Results for “waste reduction” — Page 7

DOE OSTI2025

Electrocatalytic Reductive Amination of Aldehydes and Ketones with Aqueous Nitrite

The electrocatalytic utilization of oxidized nitrogen waste for C–N coupling chemistry is an exciting research area with great potential to be adopted as a sustainable method for generation of organonitrogen molecules. The most widely used C–N coupling reaction is reductive amination. In this work, we develop an alternative electrochemical reductive amination reaction that can proceed in neutral aqueous electrolyte with nitrite as the nitrogenous reactant and via an oxime intermediate. We develop a selection criterion for nitrite reduction electrocatalysts suited for oxime electrosynthesis and, in doing so, find Pd to be a highly efficient catalyst for this reaction, reaching an oxime Faradaic efficiency of 82% at −0.21 V vs the reversible hydrogen electrode. The aliphatic or aromatic structure of the carbonyl reactant impacts the efficacy of the catalyst, with aromatic substrates leading to suppressed oxime formation and detrimental reduction of the carbonyl to the alcohol. We developed a Pb/PbO electrocatalyst that selectively performs oxime reduction in the neutral aqueous electrolyte. With acetone as a model substrate, we demonstrate an efficient one-pot, two-step electrochemical reaction for the conversion of acetone to isopropyl amine with 85% yield and 50% global Faradaic efficiency.

catalysts↗

NASA NTRS2013

Analysis of Water Recovery Rate from the Heat Melt Compactor

Human space missions generate trash with a substantial amount of plastic (20% or greater by mass). The trash also contains water trapped in food residue and paper products and other trash items. The Heat Melt Compactor (HMC) under development by NASA Ames Research Center (ARC) compresses the waste, dries it to recover water and melts the plastic to encapsulate the compressed trash. The resulting waste disk or puck represents an approximately ten-fold reduction in the volume of the initial trash loaded into the HMC. In the current design concept being pursued, the trash is compressed by a piston after it is loaded into the trash chamber. The piston face, the side walls of the waste processing chamber and the end surface in contact with the waste can be heated to evaporate the water and to melt the plastic. Water is recovered by the HMC in two phases. The first is a pre-process compaction without heat or with the heaters initially turned on but before the waste heats up. Tests have shown that during this step some liquid water may be expelled from the chamber. This water is believed to be free water (i.e., not bound with or absorbed in other waste constituents) that is present in the trash. This phase is herein termed Phase A of the water recovery process. During HMC operations, it is desired that liquid water recovery in Phase A be eliminated or minimized so that water-vapor processing equipment (e.g., condensers) downstream of the HMC are not fouled by liquid water and its constituents (i.e., suspended or dissolved matter) exiting the HMC. The primary water recovery process takes place next where the trash is further compacted while the heated surfaces reach their set temperatures for this step. This step will be referred to herein as Phase B of the water recovery process. During this step the waste chamber may be exposed to different selected pressures such as ambient, low pressure (e.g., 0.2 atm), or vacuum. The objective for this step is to remove both bound and any remaining free water in the trash by evaporation. The temperature settings of the heated surfaces are usually kept above the saturation temperature of water but below the melting temperature of the plastic in the waste during this step to avoid any encapsulation of wet trash which would reduce the amount of recovered water by blocking the vapor escape. In this paper, we analyze the water recovery rate during Phase B where the trash is heated and water leaves the waste chamber as vapor, for operation of the HMC in reduced gravity. We pursue a quasi-one-dimensional model with and without sidewall heating to determine the water recovery rate and the trash drying time. The influences of the trash thermal properties, the amount of water loading, and the distribution of the water in the trash on the water recovery rates are determined.

