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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7

Quaternary slip rates and most recent surface rupture of the Bitterroot fault, western Montana

The Bitterroot fault is a ~100-km-long Quaternary active normal fault that bounds the eastern margin of the north–south-trending Bitterroot Mountains and accommodates extension near the Intermountain Seismic Belt. Here, new detailed mapping using high-resolution topographic data derived from light detection and ranging (lidar) along the southern Bitterroot Range documents multiple generations of fault scarps in Holocene–Pleistocene deposits with vertical off sets that increase in magnitude with age. Fault mapping indicates a complex fault geometry characterized by an en echelon pattern of discontinuous segments of 41–78° east-dipping normal faults that appear to cut the older Eocene detachment fault, and locally 70–88° west-dipping antithetic normal faults. 10 Be cosmogenic exposure dating provides in situ age control for 32 surface boulders (>1 m) sampled in glacial deposits. Near Como Dam, two Pinedale-age glacial moraine sequences yield peak age distributions of 15.0 ± 0.4 ka and 16.4 ± 0.6 ka as apparent exposure ages (e = 0), and 15.4 ± 0.4 ka and 16.8 ± 0.6 ka based on the maximum allowed boulder surface erosion rate (e = 2 mm/ka). Vertical separation of 3.5 ± 0.2 m across the ~16–17 ka glacial moraine off set by the Bitterroot fault scarp yields a fault slip rate of 0.2–0.3 mm/yr. Glacial Lake Missoula highstand shorelines, inset into the ~15 ka glacial moraine and vertically off set 4.6 ± 1.6 m by an antithetic strand of the Bitterroot fault, yield fault slip rates of 0.2–0.5 mm/yr that overlap with fault slip rates on the main strand near Lake Como (0.2–0.3 mm/yr). At the Ward Creek fan located ~15 km to the north of Lake Como, two glacial debris fan sequences yield peak age distributions of 16.6 ± 0.4 ka and 62.8 ± 1.7 ka (e = 0), and 17.0 ± 0.4 ka and 69.9 ± 2.2 ka (e = 2 mm/ka). Vertical separations of 2.4 ± 0.3 m and 4.5 ± 0.2 m on the ~17 ka and ~63–70 ka fan surfaces off set by the Bitterroot fault yield fault slip rates of 0.2–0.3 mm/yr and 0.1 mm/yr, respectively. Our results indicate broadly consistent fault slip rates for the main fault segments at Lake Como (0.2–0.3 mm/yr) and the Ward Creek fan (0.1–0.3 mm/yr) with an along-strike range of 0.1–0.3 mm/yr for the southern Bitterroot fault. Fault scaling relations and evidence of multiple late Quaternary fault surface ruptures suggest the Bitterroot fault could produce a Mw ~7.2 earthquake. Structural model constraints and our slip rate results indicate both high-angle or low-angle fault geometries are possible at depth. A seismogenic low-angle fault model could generate a larger earthquake of Mw >7.2. Earthquake history is unknown for the Bitterroot fault, but fault scarps in young glacial deposits demonstrate its seismogenic potential. Data from this study suggest seismic hazards from the Bitterroot fault may pose a high level of risk to the Missoula metropolitan area, the State’s second most populous region, and major infrastructures across the Missoula and Bitterroot Valleys.

58 GEOSCIENCES↗

Development of a Global Reference Surface Reflectance and BRDF Datasets from Geostationary Satellite Observations and AERONET Measurements

Surface reflectances and their dependency on illumination-view geometries (i.e., BRDF) are the foundation of many high-level satellite products for land and water monitoring. Yet it is difficult to evaluate the quality of satellite-based surface reflectances with ground-based measurements due to the spatial scale differences. In order to fill the gap, here we develop a reference dataset of surface reflectance and BRDF at the global AERONET sites with data streams from operational geostationary sensors including Himawari 8/9 AHI, GK-2A AMI, and GOES 16/17 ABI. Taking the top-of-atmosphere (TOA) reflectance and the site measured atmospheric aerosol optical depth (AOD) as the main inputs, we apply the GeoNEX-AC algorithm to performance accurate atmospheric correction and derive 10-minute surface reflectance and daily Ross-Thick-Li-Sparse (RTLS) BRDF parameters at AERONET sites where coincident AOD measurements and TOA observations are available from 2016 (for Himawari) or 2018 (for GOES) onwards. The algorithm ensures that the retrieved surface BRDF parameters, along with the site-measured AOD, allow the atmospheric radiative transfer model, SHARM, accurately simulate the observed TOA reflectance at diurnal and longer time scales. They are our best estimates of the surface optical properties and thus can serve as the “reference” to evaluate the performance of operational atmospheric correction algorithms (where AOD is assumed unknown and needs to be retrieved). The reference BRDF also allow us to evaluate the spectral band ratios between the SWIR (e.g., 2200 nm) and the visible (e.g., 650 nm) regions, which are commonly used in operational atmospheric correction algorithms. Finally, we demonstrate that the reference dataset can be used to develop potential data synergies between different GEO satellites as well as GEO-LEO sensors.

