Effects of moisture on graphite/epoxy composites
Report describes tests made on commercially available graphite/epoxy composites to analyze effects of water absorption and temperature spiking on composite strength and stiffness.
Dill, C. W.↗
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Ozone damage detection in cantaloupe plants
Ozone causes up to 90 percent of air pollution injury to vegetation in the United States; excess ozone affects plant growth and development and can cause undetected decrease in yields. Laboratory and field reflectance measurements showed that ozone-damaged cantaloupe (Cucumis melo L.) leaves had lower water contents and higher reflectance than did nondamaged leaves. Cantaloupe plants which were lightly, severely, and very severely ozone-damaged were distinguishable from nondamaged plants by reflectance measurements in the 1.35- to 2.5 micron near-infrared water absorption waveband. Ozone-damaged leaf areas were detected photographically 16 h before the damage was visible. Sensors are available for use with aircraft and spacecraft that possibly could be used routinely to detect ozone-damaged crops.
Gausman, H. W.↗
Distinguishing succulent plants from crop and woody plants
We compared laboratory spectrophotometrically measured leaf reflectances of six succulents (peperomia, possum-grape, prickly pear, spiderwort, Texas tuberose, wolfberry) with those of four nonsucculents (cenizo, honey mesquite, cotton, sugarcane) for plant species discrimination. Succulents (average leaf water content of 92.2 percent) could be distinguished from nonsucculents (average leaf water content of 71.2 percent) within the near-infrared water absorption waveband (1.35 to 2.5 microns). This was substantiated by field spectrophotometric reflectances of plant canopies. Sensor bands encompassing either the 1.6- or 2.2-wavelengths may be useful to distinguish succulent from nonsucculent plant species.
Gausman, H. W.↗
Using reflectance and photography to detect ozone damage to cantaloupe plants
Laboratory and field reflectance measurements showed that ozone-damaged cantaloupe (Cucumis melo L.) leaves had lower water contents and higher reflectance than nondamaged leaves. Cantaloupe plants with lightly, severely, and very severely ozone-damaged leaves were distinguishable from nondamaged plants by reflectance measurements in the 1.35-2.5-micron near-IR water absorption band. Ozone-damaged leaf areas were detected photographically 16 hours before the damage was visible.
Gausman, H. W.↗
Development and fabrication of bismaleimide-graphite composites
The successful fabrication of high temperature resistant composites depends mainly on the processability of the resin binder matrix. For two new bismaleimide type resins the processing of graphite fabric prepregs to composites is described. One resin coded M 751 has to be processed from N-Methylpyrrolidone, the other resin evaluated is a so-called hot melt solvent-less system. Commercial T300/3000 Graphite fabrics were used as reinforcement. The M 751 - Resin is a press grade material and laminates are therefore moulded in high pressure conditions (400 N/sq cm). The solvent-less resin system H 795 is an autoclave grade material and can be cured at 40 N/sq cm. The cure cycles for both the press grade and the autoclave grade material (Fiberite W 143 fabric prepregs) are provided and the mechanical properties of laminates at low (23 C) and high (232 C) temperatures were measured. For comparison, the neat resin flexural properties are also presented. The water absorption for the neat resins and the graphite fabric laminates after a 1000 hour period was evaluated.
Stenzenberger, H.↗
Water frost and ice - The near-infrared spectral reflectance 0.65-2.5 microns
The spectral reflectance of water frost and frost on ice as a function of temperature and grain size is presented with 1-1/2% spectral resolution in the 0.65- to 2.5-micron wavelength region. The well-known 2.0-, 1.65-, and 1.5-micron solid water absorption bands are precisely defined along with the little studied 1.25-micron band and the previously unidentified (in reflectance) 1.04-, 0.90-, and 0.81-micron absorption bands. The 1.5-microns band complex is quantitatively analyzed using a nonlinear least squares algorithm to resolve the band into four Gaussian components as a function of grain size and temperature. It is found that the 1.65-micron component, which was thought to be a good temperature sensor, is highly grain-size dependent and poorly suited to temperature sensing. Another Gaussian component appears to show a dependence of width on grain size while being independent of temperature. The relative apparent band depths are different for frost layers on ice than for thick layers of frost and may explain the apparent band depths seen in many planetary reflectance spectra.
Clark, R. N.↗
Fabrication and evaluation of RX-6450 /NCNS-13P/ composites
The chemistry, processing, and laminate properties of NCNS-13P resin are described. The effect on graphite fiber laminates of temperature, oxidative aging, water absorption, and humidity-temperature aging were determined. Glass laminates were evaluated for the fire resistance and smoke and toxic gas evolution under flaming conditions.
