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Ag3PO4 crystallizes in the cubic Pm-3n space group. The structure is three-dimensional and consists of two phosphine molecules and one Ag3O4 framework. In the Ag3O4 framework, Ag1+ is bonded in a square co-planar geometry to four equivalent O2- atoms. All Ag–O bond lengths are 2.13 Å. O2- is bonded in a trigonal planar geometry to three equivalent Ag1+ atoms.
Al(CH3)2(Sn(CH3)3)2P crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 84840-89-1 molecules, two phosphine molecules, and four trimethyltin molecules.
In(CH3)2Si2P(CH3)6 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two dimethylindium molecules and two phosphine, bis(trimethylsilyl)- molecules.
(CuI)2P8Se3 crystallizes in the orthorhombic Pbcm space group. The structure is zero-dimensional and consists of four iodocopper molecules, eight phosphine molecules, and twelve PPSe clusters. In each PPSe cluster, P+0.75+ is bonded in a distorted single-bond geometry to one Se2- atom. The P–Se bond length is 2.28 Å. Se2- is bonded in an L-shaped geometry to two equivalent P+0.75+ atoms.
(Ni)3(Ni2SiP)2(P)3 crystallizes in the orthorhombic Pbcn space group. The structure is two-dimensional and consists of twelve nickel molecules; twelve phosphine molecules; and two Ni2SiP sheets oriented in the (0, 0, 1) direction. In each Ni2SiP sheet, there are two inequivalent Ni1+ sites. In the first Ni1+ site, Ni1+ is bonded in a 4-coordinate geometry to four equivalent Si4- atoms. There are a spread of Ni–Si bond distances ranging from 2.26–2.58 Å. In the second Ni1+ site, Ni1+ is bonded in a 2-coordinate geometry to two equivalent Si4- atoms. There are one shorter (2.38 Å) and one longer (2.49 Å) Ni–Si bond lengths. Si4- is bonded in a 7-coordinate geometry to six Ni1+ and one P+0.20+ atom. The Si–P bond length is 2.84 Å. P+0.20+ is bonded in a 1-coordinate geometry to one Si4- atom.
W(CO)5(PH3) crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four phosphine molecules and four W(CO)5 clusters. In each W(CO)5 cluster, W6+ is bonded in a square pyramidal geometry to five C+0.80- atoms. There are a spread of W–C bond distances ranging from 2.03–2.08 Å. There are five inequivalent C+0.80- sites. In the first C+0.80- site, C+0.80- is bonded in a distorted single-bond geometry to one W6+ and one O2- atom. The C–O bond length is 1.16 Å. In the second C+0.80- site, C+0.80- is bonded in a distorted single-bond geometry to one W6+ and one O2- atom. The C–O bond length is 1.16 Å. In the third C+0.80- site, C+0.80- is bonded in a distorted single-bond geometry to one W6+ and one O2- atom. The C–O bond length is 1.16 Å. In the fourth C+0.80- site, C+0.80- is bonded in a distorted single-bond geometry to one W6+ and one O2- atom. The C–O bond length is 1.17 Å. In the fifth C+0.80- site, C+0.80- is bonded in a distorted single-bond geometry to one W6+ and one O2- atom. The C–O bond length is 1.16 Å. There are five inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one C+0.80- atom. In the second O2- site, O2- is bonded in a single-bond geometry to one C+0.80- atom. In the third O2- site, O2- is bonded in a single-bond geometry to one C+0.80- atom. In the fourth O2- site, O2- is bonded in a single-bond geometry to one C+0.80- atom. In the fifth O2- site, O2- is bonded in a single-bond geometry to one C+0.80- atom.
(CN)3P crystallizes in the tetragonal I-42d space group. The structure is zero-dimensional and consists of forty-eight hydrogen cyanide molecules and sixteen phosphine molecules.
(Ru)4P(CO)14CF3 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four fluoroform molecules, fifty-six formaldehyde molecules, four phosphine molecules, and sixteen ruthenium molecules.
(CuBr)2P8Se3 crystallizes in the orthorhombic Pbcm space group. The structure is zero-dimensional and consists of four bromocopper molecules, eight phosphine molecules, and twelve PPSe clusters. In each PPSe cluster, P+0.75+ is bonded in a distorted single-bond geometry to one Se2- atom. The P–Se bond length is 2.29 Å. Se2- is bonded in an L-shaped geometry to two equivalent P+0.75+ atoms.
