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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7

Techno-economic and Life Cycle Analysis for Bioleaching Rare-Earth Elements from Waste Materials

A bioleaching process to extract rare earth elements (REE) from fluidized catalytic cracking (FCC) catalysts was optimized using a heterotrophic bacterium Gluconobacter oxydans to produce organic acids from glucose. Parameters optimized included agitation intensity, oxygen levels, glucose concentrations and nutrient additions. Biolixiviants from the optimized batch process demonstrated REE leaching efficiencies up to 56%. A continuous bioreactor system was subsequently developed to feed a continuous leach process and demonstrated leaching efficiencies of 50%. A techno-economic analysis showed glucose to be the single largest expense for the bioleach process constituting 37.8% of the total cost. The bioleaching plant described here was found profitable although the margin was small. Lower cost carbon and energy sources for producing the biolixiviant and improved leaching efficiencies would improve profitability as well as sourcing FCC catalysts with higher levels of REE. In conclusion, a life cycle analysis showed that electricity generation and glucose production required for the bioreactor had the largest potential for environmental impacts.

60 APPLIED LIFE SCIENCES↗

Magnetic Nanofluid Rare Earth Element Extraction Process Report, Techno Economic Analysis, and Results for Geothermal Fluids

This GDR submission is an interim technical report and raw data files from the first year of testing on functionalized nanoparticles for rare earth element extraction from geothermal fluids. The report contains Rare Earth Element uptake results (percent removal, mg Rare Earth Element/gram of sorbent, distribution coefficient) for the elements of Neodymium, Europium, Yttrium, Dysprosium, and Cesium. A detailed techno economic analysis is also presented in the report for a scaled up geothermal rare earth element extraction process. All rare earth element uptake testing was done on simulated geothermal brines with one rare earth element in each brine. The rare earth element uptake testing was conducted at room temperature.

15 GEOTHERMAL ENERGY↗

Battery‐Grade Lithium Materials: Virgin Production and Recycling, a Techno‐Economic Comparison

Lithium has been identified as an essential mineral to the economic and national security of the United States. It is vital for rechargeable batteries that surround us daily from the personal electronics to large-scale energy storage. With a comprehensive techno-economic analysis, the cost of battery-grade lithium compounds production, i.e., lithium carbonate (LC) is evaluated and lithium hydroxide monohydrate (LHM), from both virgin (spodumene ore and brine) and recycled feedstocks (spent lithium-ion batteries). The goal of this study is to inform about the economics of lithium compounds production with comprehensive insights into differences in manufacturing routes and pave a pathway to explore more innovative, domestic manufacturing processes in future for their cost competitiveness and environmental impact. The study includes details on mining and extraction operations as well as unit level operation in the refining process. Moreover, process level information has been collected for pyrometallurgical and hydrometallurgical battery recycling routes. This analysis shows that brine and direct lithium extraction are the cheapest pathways to produce LC or LHM (between $\$3.39$ and 6.20 kg −1 ). The cost of production in the ore and recycling routes can range between $\$4.17$ and $\$53.41$ kg −1 and is highly depending on capital equipment investment, plant location, and the price of spodumene concentrate SC6.0.

battery recycling↗

Techno‐economic, environmental, and social measurement of clean energy technology supply chains

Abstract In addition to the criteria of reliability and cost, clean energy technologies, such as wind, solar, and batteries, need to strive to a higher standard of environmental and societal benefit along their entire supply chain. This means additional performance metrics for these technologies should be considered, such as embodied energy, embodied carbon, recycled content and recyclability, environmental impact of material sourcing, impact on land and ecosystems, materials recovery at end of life, and production through quality nonexploitive jobs with community benefit. Many commercial and emerging energy technologies have not yet been explicitly evaluated based on these environmental and social performance metrics, which presents multiple opportunities for researchers and analysts. In this paper, we review the importance and current limitations of techno‐economic and life‐cycle assessment models for research design and manufacturing decisions. We explore emerging manufacturing modeling options that could improve environmental and social performance and how they could be used to help guide research. Even with the deployment of low‐carbon energy‐generation technologies, the future of a successful clean energy transition requires collaboration between researchers, advanced manufacturers, independent standards and tracking organizations, local communities, and national governments, to ensure the financial, environmental, and social sustainability of the entire supply and manufacturing process of energy technologies.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Techno-economic analysis of biodiesel and ethanol co-production from lipid-producing sugarcane: Biodiesel and Ethanol Co-Production from Lipid-Producing Sugarcane