Heat Melt Compactor↗

NASA NTRS2018

Improving Logistics and Waste Management for Deep Space Human Exploration

NASA's Advanced Exploration Systems Logistics Reduction Project is developing technologies that reduce mission mass and volume for exploration. Recently there has been increasing interest in determining the quantity of consumable logistics and system spares necessary to ensure a certain level of reliability. This is influenced by a technology's criticality and degree of impact to the overall mission. Technologies that directly reduce mass (e.g. longer wear crew clothing) are relatively straightforward for calculating the savings and understanding the mission impacts. Waste management technologies that process waste can reduce mass, but spares and contingency modes are more interwoven with other vehicle systems, so assessment is more complex. This paper considers mission benefits while also considering impacts from hardware failures for technologies including: crew clothing, reusable cargo bags for habitat outfitting, automated RFID cargo tracking, trash processing/storage/repurposing, and high reliability toilets.

Broyan, James Lee, Jr.↗

NASA NTRSDate not supplied

Advancements in Logistics Reduction for Exploration Missions

Management of logistics on exploration missions includes both looking for ways to minimize the quantities, mass and volume of various consumables, supplies, spares and equipment as well as ways to minimize the crew time needed for locating and handling those items. Also included are ways to minimize the waste, handling and resultant products from the processes of maintaining a crew on these missions. The Logistics Reduction project encompasses technologies for management of waste, trash, autonomous logistics, and clothing. This paper provides a status of work in these areas including recent accomplishments and challenges encountered. Future objectives will also be covered along with the work currently in progress. Specifically, the paper will cover technologies in waste management, namely, the Universal Waste Management System (UWMS) or exploration toilet and work on an alternative waste collection container, the Alternate Fecal Canister. Trash management technologies work on the Trash Compaction and Processing System (TCPS) and Trash to Gas (TtG) is summarized with progress to date as well as information on how Jettison as an option is related. Progress and summary of recent accomplishment on the RFID (Radio Frequency ID) Enabled Autonomous Logistics Management (REALM) and the Autonomous Logistics (AL) technologies is detailed. Advanced Clothing System (ACS) and work in the area of Systems Engineering and Integration (SE&I) is also included. Status of the technologies, accomplishments and how the focus areas inform program decisions will be addressed.

human spaceflight↗

NASA NTRSDate not supplied

Advancements in Logistics Reduction Technologies for Exploration Missions

Management of logistics on exploration missions includes both looking for ways to minimize the quantities, mass and volume of various consumables, supplies, spares and equipment as well as ways to minimize the crew time needed for locating and handling those items. Also included are ways to minimize the waste, handling and resultant products from the processes of maintaining a crew on these missions. The Logistics Reduction project encompasses technologies for management of waste, trash, autonomous logistics, and clothing. This paper provides a status of work in these areas including recent accomplishments and challenges encountered. Future objectives will also be covered along with the work currently in progress. Specifically, the paper will cover technologies in waste management, namely, the Universal Waste Management System (UWMS) or exploration toilet and work on an alternative waste collection container, the Alternate Fecal Canister. Trash management technologies work on the Trash Compaction and Processing System (TCPS) and Trash to Gas (TtG) is summarized with progress to date as well as information on how Jettison as an option is related. Progress and summary of recent accomplishment on the RFID (Radio Frequency ID) Enabled Autonomous Logistics Management (REALM) and the Autonomous Logistics (AL) technologies is detailed. Advanced Clothing System (ACS) and work in the area of Systems Engineering and Integration (SE&I) is also included. Status of the technologies, accomplishments and how the focus areas inform program decisions will be addressed.

human spaceflight↗

NASA NTRSDate not supplied

Microbial Characterization of Heat Melt Compaction for Treatment of Space Generated Solid Wastes

