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At least 127 records · Page 7

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NASA NTRS1982

Study of outgassing and decomposition of space shuttle heat protection tiles, fillers and adhesive

The purpose of this project was to determine the chemicals desorbing from the space shuttle heat protection tiles. The original protocol for this project involved direct insertion probe mass spectrometry (DIPMS) analysis of the outgassing products from the tiles. However, this method proved unsatisfactory due to the large number of compounds desorbing from the tiles. A purge and trap technique was then employed to collect and separate the chemicals desorbing from the tiles. The maximum temperature in this analysis was 180 C which is the gas chromatograph fused silica capillary column's temperature limit. The desorption was also carried out at atmospheric pressure with helium as the purge gas. A description of the modified protocol is given. All compounds are tentatively identified.

Proctor, B. L.↗

NASA NTRS1985

The effect of dust halos and dust mantles on nuclear outgassing

Studies of the effects of cometary dust halos and dust mantles on outgassing from the nucleus are reviewed. The chemical differentiation of the outer layers of a comet during perihelion passage is discussed. It is shown how this differentiation may explain a number of observations pertaining to the relative production rates of various cometary molecules.

Mendis, D. A.↗

NASA NTRS1988

Outgassing asymmetry of periodic Comet Encke. II - Apparitions 1868-1918 and a study of the nucleus evolution

Directed outgassing from isolated sources on P/Encke's rotating nucleus is investigated based on observations made between 1868 and 1918. A model of a collimated particle flow which identifies a sunward fan-like coma with the emission cone described by the ejecta from a discrete active region is shown to account for physical observations of the comet's perihelion. The results support nucleus precession, with a time-variable rate averaging about 1 degree per revolution. It is suggested that wall collapse and other processes limit the lifespans of individual vents to only a few hundred years or so. Differences between new and old vents are considered.

Sekanina, Z.↗

NASA NTRS1989

An asymmetric outgassing model for cometary nongravitational accelerations

The standard nongravitation force model has been modified by allowing the water-vaproization curve to peak a certain number of days (DT) either before or after perihelion, and the modification is shown to often improve the data fit. The best fit to the astrometric data is generally achieved for a value of DT corresponding to the offset in the comet's visual light curve. The asymmetric model, which more accurately mimics the comet's outgassing history, suggests only weakly that the rotation direction of Comet Halley is direct, and it does not provide evidence that the rotation axis of Comet Kopff passed through its orbit plane in the early twentieth century. Approximate lag angles of 4 deg for Comet Halley and 10 deg for Comet d'Arrest are found using the asymmetric model, and it is noted that these values are lower than those obtained with the standard model.

Yeomans, D. K.↗

NASA NTRS1991

Early outgassing of Mars supported by differential water solubility of iodine and xenon

The Martian atmosphere has a high X-129/Xe-132 ratio compared to the Martian mantle. As Xe-129 is the daughter product of the extinct nuclide I-129, a means of fractionating iodine from xenon early in Martian history appears necessary to account for the X-129/Xe-132 ratios of its known reservoirs. A model is presented here to account for the Marian xenon data which relies on the very different solubilities of xenon and iodine in water to fractionate them after outgassing. Atmospheric xenon is lost by impact erosion during heavy bombardment, followed by release of Xe-129 produced from I-129 decay in the crust.

Musselwhite, Donald S.↗

NASA NTRS1991

A self-consistent model for the particles and fields upstream of an outgassing comet. I - Gyrotropic and isotropic ion distributions

The magnetic field and solar wind flow parameters in the vicinity of a weakly outgassing comet are determined using a self-consistent model which treats the cometary ions kinetically. Two different assumptions are made concerning the cometary ion distribution function; the pickup cometary ions from either a velocity space gyrotropic ring distribution or a velocity space isotropic shell distribution in the solar wind frame of reference. The individual currents due to the solar wind and cometary ions, which determine the magnetic field, are calculated in each case. Using theoretically determined parameters which reflect the conditions expected to comet Kopff (a typical short-period comet and one possible target for the future CRAF/Cassini mission) for various heliocentric distances, the way in which global field and flow characteristics are influenced by the nature of the cometary ion distribution function is determined.

