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NASA NTRSDate not supplied

The Effect of Temperature on the Preservation of Volatile-Rich Lunar Samples

Introduction. The Moon’s south pole is a high-priority target for human exploration and scientific study. This interest is, in part, due to the presence of Permanently Shadowed Regions (PSRs), which could contain high concentrations of unique volatiles at cryogenic temperatures [1]. Returned samples from PSRs may include a unique combination of rocks, regolith, and volatile species, providing unprecedented insights into the history of the Solar System and the potential for resource utilization on the Moon. However, because PSR samples are cryogenic up-on collection, lunar polar sample return will eventually require cold stowage for the journey from the Moon to Earth. Without cold stowage, PSR sample return will likely result in phase changes and chemical reactions within the volatile component of the sample, which would negatively impact the resulting scientific studies of those samples. This abstract summarizes the initial results from an ongoing characterization of analog PSR samples at a range of temperatures, with the goal of defining the temperatures needed for a flight cold stowage freezer. Background. Based on remote sensing observations of the Moon [2], south polar PSRs range in temperature from ~120K for small and/or shallow PSRs to ~20K at the most extreme locations in large, deep PSRs. A range of volatiles have been hypothesized to exist at the surface or subsurface of the lunar poles [3-5 and others]. This hypothesis was verified when the LCROSS mission impacted the <50-K PSR in the crater Cabeus, detecting a range of volatiles from water to low condensation temperature species such as H2S and methane [6]. Species such as H2S and ammonia (also detected by LCROSS) are also highly reactive, and increase the likelihood of chemical reactions at elevated (non-cryogenic) temperatures. At the Johnson Space Center’s Planetary Exploration and Astromaterials Research Laboratory (JSC-PEARL), we have developed a volatile-bearing lunar simulant that incorporates several of the species detected by LCROSS [Table 1] mixed cryogenically with the USGS Lunar Highlands Type (LHT) regolith simulant. The new volatile-regolith simulant will be used to assess the degree of sample alteration at room temperature, -20°C, -80°C, and -196°C (liquid nitro-gen), over a two-week period. Room temperature samples represent those likely to be returned during initial missions without cold stowage, -20°C provides an analog to Apollo cold curated samples, -80°C is the temperature of multiple flight payload freezers (e.g., MELFI), and -196°C is analogous to lunar PSRs. Two weeks is an approximation of the time between sample collection and Earth return for initial Artemis missions. Over this period of time, sample head-space gases will be analyzed using a Universal Gas Analyzer (UGA, a type of mass spectrometer) coupled with a Baratron pressure sensor. After testing, the regolith component of the simulant will be purged of volatiles and preserved for future electron beam and/or FTIR analysis. Experimental Procedure. Volatile-regolith simulants will be produced as an initial homogenous batch; this batch will then be distributed into aliquots (gas chromatography/GC vials or cryo vials), ensuring that each sample has the same starting composition and conditions [Fig. 1]. In addition to the “full” simulant shown in Table 1, less complex simulant compositions will be used as baseline and control samples [Table 2]. Aliquots will be produced in triplicate for each simulant composition, storage temperature, and date of sampling. Headspace gases in all Day 0 samples will be analyzed by the UGA immediately. Cold storage samples for future analytical days will be placed in freezers appropriate to their target temperatures (-20°C, -80°C, -196°C). For ambient-temperature samples, regolith and regolith-water samples will be stored in a fume hood, while the full simulant will be stored in a sealed Parr vessel for safety; no other simulants (RWCM/ RWCM+) will be stored at ambient temperature for this test. Samples will be analyzed by UGA in this manner on each Analysis Day outlined in Table 2. Analytical Data. The UGA measures the partial pressures in a single sample aliquot over a set mass range of 0-105 atomic mass units (AMU) [Figure 2]; this set range was selected to slightly exceed the mass of the highest-mass expected reaction product (H2SO4). The Baratron complements the UGA by measuring the total pressure in the headspace of a sample vial. Coupled together, the quantitative abundances of gases will be monitored throughout the test. UGA analyses of the triplicate samples for each storage temperature, day, and simulant composition will be averaged, and standard deviations for each will be calculated. The compositions of starting species (shown in Table 1) will be characterized as a function of time, and the presence of any new compounds (reaction products) will be monitored as well. Total pressures will be recorded for each sample analysis, and any samples that show signs of leakage (e.g., a significant reduction in pressure or simulant volatiles) will be discarded. Anticipated Results. Testing is planned to begin in January 2022. The resulting data will allow compositional and phase changes in the volatile component of the simulants to be determined. Both the reduction in initial compounds and the addition of reaction products are expected to be observed. In addition, the relative efficacy of the different temperatures at pre-serving the initial composition of the simulants will be quantified. Finally, the regolith component of each sample will be argon-purged and stored in a controlled environment for future laboratory analysis. Compositional and morphological changes in the regolith are expected for samples above 0°C. This test will be repeated three times over the course of 2022. Understanding the effect of temperature on both the volatile and regolith components of analog lunar materials will allow requirements for a cold stowage freezer to be developed. The implementation of cold stowage for lunar polar missions will maximize the preservation of returned samples, enabling ground-breaking lunar and Solar System volatiles science for decades to come.

