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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7

Primary electron spectrometer, 18:63 UE: Electrostatic analyzer description and energy spectrum determination

The primary electron spectrometer used to detect auroral electrons on sounding rocket 18:63 UE is described. The spectrometer used exponentially decaying positive and negative voltages applied to spherical deflection plates for energy analysis. A method for determining the analyzer response which does not require the assumptions that the ratio of plate separation to mean radius, the entrance or the exit apertures are small is described. By comparison with experiment it is shown that the effect of neither entrance nor exit collimation can be ignored. The experimental and calculated values of the limiting orbits agree well. A non-iterative technique of unfolding the electron differential energy spectrum is described. This method does not require the usual assumption of a flat or histogram-type energy spectrum. The unfolded spectra using both this technique and one which assumes a flat spectrum are compared to actual input spectra. This technique is especially useful in analyzing peaked auroral electron energy spectra.

Pongratz, M. B.↗

Whole earth telescope observations of the DBV white dwarf GD 358

We report on the analysis of 154 hours of early continuous high-speed photometry on the pulsating DB white dwarf (DBV) GD 358, obtained during the Whole Earth Telescope (WET) run of 1990 May. The power spectrum of the light curve is dominated by power in the range from 1000 to 2400 microHz with more than 180 significant peaks in the total spectrum. We identify all of the triplet frequencies as degree l = 1, and from the details of their spacings we derive the total stellar mass as 0.61 + or - 0.03 solar mass, the mass of the outer helium envelope as 2.0 + or - 1.0 x 10(exp -6) M(sub *), the absolute luminosity as 0.050 + or - 0.012 solar luminosity and the distance as 42 + or - 3 pc. We find strong evidence for differential rotation in the radial direction -- the outer envelope is rotating at least 1.8 times faster than the core -- and we detect the presence of a weak magnetic field with a strength of 1300 + or - 300 G. We also find a significant power at the sums and differences of the dominant frequencies, indicating nonlinear processes are significant, but they have a richness and complexity that rules out resonant mode coupling as a major cause.

Winget, D. E.↗

Quantitative analysis of cost savings and occupants’ preferences in grid-interactive smart home operation

Many utility companies in the United States have introduced time-of-use (TOU) rates for homeowners with the goal of regulating electricity consumption during peak hours. The electrical appliances in homes include various thermostatically controlled devices, such as air conditioners (AC) for thermal comfort, and nonthermostatically controlled devices such as clothes washers. As a result, homeowners face the complicated challenge of economically operating multiple electrical appliances in their homes while maintaining comfort and convenience. This is usually due to the lack of an explicit understanding of the correlation between cost saving and the users’ comfort. To understand the correlation, this article is designed to construct a framework by integrating three major components: a multi-objective optimization method accommodating multiple competing goals with different weights, a learning-based system modeling approach describing the dynamics and thermal coupling effects of appliances, and a novel comfort index method differentiating preferred and acceptable thermal comfort. Our proposed framework can allow the indoor air temperature to fall into the "preferred" range with a marginal cost increase. Furthermore, the simulation result shows that an additional 8 h for the preferred thermal comfort can be achieved with a cost increase of only 1.77%.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Simple new methods for deducing lifetimes in recoil distance Doppler-shift measurements

In this work, new approaches for lifetime determination using data from recoil distance Doppler-shift experiments are presented based on the fundamental properties of the functions describing the time evolution of the population of excited nuclear states. To some extent, one of them represents a contraction of the well-known Differential decay-curve method (DDCM) by using the most reliable data point [the maximum of the $n_i(t)$ function describing the population of level $\textit{i}$ in time] and a purely numerical procedure avoiding any fitting of decay curves. The combination with the standard DDCM analysis is promising for improving the reliability and the precision of the results for the lifetimes obtained. The novel part of the approach consists of using a chain of equations at the consecutive maxima of the ni(t) functions, which allow us to precisely determine the ratio of the lifetimes of two consecutive levels and, in the case where one of these lifetimes is known, to determine the unknown one. In addition, a simple integral derivation of the lifetime is presented involving the peak areas measured at different distances, and an application of the first moments (expectation values and centroids in time) of the $n_i(t)$ functions for determining lifetimes is also demonstrated to be useful.

