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At least 127 records · Page 7

Data from a synchronous altitude satellite quartz crystal microbalance monitor

Results of one year's operation in orbit of the Quartz Crystal Microbalance Monitor on the ATS-6 satellite are presented. The data indicate a general decreasing trend for the first four and one-half months in orbit. At that time, a sudden increase in beat frequency occurred; this correlates in time with the firing of the North Cesium Ion Engine. A general increase in beat frequency is evidenced since that time. Laboratory tests conducted to investigate the phenomenon are described.

Rogers, J. F.↗

Cryogenic Quartz Crystal Microbalance

A radiatively cooled Cryogenic Quartz Crystal Microbalance designed to monitor highly volatile contaminants on the shuttle is described. Measurements are made with two 15-MHz microbalances having removable, optically polished sensors mounted in a radiant cooler. One sensor operates below the freezing point of water and monitors contamination including that of water vapor. The second sensor is heated and monitors the contamination background. It provides a reference from which the density of the water vapor cloud enveloping the shuttle is determined. The design incorporates a low-power dissipation oscillator, heaters for ice removal, and a method for attaching second-surface mirrors to the radiator employing an indium type solder instead of a room temperature vulcanizer.

D Mckeown↗

Feasibility demonstration for hydrogen chloride detection using a chemisorption technique and a quartz crystal microbalance

A method of measuring concentrations of hydrogen chloride between 1 part per billion and 10 parts per million at standard temperature and pressure is presented. The feasibility of a low-cost device incorporating a chemisorption technique coupled with a quartz crystal microbalance was demonstrated in the field at the Viking B launch using a Titan-Centaur vehicle from Kennedy Space Center on August 20, 1975. Hydrogen chloride is a product of solid rocket combustion. The concentration level of hydrogen chloride for this particular launch was measured as approximately 0.2 parts per million at 4 km from the launch site.

Jex, D. W.↗

Inherent time delay for dielectric breakdown in shock-loaded x-cut quartz

Dielectric breakdown in shock-loaded x-cut quartz is examined under conditions of both impact loading and Q-switched laser-irradiation loading. It is observed that breakdown is characterized by an inherent time delay which depends on the magnitude of the electric field. For pulse duration less than about 30 ns, dielectric breakdown is not observed.

Graham, R. A.↗

ATS-6 - Quartz-Crystal Microbalance

The Quartz-Crystal Microbalance Experiment provided data on the possible return of contaminants to the exterior surfaces of the spacecraft. The experiment measures the change in resonant frequency of the crystal due to deposition of material on the surface. There has been no mass accretion corresponding to the firing of hydrazine thrusters to unload the spacecraft momentum wheels. There have been accretions corresponding to the firing of the cesium ion engines.

Rogers, J. F.↗

Correlation between stimulated scattering processes and laser-induced damage in crystalline quartz

The results of a systematic series of experiments to uncover possible correlation between laser-induced stimulated-Brillouin-scattering (SBS) phonons and damage in quartz are presented. Such correlation is confirmed and the various thresholds are established. The anomalous transmission factor under phonon generation is found to decay exponentially as predicted with increasing incident laser power. The LF SBS phonon is also demonstrated to be a sensitive probe for precatastrophic damage.

Yu, C.↗

Experimental hypervelocity impact into quartz sand. II - Effects of gravitational acceleration

Experimental results for craters formed by aluminum spheres impacting at normal incidence against quartz sand targets in gravitational acceleration environments ranging from 0.073 to 1.0 g (g = 980 cm/sq sec) are reported. Impact velocities varied from 0.4 to 8.0 km/sec. Crater dimensions and formation times are compared with results from a simplified dimensional analysis of the cratering processes. Although the comparison indicates a dominant role of gravity relative to the target strength for craters formed in sand, the results serve primarily to emphasize that both gravity and strength are variables of fundamental significance to cratering processes.

Gault, D. E.↗

Effects of accumulated film layers on the accuracy of quartz film thickness monitors

The effect of accumulation layers on the accuracy of quartz thin-film thickness monitors is evaluated. Use of an expanded plane wave ultrasonic propagation theory correctly accounts for observed experimental data. The magnitude of the maximum errors calculated for simply reversing the order of a series of aluminum gold deposits is on the order of 5%. If one totally neglects intervening layers, multiple film propagation and nonlinearity can produce errors greater than 50%.

Heyman, J. S.↗

Experimental study of pyroxene-liquid interaction in quartz-normative basalt 15597

Equilibrium and controlled cooling rate experiments on a synthetic analog of Apollo 15 quartz normative basalt 15597 are reported. While the partitioning of the major elements Ca, Mg, and Fe between pyroxene and liquid is rate independent, the K sub D parameter for Fe/Mg, which is calculated for low-Ca pyroxene, is temperature dependent. It is suggested that chemical trends observed in lunar pyroxenes are a consequence of three rate processes. The processes are (1) rate-dependent suppression of crystallization of other phases until lower temperature alters liquid composition and, therefore, the composition of the pyroxene that crystallizes; (2) the efficiency of fractional crystallization and the extent of crystal zoning are rate dependent; and (3) the partitioning of Al2O3, TiO2, and Cr2O3 between pyroxene and liquid depends on cooling rate.

