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NASA NTRS1999

Land-Atmosphere Interactions: Successes, Problems and Prospects

After two decades of active research, a much better understanding of the broader role of biospheric processes on the local climate has emerged. A surface-albedo increase, particularly in desert border regions of the subtropics (as well as the deforested tropical regions), leads to a net surface energy deficit, which in turn leads to a relative sinking and reduced rainfall. On the other hand, studies of the influence of altered ratios of evapotranspiration and sensible fluxes, in situations where the net solar income is unchanged, show that evapotranspiration is a more desirable flux for increased precipitation and vitality of the biosphere. Besides providing water vapor and convective available potential energy (CAPE) to the lower troposphere, evapotranspiration helps in building larger CAPE before "turning on" the moist-convection. Larger CAPE in the lower troposphere enables convection to reach into the deeper atmosphere thereby heating the upper troposphere; indeed, moist-convection is also accompanied by the evaporation of falling precipitation that cools and moistens the lower atmosphere. While convective, as opposed to stratiform, precipitation reduces the fractional cloud cover; it also allows more solar radiation to reach the surface thereby invigorating surface fluxes. These, together with moist convection and associated downdrafts help to maintain the characteristic upper temperature limit(s) of the moist-land as well as oceanic regions. Regardless of the above understanding, several important problems continue to hinder the accurate simulation of a realistic land atmosphere interaction in a numerical model (both GCM and/or Meso-scale models). Among the unsolved problems are parameterization of sub-grid scale land processes that include small-scale variability of soil moisture, snow-cover and snow-physics, the biodiversity of the biosphere, orography, local drainage characteristics under natural conditions, and surface flow over the natural terrain. A well-known non-linear response of surface fluxes to these variations makes the problem of parameterizing land-atmosphere interaction processes hard-to-address and simulate, particularly in a GCM. In our presentation, we will discuss how orographic, snow-cover, and water table interactions can be included into a Simple Biosphere Model such as SiB/SSiB. Figure I shows how, in the Russian region, spring snowmelt affects the soil moisture profile. Corresponding figure 2 shows how interaction with the water table decreases the natural evapotranspiration in the Sahel region simulation. While these simulations need better validation with data, the simulations reveal that surface processes are sensitive to these parameterizations. With these developments, we continue to advance our understanding of the interaction of land with the atmosphere aloft, but the intrinsic variability of the newer parameters, e. g., hydraulic properties of the soil, diminish the positive influences of these advances on the improved climate simulation with GCMs.

Sud, Y. C.↗

DOE OSTI2020

Impact of ocean model resolution on understanding the delayed warming of the Southern Ocean

Abstract Currently available historical climate change simulations indicate a relatively delayed Southern Ocean warming, particularly poleward of the Antarctic Circumpolar Current (ACC) compared much of the rest of the globe. However, even this simulated delayed warming is inconsistent with observational estimates which show a cooling trend poleward of the ACC for the period 1979–2014. A fully coupled model run at two resolutions, i.e. ocean eddy parameterized and ocean eddy resolving, driven by historical and fixed CO2 concentration is used to investigate forced trends south of the ACC. We analyze the 1961–2005 Southern Ocean surface and upper ocean temperatures trends simulated by the model and observational estimates to understand the observed trends in the SO. At both resolutions, the models successfully reproduce the observed warming response for the northern flank of the ACC. The eddy resolving simulations, however, are able to reproduce the observed near Antarctic cooling in contrast to the eddy parameterized simulation which shows a warming trend. The cause of this inconsistency between the observations and the ocean eddy parameterized climate models is still a matter of debate, and we show here results that suggest resolved ocean meso-scale processes may be an integral part of capturing the observed trends in the Southern Ocean.

