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The 6300 A predawn enhancement - Excitation by photoelectrons from the magnetic conjugate point.

Incoherent scatter and tilting filter photometer data from Arecibo Observatory were combined to search for a contribution to the 6300 A predawn enhancement due to impact excitation by photoelectrons from the magnetic conjugate point. Prior to about 105 deg conjugate solar zenith angle, calculations of the 6300 A intensities due to dissociative recombination gave good agreement with the observed intensities. Then, with the arrival of conjugate photoelectrons (confirmed by plasma line enhancements), the observed intensities rose above the calculated, the difference increasing until a plateau was achieved at a conjugate solar zenith angle of about 95 deg. The difference or residual intensity is attributed to direct photoelectron impact excitation. Significant day-to-day variations in the onset angle and intensity have a strong negative correlation with ionospheric electron density.

Wickwar, V. B.↗

Initial observations of the nightside ionosphere of Venus from Pioneer Venus Orbiter radio occultations

Results of radio occultation measurements of electron density profiles of the nightside ionosphere of Venus at solar zenith angles from 90 to 164 deg, obtained from the Pioneer Venus Orbiter, are reported. Data were derived from closed-loop S- and X-band signals received by the Deep Space Network upon ionospheric entry and exit of the spacecraft. Nightside electron density profiles are found to be rather uniform in the solar zenith angle range of from 95 to 107 deg, with peak electron densities ranging from 23,000 to 40,000/cu cm, while between 110 and 164 deg, profiles exhibit a high degree of variability and peak electron densities vary from 7,600 to 31,800/cu cm. A possible mechanism for the maintenance of the nightside Venus ionosphere during the long Venus night, which is consistent with the observed spatial and temporal variability of deep ionospheric electron density profiles, is proposed to be impact ionization by precipitating particles, although transport processes from the dayside may also be important.

Kliore, A. J.↗

Ground-based Photon Path Measurements from Solar Absorption Spectra of the O2 A-band

High-resolution solar absorption spectra obtained from Table Mountain Facility (TMF, 34.38degN, 117.68degW, 2286 m elevation) have been analyzed in the region of the O2 A-band. The photon paths of direct sunlight in clear sky cases are retrieved from the O2 absorption lines and compared with ray-tracing calculations based on the solar zenith angle and surface pressure. At a given zenith angle, the ratios of retrieved to geometrically derived photon paths are highly precise (approx.0.2%), but they vary as the zenith angle changes. This is because current models of the spectral lineshape in this band do not properly account for the significant absorption that exists far from the centers of saturated lines. For example, use of a Voigt function with Lorentzian far wings results in an error in the retrieved photon path of as much as 5%, highly correlated with solar zenith angle. Adopting a super-Lorentz function reduces, but does not completely eliminate this problem. New lab measurements of the lineshape are required to make further progress.

Yang, Z.↗

The downward flux of O(+) over the nightside of Venus

We have constructed a map of the downward flux of O(+) over the nightside of Venus at high and low solar activities through a combination of modeling and analysis of Pioneer Venus ion mass spectrometer data. O(+) density profiles were obtained for almost 40 inbound or outbound segments of orbits from the first 2 years of the mission and about 40 more in the recent reentry phase of the mission. We have determined the nearly linear relationship between the 0(+) maximum density and the downward O(+) flux for several solar zenith angles and local times by constructing models of the nightside ionosphere of Venus for a range of downward ion fluxes at the upper boundaries. We find that the largest downward fluxes occur near the terminators, and the fluxes fall off sharply toward the antisolar point. Although the standard deviations in the data are large, there is a suggestion of a local maximum near 155 deg, and the location of this maximum correlates fairly well with structure in the peak electron density as a function of solar zenith angle reported for the Pioneer Venus radio occulation experiment. The average downward ion flux is inferred to be about 1.7 x 10(exp 8)/sq cm/sec over the nightside hemisphere at solar maximum and a factor of 7 less at moderately low solar activity.