Weile Wang↗

Zeta potential measurements of SiO 2 and TiO 2 particles in anionic and cationic surfactant solutions

Zeta potential measurements can provide valuable insights into colloidal stability and may reflect changes in the electrochemical double layer that influence electrocatalysis. In this study, we used zeta potential measurements to monitor and investigate the adsorption behavior of anionic sodium dodecyl sulfate (SDS), cationic dodecyl trimethyl ammonium bromide (DTAB), and cationic cetyl trimethyl ammonium bromide (CTAB) surfactants on SiO 2 and TiO 2 particles in DI water. The zeta potentials of SiO 2 and TiO 2 particles were measured as a function of particle concentration in 1.0 mM, 5.0 mM, and 10.0 mM surfactant solutions. Results indicate that there is no significant adsorption of DS - ions on SiO 2 particles across all SDS concentrations investigated in this study. The zeta potential of TiO 2 particles shifts from negative to positive as particle concentration increases at 1.0 mM SDS, indicating a decrease in DS - ions adsorption per TiO 2 particle. Adsorption plateaus at 5.0 mM SDS for all TiO 2 concentrations studied. In contrast, DTA + and CTA + ions showed clear adsorption on SiO 2 particles, but DTA + exhibited no apparent adsorption on TiO 2 particles. Interestingly, CTA + adsorption on TiO 2 was only evident at higher surfactant concentrations. This study presents a systematic investigation of zeta potential behavior as a function of particle and surfactant concentration, highlighting adsorption saturation and electrostatic reversal. Unlike prior work that was limited to single particle concentration measurements, our approach reveals how surfactant adsorption per particle decreases with increasing surface area. Despite the structural similarity between DTAB and CTAB, this study captured the different adsorption behaviors of both surfactants on SiO 2 and TiO 2 , emphasizing the role of the overall structure of the surfactant on surfactant adsorption behavior. These insights refine the interpretation of zeta potential data and advance understanding of surfactant adsorption on oxide particles. The insight provided in this study about surfactant adsorption on SiO 2 and TiO 2 particles could have important implications for the design of more effective colloidal and catalytic systems.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Direct Evidence for a Sequential Electron Transfer–Proton Transfer Mechanism in the PCET Reduction of a Metal Hydroxide Catalyst

Here, the proton-coupled electron transfer (PCET) mechanism for the reaction M ox -OH + e − + H + → M red -OH 2 was de-termined through kinetic resolution of the independent electron transfer (ET) and proton transfer (PT) steps. The reaction of interest was triggered by visible light excitation of [Ru II (tpy)(bpy′)H 2 O] 2+ , Ru II -OH 2 , where tpy is 2,2′:6′,2″-terpyridine and bpy′ is 4,4′-diaminopropylsilatrane-2,2′-bipyridine, anchored to In 2 O 3 :Sn (ITO) thin films in aqueous solutions. Interfacial kinetics for the PCET reduction reaction were quantified by nanosecond transient absorption spectroscopy as a function of solution pH and applied potential. Data acquired from pH = 5-10 revealed a stepwise electron-transfer proton-transfer (ET-PT) mechanism, while kinetic measurements made below the pK a (Ru III -OH/OH 2 ) = 1.3 were used to study the analogous interfacial reaction where electron transfer was the only mechanistic step. Analysis of this data with a recently reported multi-channel kinetic model was used to construct a PCET zone diagram and supported the assignment of an ET-PT mechanism from pH = 5-10. Ultimately, this study represents a unique example amongst M ox -OH/M red -OH 2 reactivity where the protona-tion and oxidation state of the intermediate was kinetically and spectrally resolved to firmly establish the PCET mechanism.