Environmental Sciences & Ecology↗

NASA NTRS2004

The Response of the North Atlantic Bloom to NAO Forcing

Results from the climatologically forced coupled ice/ocean/biogeochemical model that covers the Arctic and North Atlantic Oceans are presented and compared to the chlorophyll fields of satellite-derived ocean color measurements. Biogeochemical processes in the model are determined from the interactions among four phytoplankton functional groups (diatoms, chlorophytes, cyanobacteria and coccolithophores) and four nutrients (nitrate, ammonium, silicate and dissolved iron). The model simulates the general large-scale pattern in April, May and June, when compared to both satellite-derived and in situ observations. The subpolar North Atlantic was cool in the 1980s and warm in the latter 1990s, corresponding to the CZCS and SeaWiFS satellite observing periods, respectively. The oceanographic conditions during these periods resemble the typical subpolar upper ocean response to the NAO+ and NAO-phases, respectively. Thus, we use the atmospheric forcing composites from the two NAO phases to simulate the variability of the mid-ocean bloom during the satellite observing periods. The model results show that when the subpolar North Atlantic is cool, the NAO+ case, more nutrients are available in early spring than when the North Atlantic is warm, the NAO-case. However, the NAO+ simulation produces a later bloom than the NAO-simulation. This difference in the bloom times is also identified in SeaWiFS and CZCS satellite measurements. In the model results, we can trace the difference to the early diatom bloom due to a warmer upper ocean. The higher nutrient abundance in the NAO+ case did not provide larger total production than in the NAO- case, instead the two cases had a comparable area averaged amplitude. This leads us to conclude that in the subpolar North Atlantic, the timing of the spring phytoplankton bloom depends on surface temperature and the magnitude of the bloom is not significantly impacted by the nutrient abundance.

Mizoguchi, Ken-Ichi↗

NASA NTRS2001

Predictability of the California Current System

The physical and biological oceanography of the Southern California Bight (SCB), a highly productive subregion of the California Current System (CCS) that extends from Point Conception, California, south to Ensenada, Mexico, continues to be extensively studied. For example, the California Cooperative Oceanic Fisheries Investigations (CalCOFI) program has sampled this region for over 50 years, providing an unparalleled time series of physical and biological data. However, our understanding of what physical processes control the large-scale and mesoscale variations in these properties is incomplete. In particular, the non-synoptic and relatively coarse spatial sampling (70km) of the hydrographic grid does not completely resolve the mesoscale eddy field (Figure 1a). Moreover, these unresolved physical variations exert a dominant influence on the evolution of the ecosystem. In recent years, additional datasets that partially sample the SCB have become available. Acoustic Doppler Current Profiler (ADCP) measurements, which now sample upper-ocean velocity between stations, and sea level observations along TOPEX tracks give a more complete picture of the mesoscale variability. However, both TOPEX and ADCP are well-sampled only along the cruise or orbit tracks and coarsely sampled in time and between tracks. Surface Lagrangian drifters also sample the region, although irregularly in time and space. SeaWiFS provides estimates of upper-ocean chlorophyll-a (chl-alpha), usually giving nearly complete coverage for week-long intervals, depending on cloud coverage. Historical ocean color data from the Coastal Zone Color Scanner (CZCS) has been used extensively to determine phytoplankton patterns and variability, characterize the primary production across the SCB coastal fronts, and describe the seasonal and interannual variability in pigment concentrations. As in CalCOFI, these studies described much of the observed structures and their variability over relatively large space and time scales.

Miller, Arthur J.↗

NASA NTRS1985

On the differences in continental rifting at the Earth, Mars and Venus

During the process of continental rifting on Earth, the lower ductile crust stretches, forming a neck, while the upper brittle crust is broken in blocks by faults, and the blocks sink down the thinned lower crust; if the stretching continues, the neck may break and a newly originated oceanic crust is formed at this place. The rift system structure depends on the depth of the boundary surface between the brittle crust and the ductile crust, the litospheric thickness, the tension value, etc.. The rigid brittle rifting when narrow necks form in the lower crust is characteristic of the contemporary Earth; on Mars the brittle rifting with large subsidence was characteristic of the Tharsis upland formation epoch. The ductile rifting is typical of the Venus. The differences in rheologic features of the lithospheres of different planets causes the variation in types of rifting.

