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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
NASA NTRS1992

Evidence for liquid-phase cirrus cloud formation from volcanic aerosols - Climatic implications

Supercooled droplets in cirrus uncinus cell heads between -40 and -50 C are identified from the First International Satellite Cloud Climatology Project Regional Experiment polarization lidar measurements. Although short-lived, complexes of these small liquid cells seem to have contributed importantly to the formation of the cirrus. Freezing-point depression effects in solution droplets, apparently resulting from relatively large cloud condensation nuclei of volcanic origin, can be used to explain this rare phenomenon. An unrecognized volcano-cirrus cloud climate feedback mechanism is implied by these findings.

Sassen, Kenneth↗
NASA NTRS1984

Nucleation of (He-3)-B from the A phase - A cosmic-ray effect?

When He-3 is liquified and subsequently cooled, it undergoes, at a temperature of approximately 2.0-2.5 mK, a second-order transition into the so-called A phase. On further cooling, a first-order transition occurs, and the liquid passes into the B phase. Supercooling occurs with respect to the second transition, and the problem of nucleation arises. In connection with the experimental interest in studying metastable (He-3)-A down to the lowest temperatures in weak magnetic fields, the understanding of the mechanism of this transition and the feasibility of its inhibition is of some importance. The present investigation is concerned with the possibility that the transition is nucleated by the passage of a cosmic ray through the sample cell.

Leggett, A. J.↗
NASA NTRS2017

An Initial Study of the Fundamentals of Ice Crystal Icing Physics in the NASA Propulsion Systems Laboratory

This presentation shows results from an initial study of the fundamental physics of ice-crystal ice accretion using the NASA Propulsion Systems Lab (PSL). Ice accretion due to the ingestion of ice-crystals is being attributed to numerous jet-engine power-loss events. The NASA PSL is an altitude jet-engine test facility which has recently added a capability to inject ice particles into the flow. NASA is evaluating whether this facility, in addition to full-engine and motor-driven-rig tests, can be used for more fundamental ice-accretion studies that simulate the different mixed-phase icing conditions along the core flow passage of a turbo-fan engine compressor. The data from such fundamental accretion tests will be used to help develop and validate models of the accretion process. The present study utilized a NACA0012 airfoil. The mixed-phase conditions were generated by partially freezing the liquid-water droplets ejected from the spray bars. This presentation shows data regarding (1) the freeze out characteristics of the cloud, (2) changes in aerothermal conditions due to the presence of the cloud, and (3) the ice accretion characteristics observed on the airfoil model. The primary variable in this test was the PSL plenum humidity which was systematically varied for two duct-exit-plane velocities (85 and 135 ms) as well as two particle size clouds (15 and 50 m MVDi). The observed clouds ranged from fully glaciated to fully liquid, where the liquid clouds were at least partially supercooled. The air total temperature decreased at the test section when the cloud was activated due to evaporation. The ice accretions observed ranged from sharp arrow-like accretions, characteristic of ice-crystal erosion, to cases with double-horn shapes, characteristic of supercooled water accretions.

upwind schemes↗
NASA NTRS2017

An Initial Study of the Fundamentals of Ice Crystal Icing Physics in the Nasa Propulsion Systems Laboratory

This paper presents results from an initial study of the fundamental physics of ice-crystal ice accretion using the NASA Propulsion Systems Lab (PSL). Ice accretion due to the ingestion of ice-crystals is being attributed to numerous jet-engine power-loss events. The NASA PSL is an altitude jet-engine test facility which has recently added a capability to inject ice particles into the flow. NASA is evaluating whether this facility, in addition to full-engine and motor-driven-rig tests, can be used for more fundamental ice-accretion studies that simulate the different mixed-phase icing conditions along the core flow passage of a turbo-fan engine compressor. The data from such fundamental accretion tests will be used to help develop and validate models of the accretion process. The present study utilized a NACA0012 airfoil. The mixed-phase conditions were generated by partially freezing the liquid-water droplets ejected from the spray bars. This paper presents data regarding (1) the freeze out characteristics of the cloud, (2) changes in aerothermal conditions due to the presence of the cloud, and (3) the ice accretion characteristics observed on the airfoil model. The primary variable in this test was the PSL plenum humidity which was systematically varied for two duct-exit-plane velocities (85 and 135 ms) as well as two particle size clouds (15 and 50 m MVDi). The observed clouds ranged from fully glaciated to fully liquid, where the liquid clouds were at least partially supercooled. The air total temperature decreased at the test section when the cloud was activated due to evaporation. The ice accretions observed ranged from sharp arrow-like accretions, characteristic of ice-crystal erosion, to cases with double-horn shapes, characteristic of supercooled water accretions.