One treatment process in development for solid waste management in space has been the Trash Compaction Processing System (TCPS). Human space mission wastes typically contain large percentages of contaminated wet solid waste. The Heat Melt Compactor (HMC) is being developed to be a multi-function means of water recovery, volume reduction, and the making safe of contaminant-rich trash with the potential for waste stabilization and/or sterilization. To determine the efficacy of the HMC treatment to kill microorganisms in solid waste and remain biologically stable, testing was conducted on three tiles produced by HMC-Gen 2 at Ames Research Center. Samples were shipped to Kennedy Space Center to test for microbial viability after compaction, determine the bio-stability of the HMC disks during storage (43 days), and assess potential airborne contaminate microbial growth on surfaces at low and high humidity conditions. In addition to the products of solid waste processing technologies, there is a concern that the crew might come into contact with hardware surfaces that have been contaminated by microorganisms during waste processing. The extent of microbial surface contamination of waste processing hardware was determined by surface sample swabbing and analysis for total bacterial and yeast counts and cultivable counts of aerobic and anaerobic bacteria, spore-forming bacteria, and fungi. Results indicate that trash processing increased bacterial counts on the surfaces of the compacter. All but one biological indicator spore strip imbedded in the HMC produced tiles were negative for growth after incubation for five days indicating effective sterilization through the heat melt compaction process. Analysis of core samples as well as surface growth of tiles inoculated with Aspergillus niger fungal spores incubated at three levels of humidity indicate that HMC created tiles did not support the proliferation of bacterial and fungal growth.

Mary E Hummerick↗

NASA NTRSDate not supplied

Logistics Reduction Advancements and Future Plans for NASA's Exploration Missions

Management of logistics on exploration missions includes both looking for ways to minimize the quantities, mass and volume of various consumables, supplies, spares, and equipment as well as ways to minimize the crew time needed for locating and handling those items. Also included are ways to minimize the waste, handling, and resultant products from the processes of maintaining a crew on these missions. The Logistics Reduction project encompasses technologies for management of waste, trash, autonomous logistics, and clothing. This paper provides a status of work from 2023 in these areas including recent accomplishments and challenges encountered. Future objectives and plans for 2024 will also be covered along with the work currently in progress. Specifically, the paper will cover technologies in waste management, namely, the Universal Waste Management System (UWMS) or exploration toilet and work on an alternative waste collection container, the Alternate Fecal Canister. Trash management technologies work on the Trash Compaction Processing System (TCPS) and Trash to Gas (TtG) is summarized with progress to date as well as information on how Jettison as an option is related. Progress and summary of recent accomplishment on the RFID (Radio Frequency ID) Enabled Autonomous Logistics Management (REALM) and the Autonomous Logistics (AL) technologies is detailed. Advanced Clothing System (ACS) and work in the area of Systems Engineering and Integration (SE&I) is also included. Status of the technologies, accomplishments and how the focus areas inform program decisions will be addressed.

Toilet↗

NASA NTRSDate not supplied

Logistics Reduction Advancements and Future Plans for NASA's Exploration Missions

Management of logistics on exploration missions includes both looking for ways to minimize the quantities, mass and volume of various consumables, supplies, spares, and equipment as well as ways to minimize the crew time needed for locating and handling those items. Also included are ways to minimize the waste, handling, and resultant products from the processes of maintaining a crew on these missions. The Logistics Reduction project encompasses technologies for management of waste, trash, autonomous logistics, and clothing. This paper provides a status of work from 2023 in these areas including recent accomplishments and challenges encountered. Future objectives and plans for 2024 will also be covered along with the work currently in progress. Specifically, the paper will cover technologies in waste management, namely, the Universal Waste Management System (UWMS) or exploration toilet and work on an alternative waste collection container, the Alternate Fecal Canister. Trash management technologies work on the Trash Compaction Processing System (TCPS) and Trash to Gas (TtG) is summarized with progress to date as well as information on how Jettison as an option is related. Progress and summary of recent accomplishment on the RFID (Radio Frequency ID) Enabled Autonomous Logistics Management (REALM) and the Autonomous Logistics (AL) technologies is detailed. Advanced Clothing System (ACS) and work in the area of Systems Engineering and Integration (SE&I) is also included. Status of the technologies, accomplishments and how the focus areas inform program decisions will be addressed.