Brannon, J. J.↗

Periodic behaviors in the observed vertical column abundances of atmospheric hydroxyl

The data base for the vertical column abundance of atmospheric hydroxyl (OH) for Fritz Peak Observatory, Colorado (40 N, 105 W), now extends from 1976 through 1988 and is composed of 8849 independent data sets, averaging about 15 percent uncertainty and 20-minute time resolution each. The dominant solar zenith angle (chi) dependence of the OH abundance is characterized by an empirical curve, N(88), which has been updated from N(82) to include all valid data from 1980 through 1988. The chi-dependence of the OH abundance has been, to a first order, removed from the data base by a normalization procedure in which each data point is divided by the N(88,AM) value for the corresponding solar zenith angle. The resulting normalized OH values may then be examined for other systematic effects, particularly for periodic variations. Observations have also been made at Boca Raton, Florida (26 N, 80 W) and at Truk, Federated States of Micronesia (7 N, 152 E). These data bases are much less extensive and, as such, are less amenable to analysis for periodic behaviors. Some comparisons with the Colorado data may be made, however.

Burnett, Elizabeth Beaver↗

Observations of OI 7774 emission excited by conjugate photoelectrons

Observations and computer calculations of O I 7774 A airglow emissions excited by conjugate photoelectrons have been carried out. The observations were made at McDonald Observatory, Texas using a 2 m grille spectrometer from December 1972 to June 1973. The zenithal emission intensity during conjugate photoelectron precipitation was fairly constant at 2-4 R until conjugate sunset, after which it diminished steadily and ceased near a conjugate solar zenith angle of 105 (plus or minus 3) deg. A predawn enhancement in both O I 7774 A and forbidden O I 6300 A was observed to commence near 102 deg. The computations utilize the two-stream technique of Nagy and Banks (1970) to obtain the escaping photoelectron flux and the local excitation rates of the oxygen emissions. Good agreement with the observations is obtained for the dependence of the emission rate on conjugate solar zenith angle.

Christensen, A. B.↗

Mesospheric ozone measurements by SAGE II

SAGE II observations of ozone at sunrise and sunset (solar zenith angle = 90 deg) at approximately the same tropical latitude and on the same day exhibit larger concentrations at sunrise than at sunset between 55 and 65 km. Because of the rapid conversion between atomic oxygen and ozone, the onion-peeling scheme used in SAGE II retrievals, which is based on an assumption of constant ozone, is invalid. A one-dimensional photochemical model is used to simulate the diurnal variation of ozone particularly within the solar zenith angle of 80 deg - 100 deg. This model indicates that the retrieved SAGE II sunrise and sunset ozone values are both overestimated. The Chapman reactions produce an adequate simulation of the ozone sunrise/sunset ratio only below 60 km, while above 60 km this ratio is highly affected by the odd oxygen loss due to odd hydrogen reactions, particularly OH. The SAGE II ozone measurements are in excellent agreement with model results to which an onion peeling procedure is applied. The SAGE II ozone observations provide information on the mesospheric chemistry not only through the ozone profile averages but also from the sunrise/sunset ratio.

Chu, D. A.↗

Profile shape dependence in backscattered ultraviolet satellite retrievals of total ozone

Total ozone operational algorithms use climatological mean ozone profiles. When the actual ozone profiles have significantly different shapes versus the climatology and the solar zenith angles are large, retrieved total ozone will have an error. Recalibrated SBUV profiles are used to estimate this error. Preliminary results suggest that, on the average, the change and variation in significant profiles shapes can to a large degree be estimated by the SBUV derived profiles. Preliminary results suggest the average error in the report algorithm ozone trend (trend in reported ozone) from profile shape is relatively small during the north hemisphere winter (less than 2 percent) for solar zenith angles less than 82 degrees (for 60 degrees North Latitude).

Taylor, S. L.↗

Absorption of Sunlight by Water Vapor in Cloudy Conditions: A Partial Explanation for the Cloud Absorption Anomaly

The atmospheric radiative transfer algorithms used in most global general circulation models underestimate the globally-averaged solar energy absorbed by cloudy atmospheres by up to 25 W/sq m. The origin of this anomalous absorption is not yet known, but it has been attributed to a variety of sources including oversimplified or missing physical processes in these models, uncertainties in the input data, and even measurement errors. Here, a sophisticated atmospheric radiative transfer model was used to provide a more comprehensive description of the physical processes that contribute to the absorption of solar radiation by the Earth's atmosphere. We found that the amount of sunlight absorbed by a cloudy atmosphere is inversely proportional to the solar zenith angle and the cloud top height, and directly proportional to the cloud optical depth and the water vapor concentration within the clouds. Atmospheres with saturated, optically-thick, low clouds absorbed about 12 W/sq m more than clear atmospheres. This accounts for about 1/2 to 1/3 of the anomalous ab- sorption. Atmospheres with optically thick middle and high clouds usually absorb less than clear atmospheres. Because water vapor is concentrated within and below the cloud tops, this absorber is most effective at small solar zenith angles. An additional absorber that is distributed at or above the cloud tops is needed to produce the amplitude and zenith angle dependence of the observed anomalous absorption.