Evaporative Cooling↗
NASA NTRS1985

Influence of Melt Convection on Solid-Liquid Interface Under Terrestrial and Reduced Gravity Environments

Solidification and crystal growth processes involve thermal and solutal gradients within a molten phase. In the presence of gravity, such gradients result in convective flows which interact with diffusion fields at the solid-liquid interface. Dendritic growth kinetics was studied in transparent model systems which freeze similarily to most metals. Succinonitrile shows a strong influence of convection at supercoolings below about 1K. Fluid flows adjacent to solid-liquid interfaces and the behavior of shear flows in vertical annular geometries are studied. Novel low-frequency eigenstates were discovered and classified as coupled modes, for their involvement with interfacial deformation coupled to the fluid flow, and are unknown in systems without deformable interfaces. The dependence of coupled convection modes on interfacial geometry, gravity, fluid properties, and transformation characteristics studied for several annual flow arrangements with nominally pure solid-liquid systems.

Glicksman, M. E.↗
NASA NTRS2001

Coupled Growth in Hypermonotectics

The overall objective of this project is to obtain a fundamental understanding of the physics controlling solidification processes in immiscible alloy systems. The investigation involves both experimentation and the development of a model describing solidification in monotectic systems. The experimental segment was designed to first demonstrate that it is possible to obtain interface stability and steady state coupled growth in hypermonotectic alloys through microgravity processing. Microgravity results obtained to date have verified this possibility. Future flights will permit experimental determination of the limits of interface stability and the influence of alloy composition and growth rate on microstructure. The objectives of the modeling segment of the investigation include prediction of the limits of interface stability, modeling of convective flow due to residual acceleration, and the influence of surface tension driven flows at the solidification interface. The study of solidification processes in immiscible alloy systems is hindered by the inherent convective flow that occurs on Earth and by the possibility of sedimentation of the higher density immiscible liquid phase. It has been shown that processing using a high thermal gradient and a low growth rate can lead to a stable macroscopically planar growth front even in hypermonotectic alloys. Processing under these growth conditions can avoid constitutional supercooling and prevent the formation of the minor immiscible liquid phase in advance of the solidification front. However, the solute depleted boundary layer that forms in advance of the solidification front is almost always less dense than the liquid away from the solidification front. As a result, convective instability is expected. Ground based testing has indicated that convection is a major problem in these alloy systems and leads to gross compositional variations along the sample and difficulties maintaining interface stability. Sustained low gravity processing conditions are necessary in order to minimize these problems and obtain solidification conditions which approach steady state.

Andrews, J. Barry↗
NASA NTRS2020

Effects of Hydrogen Bonding and Molecular Chain Flexibility of Substituted n-Alkyldimethylsilanes On Impact Ice Adhesion Shear Strength

The effects of hydrogen bonding and molecular flexibility upon ice adhesion shear strength were investigated using aluminum substrates coated with substituted n-alkyldimethylalkoxysilanes. The location of the chemical group substitution was on the opposing end of the linear n-alkyl chain with respect to silicon. Three hydrogen-bonding characteristics were evaluated: 1) non-hydrogen bonding, 2) donor/acceptor, and 3) acceptor. Varying the length of the n-alkyl chain provided an assessment of molecular chain flexibility. Coated and uncoated aluminum surfaces were characterized by receding water contact angle and surface roughness. Ice adhesion shear strength was determined in the Adverse Environment Rotor Test Stand facility from -16 to -8°C that simulated aircraft in-flight icing conditions within the FAR Part 25/29 Appendix C icing envelope. Surface roughness of the coatings was similar allowing for comparison of the test results. An adhesion reduction factor, based on the ice adhesion shear strength data with respect to uncoated aluminum obtained at the same temperature, was calculated to compare the data. The results revealed complex interactions with impacting supercooled water droplets that were interdependent upon ice accretion temperature, surface energy characteristics of water and ice, hydrogen bonding characteristic of the substituent, and length of the n-alkyl chain. To aid in explaining the results, 1) changes in the surface energy component (i.e., non-polar and polar) values that water undergoes during its’ phase change from liquid to solid that arise from the freezing of impacting supercooled water droplets on the surface depended upon the temperature during accretion were taken into account and 2) the physical properties (i.e., water solubility and melting point) of small compounds analogous to the substituted n-alkyldimethylalkoxysilanes used in this study were compared.

