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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
NASA NTRS1983

The effect of a coating on the thermo-oxidative stability of Celion 6000 graphite fiber/PMR 15 polyimide composites

The thermooxidative stability in air at 316 C of unidirectional, uncoated and aluminum-coated Celion 6000 graphite fiber/PMR 15 polyimide composites has been determined for exposure times up to nominally 2000 h. Comparison of the weight loss data and microstructural integrity reveals that a thin aluminum-foil coating can provide significant protection from oxidation. A quantitative description of the average depth of the reaction zone and the maximum length of cracks produced during oxidation as a function of time in uncoated Celion 6000/PMR 15 are given.

Hurwitz, F. I.↗
NASA NTRS1987

Thermo-oxidatively stable condensation polyimides containing 1,1,1-triaryl-2,2,2-trifluoroethane dianhydride and diamine monomers

Nine new condensation polyimides containing the trifluorophenylethylidene linkage were synthesized by the amic-acid route. Several other polyimides, including some with the hexafluoroisopropylidene linkage, were also prepared as controls. Amic-acid solutions were characterized by determining their inherent viscosities prior to thermal conversion into polyimide films. Glass transition temperatures (T sug g), thermogravimetric analysis (TGA), and isothermal weight loss data were obtained for the films. The films were pulverized into molding powders which, in turn, were thermally processed under pressure into neat resin discs. The discs were also characterized by T sub gs and 316 C and 371 C isothermal weight losses. The film study identified two new polyimides with T sub gs greater that 371 C and two new polyimides with low rates of weight loss. The resin discs exhibited the same overall trends in T sub g and weight loss as the respective films, however the weight loss per unit surface area was always greater, presumably due to voids or to mechanical degradation induced during preparation of the molding powders.

Alston, William B.↗
NASA NTRS1987

Thermo-elasto-viscoplastic analysis of problems in extension and shear

The problems of extension and shear behavior of structural elements made of carbon steel and subjected to large thermomechanical loads are investigated. The analysis is based on nonlinear geometric and constitutive relations, and is expressed in a rate form. The material constitutive equations are capable of reproducing all nonisothermal, elasto-viscoplastic characteristics. The results of the test problems show that: (1) the formulation can accommodate very large strains and rotations; (2) the model incorporates the simplification associated with rate-insensitive elastic response without losing the ability to model a rate-temperature dependent yield strength and plasticity; and (3) the formulation does not display oscillatory behavior in the stresses for the simple shear problem.

Riff, R.↗
NASA NTRS1987

The dynamic aspects of thermo-elasto-viscoplastic snap-through and creep buckling phenomena

Use of a mathematical model and solution methodology, to examine dynamic buckling and dynamic postbuckling behavior of shallow arches and spherical caps made of a realistic material and undergoing non-isothermal, elasto-viscoplastic deformation was examined. Thus, geometric as well as material type nonlinearities of higher order are included in this analysis. The dynamic stability problem is studied under impulsive loading and suddenly applied loading with loads of constant magnitude and infinite duration. A finite element model was derived directly from the incrementally formulated nonlinear shell equations, by using a tensor-oriented procedure. As an example of the results, the time history of the midspan displacement of a damped shallow circular arch is presented.

Riff, R.↗
NASA NTRS1986

Space radiation effects on the thermo-mechanical behavior of graphite-epoxy composites

This investigation of composite material properties utilized T300/934 graphite-epoxy that was subjected to 1.0 MeV electron radiation for a total dose of 1.0 x 10 to the 10th rads at a rate of 5.0 x 10 to the 7th rads/hour, simulating a worst-case exposure equivalent to 30 years in space. Mechanical testing was performed on 4-ply unidirectional laminates over the temperature range of -250 F (116 K) to +250 F (394 K). In-plane elastic tensile and shear properties as well as strength were obtained. The results show that electron radiation degrades the epoxy matrix and produces products that volatilize at the temperatures considered. These degradation products plasticize the epoxy at elevated temperatures and embrittle it at low temperatures, thereby altering the mechanical properties of the composite.

