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DOE OSTI2019

High-temperature, spectrally-selective, scalable, and flexible thin-film Si absorber and emitter

Solar thermal technologies have great potential to provide low-cost storage for solar energy. However, their efficiencies are limited by a lack of scalable, mechanically flexible, durable, yet highly-efficient spectrally-selective solar absorbers suitable for high temperatures at low solar concentrations. Here, we overcome these challenges by fabricating a scalable free-standing spectrally-selective thin-film Si absorber and emitter (SSTFS) composite. Its high-temperature emittance shows strong spectral selectivity, even at 595 °C. Thermal stability is proven by measuring optical properties before and after thermal cycling equivalent to one day of concentrated sunlight. Despite the use of crystalline Si, the fabricated SSTFS composite exhibits exceptional mechanical flexibility to cover most surface geometries. The SSTFS composite demonstrates the potential of high-temperature, efficient and flexible solar absorbers and thermal emitters to advance renewable solar energy with storage.

36 MATERIALS SCIENCE↗

NASA NTRS2005

Lessons From the Pioneer Venus Program

We began the Pioneer Venus contract in late 1974 with a planned launch of the Orbiter in May 1978 and the Multiprobe in August 1978. Because we had four years, we thought there was plenty of time. As it turned out, we barely made the launch dates. The Orbiter was relatively straightforward, compared to the Multiprobe Bus and Probes that had to survive descent through the harsh Venusian atmosphere. To help overcome our many Multiprobe problems we formed a strong global team. The GE reentry team in Philadelphia, experienced in designing vehicles to enter the earth s atmosphere, was assigned the responsibility for the Probe entry system, including protective heat shielding and parachute design to extract the scienceladen Large Probe pressure vessel and control its descent through the Venusian clouds. Since the Probes had to remain stable as they descended through the Venus atmosphere, we used the aerodynamic expertise at the Hughes Missile Division, NASA s Ames Research Center and the Langley Research Center. Since the pressure at the surface of Venus was equivalent to an ocean depth of 3300 feet, we went to the Navy s David Taylor Research Center for their deepsea expertise. To test the pressure vessel at the high pressure and temperatures anticipated at Venus we went to the only facility capable of simulating the Venus surface environment, the Southwest Research Institute in San Antonio, Texas. We had dozens of subcontractors all over the world. As we developed our design, we began an extensive program to validate the ability of our Probe hardware to withstand the Venus environment. During this testing, we encountered numerous problems, mostly associated with adapting earth-based hardware to operate in the anticipated Venus environment. For example, the Large Probe pressure vessel imploded with a very loud bang the first time we tested its ability to withstand the high pressure and temperature on the Venusian surface. We had to go back and redesign, increasing the pressure vessel wall thickness. In addition, during the first tests of the parachute system, our parachute system ripped apart and had to be redesigned. Finally, at the aptly named test range in Truth or Consequences, New Mexico, we successfully demonstrated the parachute design by drop

Dorfman, Steven D.↗

NASA NTRS1981

IUE spectra of the hot close binary V Puppis

Low- and high-dispersion ultraviolet spectra obtained by the IUE of the early B-type close binary V Puppis are reported. The continuum derived from the low-dispersion images is consistent with a solar abundance model of effective temperature 25,000 K and log surface gravity 4.0. The high-dispersion spectra show shallow double lines, representing Doppler-resolved stellar lines, which are broadened as expected for the fast rotational velocities given by Levato (1974). The equivalent widths of the silicon lines, however, do not agree with the temperature derived for the star, while the silicon and carbon absorptions indicate a disordered photosphere in the presence of circumstellar gas. Several interstellar lines are also observed for the first time.