Toilet↗

NASA NTRS2024

Logistics Reduction Advancements and Future Plans for NASA's Exploration Missions

Management of logistics on exploration missions includes both looking for ways to minimize the quantities, mass and volume of various consumables, supplies, spares, and equipment as well as ways to minimize the crew time needed for locating and handling those items. Also included are ways to minimize the waste, handling, and resultant products from the processes of maintaining a crew on these missions. The Logistics Reduction project encompasses technologies for management of waste, trash, autonomous logistics, and clothing. This paper provides a status of work from 2023 in these areas including recent accomplishments and challenges encountered. Future objectives and plans for 2024 will also be covered along with the work currently in progress. Specifically, the paper will cover technologies in waste management, namely, the Universal Waste Management System (UWMS) or exploration toilet and work on an alternative waste collection container, the Alternate Fecal Canister. Trash management technologies work on the Trash Compaction Processing System (TCPS) and Trash to Gas (TtG) is summarized with progress to date as well as information on how Jettison as an option is related. Progress and summary of recent accomplishment on the RFID (Radio Frequency ID) Enabled Autonomous Logistics Management (REALM) and the Autonomous Logistics (AL) technologies is detailed. Advanced Clothing System (ACS) and work in the area of Systems Engineering and Integration (SE&I) is also included. Status of the technologies, accomplishments and how the focus areas inform program decisions will be addressed.

Toilet↗

NASA NTRS2016

Advanced Technologies to Improve Closure of Life Support Systems

As NASA looks beyond the International Space Station toward long-duration, deep space missions away from Earth, the current practice of supplying consumables and spares will not be practical nor affordable. New approaches are sought for life support and habitation systems that will reduce dependency on Earth and increase mission sustainability. To reduce launch mass, further closure of Environmental Control and Life Support Systems (ECLSS) beyond the current capability of the ISS will be required. Areas of particular interest include achieving higher degrees of recycling within Atmosphere Revitalization, Water Recovery and Waste Management Systems. NASA is currently investigating advanced carbon dioxide reduction processes that surpass the level of oxygen recovery available from the Sabatier Carbon Dioxide Reduction Assembly (CRA) on the ISS. Candidate technologies will potentially improve the recovery of oxygen from about 50% (for the CRA) to as much as 100% for technologies who's end product is solid carbon. Improving the efficiency of water recycling and recovery can be achieved by the addition of advanced technologies to recover water from brines and solid wastes. Bioregenerative technologies may be utilized for water reclaimation and also for the production of food. Use of higher plants will simultaneously benefit atmosphere revitalization and water recovery through photosynthesis and transpiration. The level at which bioregenerative technologies are utilized will depend on their comparative requirements for spacecraft resources including mass, power, volume, heat rejection, crew time and reliability. Planetary protection requirements will need to be considered for missions to other solar system bodies.

Barta, Daniel J.↗

DOE OSTI2024

Cesium Removal from Surrogate Pyroprocessing Salt by Electrodeposition

Active metals in used nuclear fuel dissolve into the salt during pyroprocessing and are not removed by electrorefining or drawdown operations. The buildup of 137 Cs over time increases the heat load and ionizing radiation level of the salt such that it must be replaced frequently, resulting in a significant amount of salt waste. An effective means of managing cesium in the molten salt electrolyte would increase the efficiency of pyroprocessing and decrease the volume of salt waste requiring disposal. A previous report summarized issues that must be addressed when developing a removal strategy and assessed the suitability of existing methods and remaining technological gaps to their application (Rose and Thomas 2023). Cesium is extremely stable in molten salt as a chloride—even more stable than the LiCl-KCl eutectic base salt used for pyroprocessing fuel—which makes removing cesium a challenge. However, sufficiently strong atomic interactions occur between active metal species and liquid metals that make the electrodeposition of active metal fission products into liquid metal electrodes energetically favorable. The feasibility of recovering cesium from LiCl-KCl pyroprocessing salt through electrodeposition into liquid metals is eing assessed by identifying potentially effective liquid metals and performing tests to determine the effectiveness of electrodepositing cesium from a LiCl/KCl salt into these liquid metals. Previous studies investigating the electrodeposition of Sr 2+ , and Ba 2+ into zinc, cadmium, bismuth, lead, tin and antimony have shown that alkali and alkaline earth metals can be electrodeposited at liquid metal cathodes (Kim et al., 2018). The removal of Ba 2+ and Sr 2+ was measured to be more efficient than the removal of monovalent cations due to the greater thermochemical driving force for alloying those elements with the liquid metal (Jang et al. 2022). Because the equilibrium potentials are dependent on the interactions of the active metal in the liquid metal, it is likely that the other alkali metals Li + , and K + , will deposit from LiCl/KCl salt with the Cs + . Therefore, application of this method to recover active metals from pyroprocessing salt will benefit from the use of a liquid metal and set of operating conditions that sufficiently increase the reduction potential of cesium to remove cesium from the waste salt with an acceptable amount of co-deposited lithium and potassium.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