Milkovich, Scott M.↗
NASA NTRS1988

Boron Carbides As Thermo-electric Materials

Report reviews recent theoretical and experimental research on thermoelectric materials. Recent work with narrow-band semiconductors demonstrated possibility of relatively high thermoelectric energy-conversion efficiencies in materials withstanding high temperatures needed to attain such efficiencies. Among promising semiconductors are boron-rich borides, especially boron carbides.

Wood, Charles↗
NASA NTRS1988

Thermo-viscoelastic analysis of composite materials, volume 1

Advanced composite materials, especially graphite/epoxy, are being applied to aircraft structures in order to improve performance and save weight. An important consideration in composite design is the residual strength of a structure containing holes, delaminations, or interlaminar damage when subjected to compressive loads. Recent studies have revealed the importance of viscoelastic effects in polymer-based composites. The viscoelastic effect is particularly significant at elevated temperature/moisture conditions since the matrix material is strongly affected by the environment. The solution of viscoelastic problems in composites was limited to special cases which can be solved by classical lamination theory. A finite element procedure is presented for calculating time-dependent stresses and strains in composite structures with general configurations and complicated boundary conditions. Using this procedure the in-plane and interlaminar stress distributions and histories in notched and unnotched composites were obtained for mechanical and thermal loads. Both two-dimensional and three-dimensional viscoelastic problems are analyzed. The effects of layup orientation and load spectrum on creep response and stress relaxation were also studied.

Lin, K. Y.↗
NASA NTRS1988

Thermo-elasto-viscoplastic analysis of problems in extension and shear

The problems of extension and shear behavior of structural elements made of carbon steel and subjected to large thermomechanical loads are investigated. The analysis is based on nonlinear geometric and constitutive relations, and is expressed in a rate form. The material constitutive equations are capable of reproducing all nonisothermal, elasto-viscoplastic characteristics. The results of the test problems show that: (1) the formulation can accommodate very large strains and rotations; (2) the model incorporates the simplification associated with rate-insensitive elastic response without losing the ability to model a rate-temperature dependent yield strength and plasticity; and (3) the formulation does not display oscillatory behavior in the stresses for the simple shear problem.

Riff, R.↗
NASA NTRS1989

Thermo-viscoplastic analysis of hypersonic structures subjected to severe aerodynamic heating

A thermoviscoplastic computational method for hypersonic structures is presented. The method employs unified viscoplastic constitutive model implemented in a finite element approach for quasi-static thermal-structural analysis. Applications of the approach to convectively cooled hypersonic structures illustrate the effectiveness of the approach and provide insight into the transient inelastic structural behavior at elevated temperatures.

Thornton, Earl A.↗
NASA NTRS1988

Thermo-oxidative stability studies of Celion 6000/PMR-15 unidirectional composites, PMR-15, and Celion 6000 fiber

Experimental results on the influence of the thermooxidative resistance characteristics of the fiber and matrix resin on the thermal stability of isothermally aged Celion 6000/PMR-15 matrix resin composites are presented. SEM studies reveal that extreme oxidative erosion of the graphite fiber occurs at elevated temperatures in the presence of the polyimide matrix. The activation energy of oxidation of the composite was shown to be greater than those of the fiber and the matrix resin.

Bowles, Kenneth J.↗
NASA NTRS1989

Thermo-viscoplastic analysis of hypersonic structures subjected to severe aerodynamic heating

A thermoviscoplastic computational method for hypersonic structures is presented. The method employs a unified viscoplastic constitutive model implemented in a finite element approach for quasi-static thermal-structural analysis. Applications of the approach to convectively cooled hypersonic structures illustrate the effectiveness of the approach and provide insight into the transient inelastic structural behavior at elevated temperatures.