Crisp, D.↗

Conjugate excitation of atomic oxygen emissions in the far ultraviolet

Rocket observations of far-ultraviolet terrestrial airglow emissions in the 1230- to 1450-A band at night have been carried out from White Sands Missile Range. Three rockets carried 15.4-cm-diam far-ultraviolet telescopes to about 220 km altitude at various times during the night from postsunset to predawn. Postsunset and predawn observations were made when the solar zenith angle at the conjugate ionosphere was about 95 deg, and in both cases positive identification of strong O I 1304-A emissions was made. Evidence that in these cases the 1356/1304 intensity ratio was less than 0.2 is presented. Observations made well into the night yielded only an upper limit to the combined O I 1304- and 1356-A emissions of 20 Rayleighs, consistent with previous observations and theoretical calculations. These results show that meaningful rocket observations of the cosmic far ultraviolet background can be made only when the solar zenith angle at the conjugate ionosphere of the launch site is larger than 105 deg or if atomic oxygen emission lines are excluded from the detectors' bandpass.

Holberg, J.↗

Simulation of the Mars Surface Solar Spectra for Optimized Performance of Triple-Junction Solar Cells

The unparalleled success of the Mars Exploration Rovers (MER) powered by GaInP/GaAs/Ge triple-junction solar cells has demonstrated a lifetime for the rovers that exceeded the baseline mission duration by more than a factor of five. This provides confidence in future longer-term solar powered missions on the surface of Mars. However, the solar cells used on the rovers are not optimized for the Mars surface solar spectrum, which is attenuated at shorter wavelengths due to scattering by the dusty atmosphere. The difference between the Mars surface spectrum and the AM0 spectrum increases with solar zenith angle and optical depth. The recent results of a program between JPL and Spectrolab to optimize GaInP/GaAs/Ge solar cells for Mars are presented. Initial characterization focuses on the solar spectrum at 60-degrees zenith angle at an optical depth of 0.5. The 60-degree spectrum is reduced to ~1/6 of the AM0 intensity and is further reduced in the blue portion of the spectrum. JPL has modeled the Mars surface solar spectra, modified an X-25 solar simulator, and completed testing of Mars-optimized solar cells previously developed by Spectrolab with the modified X-25 solar simulator. Spectrolab has focused on the optimization of the higher efficiency Ultra Triple-Junction (UTJ) solar cell for Mars. The attenuated blue portion of the spectrum requires the modification of the top sub-cell in the GaInP/GaAs/Ge solar cell for improved current balancing in the triple-junction cell. Initial characterization confirms the predicted increase in power and current matched operation for the Mars surface 60-degree zenith angle solar spectrum.

Edmondson, Kenneth M.↗

Simple equation to approximate the bidirectional reflectance from vegetative canopies and bare soil surfaces

A simple equation has been developed for describing the bidirectional reflectance of some vegetative canopies and bare soil surfaces. The equation describes directional reflectance as a function of zenith and azimuth view angles and solar azimuth angle. The equation works for simulated and field measured red and IR reflectance under clear sky conditions. Hemispherical reflectance can be calculated as a function of the simple equation coefficients by integrating the equation over the hemisphere of view angles. A single equation for estimating soil bidirectional reflectance was obtained using the relationships between solar zenith angles and the simple equation coefficients for medium and rough soil distributions. The equation has many useful applications such as providing a lower level boundary condition in complex plant canopy models and providing an additional tool for studying bidirectional effects on pointable sensors.