DOE OSTI2025

Techno-economic and life cycle analysis of bio-hydrogen production using bio-based waste streams through the integration of dark fermentation and microbial electrolysis

Hydrogen derived from bio-based sources, or biohydrogen (bioH 2 ), has the potential to reduce GHG emissions from industrial and transportation sectors, owing to the low carbon footprint and myriad applications like refinery operation, ammonia production, steel production, fuel cell, etc. To evaluate the commercialization potential of bioH 2 production, we modeled bioH 2 production and conducted techno-economic analysis (TEA) and life cycle analysis (LCA) of two facilities producing 50 metric tonnes of bioH 2 per day from cheese whey (CW) and solid food waste (SFW) through the integration of dark fermentation (DF) and microbial electrolysis cell (MEC) technologies. LCA results showed that CW and SFW can produce carbon-negative bioH 2 , with emissions of −8.6 and −8.0 kg GHG kg −1 bioH 2 with carbon sequestration and renewable electricity resources, respectively, making bioH 2 potentially eligible for a tax credit of $\$3$ kg −1 H 2 based on provision 45 V of the U.S. Inflation Reduction Act (IRA). In this study, bioH 2 production treats waste streams to generate fresh water, thus, potentially can receive waste water treatment fee that varies with regions. The MEC capital cost dominates the bioH 2 cost, which is mainly determined by current density. With a current density of 20 A m −2 , the production cost for CW input varied between $\$17$ and $\$24$ kg −1 bioH 2 , while that for SFW input ranged from $\$29$ to $\$30$ kg −1 bioH 2 under different operating conditions, considering the 45 V tax credit, waste water treatment fee and production revenue. If the current density increases to 100 A m −2 , the bioH 2 cost decreases to a range of $\$4.0$–$\$6.9$ for CW and $\$5$–$\$6$ for SFW scenarios. This study also shows that low-cost bioH 2 can be produced using CW waste stream as feedstock.

Ganguly, Arna [Argonne National Laboratory (ANL), ↗

NASA NTRS1977

Development and testing of a wet oxidation waste processing system

The wet oxidation process is considered as a potential treatment method for wastes aboard manned spacecraft for these reasons: (1) Fecal and urine wastes are processed to sterile water and CO2 gas. However, the water requires post-treatment to remove salts and odor; (2) the residual ash is negligible in quantity, sterile and easily collected; and (3) the product CO2 gas can be processed through a reduction step to aid in material balance if needed. Reaction of waste materials with oxygen at elevated temperature and pressure also produces some nitrous oxide, as well as trace amounts of a few other gases.

Weitzmann, A. L.↗

DOE OSTI2025

Life Cycle Assessment of Methanol from Fossil, Biomass, and Waste Sources, and Its Use as a Marine Fuel in Dual-Fuel Engines

Methanol is gaining interest in the marine sector from energy security and reducing emissions perspective. This study provides a comparative life cycle assessment of methanol as a marine fuel, across GHG and criteria air pollutant emission metrics, when it is used in a dual-fuel engine. Twelve methanol pathways from four different feedstock categories were considered, including (1) cellulosic biomass forest residues and clean pine mix, corn stover, switchgrass, and miscanthus; (2) organic wastes renewable natural gas from wastewater sludge, swine manure, food waste, and landfill gas; (3) fossil resources coal and natural gas (NG); and (4) e-methanol using captured carbon dioxide. When used in a dual-fuel engine with pilot fuel, life cycle GHG emissions for woody biomass-based methanol were approximately 19 gCO 2 e MJ −1 , while emissions from waste-based sources ranged between −154 and 31 gCO 2 e MJ −1 . Methanol from renewable sources showed a GHG reduction potential between 58 and 226% compared to conventional NG-based methanol (122 gCO 2 e MJ −1 ), primarily due to the avoided emissions from conventional waste management. When carbon from process emissions were captured, the reduction could be up to 327%. All pathways exhibited lower NO X , and particulate matter emissions compared to the baseline marine fuel (MGO 0.1% sulfur), while woody biomass and coal pathways had higher SO X emissions.