47 OTHER INSTRUMENTATION↗

Electro-Thermal Simulation Studies of SiC Junction Diodes Containing Screw Dislocations Under High Reverse-Bias Operation

The objective of this work was to conduct a modeling study of SiC P-N junction diodes operating under high reverse biased conditions. Analytical models and numerical simulation capabilities were to be developed for self-consistent electro-thermal analysis of the diode current-voltage (I-V) characteristics. Data from GRC indicate that screw dislocations are unavoidable in large area SiC devices, and lead to changes in the SiC diode electrical response characteristics under high field conditions. For example, device instability and failures linked to internal current filamentation have been observed. The physical origin of these processes is not well understood, and quantitative projections of the electrical behavior under high field and temperature conditions are lacking. Thermal calculations for SiC devices have not been reported in the literature either. So estimates or projections of peak device temperatures and power limitations do not exist. This numerical study and simulation analysis was aimed at resolving some of the above issues. The following tasks were successfully accomplished: (1) Development of physically based models using one- and two-dimensional drift-diffusion theory for the transport behavior and I-V characteristics; (2) One- and two-dimensional heat flow to account for internal device heating. This led to calculations of the internal temperature profiles, which in turn, were used to update the electrical transport parameters for a self-consistent analysis. The temperature profiles and the peak values were thus obtainable for a given device operating condition; (3) Inclusion of traps assumed to model the presence of internal screw dislocations running along the longitudinal direction; (4) Predictions of the operating characteristics with and without heating as a function of applied bias with and without traps. Both one and two-dimensional cases were implemented; (5) Assessment of device stability based on the operating characteristics. The presence of internal non-uniformities, particularly filamentary structures, was probed and demonstrated; (6) Cause and physical origins of filamentary behavior and unstable I-V characteristics were made transparent; (7) It was demonstrated that diodes containing defects would be more prone to thermal breakdown associated with the temperature dependent decrease in the thermal conductivity; and (8) Finally, negative differential resistance (S-shaped NDR) which can potential lead to device instability and filamentary behavior was shown to occur for diodes containing a line of defects such as could be associated with a screw dislocation line.

Joshi, R. P.↗

A critical analysis of U-Pu-Zr phase transitions using calorimetric, microstructural, and phase equilibria data

Metallic fuels consisting primarily of uranium, plutonium, and zirconium (U-Pu-Zr) are a leading material candidate for fast-spectrum nuclear reactors. Early demonstration programs proved the principle of safe and efficient fast reactor operation, however there is still considerable uncertainty regarding the phase equilibria and microstructural evolution across the ternary composition space. Quantitative phase formation and identification measurements are scarce and often incomplete, with studies reporting either phase transition temperatures or phase identification data, but not both from the same specimens. In this study, we critically compared experimental and calculated phase transition data and correlated with the microstructure and phase characterization data of as-cast and annealed U-Pu-Zr alloys. Differential scanning calorimetry (DSC) was used to measure phase transitions in the subsolidus regions (723−948 K) of three ternary U-Pu-Zr alloys with similar plutonium concentrations but various U/Zr ratios. Due to sluggish kinetics and narrow ranges of phase stability, complex peaks required the use of a Frazier-Suzuki peak fitting algorithm to deconvolute and calculate transition peak temperatures and enthalpies. We also identified trends of phase transition behavior by critically comparing our DSC data with previous phase transition measurements as well as historical and calculated phase equilibrium diagrams. In conclusion, this provides a critical approach for benchmarking and assessing the quality of new U-Pu-Zr phase equilibria data prior to its incorporation into nuclear material databases.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Application of Gaussian Bayes classifier to differentiate chlorine-based chemical agents