J L Mitchell↗

NASA NTRS1971

Methyl alcohol used as penetrant inspection medium for porous materials

Porous material thoroughly wetted with alcohol shows persistent wet line or area at locations of cracks or porosity. Inspection is qualitative and repeatable, but is used quantitatively with select samples to grade density variations in graphite blocks. Photography is employed to achieve permanent record of results.

Hendron, J. A.↗

NASA NTRS1975

Acoustic emission characteristics of copper alloys under low-cycle fatigue conditions

The acoustic emission (AE) characteristics of pure copper, zirconium-copper, and several copper alloys were determined to develop nondestructive evaluation schemes of thrust chambers through AE techniques. The AE counts rms voltages, frequency spectrum, and amplitude distribution analysis evaluated AE behavior under fatigue loading conditions. The results were interpreted with the evaluation of wave forms, crack propagation characteristics, as well as scanning electron fractographs of fatigue-tested samples. AE signals at the beginning of a fatigue test were produced by a sample of annealed alloys. A sample of zirconium-containing alloys annealed repeatedly after each fatigue loading cycle showed numerous surface cracks during the subsequent fatigue cycle, emitting strong-burst AE signals. Amplitude distribution analysis exhibits responses that are characteristic of certain types of AE signals.

Krampfner, Y.↗

NASA NTRS2012

Kepler Observations of Rapid Optical Variability in Active Galactic Nuclei

Over three quarters in 2010 - 2011, Kepler monitored optical emission from four active galactic nuclei (AGN) with approx 30 min sampling, > 90% duty cycle and approx < 0.1% repeatability. These data determined the AGN optical fluctuation power spectral density functions (PSDs) over a wide range in temporal frequency. Fits to these PSDs yielded power law slopes of -2.6 to -3.3, much steeper than typically seen in the X-rays. We find evidence that individual AGN exhibit intrinsically different PSD slopes. The steep PSD fits are a challenge to recent AGN variability models but seem consistent with first order MRI theoretical calculations of accretion disk fluctuations.

Mushotzky, R. F.↗

NASA NTRS2013

Using a Blender to Assess the Microbial Density of Encapsulated Organisms

There are specific NASA requirements for source-specific encapsulated microbial density for encapsulated organisms in non-metallic materials. Projects such as the Mars Science Laboratory (MSL) that use large volumes of non-metallic materials of planetary protection concern pose a challenge to their bioburden budget. An optimized and adapted destructive hardware technology employing a commercial blender was developed to assess the embedded bioburden of thermal paint for the MSL project. The main objective of this optimization was to blend the painted foil pieces in the smallest sizes possible without excessive heating. The small size increased the surface area of the paint and enabled the release of the maximum number of encapsulated microbes. During a trial run, a piece of foil was placed into a blender for 10 minutes. The outside of the blender was very hot to the touch. Thus, the grinding was reduced to five 2-minute periods with 2-minute cooling periods between cycles. However, almost 20% of the foil fraction was larger (>2 mm). Thus, the largest fractions were then put into the blender and reground, resulting in a 71% increase in particles less than 1 mm in size, and a 76% decrease in particles greater than 2 mm in size. Because a repeatable process had been developed, a painted sample was processed with over 80% of the particles being <2 mm. It was not perceived that the properties (i.e. weight and rubber-like nature) of the painted/foil pieces would allow for a finer size distribution. With these constraints, each section would be ground for a total of 10 minutes with five cycles of a 2-minute pulse followed by a 2-minute pause. It was observed on several occasions that a larger blade affected the recovery of seeded spores by approximately half an order of magnitude. In the standard approach, each piece of painted foil was aseptically removed from the bag and placed onto a sterile tray where they were sized, cut, and cleaned. Each section was then weighed and placed into a sterile Waring Laboratory Blender. Samples were processed on low speed. The ground-up samples were then transferred to a 500-mL bottle using a sterile 1-in. (.2.5-cm) trim brush. To each of the bottles sterile planetary protection rinse solution was added and a modified NASA Standard Assay (NASA HBK 6022) was performed. Both vegetative and spore plates were analyzed.