Smith, Joseph G.↗
NASA NTRSDate not supplied

Isokinetic Probe Total Water Content Measurements in the NASA Icing Research Tunnel with Supercooled Large Drop Conditions

An Isokinetic Total Water Content Evaporator (IKP2) was used to measure liquid water content (LWC) in the NASA Icing Research Tunnel (IRT) with spray conditions that ranged in LWC and cloud drop size spectra as characterized by the median volumetric diameter (MVD). The IKP2 measurements were made as part of an international collaborative effort to investigate the measurement of supercooled large drop (SLD) conditions in several icing wind tunnels. This report focuses on the IKP2 and background water vapor (BWV) measurements made within the NASA IRT during the October 2017 test entry. The IKP2 TWC results are compared to the IRT LWC calibration values for a range of LWC and MVD values. The IRT LWC calibration is based on measurements from a multi-element hot-wire probe. In general, the IKP2 TWC values were approximately 9% greater than the IRT LWC calibration values over a range of LWC from 0.4 g/m3 to 3.0 g/m3. The ratio of IKP2 TWC to IRT LWC calibration ranged from approximately 0.9 to 1.27 over a range of MVD from 15µm to 460 µm. Comparisons of this data set to IKP2 data from a 2014 IRT test entry show similar results in the regions where overlaps occurred. The results support the theory and observations of water mass loss from hot-wire TWC sensors when subjected to large MVD conditions.

Icing cloud instruments↗
NASA NTRSDate not supplied

Isokinetic Probe Total Water Content Measurements in the NASA Icing Research Tunnel with Supercooled Large Drop Conditions

An Isokinetic Total Water Content Evaporator (IKP2) was used to measure liquid water content (LWC) in the NASA Icing Research Tunnel (IRT) with spray conditions that ranged in LWC and cloud drop size spectra as characterized by the median volumetric diameter (MVD). The IKP2 measurements were made as part of an international collaborative effort to investigate the measurement of supercooled large drop (SLD) conditions in several icing wind tunnels. This report focuses on the IKP2 and background water vapor (BWV) measurements made within the NASA IRT during the October 2017 test entry. The IKP2 TWC results are compared to the IRT LWC calibration values for a range of LWC and MVD values. The IRT LWC calibration is based on measurements from a multi-element hot-wire probe. In general, the IKP2 TWC values were approximately 9% greater than the IRT LWC calibration values over a range of LWC from 0.4 g/m3 to 3.0 g/m3. The ratio of IKP2 TWC to IRT LWC calibration ranged from approximately 0.9 to 1.27 over a range of MVD from 15m to 460 m. Comparisons of this data set to IKP2 data from a 2014 IRT test entry show similar results in the regions where overlaps occurred. The results support the theory and observations of water mass loss from hot-wire TWC sensors when subjected to large MVD conditions.

o Aircraft Icing↗
NASA NTRS2021

Isokinetic Probe Total Water Content Measurements in the NASA Icing Research Tunnel with Supercooled Large Drop Conditions

An Isokinetic Total Water Content Evaporator (IKP2) was used to measure liquid water content (LWC) in the NASA Icing Research Tunnel (IRT) with spray conditions that ranged in LWC and cloud drop size spectra as characterized by the median volumetric diameter (MVD). The IKP2 measurements were made as part of an international collaborative effort to investigate the measurement of supercooled large drop (SLD) conditions in several icing wind tunnels. This report focuses on the IKP2 and background water vapor (BWV) measurements made within the NASA IRT during the October 2017 test entry. The IKP2 TWC results are compared to the IRT LWC calibration values for a range of LWC and MVD values. The IRT LWC calibration is based on measurements from a multi-element hot-wire probe. In general, the IKP2 TWC values were approximately 9% greater than the IRT LWC calibration values over a range of LWC from 0.4 g/m3 to 3.0 g/m3. The ratio of IKP2 TWC to IRT LWC calibration ranged from approximately 0.9 to 1.27 over a range of MVD from 15um to 460 um. Comparisons of this data set to IKP2 data from a 2014 IRT test entry show similar results in the regions where overlaps occurred. The results support the theory and observations of water mass loss from hot-wire TWC sensors when subjected to large MVD conditions.