Koch, R. H.↗

NASA NTRS1990

Stratus: An interactive steady state mixed layer model for personal computers

A steady-state, horizontally homogeneous, cloud-topped marine boundary layer model based primarily on the work of Lilly (1968) and Schubert et al., (1979) is presented. The conservative thermodynamic variables are equivalent potential temperature, theta(sub e), and total water mixing ratio, q + l. Some of the differences between this and Lilly's (1968) model are: radiation is allowed to penetrate into the boundary layer; cloud top values of longwave radiation, equivalent potential temperature, and water vapor mixing ratio are linear functions of height derived from climatological data at California coastal stations; and the closure assumption assumes a weighted average of Lilly's (1968) maximum and minimum entrainment theories. This model was programmed in FORTRAN and will run interactively on an IBM-compatible personal computer. The program allows the user to specify the geographical location, the wind speed, the sea-surface temperature, the large scale horizontal divergence, and the initial guess for cloud top height. Output includes the steady state values of cloud top and cloud base height, mixed layer equivalent potential temperature and total water mixing ratio, and the associated convective and radiative fluxes.

Guinn, Thomas A.↗

NASA NTRS1998

Baseline Observations of Hemispheric Sea Ice with the Nimbus 7 Scanning Multichannel Microwave Radiometer

The Scanning Multichannel Microwave Radiometer (SMMR) on board the NASA Nimbus 7 satellite was designed to obtain data for sea surface temperatures (SSTs), near-surface wind speeds, sea ice coverage and type, rainfall rates over the oceans, cloud water content, snow water equivalent, and soil moisture. In this paper, I shall emphasize the sea ice observations and mention briefly some important SST observations. A prime factor contributing to the importance of SMMR sea ice observations lies in their successful integration into a long-term time series, presently being extended by observations from the series of Special Sensor Microwave/Imager (SSMI) on board the DOD/DMSP F8, Fl1, and F12 satellites. This currently constitutes a 19-year data set. Almost half of this was provided by the SMMR. Unfortunately, the 4-year data set produced earlier by the single-channel Electrically Scanned Microwave Radiometer (ESMR) was not successfully integrated into the SMMR/SSMI data set. This resulted primarily from the lack of an overlap period to provide intersensor adjustment, but also because of the large difference between the algorithms to produce ice concentrations and large temporal gaps in the ESMR data. The lack of overlap between the SeaSat and Nimbus 7 SMMR data sets was an important consideration for also excluding the SeatSat one, but the spatial gaps especially in the Southern Hemisphere daily SeaSat observations was another. The sea ice observations will continue into the future by means of the Advanced Microwave Scanning Radiometer (AMSR) on board the ADEOS II and EOS satellites due to be launched in mid- and late-2000, respectively. Analysis of the sea ice data has been carried out by a number of different techniques. Long-term trends have been examined by means of ordinary least squares and band-limited regression. Oscillations in the data have been examined by band-limited Fourier analysis. Here, I shall present results from a novel combination of Principal Component analysis and the recently-developed Empirical Mode Decomposition (EMD). In this method, the data are first separated into spatial and temporal parts, and then the temporal parts of the first few PCs are broken into intrinsic modes by the EMD method.

Gloersen, Per↗

DOE OSTI2022

Seasonally and Regionally Dependent Shifts of the Atmospheric Westerly Jets under Global Warming

A distinct feature of the atmospheric circulation response to increasing greenhouse gas forcing is the poleward shift of the zonal-mean westerly jet. The dynamical mechanisms of the zonal-mean poleward jet shift have been extensively studied in literature. At seasonal/regional scales, however, the westerly jets can shift equatorward, such as in the early-summer Asia–Pacific region, the late-winter America–Atlantic region, and the winter/spring east Pacific. These equatorward jet shifts imply climate impacts distinct from those of the poleward shifts, yet their causes are not well understood. In this work, based on a hierarchy of coupled, prescribed-SST, and aquaplanet simulations, we attribute the seasonal/regional equatorward jet shifts to the enhanced tropical upper-level warming (ETUW), which arises from both the tropical moist adiabat and the enhanced equatorial surface warming. By steepening the meridional temperature gradient in the subtropical upper-to-middle level and assisted by positive eddy feedback, the ETUW increases the zonal wind equatorward of the climatological jet. When the regional/seasonal meridional temperature gradients (or equivalently the westerly jets) are weak and peak close to the tropics, the ETUW effect overcomes the poleward jet-shift mechanisms and leads to the equatorward jet shifts. This climatological-state dependency is consistently seen in the decomposed jet responses to uniform warming and surface warming pattern, and further demonstrated through idealized aquaplanet experiments with designed climatological states. For uniform warming, the ETUW arising from moist adiabat makes the general poleward jet shifts insignificant in the aforementioned favorable regions/seasons. For warming pattern, the ETUW from enhanced equatorial warming drives substantial equatorward jet shifts in these favorable seasons/regions.

