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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7

The Importance of Accounting for Landscape Position When Investigating Grasslands: A Multidisciplinary Characterisation of a California Coastal Grassland

Abstract Grasslands are one of the most common land‐cover types, providing important ecosystem services globally, yet few studies have examined grassland critical‐zone functioning throughout hillslopes. This study characterised a coastal grassland over a small hillslope at Point Reyes National Seashore, California, using multidisciplinary techniques, combining remotely‐sensed, geophysical, plant, and soil measurements. Clustering techniques delineated the study area into four landscape zones, up‐, mid‐, and down‐slope, and a bordering riparian ecotone, which had distinct environmental properties that varied spatially across the site, with depth, and time. Soil moisture increased with depth and down slope towards a bordering riparian zone, and co‐varied with soil CO 2 flux rates both spatially and temporally. This highlighted three distinct controls of soil moisture on soil respiration: CO 2 fluxes were inhibited by high moisture content in the down‐slope during the wet winter months, and converged across landscape positions in the dry summer months, while also displaying post‐rain pulses. The normalised difference vegetation index (NDVI) ranged from 0.32 (September)–0.80 (April) and correlated positively with soil moisture and aboveground biomass, moving down slope. Yet, NDVI, aboveground biomass, and soil moisture were not correlated to soil organic carbon (SOC) content (0.4%–4.5%), which was highest in the mid‐slope. The SOC content may instead be linked to shifts in dominant grassland species and their rhizosphere properties with landscape position. This multidisciplinary characterisation highlighted significant heterogeneity in grassland properties with landscape position, and demonstrated an approach that could be used to characterise other critical‐zone environments on hillslopes.

54 ENVIRONMENTAL SCIENCES↗

A new non-diffusional gas bubble production route in used nuclear fuel: Implications for fission gas release, cladding corrosion, and next generation fuel design

The relationship between noble metal phase particles and fission gas bubble production in used nuclear fuel is described. The majority of Te atoms within noble metal phase undergo radioactive decay to form stable Xe within a few hours after particle formation. This results in the production of clusters of Xe atoms contained within the solid metal matrix exhibiting an equivalent gas bubble pressure approaching 1 GPa. These high pressure bubbles are stabilized by the UO2 within the bulk of the fuel. However, when these bubbles form near the fuel / cladding interface, in combination with local and temporal damage caused by fission recoil, they are capable of overcoming the fracture strength of the UO2 and rupturing catastrophically. The force of the resulting bubble rupture is sufficient to eject noble metal phase particles several microns into the cladding. This proposed mechanism explains the observance of noble metal phase in cladding and is consistent with a host of morphological features found near the fuel / cladding interface.

Schwantes, Jon M.↗

47 Tuc in Rubin Data Preview 1. Exploring Early LSST Data and Science Potential

We present analyses of the early data from Rubin Observatory’s Data Preview 1 (DP1) for the field of the globular cluster 47 Tuc. The DP1 data set for 47 Tuc includes four nights of observations from the Rubin Commissioning Camera (LSSTComCam), covering multiple bands (ugriy). We address challenges of crowding in the inner region of the cluster and toward the SMC in DP1, and demonstrate improved star–galaxy separation by fitting fifth-degree polynomials to the stellar loci in color–color diagrams and applying multidimensional sigma clipping. We compile a catalog of 3576 probable 47 Tuc member stars selected via a combination of isochrone, Gaia proper-motion, and color–color space matched filtering. We explore the sources of photometric scatter in the 47 Tuc color–color sequence, evaluating contributions from various potential sources, including differential extinction within the cluster. Finally, of the 72 well-characterized variables in the field, we recover three known variable stars, including two RR Lyrae and one eclipsing binary, in the coadd-based object catalog, and identify 62 in the difference image-based object catalog. Although the DP1 lightcurves have sparse temporal sampling, they appear to follow the patterns of densely sampled literature lightcurves well. Despite some data limitations for crowded-field stellar analysis, DP1 demonstrates the promising scientific potential for future LSST data releases.