Benardini, James N.↗

NASA NTRS1989

On optimizing a constellation of altimetric satellites for measuring global oceanic mesoscale

The orbital configuration of the Eos polar-platform constellation is examined to determine if baseline orbital parameters are appropriately specified to meet the mission goal of measuring global oceanic mesoscale variability. Using the Nyquist sampling theorem, spatial and temporal measurement requirements are first established for the constellation. Based upon these requirements, the optimum solution indicates that a total of five spacecraft are required to meet the mesoscale mapping task. Additional analyses are performed on both a two-platform configuration as well as the complete four-platform Eos constellation. The results of these calculations show that an optimized configuration of four properly-phased Eos platforms, placed into identical 835-km sun-synchronous orbits with 13-day repeat periods, can very nearly meet statistically significant sampling criteria for mapping global oceanic mesoscale variability.

Chase, Robert↗

NASA NTRS1986

Radionuclide measurements by accelerator mass spectrometry at Arizona

Over the past years, Tandem Accelerator Mass Spectrometry (TAMS) has become established as an important method for radionuclide analysis. In the Arizona system the accelerator is operated at a thermal voltage of 1.8MV for C-14 analysis, and 1.6 to 2MV for Be-10. Samples are inserted into a cesium sputter ion source in solid form. Negative ions sputtered from the target are accelerated to about 25kV, and the injection magnet selects ions of a particular mass. Ions of the 3+ charge state, having an energy of about 9MeV are selected by an electrostatic deflector, surviving ions pass through two magnets, where only ions of the desired mass-energy product are selected. The final detector is a combination ionization chamber to measure energy loss (and hence, Z), and a silicon surface-barrier detector which measures residual energy. After counting the trace iosotope for a fixed time, the injected ions are switched to the major isotope used for normalization. These ions are deflected into a Faraday cup after the first high-energy magnet. Repeated measurements of the isotope ratio of both sample and standards results in a measurement of the concentration of the radionuclide. Recent improvements in sample preparation for C-14 make preparation of high-beam current graphite targets directly from CO2 feasible. Except for some measurements of standards and backgrounds for Be-10 measurements to date have been on C-14. Although most results have been in archaeology and quaternary geology, studies have been expanded to include cosmogenic C-14 in meteorites. The data obtained so far tend to confirm the antiquity of Antarctic meteorites from the Allan Hills site. Data on three samples of Yamato meteorites gave terrestrial ages of between about 3 and 22 thousand years.

Jull, A. J. T.↗

NASA NTRS2020

Returning Samples from Enceladus for Life Detection

Evidence suggests that Saturn’s icy moon Enceladus has a subsurface ocean that sources plumes of water vapor and ice vented to space from its south pole. In situ analyses of this material by the Cassini spacecraft have shown that the ocean contains key ingredients for life (elements H, C, N, O and possibly S; simple and complex organic compounds; chemical disequilibria at water-rock interfaces; clement temperature, pressure, and pH). The Cassini discoveries make Enceladus’ interior a prime locale for life detection beyond Earth. Scant material exchange with the inner Solar System makes it likely that such life would have emerged independently of life on Earth. Thus, its discovery would illuminate life’s universal characteristics. The alternative result of an upper bound on a detectable biosphere in an otherwise habitable environment would likewise considerably advance our understanding of the prevalence of life beyond Earth. Here we outline the rationale for returning vented ocean samples, accessible from Enceladus’ surface or low altitudes, to Earth for life detection. Returning samples allows analyses using laboratory instruments that cannot be flown, with decades or more to adapt and repeat analyses. We describe an example set of measurements to estimate the amount of sample to be returned and discuss possible mission architectures and collection approaches. We then turn to the challenges of preserving sample integrity and implementing planetary protection policy. We conclude by placing such a mission in the broader context of Solar System exploration.