Charge transfer↗

Energy Gap of the Even-Denominator Fractional Quantum Hall State in Bilayer Graphene

Bernal bilayer graphene hosts even-denominator fractional quantum Hall states thought to be described by a Pfaffian wave function with non-Abelian quasiparticle excitations. Here, in this study, we report the quantitative determination of fractional quantum Hall energy gaps in bilayer graphene using both thermally activated transport and by direct measurement of the chemical potential. We find a transport activation gap of 5.1 K at B = 12 T for a half filled N = 1 Landau level, consistent with density matrix renormalization group calculations for the Pfaffian state. However, the measured thermodynamic gap of 11.6 K is smaller than theoretical expectations for the clean limit by approximately a factor of 2. We analyze the chemical potential data near fractional filling within a simplified model of a Wigner crystal of fractional quasiparticles with long-wavelength disorder, explaining this discrepancy. Our results quantitatively establish bilayer graphene as a robust platform for probing the non-Abelian anyons expected to arise as the elementary excitations of the even-denominator state.

36 MATERIALS SCIENCE↗

Exploring Electrode-Level State-of-Charge and State-of-Health Dynamics in Lithium-Ion Battery Cells: Modeling and Experimental Identification

A computationally efficient model serves as a critical prerequisite for battery performance analysis and advanced battery management algorithm design. Although battery models that capture cell-level behavior have been widely explored in existing literature, electrode-level battery models have received much lesser attention till to date. However, such electrode-level models can significantly increase battery performance and life by enabling electrode-level health-conscious control. Such electrode-level control can effectively expand usable energy and power limits of the battery cells by utilizing the knowledge of individual electrodes' charge and health. In this context, this paper presents a comprehensive battery model developed with a reference electrode insertion that captures (i) electrode-level charge/discharge dynamics, (ii) stoichiometric and temporal dependencies of electrode-level resistances, (iii) solid electrolyte interface (SEI) layer growth as key degradation phenomenon, and (iv) capacity fade and resistance rise in each electrode due to nominal battery aging. The proposed model is identified, and a preliminary validation is performed utilizing terminal voltage and negative electrode potential data collected from a pouch cell under one continuous cycling and accelerated aging conditions where the cell experienced 14% capacity loss.

aging↗

The role of gamma radiation on zircaloy-4 corrosion - 2016-0029

A key microstructural feature of irradiated oxide films that form on Zircaloy-4 is the development of significant amounts of interconnected porosity or microcracking, particularly along oxide grain boundaries. This development disrupts the protective nature of the barrier layer, effectively resulting in an increase in the observed post-transition corrosion rates. This observation suggests that some aspect of oxide dissolution may be occurring. It is noteworthy that when exposed to photons with energies greater than that of the oxide band gap, n-type semiconducting oxides are prone to dissolution. Because zirconia (ZrO{sub 2}) is an n-type semiconductor, it is plausible that high-energy photons may play an important role in corrosion. In an operating nuclear reactor, neutron and gamma flux levels are closely interrelated because they arise, for the most part, from the same originating process (i.e., the fissioning of nuclear fuel). Thus, it is difficult to isolate the independent effects of neutron and gamma radiation on corrosion. It is, however, theoretically conceivable to assess the role that gamma radiation may have on corrosion by comparing instances where variations in radiation environment exists; specifically by comparing where variations in gamma flux levels relative to neutron flux levels within different regions of a reactor or from reactor to reactor exist. Comparisons of the corrosion rates obtained between two different reactors (the Halden test reactor and the advanced test reactor [ATR]) that have differing gamma-to-neutron ratios were performed. In addition, an examination of corrosion rate data from the ATR, in which a variation in gamma-to-neutron flux ratio exists, was also conducted. Results are presented, from both assessments, which indicate that gamma radiation plays a role in the irradiated corrosion behavior of Zircaloy-4. In addition to a discussion of experimental data, potential mechanisms associated with photon-induced oxide dissolution of n-type semiconducting oxides, such as zirconia, is also provided. (authors)