Choi, Yumi [NSF National Optical-Infrared Astronom↗

Growth of cosmic structure

We review one of the most fruitful areas in cosmology today that bridge theory and data - the temporal growth of large-scale structure. We go over the growth's physical foundations, and derive its behavior in simple cosmological models. While doing so, we explain how measurements of growth can be used to understand theory. We then review how some of the most mature cosmological probes-galaxy clustering, gravitational lensing, the abundance of clusters of galaxies, cosmic velocities, and cosmic microwave background-can be used to probe the growth of structure. We report the current constraints on growth, which are summarized as measurements of the parameter combination fσ 8 as a function of redshift, or else as the mass fluctuation amplitude parameter S 8 . Here, we finally illustrate several statistical approaches, ranging from the "growth index" parameterization to more general comparisons of growth and geometry, that can sharply test the standard cosmological model and indicate the presence of modifications to general relativity.

79 ASTRONOMY AND ASTROPHYSICS↗

Reversible disorder-order transitions in atomic crystal nucleation

Nucleation in atomic crystallization remains poorly understood, despite advances in classical nucleation theory. The nucleation process has been described to involve a nonclassical mechanism that includes a spontaneous transition from disordered to crystalline states, but a detailed understanding of dynamics requires further investigation. In situ electron microscopy of heterogeneous nucleation of individual gold nanocrystals with millisecond temporal resolution shows that the early stage of atomic crystallization proceeds through dynamic structural fluctuations between disordered and crystalline states, rather than through a single irreversible transition. Our experimental and theoretical analyses support the idea that structural fluctuations originate from size-dependent thermodynamic stability of the two states in atomic clusters. These findings, based on dynamics in a real atomic system, reshape and improve our understanding of nucleation mechanisms in atomic crystallization.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Spatial and temporal metagenomics of river compartments reveals viral community dynamics in an urban impacted stream

Although river ecosystems constitute a small fraction of Earth’s total area, they are critical modulators of microbially and virally orchestrated global biogeochemical cycles. However, most studies either use data that is not spatially resolved or is collected at timepoints that do not reflect the short life cycles of microorganisms. To address this gap, we assessed how viral and microbial communities change over a 48-hour period by sampling surface water and pore water compartments of the wastewater-impacted River Erpe in Germany. We sampled every 3 hours resulting in 32 samples for which we obtained metagenomes along with geochemical and metabolite measurements. From our metagenomes, we identified 6,500 viral and 1,033 microbial metagenome assembled genomes (MAGs) and found distinct community membership and abundance associated with each river compartment (e.g., Competibacteraceae in surfacewater and Sulfurimonadaceae in pore water). We show that 17% of our viral MAGs clustered to viruses from other ecosystems like wastewater treatment plants and rivers. Our results also indicated that 70% of the viral community was persistent in surface waters, whereas only 13% were persistent in the pore waters taken from the hyporheic zone. Finally, we predicted linkages between 73 viral genomes and 38 microbial genomes. These putatively linked hosts included members of the Competibacteraceae, which we suggest are potential contributors to river carbon and nitrogen cycling via denitrification and nitrogen fixation. Together, these findings demonstrate that members of the surface water microbiome from this urban river are stable over multiple diurnal cycles. These temporal insights raise important considerations for ecosystem models attempting to constrain dynamics of river biogeochemical cycles.