54 ENVIRONMENTAL SCIENCES↗

NASA NTRSDate not supplied

Constraints on the surface materials of Ryugu from spectral and water analysis of experimentally-heated CI carbonaceous chondrite

We performed heating experiments of the Orgueil CI chondrite in vacuum conditions at fO2 around I/W to evaluate systematic changes in mineralogy, water contents, and visible to infrared spectral features. Our goal is to interpret the spectra of Ryugu, the target C asteroid of the Hayabusa2 mission, because Ryugu shows spectral features similar to partially dehydrated carbonaceous chondrites. However heated carbonaceous chondrites can be easily contaminated by terrestrial water, which makes it almost impossible for laboratory data to be compared with spectra of asteroids directly. Therefore, our heated samples were analyzed without exposure to the air after experimental heating to minimize the effects of terrestrial water. The depth of the 2.7-µm absorption band and the water content of the heated Orgueil form a positive correlation trend which follows the results of experimental heating of CM and Tagish Lake meteorites using our experimental procedures. It is found that 500-°C heated Orgueil sample shows the best spectral match with Ryugu in terms of the low reflectance (~2%) at visible wavelengths and a weak absorption (~10%) at around 2.72 µm owing to survival of Mg-rich phyllosilicates. We suggest that Ryugu might have experienced heating and dehydration at a temperature around 500 °C, after aqueous alteration, and presently contains a small quantity of hydrated minerals equivalent to 1-2 wt.% of water at the surface.

K. Amano↗

NASA NTRS1992

Titan: a laboratory for prebiological organic chemistry

When we examine the atmospheres of the Jovian planets (Jupiter, Saturn, Uranus, and Neptune), the satellites in the outer solar system, comets, and even--through microwave and infrared spectroscopy--the cold dilute gas and grains between the stars, we find a rich organic chemistry, presumably abiological, not only in most of the solar system but throughout the Milky Way galaxy. In part because the composition and surface pressure of the Earth's atmosphere 4 x 10(9) years ago are unknown, laboratory experiments on prebiological organic chemistry are at best suggestive; but we can test our understanding by looking more closely at the observed extraterrestrial organic chemistry. The present Account is restricted to atmospheric organic chemistry, primarily on the large moon of Saturn. Titan is a test of our understanding of the organic chemistry of planetary atmospheres. Its atmospheric bulk composition (N2/CH4) is intermediate between the highly reducing (H2/He/CH4/NH3/H2O) atmospheres of the Jovian planets and the more oxidized (N2/CO2/H2O) atmospheres of the terrestrial planets Mars and Venus. It has long been recognized that Titan's organic chemistry may have some relevance to the events that led to the origin of life on Earth. But with Titan surface temperatures approximately equal to 94 K and pressures approximately equal to 1.6 bar, the oceans of the early Earth have no ready analogue on Titan. Nevertheless, tectonic events in the water ice-rich interior or impact melting and slow re-freezing may lead to an episodic availability of liquid water. Indeed, the latter process is the equivalent of a approximately 10(3)-year-duration shallow aqueous sea over the entire surface of Titan.