Nikishin, A. M.↗

NASA NTRS2003

Refinement of Protocols for Measuring the Apparent Optical Properties of Seawater

Ocean color satellite missions, like the Sea-viewing Wide Field-of-view Sensor (SeaWiFS) or the Moderate Resolution Imaging Spectroradiometer (MODIS) projects, are tasked with acquiring a global ocean color data set, validating and monitoring the accuracy and quality of the data, processing the radiometric data into geophysical units using a set of atmospheric and bio-optical algorithms, and distributing the final products to the scientific community. The long-standing requirement of the SeaWiFS Project, for example, is to produce spectral water-leaving radiances, LW(lambda), to within 5% absolute (lambda denotes wavelength) and chlorophyll a concentrations to within 35% (Hooker and Esaias 1993), and most ocean color sensors have the same or similar requirements. Although a diverse set of activities are required to ensure the accuracy requirements are met (Hooker and McClain 2000), the perspective here is with field observations. The accurate determination of upper ocean apparent optical properties (AOPs) is essential for the vicarious calibration of ocean color data and the validation of the derived data products, because the sea-truth measurements are used to evaluate the satellite observations (Hooker and McClain 2000). The uncertainties with in situ AOP measurements have various sources: a) the sampling procedures used in the field, including the environmental conditions encountered; b) the absolute characterization of the radiometers in the laboratory; c) the conversion of the light signals to geophysical units in a processing scheme, and d) the stability of the radiometers in the harsh environment they are subjected to during transport and use. Assuming ideal environmental conditions, so this aspect can be neglected, the SeaWiFS ground-truth uncertainty budget can only be satisfied if each uncertainty is on the order of 1-2%, or what is generally referred to as 1% radiometry. In recent years, progress has been made in estimating the magnitude of some of these uncertainties and in defining procedures for minimizing them. For the SeaWiFS Project, the first step was to convene a workshop to draft the SeaWiFS Ocean Optics Protocols (hereafter referred to as the Protocols). The Protocols initially adhered to the Joint Global Ocean Flux Study (JGOFS) sampling procedures (JGOFS 1991) and defined the standards for optical measurements to be used in SeaWiFS calibration and validation activities (Mueller and Austin 1992). Over time, the Protocols were revised (Mueller and Austin 1995), and then recurringly updated on essentially an annual basis (Mueller 2000, 2002, and 2003) as part of the Sensor Inter-comparison and Merger for Biological and Interdisciplinary Oceanic Studies (SIMBIOS) project. 98

Hooker, Stanford B.↗

NASA NTRS1992

Transport and mixing processes in the lower troposphere over the ocean

Aircraft observations in the lower troposphere over the eastern Pacific Ocean in summer are examined. The free troposphere was found to have a distinctly nonuniform, layered structure. In maritime air the layers consist of partially mixed air from several sources: moist ozone-depleted boundary layer air; very dry air with high ozone content that probably originated in the middle or upper troposphere; and air with relatively low ozone and moderate, varying moisture content that probably represents residues of convective clouds that had formed over the ocean upstream of the research area. The subtropical high results in stably stratified, subsiding air, where discrete horizontal layers with differing flow velocities transport air over long distances with little vertical mixing.