54 ENVIRONMENTAL SCIENCES↗

HFTS-2 Completions Design and State-of-the-Art Diagnostics Results

Various completion schemes were tested as part of the Hydraulic Fracture Test Site-2 (HFTS-2) project. The wells were instrumented with permanent fiber optic (FO) cable, and unique near-wellbore and far-field region surveys were acquired to evaluate spatial and temporal hydraulic fracture characteristics. The state-of-the-art diagnostics included substantial monitoring of both the well stimulation and longer-term production performance. The objective was to evaluate and improve stimulation distribution effectiveness (SDE) for different completion designs based on the diagnostics results. A hydraulic fracturing (HF) profile (i.e., proppant/fluid allocation among clusters) was obtained using near-wellbore Distributed Acoustic Sensing (DAS) data acquired during stimulation. Statistical analysis provided a quantitative assessment of SDE for the different completion designs. A novel workflow was developed to assess time-lapse fracture property changes at the cluster and stage levels based on Distributed Strain Sensing (DSS) data acquired during the production phase. These time-lapse fracture property changes were compared with the HF profile. Based on the statistical analysis, Rate Per Cluster (RPC) during proppant slurry placement appears to be a primary completion design variable, rather than the typical Rate Per Perf (RPP). If RPC was not maintained at a certain level, the likelihood of uneven distribution increased dramatically. The stage configurations that created low RPC while maintaining high RPP did not show improved SDE. The strain change results based on DSS data during the production phase indicated near-wellbore fracture property changes (e.g., aperture changes during well shut-in and flow periods) and aligned well with near-wellbore DAS signals acquired during stimulation. More importantly, fracture property changes based on DSS data acquired during two tests over a 7-month period show high consistency and good alignment with the near-wellbore HF profile. This workflow quantitatively evaluates SDE for different completion designs using diagnostic results and could help optimize completion strategy for future development projects. Here, the analysis and interpretation of results demonstrate the technical feasibility of using permanent fiber optic cable for stimulation and production monitoring and indic

58 GEOSCIENCES↗

Streamlined spatial and environmental expression signatures characterize the minimalist duckweed Wolffia australiana

Single-cell genomics permits a new resolution in the examination of molecular and cellular dynamics, allowing global, parallel assessments of cell types and cellular behaviors through development and in response to environmental circumstances, such as interaction with water and the light–dark cycle of the Earth. Here, we leverage the smallest, and possibly most structurally reduced, plant, the semiaquaticWolffia australiana, to understand dynamics of cell expression in these contexts at the whole-plant level. We examined single-cell-resolution RNA-sequencing data and foundWolffiacells divide into four principal clusters representing the above- and below-water-situated parenchyma and epidermis. Although these tissues share transcriptomic similarity with model plants, they display distinct adaptations thatWolffiahas made for the aquatic environment. Within this broad classification, discrete subspecializations are evident, with select cells showing unique transcriptomic signatures associated with developmental maturation and specialized physiologies. Assessing this simplified biological system temporally at two key time-of-day (TOD) transitions, we identify additional TOD-responsive genes previously overlooked in whole-plant transcriptomic approaches and demonstrate that the core circadian clock machinery and its downstream responses can vary in cell-specific manners, even in this simplified system. Distinctions between cell types and their responses to submergence and/or TOD are driven by expression changes of unexpectedly few genes, characterizingWolffiaas a highly streamlined organism with the majority of genes dedicated to fundamental cellular processes.Wolffiaprovides a unique opportunity to apply reductionist biology to elucidate signaling functions at the organismal level, for which this work provides a powerful resource.

Biochemistry & Molecular Biology↗

Nanoscale defect evaluation framework combining real-time transmission electron microscopy and integrated machine learning-particle filter estimation

Observation of dynamic processes by transmission electron microscopy (TEM) is an attractive technique to experimentally analyze materials’ nanoscale phenomena and understand the microstructure-properties relationships in nanoscale. Even if spatial and temporal resolutions of real-time TEM increase significantly, it is still difficult to say that the researchers quantitatively evaluate the dynamic behavior of defects. Images in TEM video are a two-dimensional projection of three-dimensional space phenomena, thus missing information must be existed that makes image’s uniquely accurate interpretation challenging. Therefore, even though they are still a clustering high-dimensional data and can be compressed to two-dimensional, conventional statistical methods for analyzing images may not be powerful enough to track nanoscale behavior by removing various artifacts associated with experiment; and automated and unbiased processing tools for such big-data are becoming mission-critical to discover knowledge about unforeseen behavior. We have developed a method to quantitative image analysis framework to resolve these problems, in which machine learning and particle filter estimation are uniquely combined. The quantitative and automated measurement of the dislocation velocity in an Fe-31Mn-3Al-3Si autunitic steel subjected to the tensile deformation was performed to validate the framework, and an intermittent motion of the dislocations was quantitatively analyzed. The framework is successfully classifying, identifying and tracking nanoscale objects; these are not able to be accurately implemented by the conventional mean-path based analysis.