Enceladus↗

NASA NTRSDate not supplied

VEG-04 PICK-AND-EAT CROP PRODUCTION AND HUMAN RESEARCH ON THE INTERNATIONAL SPACE STATION

Growing fresh, nutritious, palatable produce for crew consumption during spaceflight may provide health-promoting, bioavailable nutrients and enhance the astronaut dietary experience as we move toward longer-duration missions. Tending plants may also serve as a countermeasure for crew psychological stresses associated with spaceflight. However, requirements to support consistent growth of a variety of nutritious crops under spaceflight environmental conditions remain unclear. This study explores the potential to grow crops for consumption on the International Space Station (ISS) using the Veggie vegetable-production system. VEG-04A and B were two flight tests conducted in 2019 with the leafy green crop Mizuna mustard. Mizuna was grown in two Veggie chambers simultaneously, with the chambers set to different red-to-blue light formulations; one Veggie was programmed as “red-rich” and the second as “blue-rich.” Light quality is known to impact plant growth, nutrition, microbiology, and organoleptic characteristics on Earth, and the Veggie flight tests examined how these impacts might differ in microgravity. VEG-04A was a 35-day growth test with a single harvest. VEG-04B, a 58-day test with harvests at four, six, and eight weeks from the same plants, assessed sustained productivity. Challenges with the watering program occurred early during VEG-04A, and several plants failed to survive in both the flight and ground control operations. Thus, prior to VEG-04B, an extra test was conducted to tailor water timing and volumes. This test allowed a fine tuning of methods for VEG-04B, and generally plant survival was better in that experiment. At each harvest, the astronauts froze half of the edible plant tissue to return to Earth and weighed the remaining half using the ISS Mass Measurement Device (MMD). Weighed samples were then cleaned with produce-sanitizing wipes, and consenting crew members participated in organoleptic evaluation of the fresh produce. Organoleptic evaluations were conducted on the Mizuna crops grown in both light treatments, and data from these tests are compared to ground data collected at JSC. The remaining sanitized produce was available for crew consumption as desired. Frozen flight samples were returned for microbial and chemical analyses to assess food safety and nutritional quality. Microbial assessments included culturing and identifying aerobic bacteria, yeasts, and molds, and screening for specific human pathogens. Chemical nutrient analyses included assessing elements, antioxidants, and phenolics in plant tissues. Crew members involved in plant operations completed behavioral health surveys pre-flight, in-flight associated with plant growth and harvest activities, and post-flight. Surveys captured the amount of time spent on different plant-related operations, enjoyment of the different activities, engagement with Veggie, experience interacting with Veggie, and sensory stimulation associated with growing plants in Veggie. Within each study, plant growth did not differ across light treatment or location (flight versus ground). In general, more biomass was produced in most treatments during the longer study, but growth of this crop declined over time with the repeated harvests. On average, bacterial and fungal counts were significantly lower on ground control samples than flight samples, and microbial counts increased with repeated harvests. Light treatment did not influence any elements in tissues tested; however, the growth duration did impact levels of several elements. Organoleptic scores were generally higher in flight, and ground tasters considered samples more bitter. Amount of interaction and responses to Veggie varied widely by individual. Enjoyable tasks had higher impact than non-enjoyable tasks and interacting with Veggie was generally viewed as positive. These tests on ISS are helping to mitigate the risk of an inadequate food supply for long-duration missions by adding fresh vegetables and key nutrients to the crew diet, and indicating which plant care activities are providing behavioral health benefits for the crew. This research was co-funded by the Human Research Program and Space Biology (MTL#1075) in the ILSRA 2015 NRA call. Videos due Jan. 25th.

