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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Enabling Highly Stable Li–O 2 Batteries with Full Discharge–Charge Capability: The Porous Binder- and Carbon-Free IrNi Nanosheet Cathode

Rechargeable aprotic Li-O 2 batteries have drawn much attention in light of their ultrahigh theoretical energy density. However, the sluggish kinetics of oxygen cathode reactions lead to huge energy loss, while the unfavorable side reactions associated with the widely used carbon and binder account for fast battery decay during cycles. In this work, hierarchically holey IrNi alloy nanosheets are facilely designed on Ni foam substrate as a freestanding, binder- and carbon-free cathode to address these challenges. The IrNi nanosheets consist of numerous interconnected nanoparticles, forming abundant nanoholes, benefiting active-site exposure. Moreover, the meso-/macropores pave channels for the transfer of oxygen and lithium ions and provide enough accommodation for the insoluble Li 2 O 2 product. The corresponding Li-O 2 batteries demonstrate low polarization and excellent cycle stability with full discharge/charge capability (up to 292 cycles at a current density of 0.2 mA cm -2 within a voltage range from 2.3 to 4.3 V). The long-term cycling performance is principally attributed to the exclusive catalytic stability of the holey IrNi nanosheets and its good compatibility with dimethyl sulfoxide-based electrolyte. Our research provides novel insights into the design of robust and freestanding porous cathodes for high energy density Li-O 2 batteries.

25 ENERGY STORAGE↗
DOE OSTI2021

Temperature and solvent-dependent photoluminescence quenching in [Ru(bpy) 2 (bpy-cc-AQ)] 2+

I have herein investigated the solvent-dependent photoluminescence quenching mechanism of [Ru(bpy) 2 (bpy-cc-AQ)] 2+ using variable temperature emission spectroscopies. In this wok, the photophysics of this complex are dominated by an excited-state thermal equilibrium between a photoluminescent 3 MLCT state and a charge-separated state that lies higher in energy relative to the 3 MLCT state in low polarity solvents and approximately isoenergetic in high polarity solvents. Furthermore, an unusual photoluminescence temperature-dependence in high polarity solvents is shown to arise from competition between enthalpic factors favouring the charge-separated state and entropic factors favouring the photoluminescent 3 MLCT state, analogous to the molecular light-switch effect of [Ru(bpy) 2 (dppz)] 2+ . The solvent-dependent photoluminescence quenching of [Ru(bpy)2(bpy-cc-AQ)] 2+ is attributed to two key solvent-dependent factors: (1) the excited-state equilibrium position and (2) the rate of charge-recombination from the charge-separated state.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Tape Casting of Thin Electrolyte and Thick Cathode for Halide-Based All-Solid-State Batteries

Most previous studies about halide solid-state electrolytes have used pellets prepared by uniaxial pressing, which is a good approach for materials development but is not suitable for commercialization. Thinner electrolyte layers that can be scaled up to large cell areas are required, and tape casting is a promising approach. It is challenging, however, as halide materials are reactive with most of the conventional solvents used in the process. In this study, solvents with low polarity, such as toluene, are found to be compatible with the Li 3 YBr 6 halide material. A wide variety of candidate binders that are soluble in toluene are studied. MSB1–13 binder is preferred, based on the ionic conductivity and mechanical properties of the tape. Electrolyte tapes (<70 μ m) are successfully cast on Al substrates, using 2 wt% binder. The resulting room temperature ionic conductivity is 2 × 10 −4 S cm −1 . Two composite cathodes including active material (LiFePO 4 or LiNi 0.82 Mn 0.07 Co 0.11 O 2 ) and 1 to 1.5 wt% MSB1–13 are tape cast as proof-of-concept for a scalable cell fabrication approach. A LiFePO 4 cell shows good retention at 25 °C. The performance of NMC cells with tape electrolyte or pellet electrolyte is similar. This study demonstrates the feasibility of tape casting halide-based electrolytes and cathodes.