36 MATERIALS SCIENCE↗

Machine learning to discover mineral trapping signatures due to CO 2 injection

Mineral trapping is pursued as a geological CO 2 sequestration (GCS) mechanism because it permanently stores CO 2 in solid phases or minerals. However, CO 2 mineral-trapping mechanisms are poorly understood due to (1) lack of sufficient field and laboratory data characterizing these complex processes, and (2) challenges to develop site-specific reactive-transport models coupling fluid flow and geochemical reactions occurring at various temporal (from milliseconds to years) and spatial (from pore (millimeters) to field (kilometers)) scales. Reactive transport with additional complexities such as heterogeneity can make the simulation outputs even more difficult to interpret because of complex nonlinearity and multi-scale interdependencies. Furthermore, the values of model outputs such as concentrations can vary by several orders of magnitude, making it harder to correlate and characterize the impact of the variables via traditional data interpretation techniques such as exploratory data analyses. Recently, machine learning (ML) has shown promise in feature discovery and in highlighting hidden mechanisms that cannot be obtained by existing data-analytics and statistical methods. In this study, we applied an unsupervised ML approach, non-negative matrix factorization with custom -means clustering (NMF) to the data generated by reactive-transport simulations of GCS. The reactive-transport data consisted of 19 attributes, including four physio-chemical variables (pH, porosity, aqueous CO 2 , and sequestered CO 2 ), six chemical species (K + , Na + , HCO, Ca 2+ , Mg 2+ , Fe 2+ ), and four carbonate minerals (calcite, dolomite, siderite, and ankerite), a feldspar mineral (albite), and four clay minerals (illite, clinochlore, kaolinite, and smectite) over a period of 200 years of simulation time. Furthermore, the simulation data used was for Morrow B sandstone at the Farnsworth hydrocarbon unit in Texas. Data are sampled at two locations within the model domain: (1) at the injection well and (2) 200 m west of the injection well. The injection was performed for a period of 10 years. Using NMF, we estimated the temporal interdependencies among the 19 attributes over a span of 200 years. We found that NMF was able to identify four reaction stages and their dominant attributes; these cannot be directly discerned through traditional visualization (e.g., line plots, Pareto analysis, Glyph-based visualization methods) or exploratory data analysis tools of the simulation data. The four stages were: reactions in the injection phase followed by short-, mid-, and long-term reactions. The NMF analysis also revealed that 10 among the 19 attributes are dominant. These dominant attributes for mineral trapping include calcite, dolomite at injection well, siderite at 200 m away from the injection well, clinochlore, kaolinite, Na + , K + , Ca 2+ , Mg 2+ , pH, and aqeuous CO 2 . Finally, at late times (65–200 years), our results showed that calcite plays a major role in mineral trapping with insignificant contribution from siderite, ankerite, and clay minerals. These findings make the proposed unsupervised ML-model attractive for reactive-transport sensing towards real-time GCS monitoring.

54 ENVIRONMENTAL SCIENCES↗

Characterizing Spatial and Temporal Variability of California’s Coastal Upwelling Using a Satellite-Derived CUTI Index

Ocean upwelling off California is a wind-driven coastal process with complex interactions between spatial wind patterns and sea surface temperatures. Large-scale spatial and temporal upwelling characterizations are traditionally based on numerical models, while quantifying upwelling with direct observations is not straightforward. To complement model-based upwelling characterizations, here we use satellite estimates of winds, sea surface temperatures, and ocean currents along the California coast to calculate the coastal upwelling transport index (CUTI), originally calculated from a numerical ocean model. The CUTI framework accounts for both Ekman and geostrophic offshore-directed ocean transport, the latter of which is often neglected in satellite-based upwelling assessments. The approach yields the CUTI over a 30-yr period at a daily temporal and 0.25° spatial resolution to analyze upwelling patterns, with focus on potential Morro Bay and Humboldt wind energy areas. Morro Bay (CUTI median of 0.63 m 2 s −1 ) exhibits stronger, more consistent upwelling throughout the year, whereas Humboldt (CUTI median of 0.45 m 2 s −1 ) exhibits a pronounced seasonal cycle with strongest upwelling in the summer and occasional downwelling in winter. The cluster analysis of 1993–2022 satellite maps of CUTI identifies four characteristic spatial upwelling patterns along the coast, corresponding to distinct spatial distributions of sea surface temperature anomalies, Ekman transport, and geostrophic ocean water transport. This dataset provides an observation-based foundation for characterizing natural coastal upwelling off the California coast, showing good agreement with the original model CUTI while being based on satellite data and offering increased spatial resolution.