o Aircraft Icing↗
NASA NTRS1980

Bulk compositions of chondrules in the Allende meteorite

The bulk chemistries of 33 chondrules from the Allende meteorite were determined by electron microbeam analyses and the modal recombination model. Chondrules were selected on the basis of a petrographic study of 2755 inclusions, of which 997 are chondrules, classified as recrystallized olivine chondrules, euhedral olivine chondrules, anhedral olivine chondrules, glassy/skeletal olivine chondrules, barred olivine chondrules, and pyroxene type chondrules. The data indicate that nonequilibrium metastable paths of crystallization were followed, a model which is supported by olivine-liquid (glassy mesostases) relationships. Variations in olivine morphology are related to cooling rate, degree of supercooling, normative olivine, and calculated viscosities. The chondrules in Allende were derived from highly undersaturated ultramafic melts in which Fe-Ni-S-O immiscible liquids were produced. The chondrule suite exhibits systematic variations in volatile loss, and this relationship is used to support a melting event (however, neither the nature of this event nor the mechanism of melt formation is established).

Simon, S. B.↗
NASA NTRS1976

The origin of chondrules - Experimental investigation of metastable liquids in the system Mg2SiO4-SiO2

Laser-melted magnesium silicate droplets were supercooled 400-750 C below their equilibrium liquidus temperatures before crystallization and their texture was compared with that of meteoritic and lunar chondrules. Crystal morphology, width and texture were studied in relation to nucleation temperature and bulk composition. It was found that the only phase to nucleate from the forsterite-enstatite normative melts was forsterite. Highly siliceous glass, about 65% SiO2 by weight, was identified interstitially to the forsterite crystals in seven of the MgSiO4 spherules and was thought to be present in all.

Blander, M.↗
NASA NTRS1997

Liquid propellant densification

Super cooling the cryogenic liquid propellant in a vehicle propellant tank densities the propellant allowing the vehicle propellant tank to carry more fuel in the same volume tank while lowering the vapor pressure and thus the tank operating pressure. Lowering the tank operating pressure reduces the stress and therefore allows the walls of the tank to be thinner. Both the smaller tank volume and thinner tank wall results in an overall smaller and lighter vehicle with increased payload capability. The cryogenic propellant can be supercooled well below the normal boiling point temperature level by transporting the liquid propellant from the vehicle tanks to a ground based cooling unit which utilizes a combination of heat exchanger and compressor. The compressor lowers the coolant fluid bath pressure resulting in a low temperature boiling liquid which is subsequently used to cool the recirculating liquid. The cooled propellant is then returned to the vehicle propellant tank. In addition to reducing the vehicle size and weight the invention also allows location of the vent valve on the ground, elimination of on-board recirculation pumps or bleed systems, smaller and lighter engine pumps and valves, lighter and more stable ullage gas, and significant reduction in tank fill operation. All of these mentioned attributes provide lower vehicle weight and cost.

Lak, Tibor I.↗
NASA NTRS1993

Immiscible phase incorporation during directional solidification of hypermonotectics