25 ENERGY STORAGE↗
DOE OSTI2023

The Role of the Anion in Imidazolium-Based Ionic Liquids for Fuel and Terpenes Processing

The potentialities of methylimidazolium-based ionic liquids (ILs) as solvents were evaluated for some relevant separation problems—terpene fractionation and fuel processing—studying selectivities, capacities, and solvent performance indices. The activity coefficients at infinite dilution of the solute (1) in the IL (3), γ13∞, of 52 organic solutes were measured by inverse gas chromatography over a temperature range of 333.2–453.2 K. The selected ILs are 1-butyl-3-methylimidazolium hexafluorophosphate, [C4mim][PF6], and the equimolar mixture of [C4mim][PF6] and 1-butyl-3-methylimidazolium chloride, [C4mim]Cl. Generally, low polar solutes follow γ1,C4mimCl∞ > γ1,C4mimPF6+C4mimCl∞ > γ1,C4mimPF6∞ while the opposite behavior is observed for alcohols and water. For citrus essential oil deterpenation, the results suggest that cations with long alkyl chains, such as C12mim+, promote capacity, while selectivity depends on the solute polarity. Promising results were obtained for the separation of several model mixtures relevant to fuel industries using the equimolar mixture of [C4mim][PF6] and [C4mim]Cl. This work demonstrates the importance of tailoring the polarity of the solvents, suggesting the use of ILs with mixed anions as alternative solvents for the removal of aliphatic hydrocarbons and contaminants from fuels.

Zambom, Aline (ORCID:0000000324512716)↗
NASA NTRS1967

Study made of dielectric properties of promising materials for cryogenic capacitors

Experimental investigations were conducted to determine dielectric properties of promising materials for cryogenic capacitors to be used in energy storage and pulse applications. The three classes of materials investigated were inorganic bonded ferroelectric materials, anodic coatings on metal foils, and polar low temperature liquids.

Mathes, K. N.↗
NASA NTRS1974

Simulation of a lunar gradiometer mission

A lunar gradiometer mission involves the mounting of a gradiometer on a satellite which is in a low, polar, and circular lunar orbit. The results of a numerical simulation of the mission is presented. It is shown that if the satellite is in a 50 km orbit, 1 deg and 2 deg gravity anomalies may be estimated with accuracies of 12 mgal and 1 mgal respectively. At a 100 km altitude, 2 deg gravity anomalies can be estimated with an accuracy of 12 mgal. These results assume a rotating type gradiometer with a .1E accuracy. The results can be readily scaled to reflect another level.

Argentiero, P. D.↗
NASA NTRS1976

On estimating gravity anomalies from gradiometer data

The Gravsat-gradiometer mission involves flying a gradiometer on a gravity satellite (Gravsat) which is in a low, polar, and circular orbit. Results are presented of a numerical simulation of the mission which demonstrates that, if the satellite is in a 250-km orbit, 3- and 5-degree gravity anomalies may be estimated with accuracies of 0.03 and 0.01 mm/square second (3 and 1 mgal), respectively. At an altitude of 350 km, the results are 0.07 and 0.025 mm.square second (7 and 2.5 mgal), respectively. These results assume a rotating type gradiometer with a 0.1 -etvos unit accuracy. The results can readily be scaled to reflect another accuracy level.

Argentiero, P.↗
NASA NTRS1979

Porous bead packings for gas chromatography

Porous polyaromatic packing beads have low polarity, high efficiency, short retention time, and may be synthesized in size range of 50 to 150 micrometers (100 to 270 mesh). Mechanically strong beads may be produced using various materials depending on elements and compounds to be identified.

Pollock, G. E.↗
NASA NTRS1981

Analysis of Meteorological Satellite location and data collection system concepts

A satellite system that employs a spaceborne RF interferometer to determine the location and velocity of data collection platforms attached to meteorological balloons is proposed. This meteorological advanced location and data collection system (MALDCS) is intended to fly aboard a low polar orbiting satellite. The flight instrument configuration includes antennas supported on long deployable booms. The platform location and velocity estimation errors introduced by the dynamic and thermal behavior of the antenna booms and the effects of the presence of the booms on the performance of the spacecraft's attitude control system, and the control system design considerations critical to stable operations are examined. The physical parameters of the Astromast type of deployable boom were used in the dynamic and thermal boom analysis, and the TIROS N system was assumed for the attitude control analysis. Velocity estimation error versus boom length was determined. There was an optimum, minimum error, antenna separation distance. A description of the proposed MALDCS system and a discussion of ambiguity resolution are included.