09 BIOMASS FUELS↗

DOE OSTI2024

Design of Hypothetical Processes for the Production of 131 I and 99 Mo from Activation Targets

For over six decades, medical isotope production has been a high-priority focus of many research reactors across the globe. The majority of these isotopes were produced using highly-enriched uranium (HEU) or low enriched uranium (LEU) – delivering millions of doses of diagnostic and therapeutic isotopes. As a consequence of this production, however, six decades of isotope production has resulted in massive quantities of spent uranium material worldwide with no known disposition pathway creating growing proliferation concerns. Supported by the National Nuclear Security Administration’s (NNSA) Material Management and Minimization (M3) program, there has been increased focus in the production of high-priority isotopes without special nuclear materials or without uranium altogether. Isotope production via activation can potentially fulfill regional isotope demands – particularly in under-developed regions without access to isotope supply chains. The benefits of this approach would be a reduction in uranium proliferation risks, less special nuclear material wastes, and reduced risk of supply disruption in the likely event that major isotope producers will again go off-line as has happened in recent years due to a number of factors.

07 ISOTOPE AND RADIATION SOURCES↗

NASA NTRS1987

Effects of hypokinesia and hypodynamia upon protein turnover in hindlimb muscles of the rat

Hypokinesia/hypodynamia was induced in the hindlimb muscles of the rat, using a suspension technique. This caused differing degrees of atrophy in different muscles. However, this atrophy was reduced in muscles held in a lenghthened position. The greatest degree of wasting was observed in the unstretched soleus, a slow postural muscle, where both Type 1 and Type 2a fibers atrophied to the same degree. However, wasting of the gastrocnemius muscle was associated with a reduction in the size of the Type 2b fibers. In both slow-postural and fast-phasic hindlimb muscles, atrophy was brought about by a reduction in the rate of protein synthesis in conjunction with an elevation in the rate of protein degradation. When inactive muscles were passively stretched, both protein synthesis and degradation were dramatically elevated. Even periods of stretch of as little as 0.5 h/d were found to significantly decrease atrophy in inactive muscles.

Loughna, Paul T.↗

NASA NTRS2015

Recent Space PV Concentrator Advances: More Robust, Lighter, and Easier to Track

Over the past three years, the authors have collaborated on several significant advances in space photovoltaic concentrator technology, including a far more robust Fresnel lens for sunlight concentration, improved color-mixing features for the lens to minimize chromatic aberration losses for next-generation 4-junction and 6-junction IMM cells, a new approach to suntracking requiring only one axis of rotation even in the presence of large beta angles (e.g., +/- 50 deg), a new waste heat radiator made of graphene, with 80-90% reduction in mass, and a new platform for deployment and support on orbit (SOLAROSA). These patent-pending advances are described in this paper.

concentrators↗

NASA NTRSDate not supplied

Plasma for the Space Environment: An Overview of the Research at NASA's Kennedy Space Center

Human life amongst other planets requires vast technological advancements to sustain nutritional, environmental, and logistical needs. Plasma systems allow for advanced chemical processing while mitigating consumable needs or reliance on industrial infrastructure. Scientists at NASA’s Kennedy Space Center are attempting to close technology gaps with research into plasmas and their applications. Some such work includes the use of plasma for waste gasification, water activation, nutrient recovery techniques, lunar regolith reduction for oxygen extraction, and space crop production support. Here we report on the needs, success criteria, and results of plasma efforts for crewed transit and planetary habitation.

Plasma↗