that evaluate radiation shielding characteristics of NASA's and the Russian Space Agency's space suits. The introduction describes the suits and presents goals of several experiments performed with them. The first chapter provides background information about the dynamic radiation environment experienced at ISS and summarized radiation health and protection requirements for activities in low Earth orbit. Supporting studies report the development and application of a computer model of the EMU space suit and the difficulty of shielding EVA crewmembers from high-energy reentrant electrons, a previously unevaluated component of the space radiation environment. Chapters 2 through 6 describe experiments that evaluate the space suits' radiation shielding characteristics. Chapter 7 describes a study of the potential radiological health impact on EVA crewmembers of two virtually unexamined environmental sources of high-energy electrons-reentrant trapped electrons and atmospheric albedo or "splash" electrons. The radiological consequences of those sources have not been evaluated previously and, under closer scrutiny. A detailed computational model of the shielding distribution provided by components of the NASA astronauts' EMU is being developed for exposure evaluation studies. The model is introduced in Chapters 8 and 9 and used in Chapter 10 to investigate how trapped particle anisotropy impacts female organ doses during EVA. Chapter 11 presents a review of issues related to estimating skin cancer risk form space radiation. The final chapter contains conclusions about the protective qualities of the suit brought to light form these studies, as well as recommendations for future operational radiation protection.

Cucinotta, Francis A.↗

NASA NTRS1999

Monte Carlo mixture model of lifetime cancer incidence risk from radiation exposure on shuttle and international space station

Estimating uncertainty in lifetime cancer risk for human exposure to space radiation is a unique challenge. Conventional risk assessment with low-linear-energy-transfer (LET)-based risk from Japanese atomic bomb survivor studies may be inappropriate for relativistic protons and nuclei in space due to track structure effects. This paper develops a Monte Carlo mixture model (MCMM) for transferring additive, National Institutes of Health multiplicative, and multiplicative excess cancer incidence risks based on Japanese atomic bomb survivor data to determine excess incidence risk for various US astronaut exposure profiles. The MCMM serves as an anchor point for future risk projection methods involving biophysical models of DNA damage from space radiation. Lifetime incidence risks of radiation-induced cancer for the MCMM based on low-LET Japanese data for nonleukemia (all cancers except leukemia) were 2.77 (90% confidence limit, 0.75-11.34) for males exposed to 1 Sv at age 45 and 2.20 (90% confidence limit, 0.59-10.12) for males exposed at age 55. For females, mixture model risks for nonleukemia exposed separately to 1 Sv at ages of 45 and 55 were 2.98 (90% confidence limit, 0.90-11.70) and 2.44 (90% confidence limit, 0.70-10.30), respectively. Risks for high-LET 200 MeV protons (LET=0.45 keV/micrometer), 1 MeV alpha-particles (LET=100 keV/micrometer), and 600 MeV iron particles (LET=180 keV/micrometer) were scored on a per particle basis by determining the particle fluence required for an average of one particle per cell nucleus of area 100 micrometer(2). Lifetime risk per proton was 2.68x10(-2)% (90% confidence limit, 0.79x10(-3)%-0. 514x10(-2)%). For alpha-particles, lifetime risk was 14.2% (90% confidence limit, 2.5%-31.2%). Conversely, lifetime risk per iron particle was 23.7% (90% confidence limit, 4.5%-53.0%). Uncertainty in the DDREF for high-LET particles may be less than that for low-LET radiation because typically there is very little dose-rate dependence. Probability density functions for high-LET radiation quality and dose-rate may be preferable to conventional risk assessment approaches. Nuclear reactions and track structure effects in tissue may not be properly estimated by existing data using in vitro models for estimating RBEs. The method used here is being extended to estimate uncertainty in spacecraft shielding effectiveness in various space radiation environments.

NASA Center LaRC↗

NASA NTRS2011

Radiolysis of Amino Acids in Outer Solar-System Ice Analogs

Amino acids have been found in cometary dust particles and in the organic component of meteorites. These molecules, important for pre-biotic chemistry and for active biological systems, might be formed in cold planetary or interstellar environments and then delivered to H20-rich surfaces in the outer solar system. Many models for the availability of organic species on Earth and elsewhere depend on the ability of these molecules to survive in radiation-rich space environments. This poster presents results of O.8-MeV proton radiolysis of ice films at lS-140K. using infrared spectroscopy, the destruction rates of glycine, alanine, and phenylalanine have been determined for both pure films and those containing amino acids diluted in H2o. our results are discussed in terms of the survivability of these molecules in the icy surfaces present in the outer solar system and the possibility of their detection by instruments on board the New Horizons spacecraft

Gerakines, Perry A.↗

NASA NTRS2012

Characterization of Spectral Absorption Properties of Aerosols Using Satellite Observations