Walthall, C. L.↗

Radio occultation studies of the Venus atmosphere with the Magellan spacecraft. 2: Results from the October 1991 experiments

On October 5 and 6, 1991, three dual-frequency ingress radio occultation experiments were conducted at Venus during consecutive orbits of the Magellan spacecraft. The radio signals probed a region of the atmosphere near 65 deg N, with a solar zenith angle of 108 deg, reaching below 35 km at 3.6 cm, and below 34 km at 13 cm (above a mean radius of 6052 km). The high effective isotropic radiated power (EIRP) of the Magellan spacecraft and highly successful attitude maneuvers allowed these signals to probe deeper than any previous radio occultation experiment and also resulted in the most accurate thermal and sulfuric acid vapor abundance profiles ever obtained at Venus through radio occultation techniques. The performance of the spacecraft and the experiment design are discussed in an accompanying paper. Average electron density profiles retrieved from the data possess peaks between 2600 and 6000/cu cm, well below typical values of 10,000/cu cm retrieved in 1979 by Pioneer Venus at similar solar zenith angles. Other basic results include vertical profiles of temperature, pressure, and density in the neutral atmosphere, 13- and 3.6-cm absorpttivity, and H2SO4 (g) abundance below the main cloud layer. H2SO4 (g) becomes significant below 50 km, reaching peaks between 18 and 24 ppm near 39 km before dropping precipitously below 38 km. These sharp decreases confirm the thermal decomposition of sulfuric acid vapor below 39 km. Since the Venus atmosphere rotated approximately 10 deg between experiments, the data contain information about the horizontal variability of the atmosphere. All derived profiles exhibit significant variations from orbit to orbit, indicating the presence of dynamical processes between 33 and 200 km. In particular, the orbit-to-orbit variations in temperature and in H2SO4 (g) abundance appear to be correlated, suggesting that a common mechanism may be responsible for the observed spatial variations.

Jenkins, Jon M.↗

A Reevaluation of Airborne HO(x) Observations from NASA Field Campaigns

In-situ observations of tropospheric HO(x) (OH and HO2) obtained during four NASA airborne campaigns (SUCCESS, SONEX, PEM-Tropics B and TRACE-P) are reevaluated using the NASA Langley time-dependent photochemical box model. Special attention is given to previously diagnosed discrepancies between observed and predicted HO2 which increase with higher NO(x) levels and at high solar zenith angles. This analysis shows that much of the model discrepancy at high NO(x) during SUCCESS can be attributed to modeling observations at time-scales too long to capture the nonlinearity of HO(x) chemistry under highly variable conditions for NO(x). Discrepancies at high NO(x) during SONEX can be moderated to a large extent by complete use of all available precursor observations. Differences in kinetic rate coefficients and photolysis frequencies available for previous studies versus current recommendations also explain some of the disparity. Each of these causes is shown to exert greater influence with increasing NO(x) due to both the chemical nonlinearity between HO(x) and NO(x) and the increased sensitivity of HO(x) to changes in sources at high NO(x). In contrast, discrepancies at high solar zenith angles will persist until an adequate nighttime source of HO(x) can be identified. It is important to note that this analysis falls short of fully eliminating the issue of discrepancies between observed and predicted HO(x) for high NO(x) environments. These discrepancies are not resolved with the above causes in other data sets from ground-based field studies. Nevertheless, these results highlight important considerations in the application of box models to observationally based predictions of HO(x) radicals.

Olson, Jennifer↗

3D Orbit Visualization for Earth-Observing Missions

This software visualizes orbit paths for the Orbiting Carbon Observatory (OCO), but was designed to be general and applicable to any Earth-observing mission. The software uses the Google Earth user interface to provide a visual mechanism to explore spacecraft orbit paths, ground footprint locations, and local cloud cover conditions. In addition, a drill-down capability allows for users to point and click on a particular observation frame to pop up ancillary information such as data product filenames and directory paths, latitude, longitude, time stamp, column-average dry air mole fraction of carbon dioxide, and solar zenith angle. This software can be integrated with the ground data system for any Earth-observing mission to automatically generate daily orbit path data products in Google Earth KML format. These KML data products can be directly loaded into the Google Earth application for interactive 3D visualization of the orbit paths for each mission day. Each time the application runs, the daily orbit paths are encapsulated in a KML file for each mission day since the last time the application ran. Alternatively, the daily KML for a specified mission day may be generated. The application automatically extracts the spacecraft position and ground footprint geometry as a function of time from a daily Level 1B data product created and archived by the mission s ground data system software. In addition, ancillary data, such as the column-averaged dry air mole fraction of carbon dioxide and solar zenith angle, are automatically extracted from a Level 2 mission data product. Zoom, pan, and rotate capability are provided through the standard Google Earth interface. Cloud cover is indicated with an image layer from the MODIS (Moderate Resolution Imaging Spectroradiometer) aboard the Aqua satellite, which is automatically retrieved from JPL s OnEarth Web service.