Biodiesel production from vegetable oils has progressively increased over the past two decades. However, due to the low amounts of oil produced per hectare from temperate oilseed crops (e.g. soybean), the opportunities for further increasing biodiesel production are limited. Genetically modified lipid-producing sugarcane (lipid-cane) possesses great potential for producing biodiesel as an alternative feedstock because of sugarcane’s much higher productivity compared with soybean. In this study, techno-economic models were developed for biodiesel and ethanol coproduction from lipid-cane, assuming 2, 5, 10, or 20% lipid concentration in the harvested stem (dry mass basis). The models were compared with a conventional soybean biodiesel process model to assess lipid-cane’s competiveness. In the lipid-cane process model, the extracted lipids were used to produce biodiesel by transesterifi cation, and the remaining sugar was used to produce ethanol by fermentation. The results showed that the biodiesel production cost from lipid-cane decreased from $0.89/L to $0.59 /L as the lipid content increased from 2 to 20%; this cost was lower than that obtained for soybeans ($1.08/L). The ethanol production costs from lipid-cane were between $0.40/L and $0.46/L. The internal rate of return (IRR) for the soybean biodiesel process was 15.0%, and the IRR for the lipid-cane process went from 13.7 to 24.0% as the lipid content increased from 2 to 20%. Because of its high productivity, lipid-cane with 20% lipid content can produce 6700 L of biodiesel from each hectare of land, whereas soybean can only produce approximately 500 L of biodiesel from each hectare of land. This would indicate that continued efforts to achieve lipid-producing sugarcane could make large-scale replacement of fossil-fuel-derived diesel without unrealistic demands on land area.

09 BIOMASS FUELS↗

Techno-economic analysis of jet-fuel production from biorefinery waste lignin

Utilizing lignin feedstock along with cellulosic ethanol for the production of high-energy-density jet fuel offers a significant opportunity to enhance the overall operation efficiency, carbon conversion efficiency, economic viability, and sustainability of biofuel and chemical production. A patented catalytic process to produce lignin-substructure-based hydrocarbons in the jet-fuel range from lignin was developed. Comprehensive techno-economic analysis of this process was conducted through process simulation in this study. The discounted cash flow rate of return (DCFROR) method was used to evaluate a 2000 dry metric ton/day lignocellulosic ethanol biorefinery with the co-production of lignin jet fuel. The minimum selling price of lignin jet fuel at a 10% discount rate was estimated to be in the range of $6.35-$1.76/gal depending on the lignin and conversion rate and capacity. With a production capacity of 1.5-16.6 million gallon jet fuel per year, capital costs ranged from $38.0 to $39.4 million. On the whole, the co-production of jet fuel from lignin improved the overall economic viability of an integrated biorefinery process for corn ethanol production by raising co-product revenue from jet fuels.

09 BIOMASS FUELS↗

Understanding the role of Fischer–Tropsch reaction kinetics in techno-economic analysis for co-conversion of natural gas and biomass to liquid transportation fuels