Wallace, R. G.↗
NASA NTRS1983

Low cost planetary science missions

The use of existing earth-orbiting satellite technology represents a potential way of fulfilling important planetary exploration goals at greatly reduced cost, at least within the region between Venus and the inner asteroid belt. The present paper reports three studies of options for such missions to near-earth asteroids, the moon and Mars. The asteroid mission projected would be that of a rendezvous with either Anteros or Eros for purposes of resource determination, using an adaptation of the Tiros-N weather satellite. Two parallel studies were done on geoscience orbiters intended to provide detailed composition mapping from low polar orbit of the moon and Mars based on the modification of the same spacecraft design: the FLTSATCOM spacecraft, and the Atmospheric Explorer/Dynamics Explorer (later changed to Tiros for combined moon-Mars missions). Studies have shown the major modifications required to involve the telecommunications, data handling, power, propulsion and attitude control subsystems, and have demonstrated concept feasibility.

French, J. R.↗
NASA NTRS1984

A Study of the Adequacy of Quasi-geostrophic Dynamics for Modeling the Effect of Frontal Cyclones on the Larger Scale Flow

The major objectives of this study are to test the validity of quasi-geostrophic (QG) dynamics, compared to primitive equation (PE) dynamics for modeling the effect of cyclone waves on the larger scale flow, and to study the formation of frontal cyclones and the dynamics of occluded frontogenesis. In order to extend the realism of the initial conditions over those used in earlier work of this nature and in order to include strong surface frontal zones in the initial conditions, a horizontal resolution on the order of 100 km between gridpoints is needed. In order to allow for integrations of up to two weeks simulated time and to keep the logistics and cost of the runs feasible, the horizontal domain of the models must be reduced. Based on work concerning polar lows, the tropospheric static stability was reduced and was also allowed to vary in different tropospheric layers. Previous work used a 'standard atmosphere' temperature lapse rate. Stratospheric stability remains unchanged. The use of one of these 'reduced stability' cases, with no surface frontal zone present resulted in the discovery of normal mode perturbations.

Mudrick, S.↗
NASA NTRS1985

Charging of DMSP/F6 spacecraft in aurora on 10 January 1983

Spacecraft charging has been widely observed in geosynchronous orbit on the ATS-5 and ATS-6 pair and on the SCATHA spacecraft. An adequate theory for explaining the observations exist. Neither the data or theory can be exported to low polar orbit and its drastically different environment. Evidence of charging on the DMSP F6 spacecraft is presented. A simple model is set up explaining the observations. Two independent instruments on the spacecraft showed charging to a moderate (44 volts) negative potential. The selection spectrometer showed a flux of 2 billion electrons per sq. cm. sec. ster. peaked at 9.5 keV. This was marginally sufficient to overcome the flux of cold ambient ions. Charging calculations are presented showing where simplications are justified and where serious uncertainties exist. More serious charging is predicted for the Shuttle in polar orbit.

Besse, A. L.↗
NASA NTRS1985

A study of the adequacy of quasi-geostrophic dynamics for modeling the effect of frontal cyclones on the larger scale flow

The validity of quasi-geostrophic (QG) dynamics were tested on compared to primitive equation (PE) dynamics, for modeling the effect of cyclone waves on the larger scale flow. The formation of frontal cyclones and the dynamics of occluded frontogenesis were studied. Surface friction runs with the PE model and the wavelength of maximum instability is described. Also fine resolution PE simulation of a polar low is described.

Mudrick, S.↗
NASA NTRS1984

A radar study of Comet IRAS-Araki-Alcock 1983d

Radar echoes from Comet IRAS-Araki-Alcock at wavelengths 3.54 and 12.9 cm indicate that the comet's nucleus is very rough on a scale larger than the radar wavelengths; however, the low polarization ratio (25 percent at 3.54 cm) indicates that the scattering is not dominated by multiple reflections, internal reflections, or large abundances of sharp edges, cracks, and pits. The shape of the nucleus probably departs greatly from a sphere with average radii near 3-4 km. The nucleus does not appear to look significantly different from a number of Apollo and Amor asteroids except that: (1) there is a suggestion that minor structure moves rapidly across the spectra, and (2) the debris not gravitationally bound to the comet was detected, and contributes 25 percent of the total radar cross section at the 12.9-cm wavelength. Other considerations suggest that the pole was at least 45 deg away from the line of sight on two days of observation, and that the rotation period is approximately 1-2 days.