Paluch, I. R.↗

NASA NTRS2013

Characteristics of Mesoscale Organization in WRF Simulations of Convection during TWP-ICE

Compared to satellite-derived heating profiles, the Goddard Institute for Space Studies general circulation model (GCM) convective heating is too deep and its stratiform upper-level heating is too weak. This deficiency highlights the need for GCMs to parameterize the mesoscale organization of convection. Cloud-resolving model simulations of convection near Darwin, Australia, in weak wind shear environments of different humidities are used to characterize mesoscale organization processes and to provide parameterization guidance. Downdraft cold pools appear to stimulate further deep convection both through their effect on eddy size and vertical velocity. Anomalously humid air surrounds updrafts, reducing the efficacy of entrainment. Recovery of cold pool properties to ambient conditions over 5-6 h proceeds differently over land and ocean. Over ocean increased surface fluxes restore the cold pool to prestorm conditions. Over land surface fluxes are suppressed in the cold pool region; temperature decreases and humidity increases, and both then remain nearly constant, while the undisturbed environment cools diurnally. The upper-troposphere stratiform rain region area lags convection by 5-6 h under humid active monsoon conditions but by only 1-2 h during drier break periods, suggesting that mesoscale organization is more readily sustained in a humid environment. Stratiform region hydrometeor mixing ratio lags convection by 0-2 h, suggesting that it is strongly influenced by detrainment from convective updrafts. Small stratiform region temperature anomalies suggest that a mesoscale updraft parameterization initialized with properties of buoyant detrained air and evolving to a balance between diabatic heating and adiabatic cooling might be a plausible approach for GCMs.

Del Genio, Anthony D.↗

NASA NTRS1994

Noble gas isotopes and halogens in volatile-rich inclusions in diamonds

Application of the (40)Ar-(39)Ar method and noble gas studies to diamonds has increased our understanding of their age relationships to the host kimberlite or lamproite, and of the source and composition of volatile-rich fluids in the upper mantle. The properties of diamond (inert, high mechanical strength and low gas diffusivities) means they are especially useful samples for studying gases trapped deep within the earth (less than 150 km) as they are unlikely to have undergone loss or exchange of entrapped material since formation. Volatile-rich fluids (H2O-CO2) are important agents for metasomatic processes in the upper mantle, and the noble gases and halogens preferentially partition into this phase leading to a strong geochemical coherence between these groups of elements. The abundances of the halogens in the major reservoirs of the Earth shows a marked progression from chlorine, concentrated in the oceans, through to iodine which, through its affinity to organic material, is concentrated mainly in sediments. Abundances in the upper mantle are low. This is particularly true for iodine which is of special interest in view of its potential significance as an indicator of sediment recycling and by way of its link to (129)Xe amomalies in the mantle through the low extinct isotope (129)I. Extensions of the (40)Ar-(39)Ar technique enable measurements of halogens and other elements (K, Ca, Ba, U) by production of noble gas isotopes from these species during neutron irradiation. Samples analyzed in this way include 15 coated stones from an unknown source in Zaire, 3 boarts from the Jwaneng and 1 boart from the Orapa kimberlites, both in Botswana.

Burgess, Raymond↗

NASA NTRS1994

Stratospheric/tropospheric exchange affecting the northern wetlands regions of Canada during summer 1990

The Arctic Boundary Layer Expedition (ABLE) 3B was conducted over the northern wetlands region of Canada during July and August 1990. Several stratospheric/tropospheric exchange events were noted by zenith-looking airborne lidar and in situ measurements of ozone and other trace gas species. Isentropic trajectories and potential vorticity analyses are utilized to determine the frequency of stratospheric inputs which would have affected the tropospheric column over the Moosonee and Schefferville regions and to describe the favored pathways of transport of stratospheric air arriving at these locations. At the 310 K potential temperature level (middle troposphere), trajectories having 'aged stratospheric' values of potential vorticity at some point in their 5-day history arrived at Moosonee or Schefferville roughly 40% of the time during the ABLE 3B study period, most often via large-scale subsidence enroute from 'stratospheric input regions' over the Arctic Ocean or northern and central Canada. At 325 K (upper troposphere), 'fresh' stratospheric input was evident on about 80% of the trajectories, most often associated with jet streaks within the polar and Arctic jet streams. A case study is presented which illustrates both of these general stratospheric input processes.