Na3H24SO15P crystallizes in the trigonal R32 space group. The structure is two-dimensional and consists of six phosphine molecules and three Na3H24SO15 sheets oriented in the (0, 0, 1) direction. In each Na3H24SO15 sheet, there are three inequivalent Na1+ sites. In the first Na1+ site, Na1+ is bonded in a 6-coordinate geometry to six O2- atoms. There are three shorter (2.35 Å) and three longer (2.54 Å) Na–O bond lengths. In the second Na1+ site, Na1+ is bonded in a distorted tetrahedral geometry to one S2- and three equivalent O2- atoms. The Na–S bond length is 2.69 Å. All Na–O bond lengths are 2.25 Å. In the third Na1+ site, Na1+ is bonded in an octahedral geometry to six O2- atoms. There are three shorter (2.41 Å) and three longer (2.64 Å) Na–O bond lengths. There are eight inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.98 Å. In the second H1+ site, H1+ is bonded in a linear geometry to two O2- atoms. There is one shorter (1.03 Å) and one longer (1.58 Å) H–O bond length. In the third H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.98 Å. In the fourth H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 1.00 Å. In the fifth H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.98 Å. In the sixth H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.97 Å. In the seventh H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.98 Å. In the eighth H1+ site, H1+ is bonded in a linear geometry to two O2- atoms. There is one shorter (1.02 Å) and one longer (1.58 Å) H–O bond length. S2- is bonded in a distorted tetrahedral geometry to one Na1+ and three equivalent O2- atoms. All S–O bond lengths are 1.54 Å. There are five inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted trigonal non-coplanar geometry to three H1+ atoms. In the second O2- site, O2- is bonded in a 2-coordinate geometry to one Na1+ and two H1+ atoms. In the third O2- site, O2- is bonded in a distorted bent 120 degrees geometry to one Na1+, one H1+, and one S2- atom. In the fourth O2- site, O2- is bonded in a distorted water-like geometry to one Na1+ and two H1+ atoms. In the fifth O2- site, O2- is bonded in a distorted water-like geometry to two Na1+ and two H1+ atoms.
PHOF2 crystallizes in the orthorhombic Pbca space group. The structure is zero-dimensional and consists of eight phosphine oxide, difluoro- molecules. P5+ is bonded in a distorted tetrahedral geometry to one H1-, one O2-, and two F1- atoms. The P–H bond length is 1.40 Å. The P–O bond length is 1.47 Å. Both P–F bond lengths are 1.57 Å. H1- is bonded in a single-bond geometry to one P5+ atom. O2- is bonded in a single-bond geometry to one P5+ atom. There are two inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one P5+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one P5+ atom.
Mn2C9SO8F3P(CF3)2 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight fluoroform molecules, four phosphine molecules, and four Mn2C9SO8F3 clusters. In each Mn2C9SO8F3 cluster, there are two inequivalent Mn2+ sites. In the first Mn2+ site, Mn2+ is bonded to four C+1.64+ and one S2- atom to form distorted corner-sharing MnC4S square pyramids. There are a spread of Mn–C bond distances ranging from 1.83–1.87 Å. The Mn–S bond length is 2.43 Å. In the second Mn2+ site, Mn2+ is bonded to four C+1.64+ and one S2- atom to form distorted corner-sharing MnC4S square pyramids. There are a spread of Mn–C bond distances ranging from 1.82–1.87 Å. The Mn–S bond length is 2.43 Å. There are nine inequivalent C+1.64+ sites. In the first C+1.64+ site, C+1.64+ is bonded in a linear geometry to one Mn2+ and one O2- atom. The C–O bond length is 1.16 Å. In the second C+1.64+ site, C+1.64+ is bonded in a linear geometry to one Mn2+ and one O2- atom. The C–O bond length is 1.16 Å. In the third C+1.64+ site, C+1.64+ is bonded in a linear geometry to one Mn2+ and one O2- atom. The C–O bond length is 1.16 Å. In the fourth C+1.64+ site, C+1.64+ is bonded in a linear geometry to one Mn2+ and one O2- atom. The C–O bond length is 1.16 Å. In the fifth C+1.64+ site, C+1.64+ is bonded in a trigonal non-coplanar geometry to one S2- and three F1- atoms. The C–S bond length is 1.82 Å. There is one shorter (1.36 Å) and two longer (1.37 Å) C–F bond length. In the sixth C+1.64+ site, C+1.64+ is bonded in a linear geometry to one Mn2+ and one O2- atom. The C–O bond length is 1.16 Å. In the seventh C+1.64+ site, C+1.64+ is bonded in a linear geometry to one Mn2+ and one O2- atom. The C–O bond length is 1.16 Å. In the eighth C+1.64+ site, C+1.64+ is bonded in a linear geometry to one Mn2+ and one O2- atom. The C–O bond length is 1.16 Å. In the ninth C+1.64+ site, C+1.64+ is bonded in a linear geometry to one Mn2+ and one O2- atom. The C–O bond length is 1.16 Å. S2- is bonded in a distorted trigonal non-coplanar geometry to two Mn2+ and one C+1.64+ atom. There are eight inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one C+1.64+ atom. In the second O2- site, O2- is bonded in a single-bond geometry to one C+1.64+ atom. In the third O2- site, O2- is bonded in a single-bond geometry to one C+1.64+ atom. In the fourth O2- site, O2- is bonded in a single-bond geometry to one C+1.64+ atom. In the fifth O2- site, O2- is bonded in a single-bond geometry to one C+1.64+ atom. In the sixth O2- site, O2- is bonded in a single-bond geometry to one C+1.64+ atom. In the seventh O2- site, O2- is bonded in a single-bond geometry to one C+1.64+ atom. In the eighth O2- site, O2- is bonded in a single-bond geometry to one C+1.64+ atom. There are three inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one C+1.64+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one C+1.64+ atom. In the third F1- site, F1- is bonded in a single-bond geometry to one C+1.64+ atom.
WFe(CO)4Fe2C6O6BrP(CO)5 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of twenty formaldehyde molecules, four phosphine molecules, four tungsten molecules, four Fe(CO)4 clusters, and four Fe2C6O6Br clusters. In each Fe(CO)4 cluster, Fe+2.67+ is bonded in a distorted see-saw-like geometry to four C+0.80+ atoms. There are a spread of Fe–C bond distances ranging from 1.79–1.84 Å. There are four inequivalent C+0.80+ sites. In the first C+0.80+ site, C+0.80+ is bonded in a linear geometry to one Fe+2.67+ and one O2- atom. The C–O bond length is 1.15 Å. In the second C+0.80+ site, C+0.80+ is bonded in a distorted single-bond geometry to one Fe+2.67+ and one O2- atom. The C–O bond length is 1.15 Å. In the third C+0.80+ site, C+0.80+ is bonded in a distorted linear geometry to one Fe+2.67+ and one O2- atom. The C–O bond length is 1.16 Å. In the fourth C+0.80+ site, C+0.80+ is bonded in a distorted linear geometry to one Fe+2.67+ and one O2- atom. The C–O bond length is 1.15 Å. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one C+0.80+ atom. In the second O2- site, O2- is bonded in a single-bond geometry to one C+0.80+ atom. In the third O2- site, O2- is bonded in a single-bond geometry to one C+0.80+ atom. In the fourth O2- site, O2- is bonded in a single-bond geometry to one C+0.80+ atom. In each Fe2C6O6Br cluster, there are two inequivalent Fe+2.67+ sites. In the first Fe+2.67+ site, Fe+2.67+ is bonded in a distorted trigonal pyramidal geometry to three C+0.80+ and one Br1- atom. There are a spread of Fe–C bond distances ranging from 1.79–1.82 Å. The Fe–Br bond length is 2.47 Å. In the second Fe+2.67+ site, Fe+2.67+ is bonded in a distorted see-saw-like geometry to three C+0.80+ and one Br1- atom. There are a spread of Fe–C bond distances ranging from 1.79–1.82 Å. The Fe–Br bond length is 2.46 Å. There are six inequivalent C+0.80+ sites. In the first C+0.80+ site, C+0.80+ is bonded in a linear geometry to one Fe+2.67+ and one O2- atom. The C–O bond length is 1.16 Å. In the second C+0.80+ site, C+0.80+ is bonded in a distorted linear geometry to one Fe+2.67+ and one O2- atom. The C–O bond length is 1.16 Å. In the third C+0.80+ site, C+0.80+ is bonded in a distorted linear geometry to one Fe+2.67+ and one O2- atom. The C–O bond length is 1.16 Å. In the fourth C+0.80+ site, C+0.80+ is bonded in a linear geometry to one Fe+2.67+ and one O2- atom. The C–O bond length is 1.16 Å. In the fifth C+0.80+ site, C+0.80+ is bonded in a distorted linear geometry to one Fe+2.67+ and one O2- atom. The C–O bond length is 1.16 Å. In the sixth C+0.80+ site, C+0.80+ is bonded in a distorted linear geometry to one Fe+2.67+ and one O2- atom. The C–O bond length is 1.16 Å. There are six inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one C+0.80+ atom. In the second O2- site, O2- is bonded in a single-bond geometry to one C+0.80+ atom. In the third O2- site, O2- is bonded in a single-bond geometry to one C+0.80+ atom. In the fourth O2- site, O2- is bonded in a single-bond geometry to one C+0.80+ atom. In the fifth O2- site, O2- is bonded in a single-bond geometry to one C+0.80+ atom. In the sixth O2- site, O2- is bonded in a single-bond geometry to one C+0.80+ atom. Br1- is bonded in a 3-coordinate geometry to two Fe+2.67+ atoms.