36 MATERIALS SCIENCE↗

ESS-DIVE Reporting Format for Sample-based Water and Soil Chemistry Measurements

The ESS-DIVE (Environmental Systems Science Data Infrastructure for a Virtual Ecosystem) reporting format for sample-based water and soil chemistry measurements are written guidelines and spreadsheet templates, that facilitate archiving water/soil/sediment chemistry data. The templates and terminology lists provided as part of the reporting format can help organize data and potentially enable data reuse.The reporting format consists of a general instructions file (instructions.md) as well as more detailed instructions files for each template (files beginning “Detailed_Instructions_*.md). The “examples” folder includes an example of each data template with just the limited set of required fields filled out as well as other examples with both required and optional fields complete.The 'templates' folder contains CSV templates for data, methods, and terminology file templates. Similar to the examples folder, the blank templates are provided with versions for required fields only as well as required and optional fields. Lastly, the term list folder provides common terminology used in each of the templates as well as a definition and any constraints for the fields.

54 ENVIRONMENTAL SCIENCES↗

Geomagnetic Storm Effects on Ionospheric Irregularities: Insights from SuperDARN, Madrigal GPS TEC, and ISR Data [Slides]

Geomagnetic disturbances trigger an influx of electrons from the magnetosphere, leading to an increase electron density (even in lower altitudes), amplified ionospheric currents, and subsequently, increased conductance. A surge in the AE index, indicating heightened auroral currents, correlates with a rise in precipitated charged particles, including electrons, into the polar ionosphere. This correlation is detectable through increased parameter values measured by SuperDARN. The downward flow of electron density towards lower altitudes, as observed in PFISR data, potentially obstructs the transmission frequency from radar stations passing through the PFISR location (just like we saw in the KOD station). During the geomagnetic storm, there is increased backscatter power (increased amount of ionospheric irregularities), and the plasma flow draws closer to the radar, suggesting a possible southward shift in the auroral oval as a result of the heightened auroral activity. Increased geomagnetic activity correlates with an elevation in average TEC and induces the occurrence of SED (Storm Enhanced Density).

58 GEOSCIENCES↗

A Life Cycle Analysis Framework for Point Source Capture Systems

NETL studies the costs and benefits of PSC for electricity, industry, and mobile applications. Mobile point source capture (MPSC) and storage applied to freight modes captures emissions directly from exhaust. This poster presents a framework for conducting LCA of PSC systems applied to heavy-duty trucks, freight trains, and marine vessels. The framework defines a wheels-to-storage (gate-to-grave) boundary, including energy demands (electricity, heat, and cooling requirements), solvent use and cycling, onboard system components, carbon storage in a saline aquifer, and upstream manufacturing impacts for equipment, with a suggested functional unit of 1 tonne-km. Potential data sources for analysis include material, energy, and operational data from Oak Ridge National Laboratory, GREET (Greenhouse gases, Regulated Emissions, and Energy use in Technologies) model, and scientific literature. The suggested analytical approach includes comparison to publicly available business-as-usual systems without capture across all modes of transportation, sensitivity to composition of the capture solvent, and sensitivity to capture rate variation, all of which would support a wholistic PSC business case analysis. For future consideration, analysis can be augmented with consideration of different sources of electricity (e.g., nuclear), fuel substitution, deploying supportive infrastructure such as pipeline offloading points, and downstream applications like enhanced oil recovery (EOR).

life cycle analysis (LCA)↗

A new method of studying the fundamental mechanisms involved in pigment liberation from recycle papers

Deinking flotation is the most efficient and widely used method of removing ink particles from printed papers to improve the recyclability. A prerequisite for successful deinking flotation is detachment of pigments from paper fibers, a subprocess known as liberation. The degree of liberation is usually determined via hyperwashing tests, which are costly and time consuming. Furthermore, they provide no information on the fundamental mechanisms controlling liberation. In the present work, we developed a new method in which ?-potentials of the particles in a pulp are measured and analyzed. If pigments are not liberated from paper fibers, a frequency distribution plot gives a single peak, while two peaks appear when they are liberated. One can readily determine the degrees of liberation from the peak positions and peak heights. In addition, the ?-potential data can be used to construct disjoining pressure isotherms using the DLVO theory that are useful to better understand the fundamental mechanisms involved and the roles of different reagents used to improve pigment liberation.