Bachmeier, A. Scott↗

NASA NTRS2008

Water Vapor Feedback and Links to Mechanisms of Recent Tropical Climate Variations

Recent variations of tropical climate on interannual to near-decadal scales have provided a useful target for studying feedback processes. A strong warm/cold ENSO couplet (e.g. 1997-2000) along with several subsequent weaker events are prominent interannual signals that are part of an apparent longer term strengthening of the Walker circulation during the mid to late1990 s with some weakening thereafter. Decadal scale changes in tropical SST structure during the 1990s are accompanied by focusing of precipitation over the Indo-Pacific warm pool and an increase in tropical ocean evaporation of order 1.0 %/decade. Here we use a number of diverse satellite measurements to explore connections between upper-tropospheric humidity (UTH) variations on these time scales and changes in other water and energy fluxes. Precipitation (GPCP, TRMM), turbulent fluxes (OAFlux), and radiative fluxes (ERBE / CERES, SRB) are use to analyze vertically-integrated divergence of moist static energy, divMSE, and its dry and moist components. Strong signatures of MSE flux transport linking ascending and descending regions of tropical circulations are found. Relative strengths of these transports compared to radiative flux changes are interpreted as a measure of efficiency in the overall process of heat rejection during episodes of warm or cold SST forcing. In conjunction with the diagnosed energy transports we explore frequency distributions of upper-tropospheric humidity as inferred from SSM/T-2 and AMSU-B passive microwave measurements. Relating these variations to SST changes suggests positive water vapor feedback, but at a level reduced from constant relative humidity.

Robertson, F. R.↗

DOE OSTI2022

Metamorphism-facilitated faulting in deforming orthopyroxene: Implications for global intermediate-depth seismicity

Significance The exothermic metamorphic reaction in orthopyroxene (Opx), a major component of oceanic lithospheric mantle, is shown to trigger brittle failure in laboratory deformation experiments under conditions where garnet exsolution takes place. The reaction product is an extremely fine-grained material, forming narrow reaction zones that are mechanically weak, thereby facilitating macroscopic faulting. Oceanic subduction zones are characterized by two separate bands of seismicity, known as the double seismic zone. The upper band of seismicity, located in the oceanic crust, is well explained by dehydration-induced mechanical instability. Our newly discovered metamorphism-induced mechanical instability provides an alternative physical mechanism for earthquakes in the lower band of seismicity (located in the oceanic lithospheric mantle), with no requirement of hydration/dehydration processes.

58 GEOSCIENCES↗

DOE OSTI2023

Stronger Tropical Cyclone–Induced Ocean Cooling in Near-Coastal Regions Compared to the Open Ocean

Abstract Tropical cyclones (TC) often induce strong mixing in the upper ocean that generates a trail of cooler sea surface temperature (Twake) in their wakes. The Twake can affect TC intensity, so its prediction is important, especially in coastal regions where TCs can make landfall. Coastal Twakes are often more complex than those in the open ocean due to the influences of coastline geometry, highly variable water depth, continental runoff, and shelf processes. Using observational data since 2002, here we show a significantly stronger global mean Twake in coastal regions compared to offshore regions. Temperature stratification is the main driver of stronger coastal Twakes in the North Atlantic and east Pacific. In the northwest Pacific and north Indian Ocean, the differences between coastal and offshore Twakes are smaller due to compensation between TC forcings and ocean stratification. The north Indian Ocean is unique in the Northern Hemisphere because salinity stratification plays a major role on the spatial distribution of Twake. In the South Pacific Ocean, TC intensity and translation speed are crucial for explaining coastal–offshore Twake differences, while ocean stratification and mixed layer depth are more important for the coastal–offshore Twake differences in the south Indian Ocean. These findings suggest that coastal–offshore differences in ocean stratification need to be properly represented in models in order to capture changes in TC-induced ocean cooling as storms approach landfall. Significance Statement Landfalling tropical cyclones (TCs) often cause considerable damage in coastal regions with dense human populations. Understanding TC–ocean interaction and how it differs between coastal and offshore regions can help predict TC intensity prior to landfall. Sea surface cooling after TC passage is an important proxy for TC–ocean interaction. A global evaluation of coastal TC-induced cooling has not been conducted. Using data covering two decades, we show significantly stronger TC-induced surface cooling in coastal regions compared to offshore regions at the global scale and in all basins except the northwest Pacific and north Indian Ocean. The difference is driven mainly by upper-ocean conditions in the North Atlantic, east Pacific, and south Indian Ocean, and by TC characteristics in the South Pacific.