Veggie↗

DOE OSTI2025

Post-composing ontology terms for efficient phenotyping in plant breeding

Abstract Ontologies are widely used in databases to standardize data, improving data quality, integration, and ease of comparison. Within ontologies tailored to diverse use cases, post-composing user-defined terms reconciles the demands for standardization on the one hand and flexibility on the other. In many instances of Breedbase, a digital ecosystem for plant breeding designed for genomic selection, the goal is to capture phenotypic data using highly curated and rigorous crop ontologies, while adapting to the specific requirements of plant breeders to record data quickly and efficiently. For example, post-composing enables users to tailor ontology terms to suit specific and granular use cases such as repeated measurements on different plant parts and special sample preparation techniques. To achieve this, we have implemented a post-composing tool based on orthogonal ontologies providing users with the ability to introduce additional levels of phenotyping granularity tailored to unique experimental designs. Post-composed terms are designed to be reused by all breeding programs within a Breedbase instance but are not exported to the crop reference ontologies. Breedbase users can post-compose terms across various categories, such as plant anatomy, treatments, temporal events, and breeding cycles, and, as a result, generate highly specific terms for more accurate phenotyping.

Mathematical & Computational Biology↗

DOE OSTI2025

TR-XPS Realtime Analysis Tool (ArroyoXPS) v0.1

The ALS has developed a Time-Resolved X-ray Photoelectron Spectroscopy (TR-XPS) technique, which involves applying a specific pattern of voltage curves to a sample while measuring XPS peaks. This pattern is repeated over multiple cycles, and changes in the material's response provide valuable scientific insights. Traditionally, file-based analysis workflows have been used: scans are run for a predetermined time, and after one or more scans are complete, calculations are made. ArroyoXPS changes this by offering in-experiment scan and analysis, allowing researchers to gain insights before a scan is finished. This enables them to adjust experimental parameters quickly, potentially saving valuable beamtime. ArroyoXPS includes tools for integrating with beamline control systems, performing analysis, and visualizing scan data in a web browser.

McReynolds, Dylan [Lawrence Berkeley National Labo↗

NASA NTRS2000

High Undercooling of Ni59Nb41 Alloy in a Containerless Electrostatic Levitation Facility

Utilizing the containerless electrostatic levitation facility at NASA/MSFC, we were able to undercool the Ni59Nb41 (atomic) alloy by 210 K which was 160 degrees farther than the results of previous flight experiments. Undercoolings were clustered around 200 K during the repeated melting-freezing cycles on a single sample. Prior to this work, a metastable liquid separation had been presumed to limit the undercooling of this alloy. However, microstructural observations have revealed that undercooling was limited by crystal nucleation.

Robinson, M. B.↗

NASA NTRS2000

High Undercooling of Ni59Nb41 Alloy in a Containerless Electrostatic Levitation Facility

Utilizing the containerless electrostatic levitation facility at NASA/MSFC, we were able to undercool the Ni-59Nb-41 (atomic) alloy by 210 K which was 160 deg. farther than the results of previous flight experiments. Undercoolings were clustered around 200 K during the repeated melting-freezing cycles on a single sample. Prior to this work, a metastable liquid separation had been presumed to limit the undercooling of this alloy. However, microstructural observations have revealed that undercooling was limited by crystal nucleation.

Robinson, M. B.↗

NASA NTRS2008

Improved Thermal Design of a Compression Mold

A compression tool used to make 1-in. (2.5-cm) diameter disks of high-temperature polymers was designed to be shorter and of larger diameter than conventional tools to reduce heat loss to the surrounding air, thus making more efficient use of applied heat. This system is less sensitive to the amount and quality of insulation than previous tools, provides more repeatable processing, and improves the quality of the samples produced. These improvements come without increasing the weight of the punch portion of the tool over that of a conventional version, an important quality when handling lower-viscosity resins. In use, the base and body of the tool are assembled, and the polymer to be processed is placed into the body of the tool. The punch is inserted, and the assembled tool is placed into the press. A temperature/ pressure profile appropriate to the nature of the polymer is applied. A series of computational and experimental runs were made using a conventional tool to validate the computational model. The new tool design was then modeled, and when the performance showed a marked improvement, the new tool was manufactured. A new series of experimental runs showed that the thermal performance of the new tool agreed well with model predictions.