With the increased availability of low-cost natural gas, the co-conversion of natural gas and biomass-to-liquid fuels has attracted attention from industry due to its potential for improving liquid fuel yields while lowering greenhouse gas emissions. In this paper, we provide an understanding of Fischer-Tropsch kinetics, improvements in processing strategies for hydrocarbon production, and of its impact on cost for the co-conversion of natural gas and biomass-to-transportation fuels. Studies that investigate the effect of Fischer-Tropsch reaction kinetics on techno-economic analysis can be used to develop process models that consider reaction stoichiometry and account for the effect of the paraffin-to-olefin ratio. We consider two processing scenarios: (1) one that does not employ a hydrocracker, and (2) the other where a hydrocracker serves as an integral part of the process scheme. Our analysis shows that co-processing natural gas not only facilitates the economic benefits of converting biomass-to-liquid fuels but also facilitates flexibility in process integration. The resulting minimum fuel selling price ranged from $2.47-$3.47/GGE (gallon gasoline equivalent) without the hydrocracker and ranged from $2.17-$3.60/GGE with the inclusion of the hydrocracker, for a 50 million GGE hydrocarbon fuel production facility and for varying blending ratios for biomass from 0-100% with natural gas. The hydrocracker helps to increase the production of diesel and jet fuels substantially, with carbon efficiencies of 50% attained for a chain growth probability of 0.87. The cost penalty comes from the capital expenses of the hydrocracker, and the expense may not be offset with hydrocarbon yield improvement.

09 BIOMASS FUELS↗

Regional techno-economic and life-cycle analysis of the pyrolysis-bioenergy-biochar platform for carbon-negative energy

This study investigates the sensitivity of greenhouse gas (GHG) emissions and the minimum fuel selling price for a 2000 metric ton day –1 integrated pyrolysis–bioenergy–biochar platform with respect to the biorefinery location and biomass types. The regional techno–economic and life–cycle analysis is evaluated in three US counties using representative crops: rice in Glenn County (California), corn in Hamilton County (Iowa), and peanuts in Jackson County (Florida). We evaluate the biochar selling price considering crop yield increases of 0.6%, 2.9%, and 10% after biochar application over 20 years in Glenn County, Hamilton County, and Jackson County, respectively. The biochar prices are calculated under low and high commodity prices to determine upper and lower bounds. Jackson County has the most economically beneficial scenario with an average minimum fuel selling price (MFSP) of 1.55 gal –1 of biofuel produced whereas Hamilton County has the highest average MFSP of 3.82 gal –1 . The life–cycle analysis shows that woody biomass has a strong potential to produce carbon–negative energy compared to grass and straw. As a result, of the 304 cases scenarios considered for this platform, 64% could produce biofuel with negative GHG emissions, which would meet the Renewable Fuel Standard (RFS) target for cellulosic biofuels.

09 BIOMASS FUELS↗

Techno-economic analysis of cellulosic ethanol conversion to fuel and chemicals

In this paper, we describe multiple scenarios investigated to assess the techno-economic results of producing fuels from corn stover-derived ethanol and the impact of co-producing higher-value, ethanol-derived n-butanol and 1,3-butadiene to improve economic feasibility. An alternative approach that produces only chemicals from the lignocellulosic-derived ethanol while producing fuels from the residual cell mass, unconverted sugars and lignin using hydrothermal liquefaction and hydrotreating also is described. Our results indicate that the hydrothermal liquefaction pathway has cost advantages relative to pathways that burn lignin from the corn stover conversion process to make ethanol when the associated ethanol stream is used to make only chemicals.

09 BIOMASS FUELS↗

The Need for and Path to Harmonized Life Cycle Assessment and Techno-Economic Assessment for Carbon Dioxide Capture and Utilization

The use of carbon dioxide as a feedstock for a broad range of products can help mitigate the effects of climate change through long-term removal of carbon or as part of a circular carbon economy. Research on capture and conversion technologies has intensified in recent years, and the interest in deploying these technologies is growing fast. However, sound understanding of the environmental and economic impacts of these technologies is required to drive fast deployment and avoid unintended consequences. Life cycle assessments (LCAs) and techno-economic assessments (TEAs) are useful tools to quantify environmental and economic metrics; however, these tools can be very flexible in how they are applied, with the potential to produce significantly different results depending on how the boundaries and assumptions are defined. Built on ISO standards for generic LCAs, several guidance documents have emerged recently from the Global CO 2 Initiative, the National Energy Technology Laboratory, and the National Renewable Energy Laboratory that further define assessment specifications for carbon capture and utilization. Overall agreement in the approaches is noted with differences largely based on the intended use cases. As a results, further guidance is needed for assessments of early-stage technologies, reporting details, and reporting for policymakers and nontechnical decision-makers.