54 ENVIRONMENTAL SCIENCES↗

NASA NTRS1984

Numerical Prediction of the President's Day Cyclone

Numerical-diagnostic studies of major anomalous weather events are being conducted in order to investigate the relevant physical processes associated with the events and the role of satellite observing systems in the analysis and prediction of these phenomena. One component of this study is concerned with the numerical prediction of intense coastal and oceanic cyclogenesis. The specific objectives of this research are: (1) to assess the accuracy of Goddard Laboratory for Atmospheric Sciences model predictions of cyclogenesis, (2) to determine the importance of large scale dynamical processes and diabatic heating to the prediction, and (3) to evaluate the sensitivity of the model predictions to the initial conditions. It was shown that diabatic heating resulting from oceanic fluxes significantly contributed to the generation of low level cyclonic vorticity and the intensification and slow rate movement of an upper level ridge over the western Atlantic. As an upper level short-wave trough approached this ridge, diabatic heating associated with the release of latent heat intensified, and the gradient of vorticity, vorticity advection, upper level divergence, and upward vertical motion in advance of the trough were greatly increased, providing strong large-scale forcing for the surface cyclogenesis.

Atlas, R.↗

NASA NTRS2003

An Examination of Issues Related to a Europa Subsurface Component for the JIMO Mission

The Galileo Europa data set served to revolutionize our view of Europa. In particular the strong evidence of a large, cold, salty Ocean beneath 5-30 km of ice has profoundly altered the significance of Europa in our thinking, especially of context of habitability in the solar system. While much remains to be learned from spacecraft observations of several sorts, there are significant questions answerable only by in-situ techniques; these relate to the formation of Europa, the nature of its ocean, and the prospects for life in its ocean, sediments, and ice. We feel that wide-ranging discussion of an in-situ subsurface mission to Europa, as part of JIMO, should proceed. The science objective of the mission is to characterize the icy shell of Europa to resolve its provenance, estimate the composition of brine of the Europa ocean, and search for evidence of Earth-like life. Probably anyone would agree that an in-situ mission to Europa would be of great value, but he or she would also immediately take the position that such a mission is utterly impractical. We take the position here of defining the least complex mission that can nonetheless justify its cost and to argue that such a mission is realistic enough that it should be seriously considered. Our mission thinking has been: 1) Soft landing. A soft lander is required on a site sufficiently flat to offer a stable platform; no further site selectivity is required. 2) Subsurface exploration. The Europa subsurface must be examined. Surficial processes on Europa arguably have exposed the upper 200 m of shell to chemical effects from the Jovian radiation belts as well as cometary infall, etc; to examine native ice we must descend below that point to, for discussion, 300 m. At that depth we argue that the ice is characteristic of ice at depth and possibly is effectively sea ice. 3) Science data. A few simple measurements at various depths and at 300 m constitute a scientifically successful mission. Measurements would include analysis of meltwater for a few inorganic ions and amino acids and an optical examination of the borehole wall. 4) Communication. Transmission of data to an orbiter is essential, but we will constrain the landed mission to a daily communication over a few days. 5) Subsurface access. Drilling to 300 m is a significant challenge; it can be addressed by several means: Thermal Probe (Cryobot) which permits water to refreeze above the vehicle. This is our tentative choice with plutonium as the fuel to generate thermal energy for drilling and electrical power for operations. Open Hole Drill, a thermal system in which the meltwater is removed for greater thermal efficiency. Meltwater removal on Europa is both a complexity and a risk, but analysis is improved. Mechanical Drilling in which cutting or grinding generates ice chips which are removed. This is too complex at Europa temperatures. The measurement objectives for the mission will be: Obj. 1: Determine the concentration of simple inorganic salts in the Europa Ice Shell and, by extrapolation, of the ocean. These data will also validate spaceborne sensors. Obj. 2: Determine the nature and abundance of amino acids in the ice such that cometary infall material in the upper ice can be compared to material at depth. Obj. 3: Optically examine the ice to resolve inclusion structure, particulate content, and stratification. Access to 300 m depth is a significant if not audacious plan; we are aware that this has not been done on any planetary body. Our approach is the use of a plutonium heat source; to overcome Europa's surface temperature and to melt ice a significant amount of plutonium is needed, and significant shielding and other protective steps will be required. The quantity of plutonium is a key concern. The mission will require subsurface collection and processing of samples for in situ analysis, calling for a miniature, high pressure micro-sampling system designed to meet needs of instruments that require low presses for operation. The inlet system itself collects a micro-sample in the external high pressure environment, then transfers it into a protected low pressure environment for analysis.