The Portable Isotopic Neutron Spectroscopy (PINS) is a commercialized system developed by Idaho National Laboratory (INL) to examine chemical warfare agents (CWA) non-destructively, utilizing Prompt Gamma Neutron Activation Analysis (PGNAA) techniques. The PINS system takes advantage of a high-resolution gamma-ray spectrum from a mechanically-cooled high-purity germanium (HPGe) detector. One of the difficult technical challenges is to discriminate the chlorine-based chemical agents. Especially, CN, CNB, CNS and CG have similar chemical compositions to make it hard to discriminate them with a higher confidence. Current identification algorithms for PINS systems with 252-Cf sources have been improved and updated continuously as more field data became available, and new algorithms was studied to complement the current algorithms by adopting the Gaussian Bayes classifier. These new algorithms were intended to be applied to a subset of chlorine-based chemical agents, and their main goal is discriminate CN, CNB, CNS and CG with their ratios of the chlorine neutron inelastic 1763keV peak to the chlorine thermal neutron capture 1959keV peak, which is referred to as the “Cl i/c” or “clic” ratio in this study. The Cl i/c ratios were assumed to follow Gaussian distributions with the means and the standard deviations unique to their corresponding chemical agents. The prior probabilities of these four chemical agents were optimized with a collection of field data to achieve the best performance in terms of precision or positive predictive value (PPV). Finally, their posterior probabilities as functions of the Cl i/c ratio were implemented in the current version of PINS analysis software in order to be tested with more field data.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗

Development of a Photon Counting System for Differential Lidar Signal Detection

Photon counting has been chosen as a means to extend the detection range of current airborne DIAL ozone measurements. Lidar backscattered return signals from the on and off-line lasers experience a significant exponential decay. To extract further data from the decaying ozone return signals, photon counting will be used to measure the low light levels, thus extending the detection range. In this application, photon counting will extend signal measurement where the analog return signal is too weak. The current analog measurement range is limited to approximately 25 kilometers from an aircraft flying at 12 kilometers. Photon counting will be able to exceed the current measurement range so as to follow the mid-latitude model of ozone density as a function of height. This report describes the development of a photon counting system. The initial development phase begins with detailed evaluation of individual photomultiplier tubes. The PMT qualities investigated are noise count rates, single electron response peaks, voltage versus gain values, saturation effects, and output signal linearity. These evaluations are followed by analysis of two distinctive tube base gating schemes. The next phase is to construct and operate a photon counting system in a laboratory environment. The laboratory counting simulations are used to determine optimum discriminator setpoints and to continue further evaluations of PMT properties. The final step in the photon counting system evaluation process is the compiling of photon counting measurements on the existing ozone DIAL laser system.

Elsayed-Ali, Hani↗

A data–model approach to interpreting speleothem oxygen isotope records from monsoon regions

Reconstruction of past changes in monsoon climate from speleothem oxygen isotope (δ 18 O) records is complex because δ 18 O signals can be influenced by multiple factors including changes in precipitation, precipitation recycling over land, temperature at the moisture source, and changes in the moisture source region and transport pathway. Here, we analyse >150 speleothem records of the Speleothem Isotopes Synthesis and AnaLysis (SISAL) database to produce composite regional trends in δ 18 O in monsoon regions; compositing minimises the influence of site-specific karst and cave processes that can influence individual site records. We compare speleothem δ 18 O observations with isotope-enabled climate model simulations to investigate the specific climatic factors causing these regional trends. We focus on differences in δ 18 O signals between the mid-Holocene, the peak of the Last Interglacial (Marine Isotope Stage 5e) and the Last Glacial Maximum as well as on δ 18 O evolution through the Holocene. Differences in speleothem δ 18 O between the mid-Holocene and the Last Interglacial in the East Asian and Indian monsoons are small, despite the larger summer insolation values during the Last Interglacial. Last Glacial Maximum δ 18 O values are significantly less negative than interglacial values. Comparison with simulated glacial–interglacial δ 18 O shows that changes are principally driven by global shifts in temperature and regional precipitation. Holocene speleothem δ 18 O records show distinct and coherent regional trends. Trends are similar to summer insolation in India, China and southwestern South America, but they are different in the Indonesian–Australian region. Redundancy analysis shows that 37 % of Holocene variability can be accounted for by latitude and longitude, supporting the differentiation of records into individual monsoon regions. Regression analysis of simulated precipitation δ 18 O and climate variables show significant relationships between global Holocene monsoon δ 18 O trends and changes in precipitation, atmospheric circulation and (to a lesser extent) source area temperature, whereas precipitation recycling is non-significant. However, there are differences in regional-scale mechanisms: there are clear relationships between changes in precipitation and δ 18 O for India, southwestern South America and the Indonesian–Australian regions but not for the East Asian monsoon. Changes in atmospheric circulation contribute to δ 18 O trends in the East Asian, Indian and Indonesian–Australian monsoons, and a weak source area temperature effect is observed over southern and central America and Asia. Precipitation recycling is influential in southwestern South America and southern Africa. Overall, our analyses show that it is possible to differentiate the impacts of specific climatic mechanisms influencing precipitation δ 18 O and use this analysis to interpret changes in speleothem δ 18 O.