Kuczmarski, Maria A.↗

NASA NTRS2004

Mars Deep Drill - A Mission Concept for the Next Decade

In the not too distant future, NASA may consider sending a robotic mission to Mars to drill tens of meters below the surface to search for evidence of life. Mars science groups, including NASA's Mars Exploration Program Analysis Group (MEPAG), have repeatedly concluded that in situ scientific analyses of samples from significant depths below the surface are important for understanding Mars in general and for searching for evidence of past or present life in particular. Furthermore, there are several ongoing technology developments for relevant drills, the readiness of which seem promising for use by the second decade of this century. By accessing and analyzing material from tens of meters below the surface, in situ science investigations may help answer some important questions about Mars, in particular about whether life ever existed there. Drilling is a proven technique for terrestrial applications that appears viable for accessing Martian subsurface samples and bringing them to the surface for analysis by a variety of instruments. An end-to-end mission concept for a Deep Drill mission has been developed and appears feasible for launch in the next decade.

Mars↗

NASA NTRS2020

The Effect of UV and Solar Wind Exposure on the Reflectance of Two Black Diffuse Materials

The Bidirectional Reflectance Distribution Function (BRDF) and Total Hemispherical Reflectance (THR) of two candidate black diffuse materials for the dim calibration targets of the NASA GSFC PACE Ocean Color Instrument (OCI)were reported in the SPIE conference last year. In this paper, we present new BRDF and THR results of the two black diffuse materials following additional UV exposure and solar wind tests. The BRDF measurements for five samples of each two black diffuse material were made at incident angles of 0° and 45° and at the wavelengths of 360 nm, 600 nm, and 1600 usi ng the Table-top Goniometer (TTG) located in the Diffuser Calibration Laboratory (DCL) at NASA GSFC. The THR of the samples, 15 mm in diameter, was measured using a commercial UV-VIS-NIR spectrophotometer from 200 nm to 2500 nm. The spectral THR results of the two black diffuse materials exposed to UV and solar wind show an approximate 10 % higher reflectivity than the unexposed samples. The spectral profiles of the THR of the exposed and unexposed samples are relatively similar. The BRDF results at the incident angle of 45° show different trends in the forward and backward scattering regions, while those at normal incident angle are consistent with the THR results. We will also present the details of the samples’ surface features and the comparison of the 0°/45° BRDF and THR results, demonstrate the significance of background subtraction in the THR measurements for small, low reflectance samples, and discuss validation of BRDF scale, measurement repeatability, and major contributions of uncertainty.

Jinan Zeng↗

NASA NTRSDate not supplied

Thermal Protection Systems (TPS) for High Velocity Earth Entry Missions

The fastest man-made object to re-enter into Earth’s atmosphere, with an entry velocity of 12.8 km/s, was the Stardust capsule, which returned samples from the comet Wild 2. Sample return missions offer high and long-lasting science yield; as such, they are discussed repeatedly in the latest planetary science decadal survey, titled Origins, Worlds, and Life. An advantage of sample return missions over in situ measurements is the ability to use state-of-the-art instruments that are not limited in power, size, or complexity; conversely, in situ measurements rely on instruments optimized to fit within the limitations of the spacecraft. Additionally, sample return provides the opportunity to revisit samples as analysis techniques improve as well as to further investigate unanticipated or ambiguous results. As launch vehicle and propulsion technologies continue to advance, it is becoming feasible to consider sample return missions from further out in the Solar System beyond Mars orbit. However, returning samples from increasingly distant destinations comes with high entry velocities, and thus requires ever more capable thermal protection systems (TPS). Evaluating the capabilities of existing mature TPS materials for a range of entry conditions and sample return aeroshell configurations is key to establishing the feasibility of future mission proposals. As such, this presentation describes the comprehensive trade study done to evaluate the feasibility of high velocity Earth entry missions with the currently available TPS materials.

Hannah S Alpert↗

NASA NTRSDate not supplied

Thermal Protection Systems (TPS) for High Velocity Earth Entry Missions

Hannah S. Alpert↗