Carsey, F. D.↗

NASA NTRS1997

Global Troposphere Experiment Project

For the Global Troposphere Experiment project Pacific Exploratory Measurements West B (PEM West B), we made determinations of sulfur dioxide (SO2) and dimethyl sulfide (DMS) using gas chromatography-mass spectrometry with isotopically labelled internal standards. This technique provides measurements with precision of 1 part-per-trillion by volume below 20 pptv and 1% above 20 pptv. Measurement of DMS and SO2 were performed with a time cycle of 5-6 minutes with intermittent zero checks. The detection limits were about 1 pptv for SO2 and 2 pptv for DMS. Over 700 measurements of each compound were made in flight. Volcanic impacts on the upper troposphere were again found as a result of deep convection in the tropics. Extensive emission of SO2 from the Pacific Rim land masses were primarily observed in the lower well-mixed part of the boundary layer but also in the upper part of the boundary layer. Analyses of the SO2 data with aerosol sulfate, beryllium-7, and lead-210 indicated that SO2, contributed to half or more of the observed total oxidized sulfur (SO2 plus aerosol sulfate) in free tropospheric air. Cloud processing and rain appeared to be responsible for lower SO2 levels between 3 and 8.5 km than above or below this region. During both phases of PEM-West, dimethyl sulfide did not appear to be a major source of sulfur dioxide in the upper free troposphere over the western Pacific Ocean. In 1991 the sources Of SO2 at high altitude appeared to be both anthropogenic and volcanic with an estimated 1% being solely from DMS. The primary difference for the increase in the DMS source was the very low concentration of SO2 at high altitude. In the midlatitude region near the Asian land masses, DMS in the mixed layer was lower than in the tropical region of the western Pacific. Convective cloud systems near volcanoes in the tropical convergence in the western Pacific troposphere were a major source of SO2 at high altitudes during PEM-West B. High levels of SO2 were observed in several instances with large number concentrations of ultrafine CN above 9 km in the tropical convergence zone. Conversion of SO2, by OH to SO3 and subsequently to sulfuric acid may have been enhanced by lightning-produced NO levels exceeding 1 part per billion. Coupling of strong convection and volcanic sources of SO2 apparently is an important source of new particle formation at high altitude in the tropical convergence zone.