speleothem oxygen isotope records↗

Unveiling real‐time crystallization with nucleators and thickeners for zinc nitrate hexahydrate as a phase change material

Abstract The primary challenge of salt hydrates as phase change materials (PCMs) is their high degree of supercooling (∆ T Sup ). Past studies have attempted to alleviate ∆ T Sup by incorporating nucleators possessing similar lattice structure, without a thorough analysis of the nucleator/PCM interactions. This work presents a novel in‐operando study to visually observe the crystallization process of zinc nitrate hexahydrate (ZNH) in real‐time using suitable nucleators and a thickener. We have introduced a new dataset where zinc acetate dihydrate (ZnAc.2H) has been employed as an additive to ZNH for thermal energy storage (TES). According to our in‐operando study, ZnAc.2H underwent hydrolysis in molten ZNH to precipitate needle‐like ZnO particles, which acted as nucleators for the PCM. In the absence of a thickener, the crystal propagation of ZNH exhibited a preferential directional tendency, whereas incorporation of thickener made the phase change process uniform along all directions. Self‐hydrolysis of ZnAc.2H generated excess water which caused the undesirable effect of broadening the endothermic peak. The addition of carboxymethyl cellulose (CMC) thickener could restrict the activity of excess water and reduce the broadening of the endothermic peak. Differential scanning calorimetry (DSC) revealed that 5 wt% ZnAc.2H additive and 2 wt% CMC thickener added to ZNH can considerably improve the TES properties of ZNH PCM (∆ H Fusion 125.9 J·g −1 , ∆ T Sup 3.0°C, melting point [M.P.] 29.0°C). Our in‐operando studies can unveil real‐time phase change behaviors to better design PCM systems with desired characteristics.

Chakraborty, Anirban↗

Solid Rocket Launch Vehicle Explosion Environments

Empirical explosion data from full scale solid rocket launch vehicle accidents and tests were collected from all available literature from the 1950s to the present. In general data included peak blast overpressure, blast impulse, fragment size, fragment speed, and fragment dispersion. Most propellants were 1.1 explosives but a few were 1.3. Oftentimes the data from a single accident was disjointed and/or missing key aspects. Despite this fact, once the data as a whole was digitized, categorized, and plotted clear trends appeared. Particular emphasis was placed on tests or accidents that would be applicable to scenarios from which a crew might need to escape. Therefore, such tests where a large quantity of high explosive was used to initiate the solid rocket explosion were differentiated. Also, high speed ground impacts or tests used to simulate such were also culled. It was found that the explosions from all accidents and applicable tests could be described using only the pressurized gas energy stored in the chamber at the time of failure. Additionally, fragmentation trends were produced. Only one accident mentioned the elusive "small" propellant fragments, but upon further analysis it was found that these were most likely produced as secondary fragments when larger primary fragments impacted the ground. Finally, a brief discussion of how this data is used in a new launch vehicle explosion model for improving crew/payload survival is presented.

Richardson, E. H.↗

Implementation of an Unsteady PSP System in the NASA Transonic Dynamics Tunnel

An unsteady pressure-sensitive paint (uPSP) system has been developed to provide time-resolved pressure measurements in the NASA Langley Transonic Dynamics Tunnel (TDT). Obtaining these measurements necessitated the development of environmental enclosures to protect the high-speed camera and ultraviolet lights required for uPSP from the harsh environment present during tunnel operation. Since the facility main drive was non-functioning during the testing window, performance of the uPSP system was demonstrated using an impinging jet with a passive oscillator attachment to provide unsteady flow with a known frequency independent of amplitude. Measurements were obtained for tunnel pressures ranging from 565 to 2116 psf, and model angles of attack between -4 degrees and 4 degrees. Results indicate that the system is capable of measuring surface pressure differentials on the order of 0.01 psi at full scale with a camera frame rate of at least 10 kHz. Spectral analysis shows that the fundamental frequency of the oscillating jet is captured by the uPSP system, as are the second and third harmonics. Dynamic mode decomposition highlights the dominant coherent spatial structures of the surface pressure, along with the associated frequency and growth rate of each mode, allowing for a de-noised reconstruction of the uPSP measurements. The experimental campaign outlined within this report also confirmed compatibility of the uPSP system with the TDT facility data acquisition system, and verified the successful integration with existing processing capabilities within the NASA advanced supercomputing environment.