16 TIDAL AND WAVE POWER↗

Small-amplitude Compressible Magnetohydrodynamic Turbulence Modulated by Collisionless Damping in Earth’s Magnetosheath: Observation Matches Theory

Plasma turbulence is a ubiquitous dynamical process that transfers energy across many spatial and temporal scales and affects energetic particle transport. Recent advances in the understanding of compressible magnetohydrodynamic (MHD) turbulence demonstrate the important role of damping in shaping energy distributions on small scales, yet its observational evidence is still lacking. This study provides the first observational evidence of substantial collisionless damping (CD) modulation on the small-amplitude compressible MHD turbulence cascade in Earth’s magnetosheath using four Cluster spacecraft. Based on an improved compressible MHD decomposition algorithm, turbulence is decomposed into three eigenmodes: incompressible Alfvén modes and compressible slow and fast (magnetosonic) modes. Our observations demonstrate that CD enhances the anisotropy of compressible MHD modes because CD has a strong dependence on wave propagation angle. The wavenumber distributions of slow modes are mainly stretched perpendicular to the background magnetic field (B 0 ) and weakly modulated by CD. In contrast, fast modes are subjected to a more significant CD modulation. Fast modes exhibit a weak, scale-independent anisotropy above the CD truncation scale. Below the CD truncation scale, the anisotropy of fast modes enhances as wavenumbers increase. As a result, fast-mode fractions in the total energy of compressible modes decrease with the increase of perpendicular wavenumber (to B 0 ) or wave propagation angle. Our findings reveal how the turbulence cascade is shaped by CD and its consequences for anisotropies in the space environment.

97 MATHEMATICS AND COMPUTING↗

Efficient Source of Shaped Single Photons Based on an Integrated Diamond Nanophotonic System

An efficient, scalable source of shaped single photons that can be directly integrated with optical fiber networks and quantum memories is at the heart of many protocols in quantum information science. We demonstrate a deterministic source of arbitrarily temporally shaped single-photon pulses with high efficiency [detection efficiency = 14.9 %] and purity [g (2) (0) = 0.0168] and streams of up to 11 consecutively detected single photons using a silicon-vacancy center in a highly directional fiber-integrated diamond nanophotonic cavity. Finally, combined with previously demonstrated spin-photon entangling gates, this system enables on-demand generation of streams of correlated photons such as cluster states and could be used as a resource for robust transmission and processing of quantum information.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Rapid detection of rare events from in situ X-ray diffraction data using machine learning

High-energy X-ray diffraction methods can non-destructively map the 3D microstructure and associated attributes of metallic polycrystalline engineering materials in their bulk form. These methods are often combined with external stimuli such as thermo-mechanical loading to take snapshots of the evolving microstructure and attributes over time. However, the extreme data volumes and the high costs of traditional data acquisition and reduction approaches pose a barrier to quickly extracting actionable insights and improving the temporal resolution of these snapshots. This article presents a fully automated technique capable of rapidly detecting the onset of plasticity in high-energy X-ray microscopy data. The technique is computationally faster by at least 50 times than the traditional approaches and works for data sets that are up to nine times sparser than a full data set. This new technique leverages self-supervised image representation learning and clustering to transform massive data sets into compact, semantic-rich representations of visually salient characteristics ( e.g. peak shapes). These characteristics can rapidly indicate anomalous events, such as changes in diffraction peak shapes. It is anticipated that this technique will provide just-in-time actionable information to drive smarter experiments that effectively deploy multi-modal X-ray diffraction methods spanning many decades of length scales.