Mn(CO)4PH2 crystallizes in the monoclinic P2/c space group. The structure is zero-dimensional and consists of six phosphine molecules and six Mn(CO)4 clusters. In two of the Mn(CO)4 clusters, Mn2+ is bonded in a rectangular see-saw-like geometry to four C+0.25- atoms. There is two shorter (1.82 Å) and two longer (1.86 Å) Mn–C bond length. There are two inequivalent C+0.25- sites. In the first C+0.25- site, C+0.25- is bonded in a linear geometry to one Mn2+ and one O2- atom. The C–O bond length is 1.16 Å. In the second C+0.25- site, C+0.25- is bonded in a linear geometry to one Mn2+ and one O2- atom. The C–O bond length is 1.16 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one C+0.25- atom. In the second O2- site, O2- is bonded in a single-bond geometry to one C+0.25- atom. In four of the Mn(CO)4 clusters, Mn2+ is bonded in a rectangular see-saw-like geometry to four C+0.25- atoms. There are a spread of Mn–C bond distances ranging from 1.82–1.86 Å. There are four inequivalent C+0.25- sites. In the first C+0.25- site, C+0.25- is bonded in a linear geometry to one Mn2+ and one O2- atom. The C–O bond length is 1.16 Å. In the second C+0.25- site, C+0.25- is bonded in a linear geometry to one Mn2+ and one O2- atom. The C–O bond length is 1.16 Å. In the third C+0.25- site, C+0.25- is bonded in a linear geometry to one Mn2+ and one O2- atom. The C–O bond length is 1.16 Å. In the fourth C+0.25- site, C+0.25- is bonded in a linear geometry to one Mn2+ and one O2- atom. The C–O bond length is 1.16 Å. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to one C+0.25- atom. In the second O2- site, O2- is bonded in a single-bond geometry to one C+0.25- atom. In the third O2- site, O2- is bonded in a single-bond geometry to one C+0.25- atom. In the fourth O2- site, O2- is bonded in a single-bond geometry to one C+0.25- atom.
Sr3BiP is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional and consists of one phosphine molecule and one Sr3Bi framework. In the Sr3Bi framework, Sr is bonded in a linear geometry to two equivalent Bi atoms. Both Sr–Bi bond lengths are 3.09 Å. Bi is bonded to six equivalent Sr atoms to form corner-sharing BiSr6 octahedra. The corner-sharing octahedral tilt angles are 0°.
Sr3AsP is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional and consists of one phosphine molecule and one Sr3As framework. In the Sr3As framework, Sr2+ is bonded in a linear geometry to two equivalent As3- atoms. Both Sr–As bond lengths are 2.90 Å. As3- is bonded to six equivalent Sr2+ atoms to form corner-sharing AsSr6 octahedra. The corner-sharing octahedral tilt angles are 0°.
Sr3SbP is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional and consists of one phosphine molecule and one Sr3Sb framework. In the Sr3Sb framework, Sr2+ is bonded in a linear geometry to two equivalent Sb3- atoms. Both Sr–Sb bond lengths are 3.05 Å. Sb3- is bonded to six equivalent Sr2+ atoms to form corner-sharing SbSr6 octahedra. The corner-sharing octahedral tilt angles are 0°.
Ca3P2 is High-temperature superconductor-like structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional and consists of one phosphine molecule and one Ca3P framework. In the Ca3P framework, Ca2+ is bonded in a linear geometry to two equivalent P3- atoms. Both Ca–P bond lengths are 2.65 Å. P3- is bonded to six equivalent Ca2+ atoms to form corner-sharing PCa6 octahedra. The corner-sharing octahedral tilt angles are 0°.