Flammer, K. R.↗

NASA NTRS1992

Solar cell arcing: The role of outgassing and contamination

The effect of outgassing, venting, and thruster firing events on spacecraft system performance has been a long standing issue. Recent laboratory measurements on negatively biased high voltage solar cells at Physical Sciences Inc. (PSI) suggest that some currently designed and certainly future space power systems must address/re-evaluate this issue. Our observations show that exposing these cells to moderate levels (10 exp -3 torr-min) of H2O vapor enhances the arcing frequency, while heating to 85 C to remove water vapor significantly reduces the arc frequency. The interaction of the adhesive used to attach the cover glass to the solar cell with ambient water vapor is the key factor in determining arcing rates. Elimination of adhesive exposed to the environmental plasma reduces the arc frequency more than two orders of magnitude, and eliminates any sensitivity to H2O exposure. The adhesive may also become a source of spacecraft contamination. Macroscopic amounts were observed to blow off some arc events, and (we assume) electrostatically precipitate at other negatively biased locations. Data, analysis, and potential impact for future space platforms are discussed.

Marinelli, W. J.↗

NASA NTRS1992

Chemical models of volcanic outgassing on Mars

During the MSATT workshop in Boulder, CO, several participants emphasized the importance of constraints on the composition and temporal evolution of outgassed volatiles on Mars. I present the results of some preliminary calculations that model the composition of volcanic gases as a function of temperature, pressure, oxygen fugacity, and quench function of temperature. These results can be used in combination with cosmochemical models for the accretion of Mars to assess the plausibility of different atmospheric compositions during the planet's early history.

Fegley, Bruce, Jr.↗

NASA NTRS1992

A self-consistent model for the particles and fields upstream of an outgassing comet. II - A time-dependent description

In a previous paper, the global variation of the magnetic field and solar wind flow parameters in the unshocked region upstream of an outgassing comet was determined using a kinetic treatment for the cometary ions. Two different assumptions were made concerning the cometary ion distribution function: the pickup cometary ions formed either a velocity space gyrotropic ring distribution or a velocity space isotropic shell distribution in the solar wind frame of reference. In the present paper the general case is considered wherein the newly picked up ions are elastically pitch angle scattered from the initial ring distribution to a shell with some characteristic time scale. Using theoretically determined parameters which reflect the conditions expected at Comet Kopff (a typical short-period comet and a possible target for the CRAF/Cassini mission) for various heliocentric distances, how the pitch angle scattering rate affects the global morphology is determined.

Flammer, K.↗

NASA NTRS1995

Further investigations of experiment A0034 atomic oxygen stimulated outgassing

Thermal control coatings within the recessed compartments of LDEF Experiment A0034 experienced the maximum leading edge fluence of atomic oxygen with considerably less solar UV radiation exposure than top-surface mounted materials of other LDEF experiments on either the leading or the trailing edge. This combination of exposure within A0034 resulted in generally lower levels of darkening attributable to solar UV radiation than for similar materials on other LDEF experiments exposed to greater cumulative solar UV radiation levels. Changes in solar absorptance and infrared thermal emittance of the exposed coatings are thus unique to this exposure. Analytical results for other applications have been found for environmentally induced changes in fluorescence, surface morphology, light scattering, and the effects of coating outgassing products on adjacent mirrors and windows of the A0034 experiment. Some atmospheric bleaching of the thermal control coatings, in addition to that presumably experience during reentry and recovery operations, has been found since initial post-flight observations and measurements.

Linton, Roger C.↗

NASA NTRS1997

Outgassing Data for Selecting Spacecraft Materials

Outgassing data, derived from tests at 398 K (125 C) for 24 hours in a vacuum as per ASTM E 595-84, have been compiled for numerous materials for spacecraft use. The data presented are the total mass loss (TML) and the collected volatile condensable materials (CVCM). The various materials are compiled by likely usage and alphabetically.

Walter, Neil A.↗

NASA NTRS2000

Mineralogical Studies of Experimentally Shocked Dolomite: Implications for the Outgassing of Carbonates