09 BIOMASS FUELS↗

Techno-economic and life cycle analyses for a supercritical biodiesel production process from waste cooking oil for a plant located in the Midwest United States

Existing literature lacks detailed techno-economic and environmental life cycle analyses (TEA-LCA) focused on supercritical biodiesel production pathways produced via waste products. Therefore, in this work, the TEA-LCA was conducted to generate supercritical biodiesel from waste cooking oil for plants located in the Midwest region of USA having annual production capacities of 10,600 and 128,000 t using Aspen Plus and GREET softwares. Here, two plant production capacities were chosen to capture the economies of scale impact on biodiesel manufacture cost. In the supercritical process, methanol and propane were used as a cosolvent to synthesize biodiesel from waste cooking oil (WCO) at 280 °C and 128 bar at a residence time of 8.4 min and a WCO conversion rate of 97%. Economic analysis revealed that the supercritical process was an economically attractive pathway with a 2-year payback period for the 10,600 t/year capacity along with a break-even selling price of $\$$ 2.42/gal of diesel. In case of the larger plant (128,000 t/year capacity), the payback period and the breakeven selling price were considerably lower at values of 0.4 years and $1.31/gal of diesel, respectively, due to economies of scale impact. The generated biodiesel from supercritical process for the both the plant capacities met European (EN14214) and US (ASTM D6751) fuel quality standards while the obtained commercially valuable side product, i.e., glycerol, adhered to a pharmaceutical grade of 99.7%. Cradle to gate life cycle analysis using GREET revealed that supercritical process possessed 17% lower CO2 emissions than alkali-catalyzed process and 4% lower CO2 emissions than the conventional diesel production process. Other biodiesel production pathways in the literature were also compared to the results of the TEA-LCA of supercritical biodiesel production pathway.

Biodiesel production↗

Conceptual process design and techno-economic assessment of ex situ catalytic fast pyrolysis of biomass: A fixed bed reactor implementation scenario for future feasibility

Ex situ catalytic fast pyrolysis of biomass is a promising route for the production of fungible liquid biofuels. There is significant ongoing research on the design and development of catalysts for this process. However, there are a limited number of studies investigating process configurations and their effects on biorefinery economics. Herein we present a conceptual process design with techno-economic assessment; it includes the production of upgraded bio-oil via fixed bed ex situ catalytic fast pyrolysis followed by final hydroprocessing to hydrocarbon fuel blendstocks. This study builds upon previous work using fluidized bed systems, as detailed in a recent design report led by the National Renewable Energy Laboratory (NREL/TP-5100-62455); overall yields are assumed to be similar, and are based on enabling future feasibility. Assuming similar yields provides a basis for easy comparison and for studying the impacts of areas of focus in this study, namely, fixed bed reactor configurations and their catalyst development requirements, and the impacts of an inline hot gas filter. A comparison with the fluidized bed system shows that there is potential for higher capital costs and lower catalyst costs in the fixed bed system, leading to comparable overall costs. The key catalyst requirement is to enable the effective transformation of highly oxygenated biomass into hydrocarbons products with properties suitable for blending into current fuels. Potential catalyst materials are discussed, along with their suitability for deoxygenation, hydrogenation and C–C coupling chemistry. This chemistry is necessary during pyrolysis vapor upgrading for improved bio-oil quality, which enables efficient downstream hydroprocessing; C–C coupling helps increase the proportion of diesel/jet fuel range product. One potential benefit of fixed bed upgrading over fluidized bed upgrading is catalyst flexibility, providing greater control over chemistry and product composition. Since this study is based on future projections, the impacts of uncertainties in the underlying assumptions are quantified via sensitivity analysis. As a result, this analysis indicates that catalyst researchers should prioritize by: carbon efficiency > catalyst cost > catalyst lifetime, after initially testing for basic operational feasibility.