The wavelength-dependence of aerosol absorption optical depth (AAOD) is generally represented in terms of the Angstrom Absorption Exponent (AAE), a parameter that describes the dependence of AAOD with wavelength. The AAE parameter is closely related to aerosol composition. Black carbon (BC) containing aerosols yield AAE values near unity whereas Organic carbon (OC) aerosol particles are associated with values larger than 2. Even larger AAE values have been reported for desert dust aerosol particles. Knowledge of spectral AAOD is necessary for the calculation of direct radiative forcing effect of aerosols and for inferring aerosol composition. We have developed a satellitebased method of determining the spectral AAOD of absorbing aerosols. The technique uses high spectral resolution measurements of upwelling radiation from scenes where absorbing aerosols lie above clouds as indicated by the UV Aerosol Index. For those conditions, the satellite measured reflectance (rho lambda) is approximately given by Beer's law rho lambda = rho (sub 0 lambda) e (exp -mtau (sub abs lambda)) where rho(sub 0 lambda) is the cloud reflectance, m is the geometric slant path and tau (sub abs lambda) is the spectral AAOD. The rho (sub 0 lambda) term is determined by means of radiative transfer calculations using as input the cloud optical depth derived as described in Torres et al. [JAS, 2012] that accounts for the effects of aerosol absorption. In the second step, corrections for molecular and aerosol scattering effects are applied to the cloud reflectance term, and the spectral AAOD is then derived by inverting the equation above. The proposed technique will be discussed in detail and application results will be presented. The technique can be easily applied to hyper-spectral satellite measurements that include UV such as OMI, GOME and SCIAMACHY, or to multi-spectral visible measurements by other sensors provided that the aerosol-above-cloud events are easily identified.

Torres, O.↗

NASA NTRS2012

Retrieval of Aerosol Absorption Properties from Satellite Observations

The Angstrom Absorption Exponent (AAE) is a parameter commonly used to characterize the wavelength-dependence of aerosol absorption optical depth (AAOD). It is closely related to aerosol composition. Black carbon (BC) containing aerosols yield AAE values near unity whereas Organic carbon (OC) aerosol particles are associated with values larger than 2. Even larger AAE values have been reported for desert dust aerosol particles. Knowledge of spectral AAOD is necessary for the calculation of direct radiative forcing effect of aerosols and for inferring aerosol composition. We have developed a satellitebased method of determining the spectral AAOD of absorbing aerosols. The technique uses multi-spectral measurements of upwelling radiation from scenes where absorbing aerosols lie above clouds as indicated by the UV Aerosol Index. For those conditions, the satellite measurement can be explained, using an approximations of Beer's Law (BL), as the upwelling reflectance at the cloud top attenuated by the absorption effects of the overlying aerosol layer. The upwelling reflectance at the cloud-top in an aerosol-free atmospheric column is mainly a function of cloud optical depth (COD). In the proposed method of AAE derivation, the first step is determining COD which is retrieved using a previously developed color-ratio based approach. In the second step, corrections for molecular scattering effects are applied to both the observed ad the calculated cloud reflectance terms, and the spectral AAOD is then derived by an inversion of the BL approximation. The proposed technique will be discussed in detail and application results making use of OMI multi-spectral measurements in the UV-Vis. will be presented.

Torres, Omar↗

NASA NTRS2011

LIFE: Enceladus Sample Return Mission Concept for Searching Evidence of Life

One of the most promising targets for the search for life other than Mars in our Solar System is the tiny Saturn moon Enceladus. The Cassini mission to the Saturian system detected an active region on Enceladus where small water particles and gas containing organic materials were being flung into space from a region near the south pole known as the tiger stripes. This discovery indicated that there is very likely a liquid subsurface ocean heated through tidal interactions as Enceladus orbits Saturn. On Earth, whenever there is an energy source, liquid water and organics, there is life; this makes Enceladus one of the prime candidates for a search for life missions. In this presentation, we describe LIFE (Life Investigation For Enceladus) sample return concept from Enceladus in the search for evidence of life.

Enceladus↗

NASA NTRS2018

Fire Induced Rock Spalls as Long-Term Traps for Ash

Severe fires accelerate rock weathering by spalling and exfoliation, creating abundant peels, flakes or spalls. In the following years, these spalls serve as physical traps which accommodate fine particles of dust, ash, organic matter, etc. We searched for traces of ash trapped under the spalls, after four major fires: 1989, 2005, 2010 and 2015 in Israel. Samples were collected beneath the spalls that formed on the rock outcrops, and in the immediate vicinity above and below them. Three laboratory analyses were performed: pH, EC and color. Five mineral/organic compounds were measured across the Mid-Infrared (MIR) spectral region at diffuse reflectance infrared Fourier transform mode: Hydroxylapatite (HAp), charcoal, organic carbon, montmorillonite and kaolinite. Several statistical analyses were performed: MANOVA, PCA and silhouette analysis on K-means clustering. The results show evidence of ash trapped under the spalls formed during the 2005 and 2010 fires, 6 to 11 years after the fires. Charcoal presence is evident, as well as increased amounts of HAp and organic carbon. In the exposed soil above or below the burned rock outcrop, these values are lower. Negligible amounts of ash were measured 27 years after the fire. In the 2015 burned outcrop, large amounts of charcoal were found above and below the outcrop, but not under the spalls. It seems that on the carbonate slopes of Israel and under Mediterranean climate, the time required for spalls to begin functioning as traps is longer than one rainy season, while ash traces are preserved in these traps for a period of two-three decades.

ash↗