Grove, T. L.↗

The Response of a Quartz Crystal Microbalance to a Liquid Deposit

A theory was developed for predicting the loss of response of a QCM (Quartz Crystal Microbalance) to a liquid deposit due to viscous effects in the deposit. The loss of response is expressed by a response factor, equal to the response of the QCM to a liquid film divided by its response to a solid film of the same mass per unit area. The theory assumes a droplet-type deposit morphology, and considers the influence of droplet distribution parameters. Experiments were conducted to examine the validity of the theory, using DC 704 silicone oil as the subject deposit material. Experiments were made in two series: one with constant deposit mass and variable temperature, the other with variable deposit mass and constant temperature. Interpretation of the data using the theory has enabled information on droplet area coverage and number density to be deduced.

Glassford, A. P. M.↗

Rocket effluent size distributions made with a cascade quartz crystal microbalance

Airborne particulate size distribution measurements were made in the stabilized ground cloud from a Titan III C rocket just after launch from the Kennedy Space Center on May 12, 1977. The measurements were made from aboard a small twin engine aircraft instrumented with particle and gas sensors. The plume was followed for about 1 hour while making multiple passes through the cloud at varying altitudes. The results obtained with a ten-stage cascade quartz crystal microbalance impactor show that the mass concentration as a function of particle diameter is bimodal with the first maximum between 0.05 micrometers and 0.1 micrometers and the second maximum between 0.8 and 1.0 micrometer. Scanning electron microscope analysis were performed on the material collected and show distinctly different kinds of particles in the two modes.

Woods, D. C.↗

Effects of kinetics on the crystallization of quartz normative basalt 15597 - An experimental study

Equilibrium experiments on a residual liquid composition from the dynamic crystallization study on quartz normative basalt (QNB) 15597 are used to evaluate the effects of kinetics on the crystallization of pyroxene-porphyritic basalts. The results indicate that the liquids coexisting with pyroxene phenocryst rims before the precipitation of groundmass plagioclase + pyroxene have left the equilibrium liquid line of descent and metastably penetrated the plagioclase primary phase volume. The precipitation of groundmass plagioclase + pyroxene brings the basalt system closer to equilibrium with respect to the residual liquid and crystals. At rapid cooling rates pyroxene phenocryst growth produces substantial compositional gradients in the residual silicate liquid at the pyroxene/liquid interface. The compositional gradients enhance the nucleation and growth of groundmass phases at the phenocryst interface, because effects related to constitutional supercooling for these phases (e.g., plagioclase, pyroxene, etc.) favor nucleation at the interface.

Grove, T. L.↗

Friction measurements in piston-cylinder apparatus using quartz-coesite reversible transition

The value of friction determined by monitoring piston displacement as a function of nominal pressure on compression and decompression cycles at 1273 K is compared with the friction value obtained by reversing the quartz-coesite transition at 1273 and 1073 K in a talc-glass-alsimag cell (Akella and Kennedy, 1971) and a low-friction salt cell (Mirwald et al., 1975). Quenching runs at 1273 K gave double values of friction of 0.25 GPa for the talc-glass-alsimag cell and 0.03 GPa for the salt cell. The piston-displacement technique gave somewhat higher values. Use of piston-displacement hysteresis loops in evaluating the actual pressure on a sample may lead to overestimates for decompression runs and underestimates for compression runs.

Akella, J.↗

Galileo quartz clock

A quartz oscillator for use in the Galileo experiment (orbiter and Probe) for Jupiter mission 1982 are described. This oscillator has achieved significant performance breakthroughs by the use of an SC cut, double rotated, crystal in a titanium dewar flask. Some of the performance parameters as well as the design feature of the oscillator are presented.

Block, M.↗

Studies on an experimental quartz tube hollow cathode

An experimental study is described in which a quartz tube, hollow cathode was operated in a test fixture allowing the simultaneous measurement of internal cathode pressure, insert temperature profiles, and the emission currents from various cathode components as a function of discharge current and propellant (mercury) mass flow rate for a number of different cathode orifice diameters. Results show that the insert temperature profile is essentially independent of orifice diameter but depends strongly on internal cathode pressure and emission current. The product of internal cathode pressure and insert diameter is shown to be important in determining the emission location and the minimum keeper voltage.

Siegfried, D. E.↗

Comparison of dynamic crystallization techniques on Apollo 15 quartz normative basalts

The paper compares dynamic crystallization techniques used on Apollo 15 quartz normative basalts which show differences related to their method. The variation of pyroxene core major element chemistry with cooling rate is confirmed, and it is shown that the Fe loss from liquid is shifted toward the En-Di joint; it is suggested that the nucleation temperature and breakdown of equilibrium partitioning as a function of cooling rate dictate the core composition. It is concluded that the different crystallization behavior that results from the Fe-capsule and Fe-loop container methods is related to the nucleation kinetics.

Lofgren, G. E.↗