09 BIOMASS FUELS↗

Finite Element Analysis and Techno-economic Modeling of Solar Silicon Molten Salt Electrolysis

A new process is presented for low-cost one-step production of pure solid silicon from natural quartzite by molten salt electrolysis. At a process temperature of 1100°C, a techno-economic model including detailed mass and energy balances estimates energy consumption below 15 kWh/kg, with operating cost of $\$1.74$/kg and capital cost around $\$10,500$ per t/a (tonne annually) of production capacity for a 160,000 t/a plant. Use of an inert solid oxide membrane anode results in a pure oxygen by-product and no direct emissions. As a result, finite element analysis estimates the current density distribution and total current to inform the design of slab-shaped solid silicon cathodes.

14 SOLAR ENERGY↗

Techno-economic analysis of hybrid PV/T systems for process heat using electricity to subsidize the cost of heat

Process heat applications make up a large potential market for renewable energy. Despite heating demand being approximately double that of electricity, relatively little work has been done to develop renewable energy for process heat applications. Concentrated solar thermal (CST) systems are capable of reaching temperatures necessary for industrial and commercial steam applications but are often overlooked due to the difficulty of competing with natural gas. Novel hybrid photovoltaic/thermal systems (PV/T) are capable of simultaneously generating electricity and heat. The electricity produced is of higher value and offsets the lifetime cost of the system by producing a cost savings to the facility, ultimately making solar heat competitive with natural gas, propane, coal, and other fuels. The design and economic feasibility of a dish concentrator PV/T (CPV/T) system utilizing a transmissive CPV array is explored through a techno-economic model including technical, financial, and geographical inputs. Through practical design choices, the levelized cost of heat (LCOH) is competitive with natural gas or could even be reduced to zero in some locations by factoring in the electricity savings from additional energy generated by the transmissive CPV module.

14 SOLAR ENERGY↗

Techno-economic analysis of DC power distribution in commercial buildings

Improvements in building end-use efficiency have significantly reduced the energy intensity of new buildings, but diminishing returns make it a challenge to build very-low energy buildings cost-effectively. A largely untapped efficiency strategy is to improve the efficiency of power distribution within buildings. Direct current (DC) distribution with modern power electronics has the potential to eliminate much of the power conversion loss in alternating current (AC) building distribution networks that include photovoltaics and DC end uses. Previous literature suggests up to 15% energy savings from DC power distribution in very energy efficient buildings with onsite generation and battery storage. This paper extends prior energy modeling of DC versus AC distribution in buildings, to consider the cost of implementing DC systems on a life-cycle basis. A techno-economic analysis framework based on commercially available products that evaluates the cost-effectiveness of DC systems is presented. The analysis is conducted for three commercial building types in two California climate zones and for various PV and battery storage capacities. Monte Carlo simulation is used to compute the payback period and lifecycle cost savings of DC versus AC distribution systems. A future-market scenario is also examined, which evaluates how future efficiency improvements in power converters and changes in electricity tariffs may affect cost savings. This analysis shows that DC systems can be cost-effective in all scenarios that include large capacities of battery storage and onsite solar, whereas for systems without storage, DC distribution is generally not cost-effective.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Managing the techno-economic impacts of partial string failure in multistring energy storage systems