Jacob, Joseph C.↗

Reflected fluxes for broken clouds over a Lambertian surface

Reflected fluxes are calculated for broken cloudiness (i.e., nonplane parallel) as a function of cloud cover, cloud optical depth, solar zenith angle and surface albedo. These calculations extend previous results for broken cloud reflected fluxes over a black surface. The present study demonstrates that not only radiances but also radiative fluxes over high albedo surfaces may be decreased by the presence of broken cloudiness. Conventional wisdom states that cloud radiances (brightnesses) are always greater than the background. While most cloud retrieval schemes are built around this assumption, it is incorrect for clouds over high albedo surfaces such as found in polar regions. However, the most startling and counterintuitive conclusion of this study is that nonabsorbing finite clouds over a highly reflecting surface will decrease the system albedo. As a result, surface absorption is increased, the result of multiple scattering between surface and cloud layer, controlled by cloud morphology and cloud optical thickness. A simple parameterization of the effects of cloud contamination upon retrieved albedo is given in terms of solar zenith angle, cloud optical depth, surface albedo, cloud cover, and plane-parallel cloud albedo. In this way, the effects of broken cloudiness are modeled in terms of easily computed plane-parallel values.

Welch, Ronald M.↗

Observations of "Hystereris" in Backscattered Ultraviolet Ozone Data

The backscattered ultraviolet (BUV) technique has been used for almost 3 decades to monitor global total ozone and the distribution of ozone in the stratosphere. Satellite BUV measurements in the 250-340 mn wavelength region are technically challenging because the Earth's radiance varies by approximately 4 orders of magnitude during a single scan. Further, the observed signal increases by over three orders of magnitude in about 2 minutes as the satellite emerges into daylight. The gain of the instrument's photomultiplier tube (PMT) detector is low when the spacecraft first emerges into the sunlit portion of the orbit relative to the gain observed after the PMT has experienced moderately high current levels. This "hysteresis" effect was first observed on the Nimbus-7 SBUV and TOMS instruments. The effect is difficult to characterize prelaunch because of the high signal levels and rapid variations required. We have recently observed and quantified the hysteresis effect for the NOAA-9 SBUV/2 instrument, which collected ozone data from February 1985 to February 1998. The instrument gain is observed to be up to 3% low at high solar zenith angles [Chi = 85-90 degrees] in the emergent hemisphere (i.e. Southern Hemisphere at launch). The gain error decreases as the SZA decreases and average PMT current increases, and is generally negligible for Chi < 65 degrees. The magnitude of the hysteresis effect varies with season, and exhibits long-term changes as the NOAA-9 sun-synchronous orbit drifts. In the latter portion of the record, when the spacecraft emerged from the dark in the Northern Hemisphere, hysteresis effects were then observed in the North. NOAA-9 total ozone errors due to the hysteresis effect are typically on the order of 2%, but can reach 5% in extreme cases. We have developed a quantitative correction for the hysteresis effect that incorporates both seasonal and long-term variations in magnitude. Results of similar analyses for the NOAA-11 and NOAA-14 SBUV/2 instruments will also be discussed. The characterization of the hysteresis effect in high solar zenith angle SBUV/2 ozone data represents a significant step towards reconciling polar ozone measurements from different satellite instruments.

DeLand, Matthew T.↗

Surface Net Solar Radiation Estimated from Satellite Measurements: Comparisons with Tower Observations

A parameterization that relates the reflected solar flux at the top of the atmosphere to the net solar flux at the surface in terms of only the column water vapor amount and the solar zenith angle was tested against surface observations. Net surface fluxes deduced from coincidental collocated satellite-measured radiances and from measurements from towers in Boulder during summer and near Saskatoon in winter have mean differences of about 2 W/sq m, regardless of whether the sky is clear or cloudy. Furthermore, comparisons between the net fluxes deduced from the parameterization and from surface measurements showed equally good agreement when the data were partitioned into morning and afternoon observations. This is in contrast to results from an empirical clear-sky algorithm that is unable to account adequately for the effects of clouds and that shows, at Boulder, a distinct morning to afternoon variation, which is presumably due to the predominance of different cloud types throughout the day. It is also demonstrated that the parameterization may be applied to irradiances at the top of the atmosphere that have been temporally averaged by using the temporally averaged column water vapor amount and the temporally averaged cosine of the solar zenith angle. The good agreement between the results of the parameterization and surface measurements suggests that the algorithm is a useful tool for a variety of climate studies.

Li, Zhanqing↗