Non-NASA Center↗

NASA NTRS2016

Isentropic Analysis of a Simulated Hurricane

Hurricanes, like many other atmospheric flows, are associated with turbulent motions over a wide range of scales. Here the authors adapt a new technique based on the isentropic analysis of convective motions to study the thermodynamic structure of the overturning circulation in hurricane simulations. This approach separates the vertical mass transport in terms of the equivalent potential temperature of air parcels. In doing so, one separates the rising air parcels at high entropy from the subsiding air at low entropy. This technique filters out oscillatory motions associated with gravity waves and separates convective overturning from the secondary circulation. This approach is applied here to study the flow of an idealized hurricane simulation with the Weather Research and Forecasting (WRF) Model. The isentropic circulation for a hurricane exhibits similar characteristics to that of moist convection, with a maximum mass transport near the surface associated with a shallow convection and entrainment. There are also important differences. For instance, ascent in the eyewall can be readily identified in the isentropic analysis as an upward mass flux of air with unusually high equivalent potential temperature. The isentropic circulation is further compared here to the Eulerian secondary circulation of the simulated hurricane to show that the mass transport in the isentropic circulation is much larger than the one in secondary circulation. This difference can be directly attributed to the mass transport by convection in the outer rainband and confirms that, even for a strongly organized flow like a hurricane, most of the atmospheric overturning is tied to the smaller scales.

convection↗

NASA NTRS2019

An Ocean-Atmosphere Simulation for Studying Air-Sea Interactions

During the past few years the Goddard Earth Observing System (GEOS) and Massachusetts Institute of Technology (MIT) modeling groups have produced, respectively, global atmosphere-only and ocean-only simulations with km-scale grid spacing. These simulations have proved invaluable for process studies and for the development of satellite and in-situ sampling strategies. Nevertheless, a key limitation of these "nature" simulations is the lack of interaction between the ocean and the atmosphere, which limits their usefulness for studying air-sea interactions and for designing observing missions to study these interactions. To remove this limitation, we aim to perform a coupled simulation using the km-scale GEOS atmosphere and the km-scale MIT ocean models. The initial attempt at the km-scale coupled simulation resulted in computational issues which will be presented here. As a preliminary step towards the km-scale objective, we present results from a high resolution but not yet km-scale simulation, wherein we have coupled a cubed-sphere-720 (~ 1/8) configuration of the GEOS atmosphere to a lat-lon-cap-1080 (~ 1/12) configuration of the MIT ocean. We compare near-surface diagnostics of this fully coupled ocean-atmosphere set-up to equivalent atmosphere-only and ocean-only simulations. A particular focus of the comparisons is the differences in interactions between Sea Surface Temperature (SST) and ocean surface wind for the coupled and uncoupled simulations. We discuss observed and modeled high temporal variability (~days) SST-wind cycle and how it is represented in the different systems. A mechanism for the cycle, which is driven by SST-wind feedback, is proposed.

Strobach, Ehud↗

NASA NTRS1974

Formation of the luminosity-sensitive O I multiplet at 7774 A

Line profiles and equivalent widths were calculated for the 7774 A multiplet of O I for model atmospheres in the effective temperature range 6000-6500 K for surface gravities in the range log g = 4.0-1.0. A kinetic equilibrium treatment of line formation can partially account for the observed luminosity sensitivity of these lines and considerably modifies the derived microturbulent broadening parameter. Line profiles obtained from kinetic equilibrium line-formation theory are much deeper than LTE profiles, and new observations of Canopus are presented to verify the essential correctness of this treatment.

Johnson, H. R.↗

NASA NTRS1974

The detection of dust storms over land and water with satellite visible and infrared measurements

The position of a large area of dust was successfully located over the Sahara Desert and off the west coast of Africa with infrared measurements from the Temperature Humidity Infrared Radiometer (THIR) and visible information from the Image Dissector Camera System (IDCS) on Nimbus 4 between 20 and 25 April 1970. Over land, near midday, the dust areas were associated with lower equivalent blackbody temperatures (TBB's) than in the surrounding areas due to the mixing of the dust with the cooler air just above the surface. Near midnight dust areas appeared to be located where the TBB's were higher than the surrounding regions. The TBB contrast was insufficient for dust detection over the ocean, but the contrast in the visible was great enough to track the movement of the dust for several days off the African west coast. Measurements from the THIR 6.5-7.2 micron channel were useful for detecting the presence of cirrus clouds which could have caused a misinterpretation of the 10.5-12.5 micron TBB's.