The role of energy storage systems (ESSs) is becoming increasingly important for today’s electric power systems. Unavailability of an ESS assigned to critical grid services may cause unwanted disruption of those services and hence, may have a significant techno-economic impact. Like any physical equipment, an ESS is vulnerable to various types of faults. Failure of one or more strings in a multistring ESS does not have to be the cause of shutting down the entire ESS. It can still operate with a partial number of strings and continue providing critical services to the grid, if there are no reliability or safety issues and is acceptable under applicable standards. However, it is important to make sure that the control strategies are adaptable to the changes in ESS capacity caused by failed strings. Also, depending on the previous operation and type of failure, the reallocation of duty cycle burden among available strings could be non-uniform. These complexities suggest that mitigation of the impact of partial failure in multistring ESSs is not trivial and needs careful consideration. This is the topic of this paper. The proposed work investigates the impact of partial failure of a large multistring ESS on the assigned service and develops strategies to adjust the ESS control duty cycles for reducing such impacts. In doing so, the paper proposes a novel two-stage framework that plans for the multistring failure using robust optimization theory and then adjusts in real-time using a rule-based algorithm, based on the real-time information on the power availability of the string. Illustrations provided in this work are based on frequency regulation use-case, which is a common application for many utility-scale ESSs. A 750 kilowatt (kW)/1500 kilowatt-hour (kWh) 3-string ESS is used for the demonstration in this work and the efficacy of the proposed method is demonstrated and compared against methods that do not incorporate string failure in their strategy. In particular, here we show that revenue loss of 93% can be incurred when partial string failure is not included in operation and planning. These losses in revenue are reduced by 60% with the proposed method.

25 ENERGY STORAGE↗

Cryogenic energy storage: Standalone design, rigorous optimization and techno-economic analysis

Energy storage allows flexible use and management of excess electricity and intermittently available renewable energy. Cryogenic energy storage (CES) is a promising storage alternative with a high technology readiness level and maturity, but the round-trip efficiency is often moderate and the Levelized Cost of Storage (LCOS) remains high. The complex flowsheets with intricate thermodynamics at cryogenic temperatures as well as the presence of multiple loops and refrigeration cycles pose considerable challenges for rigorous model-based design and optimization of CES systems. We present an optimization strategy that couples rigorous process simulation and Bayesian optimization with flowsheet decomposition and identification of hidden coupling constraints to optimally design standalone CES systems. Further refinement is done via a local search using the limited-memory Broyden–Fletcher–Goldfarb–Shanno algorithm. Here our results indicate that it is possible to achieve more than 52% round-trip efficiency and an LCOS of $153/MWh for a standalone 100 MW/400 MWh CES system limited to short-term storage with daily charging–discharging. However, a detailed techno-economic assessment reveals that the LCOS considering total capital investment may exceed $267/MWh when all direct and indirect costs of installation and operation are considered.

25 ENERGY STORAGE↗

Plant-wide modeling and techno-economic analysis of a direct non-oxidative methane dehydroaromatization process via conventional and microwave-assisted catalysis

Direct non-oxidative methane dehydroaromatization (DHA) process via conventional and microwave (MW)-assisted thermo-catalytic catalysis is studied. Rate models for methane DHA reactions, including the effect of catalyst deactivation, are developed by using the in-house experimental data. Model results for gas concentration profile and catalyst deactivation are in good agreement with the experimental data. This rate model is then used for the development of dynamic multi-scale, multi-physics commercial-scale reactor models. Total number of fixed bed reactors desired for a cyclic steady state process is estimated. Plant-wide models are then developed for conventional and MW-assisted processes for producing products of desired specifications. Techno-economic analysis of the methane DHA process is undertaken. Economics of these methane DHA processes are compared with the typical multi-step natural gas to aromatics production process via methanol synthesis. Sensitivity of internal rate of return (IRR) and net present value (NPV) to various economic and process parameters such as plant scale, desired rate of return, reactor cost, feedstock and utility cost, catalyst variable cost, and MW reactor cost is studied. Here, electric equivalent efficiency of the conventional methane DHA process is found to be 69.2 % and 67.3 % at 750 °C and 800 °C, respectively, while the MW-assisted methane DHA process has the electric equivalent efficiency of 48.9 % at 800 °C. IRRs of the conventional methane DHA process at 750 °C and 800 °C, and MW-assisted process are 15.2 %, 17.5 %, and 18.8 %, respectively for a methane feed flowrate of 19,782 kg/h, while the IRR of the multi-step natural gas to aromatics production process is estimated to be 0 % for the same plant scale. Impact of change in the methane price, electricity price, and catalyst cost is found to be considerable on the process economics, while the cost of the MW reactor is found to have negligible impact.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