Goldstein, R. M.↗
NASA NTRS1986

Spacecraft charging in the auroral plasma: Progress toward understanding the physical effects involved

The work is presented in four parts. First, main differences between the plasma environments in geostationary orbit and low polar orbit with regard to high-voltage charging situations are reviewed. Next, results are presented from a calculation of secondary-electron escape currents from negatively-charged spacecraft surfaces having various orientations relative to the local magnetic-field direction. It is shown that for finite ranges of combinations of electric and magnetic field directions, secondary-electron escape is completely suppressed and therefore cannot help to discharge the spacecraft. In such circumstances, secondary electrons may travel distances many times their gyroradii before reimpacting, and this may produce greatly increased secondary-electron surface currents. Thirdly, a simple rough estimate of the required conditions for high-voltage auroral-zone charging is developed. The results suggest that for any given spacecraft, surface potentials are likely to depend more strongly on the ratio of ambient flux of high-energy electrons to that of all ions, than on any other environmental parameter. Finally, preliminary results are presented of numerical simulation work directed toward testing this hypothesis. Numerical instabilities encountered in doing this simulation work probably are closely related to physical sensitivities inherent in the physics of the ion wake behind the spacecraft, and especially to beam-like constituents of the ion population in the wake.

Laframboise, J. G.↗
NASA NTRS1986

Earth observing system - Concepts and implementation strategy

The concepts of an Earth Observing System (EOS), an information system being developed by the EOS Science and Mission Requirements Working Group for international use and planned to begin in the 1990s, are discussed. The EOS is designed to study the factors that control the earth's hydrologic cycle, biochemical cycles, and climatologic processes by combining the measurements from remote sensing instruments, in situ measurement devices, and a data and information system. Three EOS platforms are planned to be launched into low, polar, sun-synchronous orbits during the Space Station's Initial Operating Configuration, one to be provided by ESA and two by the United States.

Hartle, R. E.↗
NASA NTRS1986

October Antarctic temperature and total ozone trends from 1979-1985

The morphology of temperature trends in the south polar stratosphere from 1979-1985 is detailed. A significant cooling has occurred in the stratosphere over this period. South polar October mean temperatures have declined 18 K at 24 km over the seven-year period. A large fraction of this decline occurs as a result of including 1979 temperatures in the trend. The years 1979 and 1982 differ from other years in that they include large mid-October wave events which produce significantly warmer polar temperatures. Nevertheless, a significant temperature decline has still occurred in the stratosphere even when the dynamically active years are not included. Comparing two relatively dynamically quiet years, 1980 and 1985, the largest temperature decrease in the 30 mb temperature field occurs not at the pole but in the subpolar temperature maximum centered near 60 deg S. The changes in temperature of both the maximum and the polar low regions correlate fairly well with total ozone changes observed by the Total Ozone Mapping Spectrophotometer.

Newman, Paul A.↗
NASA NTRS1987

Optical and near-infrared observations of BL Lacertae objects and active quasars

UBVRI and JHK photometric and polarimetric observations, obtained using the 1.5-m UCSD/UM telescope at Mount Lemmon, AZ during 1982-1984, are reported for a sample of 10 BL Lac objects, eight optically violent variable quasars, and the low-polarization quasar 3C 273. The data are presented in extensive tables and graphs and analyzed in detail. Most of the objects are found to have undergone large polarization variations on time scales ranging from 1 d to several months; five objects had fractional linear polarization P greater than 30 percent at least once during the period of observation, but four never had P greater than 10 percent. Of four objects which exhibited a preferred polarization position angle (theta), three had theta within 20 deg of the jet position angle determined by VLBI.

Smith, Paul S.↗