Zheng, Weijian↗

Isoenergetic two-photon excitation enhances solvent-to-solute excited-state proton transfer

Two-photon excitation (TPE) is an attractive means for controlling chemistry in both space and time. Since isoenergetic one- and twophoton excitations (OPE and TPE) in non-centrosymmetric molecules are allowed to reach the same excited state, it is usually assumed that they produce similar excited-state reactivity. We compare the solvent-to-solute excited-state proton transfer of the super photobase FR0-SB following isoenergetic OPE and TPE. We find up to 62% increased reactivity following TPE compared to OPE. From steady-state spectroscopy, we rule out the involvement of different excited states and find that OPE and TPE spectra are identical in non-polar solvents but not in polar ones. We propose that differences in the matrix elements that contribute to the two-photon absorption cross sections lead to the observed enhanced isoenergetic reactivity, consistent with the predictions of our high-level coupledcluster-based computational protocol. We find that polar solvent configurations favor greater dipole moment change between ground and excited states, which enters the probability for TPE as the absolute value squared. This, in turn, causes a difference in the Franck– Condon region reached via TPE compared to OPE. We conclude that a new method has been found for controlling chemical reactivity via the matrix elements that affect two-photon cross sections, which may be of great utility for spatial and temporal precision chemistry.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Identification of the weak-to-strong transition in Alfvénic turbulence from space plasma

Abstract Plasma turbulence is a ubiquitous dynamical process that transfers energy across many spatial and temporal scales in astrophysical and space plasma systems. Although the theory of anisotropic magnetohydrodynamic (MHD) turbulence has successfully described natural phenomena, its core prediction of an Alfvénic transition from weak to strong MHD turbulence when energy cascades from large to small scales has not been observationally confirmed. Here we report evidence for the Alfvénic weak-to-strong transition in small-amplitude, turbulent MHD fluctuations in Earth’s magnetosheath using data from four Cluster spacecraft. Our observations demonstrate the universal existence of strong turbulence accompanied by weak turbulent fluctuations on large scales. Moreover, we find that the nonlinear interactions of MHD turbulence are crucial to the energy cascade, as they broaden the cascade directions and fluctuating frequencies. The observed connection between weak and strong MHD turbulence systems may be present in many astrophysical environments, such as star formation, energetic particle transport, turbulent dynamos, and solar corona or solar wind heating.

79 ASTRONOMY AND ASTROPHYSICS↗

Identification of the weak-to-strong transition in Alfvénic turbulence from space plasma

Plasma turbulence is a ubiquitous dynamical process that transfers energy across many spatial and temporal scales in astrophysical and space plasma systems. Although the theory of anisotropic magnetohydrodynamic (MHD) turbulence has successfully described natural phenomena, its core prediction of an Alfvénic transition from weak to strong MHD turbulence when energy cascades from large to small scales has not been observationally confirmed. Here we report evidence for the Alfvénic weak-to-strong transition in small-amplitude, turbulent MHD fluctuations in Earth’s magnetosheath using data from four Cluster spacecraft. Our observations demonstrate the universal existence of strong turbulence accompanied by weak turbulent fluctuations on large scales. Moreover, we find that the nonlinear interactions of MHD turbulence are crucial to the energy cascade, as they broaden the cascade directions and fluctuating frequencies. The observed connection between weak and strong MHD turbulence systems may be present in many astrophysical environments, such as star formation, energetic particle transport, turbulent dynamos, and solar corona or solar wind heating.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Test Vector Development for Verification and Validation of Heavy-Duty Autonomous Vehicle Operations

The current focus in the ongoing development of autonomous driving systems (ADS) for heavy duty vehicles is that of vehicle operational safety. To this end, developers and researchers alike are working towards a complete understanding of the operating environments and conditions that autonomous vehicles are subject to during their mission. This understanding is critical to the testing and validation phases of the development of autonomous vehicles and allows for the identification of both the nominal and edge case scenarios encountered by these systems. Previous work by the authors saw the development of a comprehensive scenario generation framework to identify an operating domain specification (ODS), or external and internal conditions an autonomous driving system can expect to encounter on its mission to form critical scenario groups for autonomous vehicle testing and validating using statistical patterns, clustering, and correlation. Continuing this prior work, this paper focuses on the generation of test cases based on the critical scenarios identified that can be used to prioritize either the most common nominal driving scenarios or the least common severe driving scenarios. These test cases can then be used validate, through simulation or real-world testing, the operating design domain (ODD) for a generalized driving mission and built upon to identify spatial and temporal impacts on the driving mission of an autonomous vehicle.

Siekmann, Adam↗