unsteady pressure-sensitive paint↗

Implementation of an Unsteady PSP System in the NASA Transonic Dynamics Tunnel

An unsteady pressure-sensitive paint (uPSP) system has been developed to provide time-resolved pressure measurements in the NASA Langley Transonic Dynamics Tunnel (TDT). Obtaining these measurements necessitated the development of environmental enclosures to protect the high-speed camera and ultraviolet lights required for uPSP from the harsh environment present during tunnel operation. Since the facility main drive was non-functioning during the testing window, performance of the uPSP system was demonstrated using an impinging jet with a passive oscillator attachment to provide unsteady flow with a known frequency independent of amplitude. Measurements were obtained for tunnel pressures ranging from 565 to 2116 psf, and model angles of attack between -4 degrees and 4 degrees. Results indicate that the system is capable of measuring surface pressure differentials on the order of 0.01 psi at full scale with a camera frame rate of at least 10 kHz. Spectral analysis shows that the fundamental frequency of the oscillating jet is captured by the uPSP system, as are the second and third harmonics. Dynamic mode decomposition highlights the dominant coherent spatial structures of the surface pressure, along with the associated frequency and growth rate of each mode, allowing for a de-noised reconstruction of the uPSP measurements. The experimental campaign outlined within this report also confirmed compatibility of the uPSP system with the TDT facility data acquisition system, and verified the successful integration with existing processing capabilities within the NASA advanced supercomputing environment.

unsteady pressure-sensitive paint↗

A New Method of Deriving Time-Averaged Tropospheric Column Ozone over the Tropics Using Total Ozone Mapping Spectrometer (TOMS) Radiances: Intercomparison and Analysis Using TRACE A Data

Error analysis of archived total 03 from total ozone mapping spectrometer (TOMS) (version 6) presented. Daily total 03 maps for the tropics, from the period October 6-21, 1992, are derived from TOMS radiances following correction for these errors. These daily maps, averaged together, show a wavelike feature, which is observed in all latitude bands, underlying sharp peaks which occur at different longitudes depending on the latitude. The wave pattern is used to derive both time-averaged stratospheric and tropospheric 03 fields. The nature of the wave pattern (stratospheric or tropospheric) cannot be determined with certainty due to missing data (no Pacific sondes, no lower stratospheric Stratospheric Aerosol and Gas Experiment (SAGE) ozone for 18 months after the Mt. Pinatubo eruption) and significant uncertainties in the corroborative satellite record in the lower stratosphere (solar backscattered ultraviolet (SBUV), microwave limb sounder (MLS)). However, the time- averaged tropospheric ozone field, based on the assumption that the wave feature is stratospheric, agrees within 10% with ultraviolet differential absorption laser Transport and Atmospheric Chemistry near the Equator-Atlantic) (TRACE A) 03 measurements from the DC-8 and with ozonesonde measurements over Brazzaville, Congo, Ascension Island, and Natal, Brazil, for the period October 6-21, 1992. The derived background (nonpolluted) Indian Ocean tropospheric ozone amount, 26 Dobson units (DU), agrees with the cleanest African ozonesonde profiles for September-October 1992. The assumption of a totally tropospheric wave (flat stratosphere) gives 38 DU above the western Indian Ocean and 15-40% disagreements with the sondes. Tropospheric column 03 is high from South America to Africa, owing to interaction of dynamics with biomass burning emissions. Comparison with fire distributions from advanced very high resolution radiometer (AVHHR) during October 1992 suggests that tropospheric 03 produced from biomass burning in South America and Africa dominates the 03 budget in the tropical southern hemisphere during the study period.

Kim, J. H.↗

Martian B Storm Genesis and Evolution: Initial Analysis of Thermal Datasets.