Shenk, W. E.↗

NASA NTRS1994

Review of solar cell temperature coefficients for space

Energy conversion efficiency is an important parameter for solar cells, and well reported in the literature. However, solar cells heat up in sunlight, and the efficiency decreases. The temperature coefficient of the conversion efficiency is thus also extremely important, especially in mission modeling, but is much less well reported. It is of value to have a table which compiles into a single document values of temperature coefficients reported in the literature. In addition to modeling performance of solar cells in Earth orbit, where operating temperatures may range from about 20 C to as high as 85 C, it is of interest to model solar cells for several other recently proposed missions. These include use for the surface of Mars, for solar electric propulsion missions that may range from Venus to the Asteroid belt, and for laser-photovoltaic power that may involve laser intensities equivalent several suns. For all of these applications, variations in operating temperature away from the nominal test conditions result in significant changes in operating performance. In general the efficiency change with temperature is non-linear, however, in the range from negative 100 C through room temperature to a few hundred degrees C, efficiency is usually quite well modeled as a linear function of temperature (except for a few unusual cell types, such as amorphous silicon, and for extremely low bandgap cells, such as InGaAs).

Landis, Geoffrey A.↗

NASA NTRSDate not supplied

FORWARD AND INVERSE L-BAND RADIATIVE TRANSFER MODELING OVER THE DRY CHACO, USING SMOS OBSERVATIONS, LAND SURFACE MODELING AND IN SITU DATA

Passive microwave L-band remote sensing is well known for its sensitivity to surface soil moisture over land.The signal is also affected by other dynamic variables such as vegetation and soil salinity. In this research, L-band microwave observations of the Soil Moisture Ocean Salinity (SMOS) mission are used to explore soil surface salinity, moisture and vegetation, in the Argentinean Dry Chaco, an area with possible emerging dryland salinity. A Radiative Transfer Model (RTM) with inclusion of a correction to the soil’s dielectric constant for salinity was used in forward and inverse mode, using either in situ data or Catchment Land Surface Model (CLSM) simulations as RTM input. The forward analysis pointed out shortcomings in the modeled soil moisture and soil surface temperature estimates. The impact of salinity on forward simulations over the Dry Chaco was limited.The RTM inversion using 10 years of SMOS brightness temperature observations resulted in realistic estimates of vegetation and roughness, both with and withouto ptimizing a correction term for the dielectric constant in terms of salinity equivalents. However,the retrieval of the correction term to the dielectric constant was very uncertain and not representative of soil surface salinity, but rather of open water, texture uncertainty or soil moisture bias.

L-band↗

DOE OSTI2020

Disposal Concepts for a High-Temperature Repository in Shale.

Disposal of large, heat-generating waste packages containing the equivalent of 21 pressurized water reactor (PWR) assemblies or more is among the disposal concepts under investigation for a future repository for spent nuclear fuel (SNF) in the United States. Without a long (>200 years) surface storage period, disposal of 21-PWR or larger waste packages (especially if they contain high-burnup fuel) would result in in-drift and near-field temperatures considerably higher than considered in previous generic reference cases that assume either 4-PWR or 12-PWR waste packages (Jové Colón et al. 2014; Mariner et al. 2015; 2017). Sevougian et al. (2019c) identified high-temperature process understanding as a key research and development (R&D) area for the Spent Fuel and Waste Science and Technology (SFWST) Campaign. A two-day workshop in February 2020 brought together campaign scientists with expertise in geology, geochemistry, geomechanics, engineered barriers, waste forms, and corrosion processes to begin integrated development of a high-temperature reference case for disposal of SNF in a mined repository in a shale host rock. Building on the progress made in the workshop, the study team further explored the concepts and processes needed to form the basis for a high-temperature shale repository reference case. The results are described in this report and summarized..