42 ENGINEERING↗

An underground, wireless, open-source, low-cost system for monitoring oxygen, temperature, and soil moisture

Abstract. The use of wireless sensor networks to measure soil parameters eliminates the need to remove sensors for field operations, such as tillage, thus allowing long-term measurements without multiple disturbances to soil structure. Wireless sensors also reduce above-ground cables and the risk of undesired equipment damage and potential data loss. However, implementing wireless sensor networks in field studies usually requires advanced and costly engineering knowledge. This study presents a new underground, wireless, open-source, low-cost system for monitoring soil oxygen, temperature, and soil moisture. The process of system design, assembly, programming, deployment, and power management is presented. The system can be left underground for several years without the need to change the battery. Emphasis was given on modularity so that it can be easily duplicated or changed if needed and deployed without previous engineering knowledge. Data from this type of system have a wide range of applications, including precision agriculture and high-resolution modelling.

54 ENVIRONMENTAL SCIENCES↗

The Nimbus 4 user's guide

Background information on the Nimbus 4 spacecraft and experiments is provided for potential data users as a basis for selecting, obtaining, and utilizing Nimbus 4 data in research studies. The basic spacecraft system operation and the objectives of the Nimbus 4 flight are outlined, with a detailed discussion of each of the experiments included. The format, archiving, and access to the data are also described. Finally, the contents and format of the Nimbus 4 data catalogs are described.

Sabatini, R. R.↗

An atlas of 1977 and 1978 GEOS-3 radar altimeter data for tropical cyclone studies

All of the GEOS 3 satellite altimeter schedule information were collected with all of the available 1977 and 1978 tropical cyclone positional information. The time period covers from March 23, 1977 through Nov. 23, 1978. The geographical region includes all ocean area north of the equator divided into the following operational areas: the Atlantic area (which includes the Caribbean and Gulf of Mexico); the eastern Pacific area; the central and western Pacific area; and the Indian Ocean area. All available source material concerning tropical cyclones was collected. The date/time/location information was extracted for each disturbance. This information was compared with the GEOS 3 altimeter ON/OFF history information to determine the existence of any altimeter data close enough in both time and location to make the data potentially useful for further study (the very liberal criteria used was time less than 24 hours and location within 25 degrees). Geographic plots (cyclone versus GEOS 3 orbit track) were produced for all of the events found showing the approximate location of the cyclone and the GEOS 3 orbit traces for the full day.

Stanley, H. R.↗

"Fuel Gage" for Electric Vehicles

Gas-emmission and time-integrated-current measurements indicate battery charge state. Tests indicate possibility of monitoring state of charge of lead/acid batteries at any stage in charging cycle by measuring charging current and either gas evolution or electrode potential. Data then processed by microcomputer. Uses include cell voltage, cell pressure, cell temperature and rate of gas recombination on catalyst.

Rowlette, J. J.↗

Potential utility of the thematic mapper for surface mine monitoring

One of many potential applications of the thematic mapper (TM) is surface mine monitoring. To assess this potential, data acquired by an aircraft multispectral scanner over Pennsylvania surface mines were preprocessed to simulate the anticipated spectral, spatial, and radiometric characteristics of TM data. False color imagery and thematic maps were derived from the simulated data and compared to imagery and maps derived from LANDSAT multispectral scanner subsystems data. On the basis of this comparison, TM data should definitely increase the detail and accuracy of remotely acquired surface mine information and may enable the remote determination of compliance with reclamation regulations.

Irons, J. R.↗

A review of studies on ion thruster beam and charge-exchange plasmas

Various experimental and analytical studies of the primary beam and charge-exchange plasmas of ion thrusters are reviewed. The history of plasma beam research is recounted, emphasizing experiments on beam neutralization, expansion of the beam, and determination of beam parameters such as electron temperature, plasma density, and plasma potential. The development of modern electron bombardment ion thrusters is treated, detailing experimental results. Studies on charge-exchange plasma are discussed, showing results such as the relationship between neutralizer emission current and plasma beam potential, ion energies as a function of neutralizer bias, charge-exchange ion current collected by an axially moving Faraday cup-RPA for 8-cm and 30-cm ion thrusters, beam density and potential data from a 15-cm ion thruster, and charge-exchange ion flow around a 30-cm thruster. A 20-cm thruster electrical configuration is depicted and facility effects are discussed. Finally, plasma modeling is covered in detail for plasma beam and charge-exchange plasma.

Carruth, M. R., Jr.↗