Bandy, Alan R.↗

DOE OSTI2024

Dataset for scientific paper "Simulated plant‑mediated oxygen input has strong impacts on fine‑scale porewater biogeochemistry and weak impacts on integrated methane fluxes in coastal wetlands", a modeling study based on field observation at the tidal salt marshes of the Parker River Estuary, Massachusetts, United States

This dataset is the raw and processed data for the paper "Simulated plant ‑ mediated oxygen input has strong impacts on fine ‑ scale porewater biogeochemistry and weak impacts on integrated methane fluxes in coastal wetlands". This study investigated how plant-mediated oxygen input affects subsurface biogeochemical reactions of organic carbon degradation and the resulting methane emissions of coastal wetlands by model simulation. We used the subsurface geochemical simulator PFLOTRAN for the modeling, which produced the simulated changes in porewater chemical substances and methane emissions over 10 days under different scenarios of plant-mediated oxygen input.Specifically, this dataset contains: 1) the input files for PFLOTRAN of all simulation runs conducted in this study. Those files are with an extension of ".in", containing information of the biogeochemical reaction network (stoichiometry, reaction rate, Monod constants, etc), fluid flow rate and oxygen concentration in the fluid which together simulated the plant-mediated oxygen input, the configuration of artificial reactions that simulated the methane fluxes, etc. The PFLOTRAN input files are text files, which can be opened by NotePad, but running these input files will require proper installation of PFLOTRAN (instruction: https://documentation.pflotran.org/user_guide/how_to/installation/installation.html). 2) the raw and processed model output from PFLOTRAN of all simulation runs, and 3) the python scripts used to process the raw model output, including random allocation of root cells, converting raw data into organized formats, calculating the methane fluxes based on the model output, data visualization, etc. The raw and processed model output from PFLOTRAN are in .spydata format, which can be viewed with Python. and 3) the python scripts for data processing and analysis are programming scripts, which can be opened with Python.This modeling work, in particular the model parameterization of root density and initial conditions of porewater concentrations of biogeochemical substances, was based on field measurements at the salt marsh of the Upper Parker River Estuary, Massachusetts, United States.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2025

Advancing ocean monitoring and knowledge for societal benefit: the urgency to expand Argo to OneArgo by 2030

The ocean plays an essential role in regulating Earth’s climate, influencing weather conditions, providing sustenance for large populations, moderating anthropogenic climate change, encompassing massive biodiversity, and sustaining the global economy. Human activities are changing the oceans, stressing ocean health, threatening the critical services the ocean provides to society, with significant consequences for human well-being and safety, and economic prosperity. Effective and sustainable monitoring of the physical, biogeochemical state and ecosystem structure of the ocean, to enable climate adaptation, carbon management and sustainable marine resource management is urgently needed. The Argo program, a cornerstone of the Global Ocean Observing System (GOOS), has revolutionized ocean observation by providing real-time, freely accessible global temperature and salinity data of the upper 2,000m of the ocean (Core Argo) using cost-effective simple robotics. For the past 25 years, Argo data have underpinned many ocean, climate and weather forecasting services, playing a fundamental role in safeguarding goods and lives. Argo data have enabled clearer assessments of ocean warming, sea level change and underlying driving processes, as well as scientific breakthroughs while supporting public awareness and education. Building on Argo’s success, OneArgo aims to greatly expand Argo’s capabilities by 2030, expanding to full-ocean depth, collecting biogeochemical parameters, and observing the rapidly changing polar regions. Providing a synergistic subsurface and global extension to several key space-based Earth Observation missions and GOOS components, OneArgo will enable biogeochemical and ecosystem forecasting and new long-term climate predictions for which the deep ocean is a key component. Driving forward a revolution in our understanding of marine ecosystems and the poorly-measured polar and deep oceans, OneArgo will be instrumental to assess sea level change, ocean carbon fluxes, acidification and deoxygenation. Emerging OneArgo applications include new views of ocean mixing, ocean bathymetry and sediment transport, and ecosystem resilience assessment. Implementing OneArgo requires about $100 million annually, a significant increase compared to present Argo funding. OneArgo is a strategic and cost-effective investment which will provide decision-makers, in both government and industry, with the critical knowledge needed to navigate the present and future environmental challenges, and safeguard both the ocean and human wellbeing for generations to come.

ARGO↗