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

DOE OSTI2022

Pre-main-sequence Brackett Emitters in the APOGEE DR17 Catalog: Line Strengths and Physical Properties of Accretion Columns

Very young (t ≲ 10 Myr) stars possess strong magnetic fields that channel ionized gas from the interiors of their circumstellar disks to the surface of the star. Upon impacting the stellar surface, the shocked gas recombines and emits hydrogen spectral lines. To characterize the density and temperature of the gas within these accretion streams, we measure equivalent widths of Brackett (Br) 11–20 emission lines detected in 1101 APOGEE spectra of 326 likely pre-main-sequence accretors. For sources with multiple observations, we measure median epoch-to-epoch line strength variations of 10% in Br11 and 20% in Br20. We also fit the measured line ratios to predictions of radiative transfer models by Kwan & Fischer. We find characteristic best-fit electron densities of n e = 10 11 –10 12 cm -3 , and excitation temperatures that are inversely correlated with electron density (from T ~ 5000 K for n e ~ 10 12 cm -3 to T ~ 12,500 K at n e ~ 10 11 cm -3 ). These physical parameters are in good agreement with predictions from modeling of accretion streams that account for the hydrodynamics and radiative transfer within the accretion stream. We also present a supplementary catalog of line measurements from 9733 spectra of 4255 Brackett emission-line sources in the APOGEE Data Release 17 data set.

79 ASTRONOMY AND ASTROPHYSICS↗

NASA NTRS2002

Galactic Noise and Passive Microwave Remote Sensing from Space At L-Band

The spectral window at L-band (1.4 GHz) is important for passive remote sensing of soil moisture and ocean salinity from space, parameters that are needed to understand the hydrologic cycle and ocean circulation. At this frequency, radiation from extraterrestrial (mostly galactic) sources is strong and, unlike the constant cosmic background, this radiation is spatially variable. This paper presents a modern radiometric map of the celestial sky at L-band and a solution for the problem of determining what portion of the sky is seen by a radiometer in orbit. The data for the radiometric map is derived from recent radio astronomy surveys and is presented as equivalent brightness temperature suitable for remote sensing applications. Examples using orbits and antennas representative of those contemplated for remote sensing of soil moisture and sea surface salinity from space are presented to illustrate the signal levels to be expected. Near the galactic plane, the contribution can exceed several Kelvin.

LeVine, David M.↗

NASA NTRSDate not supplied

Earth Radiation Budget Climate Record Composed of Multiple Satellite Observations

Effects of cloud diurnal cycle on top-of-atmosphere (TOA) and surface regional monthly mean irradiances, climatological mean, and anomalies are analyzed using CERES derived TOA irradiances and surface irradiances computed with MODIS derived cloud properties. Cloud properties derived from Terra and Aqua MODIS are sufficient to capture cloud diurnal cycle to compute regional monthly mean surface irradiances. While missing cloud diurnal cycle leads to a biased TOA and surface regional irradiances for regions with a strong cloud diurnal cycle, monthly regional TOA and surface anomalies derived from one sun-synchronous orbit agrees well with those derived from two sun-synchronous orbits. Based on these results, the algorithm to produce Edition 4.2 CERES EBAF product is developed. Regional TOA and surface climatological means derived from one sun-synchronous orbit are adjusted to match corresponding climatological means derived from Terra+Aqua observations. This climatological adjustment approach is used to merge the Terra only period to the Terra+Aqua period and to extend the Terra and Aqua record by merging NOAA20 observations. Two additional differences of Edition 4.2 EBAF algorithm to compute surface irradiances compared to the earlier version are: 1) no geostationary satellite derived cloud properties are used and 2) temperature and humidity from MERRA-2 instead of GEOIS-5.4.1 are used. Once surface monthly regional mean irradiances are compared with surface observations, the agreement is equivalent to the agreement with the earlier version. However, because surface irradiances are not affected by geostationary satellite artifacts, regional surface irradiance anomaly time series is significantly improved, especially for longwave irradiances.

Seiji Kato↗