Thornton, Earl A.↗
NASA NTRS1989

Photo-thermo-dissociation. I - A general mechanism for destroying molecules

Photothermodissociation (PTD) of an isolated molecule is the name of the process when a photon is absorbed by an electronic transition, the energy is transferred to the vibrations (hot molecule) and then an atom or a fragment is ejected. A statistical physics treatment is presented that goes beyond the thermal approximation and fully takes into account the isolation of the system. A model is given that permits an explicit calculation of the ejection rates of hydrogen and carbon fragments from aromatic molecules as a function of their size and internal energy. Then, the lifetime of species against PTD in different astronomical radiation fields will result when a precise dynamical evolution of their internal energy can be established.

Leger, A.↗
NASA NTRS1989

A fully-coupled implicit method for thermo-chemical nonequilibrium air at sub-orbital flight speeds

A CFD technique is described in which the finite-rate chemistry in thermal and chemical nonequilibrium air is fully and implicitly coupled with the fluid motion. Developed for use in the suborbital hypersonic flight speed range, the method accounts for nonequilibrium vibrational and electronic excitation and dissociation, but not ionization. The steady-state solution to the resulting system of equations is obtained by using a lower-upper factorization and symmetric Gauss-Seidel sweeping technique through Newton iteration. Inversion of the left-hand-side matrices is replaced by scalar multiplications through the use of the diagonal dominance algorithm. The code, named CENS2H (Compressible-Euler-Navier-Stokes Two-Dimensional Hypersonic), is fully vectorized and requires about 8.8 x 10 to the -5th sec per node point per iteration using a Cray X-MP computer. Converged solutions are obtained after about 2400 iterations. Sample calculations are made for a circular cylinder and a 10 percent airfoil at 5 deg angle of attack. The calculated cylinder flow field agrees with that obtained experimentally. The code predicts a 10 percent change in lift, drag, and pitching moment for the airfoil due to the thermochemical phenomena.

Park, Chul↗
NASA NTRS1987

Biaxial thermo-mechanical fatigue

Stress-strain and durability information is often desirable for situations in which strain and temperature are changing simultaneously. To obtain such information, strain controlled uniaxial push-pull tests have typically been done. In order to control the mechanical strain, it is necessary in such tests to compute the mechanical strain from the total measured strain using measured temperature and the thermal expansion properties of the specimen. A system for conducting torsional thermomechanical tests is described which has the great advantage that the torsional strain is unaffected by the changing temperature and thus real time computations of quantities is not required for control of the test and the mechanical strain need not be determined from the subtraction of two measured qnantities as is the case in the uniaxial test. In addition to describing torsional thermomechanical tests, guidelines for software to be used in running biaxial thermomechanical tests will also be presented.

Jordan, Eric H.↗
NASA NTRS1989

Annealing group III-V compound doped silicon-germanium alloy for improved thermo-electric conversion efficiency

The thermoelectric conversion efficiency of a GaP doped SiGe alloy is improved about 30 percent by annealing the alloy at a temperature above the melting point of the alloy, preferably stepwise from 1200 C to 1275 C in air to form large grains having a size over 50 microns and to form a GeGaP rich phase and a silicon rich phase containing SiP and SiO2 particles.

Vandersande, Jan W.↗
NASA NTRS1990

Characteristic-based algorithms for flows in thermo-chemical nonequilibrium

A generalized finite-rate chemistry algorithm with Steger-Warming, Van Leer, and Roe characteristic-based flux splittings is presented in three-dimensional generalized coordinates for the Navier-Stokes equations. Attention is placed on convergence to steady-state solutions with fully coupled chemistry. Time integration schemes including explicit m-stage Runge-Kutta, implicit approximate-factorization, relaxation and LU decomposition are investigated and compared in terms of residual reduction per unit of CPU time. Practical issues such as code vectorization and memory usage on modern supercomputers are discussed.

Walters, Robert W.↗