Solidification processes in immiscible samples were investigated by directly observing the events taking place at the solid-liquid interface during directional solidification. Visualization of these events was made possible through the use of a transparent metal analog system and a temperature gradient stage assembly fitted to an optical microscope. The immiscible transparent analog system utilized was the succinonitrile-glycerol system. This system has been shown to exhibit the same morphological transitions as observed in metallic alloys of monotectic composition. Both monotectic and hypermonotectic composition samples were directionally solidified in order to gain an improved understanding of the manner in which the excess hypermonotectic liquid is incorporated into the solidifying structure. The processing conditions utilized prevented sedimentation of the excess hypermonotectic liquid by directionally solidifying the samples in very thin (13 microns), horizontally oriented cells. High thermal gradient to growth rate ratios (G/R) were used in an effort to prevent constitutional supercooling and the subsequent formation of L(sub 2) droplets in advance of the solidification front during the growth of fibrous composite structures. Results demonstrated that hypermonotectic composites could be produced in samples up to two weight percent off of the monotectic composition by using a G/R ratio greater than or equal to 4.6 x 10(exp 4) C(s)/mm(sup 2) to avoid constitutional supercooling. For hypermonotectic samples processed with G/R ratios below 4.6 x 10(exp 4) C(s)/mm(sup 2), constitutional supercooling occurred and resulted in slight interfacial instability. For these samples, two methods of incorporation of the hypermonotectic liquid were observed and are reported. The correlation between the phase spacing, lambda, and the growth rate, R, was examined and was found to obey a relationship generally associated with a diffusion controlled coupled growth process. For samples with compositions ranging from the monotectic composition up to 2 percent off of the monotectic composition, data indicated that the square of the phase spacing (lambda) varied linearly with the inverse of the growth rate (R).

Andrews, J. Barry↗
NASA NTRS1987

Ice growth in supercooled solutions of antifreeze glycoproteins

The effects of different degrees of supercooling on the habit and rates of growth of ice crystals from solutions of antifreeze glycoproteins are reported. To isolate the influence of different solutions and supercooling alone, a system was devised that nucleated crystals in the middle of a uniformly supercooled sample. Alternatively, single crystals of selected orientation were inserted into free liquid surface. A crystallization rate up to five times greater than that in pure water was found. A mechanism explaining these results is suggested.

Harrison, K.↗
NASA NTRS1994

Method for forming single phase, single crystalline 2122 BCSCO superconductor thin films by liquid phase epitaxy

A substantially single phase, single crystalline, highly epitaxial film of Bi.sub.2 CaSr.sub.2 Cu.sub.2 O.sub.8 superconductor which has a T.sub.c (zero resistance) of 83 K is provided on a lattice-matched substrate with no intergrowth. This film is produced by a Liquid Phase Epitaxy method which includes the steps of forming a dilute supercooled molten solution of a single phase superconducting mixture of oxides of Bi, Ca, Sr, and Cu having an atomic ratio of about 2:1:2:2 in a nonreactive flux such as KCl, introducing the substrate, e.g., NdGaO.sub.3, into the molten solution at 850.degree. C., cooling the solution from 850.degree. C. to 830.degree. C. to grow the film and rapidly cooling the substrate to room temperature to maintain the desired single phase, single crystalline film structure.

Pandey, Raghvendra K.↗
NASA NTRS1995

Epitaxial layers of 2122 BCSCO superconductor thin films having single crystalline structure

A substantially single phase, single crystalline, highly epitaxial film of Bi.sub.2 CaSr.sub.2 Cu.sub.2 O.sub.8 superconductor which has a T.sub.c (zero resistance) of 83K is provided on a lattice-matched substrate with no intergrowth. This film is produced by a Liquid Phase Epitaxy method which includes the steps of forming a dilute supercooled molten solution of a single phase superconducting mixture of oxides of Bi, Ca, Sr, and Cu having an atomic ratio of about 2:1:2:2 in a nonreactive flux such as KCl, introducing the substrate, e.g., NdGaO.sub.3, into the molten solution at 850.degree. C., cooling the solution from 850.degree. C. to 830.degree. C. to grow the film and rapidly cooling the substrate to room temperature to maintain the desired single phase, single crystalline film structure.

Pandey, Raghvendra K.↗
NASA NTRS2014

NASA Glenn Icing Research Tunnel: 2014 Cloud Calibration Procedure and Results

The results of the December 2013 to February 2014 Icing Research Tunnel full icing cloud calibration are presented. The calibration steps included establishing a uniform cloud and conducting drop size and liquid water content calibrations. The goal of the calibration was to develop a uniform cloud, and to generate a transfer function from the inputs of air speed, spray bar atomizing air pressure and water pressure to the outputs of median volumetric drop diameter and liquid water content. This was done for both 14 CFR Parts 25 and 29, Appendix C ('typical' icing) and soon-to-be released Appendix O (supercooled large drop) conditions.

liquid water content↗