Introduction: Dust lifting on Mars likely occurs primarily as a result of the exchange of momentum between the atmosphere and the surface via saltation. During saltation, sand-sized particles are mobilized but do not enter into suspension. When these larger particles fall back to the surface, kinetic energy is transferred to smaller dust particles which are then lofted into suspension in the atmosphere. Depending on the altitude to which dust is lofted, it can have a significant effect on atmospheric temperatures. As a strong absorber and emitter in the infrared, dust can influence atmospheric heating and modify the global circulation and weather on Mars [1,2]. Although dust is present in Mars’ atmosphere throughout the year, the atmosphere is generally dustier during the second half of the year when Mars is near perihelion. Observations reveal that episodic global-scale dust storms and fairly regular regional-scale dust storms are superimposed on a well-defined and highly repeatable seasonal cycle of dust opacity and associated mid-level atmospheric temperature responses. Kass et al. (2016) used 50 Pa temperature observations from MRO/MCS to identify three highly repeatable time periods during which regional dust storms occur, and designated them the “A”, “B” and “C” storms. While “A” and “C” storms have been studied a fair amount to-date, “B” storms have not yet been investigated in detail. This study explores the generation and evolution of the annually recurring regional dust storm known as the “B” storm, which was identified and categorized by Kass et al. (2016) based on 25 km (50 Pa) temperature observations. The B storm is a southern-hemisphere (SH) phenomenon that originates at the cap edge just after perihelion and which reaches peak intensity during the SH summer solstice, Ls 270. It may originate from the cap edge storms that spawn near the edge of the seasonal CO2 cap during retreat, but the mechanisms for B storm genesis have yet to be determined definitively [1]. Methods: We will use observational data sets and a global climate model (GCM) to investigate “B” regional storms. The data analysis component will include the analysis of imagery from MGS/MOC and MRO/MARCI, and spectroscopic data sets of dust and temperatures from MGS/TES and MRO/MCS with the goal of fully characterizing the behavior of these storms. Both MGS and TES provide data well-suited for temperature analysis at 25 km. MCS measures atmospheric temperature, dust extinction, and water ice extinction at 5 km intervals from the surface to about 80 km. TES measured atmospheric temperatures, column dust and water ice opacities, and column water vapor abundances. Measurements made by TES extended from the surface to about 40 km [1]. At the 50 Pa (25 km) level, local dust events usually confined to shallower depths are effectively filtered out of the analysis leaving the regional dust events identifiable by their temperature signatures [1]. Our preliminary analysis makes use of the fact that the brightness temperature at 15 microns (T15 temperature) is a close approximation to observed temperature at 25 km. We first reproduce the zonal mean 50 Pa level temperature plots for MY 29-32 to establish a baseline for our procedures moving forward [1]. Expanding on Kass et al. (2016), we include recent MCS data from MY 33 and 34 as well. Preliminary Analysis: The daytime (3PM) T15 temperatures in Figure 1 indicate: in MY 29, a strong A storm at Ls 240, a B storm at high southern latitudes just after Ls 270, and a C storm at Ls 320; in MY 30, a B storm at Ls 270; in MY 31 & MY 32, a B storm just before Ls 270; in MY 33, a B storm at Ls 270; and in MY 34, a strong A storm in the northern hemisphere at Ls 210, and a B storm around Ls 270 although there is a data gap. For the B storms, each is indicative of lofted dust and resultant warming. The daytime temperature structure illustrates that the B storm occurs annually around Ls 270 and is confined to high southern latitudes. It reaches its peak intensity around SH summer solstice, Ls 270, consistently for all six MY assessed. Since direct solar heating is absent overnight, the nighttime T15 temperatures (Figure 2) are often useful for differentiating the heat signature of direct solar heating from the dynamical response to that heating. However, in the southern polar latitudes at perihelion the sun does not set and direct solar heating remains present throughout the night. Importantly for our study, dust lofted in the B storm experiences this direct heating day and night for the entirety of its lifetime. The B storm expands as far north as -60 latitude and decays in latitudinal extent more gradually than it grows. This feature is less obvious in the nighttime (3AM) T15 temperatures (Figure 2). The temperature signal is stronger at night for MY 30-33. The warm pool is larger in area relative to the background at night in these four cases. This more uniform warming masks the “tail” feature somewhat, such that it is barely noticeable during these years. Unfortunately, gaps in MCS data in MY 29 and 34 prevent confirmation of the tail feature during those years, however, the B storm temperature signature follows a very different pattern than that described for MY 30-33. MY 29 and 34 appear to show smaller centers of warming at night and larger centers of warming during the day. This is in opposition to that previously described for MY 30-33. Conclusions and Future Work: We will continue investigating the heat signatures of B storms by looking at the total column heating as recorded by TES. We will also look at lower altitudes for patterns that may describe the relationship between B storms and the cap edge storms that develop while the seasonal cap is retreating. In the future, we will use GCM simulations to determine the atmospheric and thermo-dynamic conditions associated with these storms.