Common rock-forming rhombohedral carbonates - calcite and dolomite - constitute a considerable fraction of terrestrial sediments that may be shocked during hypervelocity impacts, such as during the Cretaceous-Tertiary (K/T) event or at the Haughton structure. The relatively modest temperatures needed to decompose carbonates and to release their CO2 are easily attained during such impacts. However, detailed and quantitative understanding of the CO2 release of carbonates as a function of shock stress is still the subject of controversy, as are a number of other reactions and phase transitions that were suggested for carbonates. The first devolatilization studies of carbonates in the early 1980s suggested that incipient devolatilization of calcite and/or dolomite commences at modest pressures, in the range < 10-18 GPa (amounting to 0.03-0.3% CO2 loss), with massive decarbonation (30-40% CO2 loss) occurring at shock pressure of 20 GPa and above. However, most later studies revealed that both calcite and dolomite are unexpectedly stable under shock conditions and no significant outgassing has been observed at pressures as high as 40 GPa for calcite and 60 GPa for dolomite. Despite these uncertainties, the calculations of O'Keefe and Ahrens (and others) serve to illustrate that the K/T bolide liberated sufficient CO2 that a substantial temperature increase of the global atmosphere is possible due to CO2-triggered greenhouse effects. The quantitative understanding of the devolatilization of carbonates as a function of shock stress is obviously critical to refine such calculations. Additional information is contained in the original extended abstract.

Skala, R.↗

NASA NTRS1984

Outgassing Data for Selecting Spacecraft Materials

Outgassing data, derived from tests at 396 K (125 C) for 24 hours in vacuum as per ASTM E 595-77, have been compiled for numerous materials for spacecraft use. The data presented are the total mass loss (TML) and the collected volatile condensable materials (CVCM). The various materials are compiled by likely usage and alphabetically.

Campbell, William A., Jr.↗

NASA NTRS2007

Hardware Outgassing Certification

This course will provide students with the understanding necessary to calculate certification requirements for and interpret the data from hardware undergoing vacuum bakeout. The fundamental physics that driv e hardware outgassing and contaminant deposition will be explained, a nd data reduction techniques will be applied to examples.

Hughes, David W.↗

NASA NTRS2007

Hardware Outgassing Certification

This viewgraph presentation reviews the outgassing of hardware to be used in space environments, to reduce the contamination levels such that the effects of the remaining contaminants are acceptable. The process of degassing materials that are to be used for constructing space hardware is detailed, and the data collection and analysis process is also detailed.

Hughes, David↗

NASA NTRS2008

Extremely High Vacuum Chamber for Low Outgassing Processing at NASA Goddard

The levels of vacuum that proceed past the high vacuum range into the ultra high and then the extremely high vacuum range become more difficult to achieve each decade that a system progresses through. This paper will explore the difficulties and cover some of the design principles used in achieving vacuum levels in the low 10-12 torr pressure range. This system was entirely built with commercially-available off the shelf (COTS) components. This chamber was designed in 1998 to provide a very low outgassing environment for the processing and sealing of charge-coupled devices (CCD's) for some of the Hubble Space Telescope replacement optics.

Webb, Andrew↗

NASA NTRS2011

The Molecular Composition of Comet C/2007 W1 (Boattini): Evidence of a Peculiar Outgassing and a Rich Chemistry

We measured the chemical composition of Comet C/2007 W1 (Boattini) using the long-slit echelle grating spectrograph at Keck-2 (NIRSPEC) on 2008 July 9 and 10. We sampled 11 volatile species (H2O, OH*, C2H6, CH3OH, H2CO, CH4, HCN, C2H2, NH3, NH2, and CO), and retrieved three important cosmogonic indicators: the ortho-para ratios of H2O and CH4, and an upper-limit for the D/H ratio in water. The abundance ratios of almost all trace volatiles (relative to water) are among the highest ever observed in a comet. The comet also revealed a complex outgassing pattern, with some volatiles (the polar species H2O and CH3OH) presenting very asymmetric spatial profiles (extended in the anti-sunward hemisphere), while others (e.g., C2H6 and HCN) showed particularly symmetric profiles. We present emission profiles measured along the Sun-comet line for all observed volatiles, and discuss different production scenarios needed to explain them. We interpret the emission profiles in terms of release from two distinct moieties of ice, the first being clumps of mixed ice and dust released from the nucleus into the sunward hemisphere. The second moiety considered is very small grains of nearly pure polar ice (water and methanol, without dark material or apolar volatiles). Such grains would sublimate only very slowly, and could be swept into the anti-sunward hemisphere by radiation pressure and solar-actuated non-gravitational jet forces, thus providing an extended source in the anti-sunward hemisphere.

Villanueva, G. L.↗

NASA NTRS1993

Outgassing Data for Selecting Spacecraft Materials

Outgassing data, derived from tests at 398 K (125 C) for 24 hours in vacuum as per ASTM E-595-90, have been compiled for numerous materials designed for spacecraft use. The data presented are the total mass loss (TML) and the collected volatile condensable materials (CVCM). The various materials are compiled by likely usage, and then in alphabetical order.

Campbell, William A.↗