Courtney Marylou Batterson↗

Methods for Quantitative Thermal Analysis of Lithium Solid-State and Beyond Battery Safety

The use of differential scanning calorimetry (DSC) to measure the thermal behavior of individual components and electrolyte/electrode combinations is common. However, here we focus on DSC tests on an anode, cathode, and electrolyte (ACE) component combination over a temperature range that includes many of the phase transitions and key reactions (i.e., to 500 °C) that contribute to thermal runaway. This method can help quantify the complex reaction network in a full cell, thereby informing potential safety issues. Here, we used DSC heat flow data from a solid-state Li 0.43 CoO 2 +C+PVDF | LLZO | Li metal ACE sample and its components to quantify key factors affecting results. We focused on three areas: (1) ACE sample preparation and assembly in DSC pans, (2) DSC measurement parameters, and (3) heat flow analysis. Key points include the choice of component ratios (e.g., commercially relevant N:P capacity ratio), the importance of conductive carbon and binder, type of pan used, DSC ramp rate, and integration method used when dealing with broad and overlapping exothermic peaks. This work deepens the scientific basis and best practices for obtaining heat flow data from ACE samples for early-stage evaluation of solid-state and beyond battery safety.

25 ENERGY STORAGE↗

Microwave Flow Cytometric Detection and Differentiation of Escherichia coli

Label-free measurement and analysis of single bacterial cells are essential for food safety monitoring and microbial disease diagnosis. We report a microwave flow cytometric sensor with a microstrip sensing device with reduced channel height for bacterial cell measurement. Escherichia coli B and Escherichia coli K-12 were measured with the sensor at frequencies between 500 MHz and 8 GHz. The results show microwave properties of E. coli cells are frequency-dependent. A LightGBM model was developed to classify cell types at a high accuracy of 0.96 at 1 GHz. Thus, the sensor provides a promising label-free method to rapidly detect and differentiate bacterial cells. Nevertheless, the method needs to be further developed by comprehensively measuring different types of cells and demonstrating accurate cell classification with improved machine-learning techniques.

59 BASIC BIOLOGICAL SCIENCES↗

Implementation of an Unsteady PSP System in the NASA TDT

An unsteady pressure-sensitive paint (uPSP) system has been developed to provide time-resolved pressure measurements in the NASA Langley Transonic Dynamics Tunnel (TDT). Obtaining these measurements necessitated the development of environmental enclosures to protect the high-speed camera and ultraviolet lights required for uPSP from the harsh environment present during tunnel operation. Since the facility main drive was non-functioning during the testing window, performance of the uPSP system was demonstrated using an impinging jet with a passive oscillator attachment to provide unsteady flow with a known frequency independent of amplitude. Measurements were obtained for tunnel pressures ranging from 565 to 2116 psf, and model angles of attack between -4 degrees and 4 degrees. Results indicate that the system is capable of measuring surface pressure differentials on the order of 0.01 psi at full scale with a camera frame rate of at least 10 kHz. Spectral analysis shows that the fundamental frequency of the oscillating jet is captured by the uPSP system, as are the second and third harmonics. Dynamic mode decomposition highlights the dominant coherent spatial structures of the surface pressure, along with the associated frequency and growth rate of each mode, allowing for a de-noised reconstruction of the uPSP measurements. The experimental campaign outlined within this report also confirmed compatibility of the uPSP system with the TDT facility data acquisition system, and verified the successful integration with existing processing capabilities within the NASA advanced supercomputing environment. Note: this presentation is an MP4 video with sound, color with a run time of 10 minutes 37 seconds.

unsteady pressure-sensitive paint↗