Kray, R. J.↗
Epoxy hydantoins as matrix resins
Tensile strength and fracture toughness of castings of the hydantoin resins cured with methylenedianiline are significantly higher than MY 720 control castings. Water absorption of an ethyl, amyl hydantoin formulation is 2.1 percent at equilibrium and Tg's are about 160 C, approximately 15 deg below the final cure temperature. Two series of urethane and ester-extended hydantoin epoxy resins were synthesized to determine the effect of crosslink density and functional groups on properties. Castings cured with methylenedianiline or with hexahydrophthalic anhydride were made from these compounds and evaluated. The glass transition temperatures, tensile strengths and moduli, and fracture toughness values were all much lower than that of the simple hydantoin epoxy resins. Using a methylene bishydantoin epoxy with a more rigid structure gave brittle, low-energy fractures, while a more flexible, ethoxy-extended hydantoin epoxy resin gave a very low Tg.
Weiss, J.↗
TM report
Key spectral, radiometric, and geometric characteristics of the TM sensor are examined. Spectrally, band 5 is slightly wider than specified and its upper edge at 50% of miximum of 1784 nm includes some unintended overlap with water absorption bands. Thermal band 6 is half the expected width. Radiometrically, the TM has extreme linearity and stability in comparison with previous MSS photomultiplier systems. Forward and reverse scans on TM show some unexplained radiometric differences of up to four digital levels. Primary focal plane bands show a monotomic decrease in gain of about 5% in the five months since launch. The relative internal gains of bands 5 and 7 varied with a period of about 60 days and an amplitude of about 6%. Radiometric calibration must be applied before histogram equalization algorithms to preserve radiometric accuracy. Geometrically, channel 4 in band 2 has a smaller modulation transfer function than desired. There is apparent misregistration of .75 pixels along scan and 0.2 pixels across scan.
Barker, J. L.↗
Composition of the surfaces of the Galilean satellites
Sulfur chemistry on Io and the surface chemistry of the icy Galilean satellites are discussed in terms of laboratory chemical findings and spectral investigations. Gaseous, liquid, and solid allotropes of sulfur are described and related to spectral data for Io. Compounds of sulfur identified on Io's surface are given and possible mechanisms for their formation are evalutated. Laboratory studies of water frost, ice, and mixtures with other minerals are discussed and their relevance in interpreting infrared spectra of the icy Galilean satellites and the apparent solid water absorption band profiles is shown.
Sill, G. T.↗
A Study of the Relation Between Crop Growth and Spectra Reflectance Parameters
The relationship between crop growth and spectra reflectance parameters was studied. The dynamic behavior of canopy reflectance versus time and the relationship of trajectories to canopy dynamics, ontogeny and morphology was investigated. The determination of which transformations of spectral data best suited for observing key canopy characteristics, such as leaf area index and vegetation identification are understood. A physical basis to understand how various spectral transform trajectories depend on vegetation type and models that describe the time delayed interaction of reflectance in the chlorophyll and water absorption bands to monitor stress were formulated. The general process of physical understanding of canopy reflectance is evaluated and existing canopy models are improved.
Badhwar, G.↗
Dielectric cure monitoring: Preliminary studies
Preliminary studies have been conducted on two types of dielectric cure monitoring systems employing both epoxy resins and phenolic composites. An Audrey System was used for 23 cure monitoring runs with very limited success. Nine complete cure monitoring runs have been investigated using a Micromet System. Two additional measurements were performed to investigate the Micromet's sensitivity to water absorption in a post-cure carbon-phenolic material. While further work is needed to determine data significance, the Micromet system appears to show promise as a feedback control device during processing.
Goldberg, B. E.↗
Breakdown of organic insulators
Solar cells and their associated electrical interconnects and leads were encapsulated in transparent elastomeric materials. Their purpose in a photovoltaic module, one of the most important for these elastomeric encapsulation materials, is to function as electrical insulation. This includes internal insulation between adjacent solar cells, between other encapsulated electrical parts, and between the total internal electrical circuitry and external metal frames, grounded areas, and module surfaces. Catastrophic electrical breakdown of the encapsulant insulation materials or electrical current through these materials or module edges to external locations can lead to module failure and can create hazards to humans. Electrical insulation stability, advanced elastomeric encapsulation materials are developed which are intended to be intrinsically free of in-situ ionic impurities, have ultralow water absorption, be weather-stable (UV, oxygen), and have high mechanical flexibility. Efforts to develop a method of assessing the life potential of organic insulation materials in photovoltaic modules are described.
Cuddihy, E. F.↗
Photovoltaic module encapsulation design and materials section, volume 2
Tests for chemical structure, material properties, water absorption, aging and curing agent of Ethylene Vinyl Acetate (EVA) and UV absorption studies are carried out. A computer model was developed for thermal optical modeling, to investigate dependence between module operating temperature and solar insolation, and heat dissapation behavior. Structural analyses were performed in order to determine the stress distribution under wind and heat conditions. Curves are shown for thermal loading conditions. An electrical isolation was carried out to investigate electrical stress aging of non-metallic encapsulation materials and limiting material flaws, and to develop a computer model of electrical fields and stresses in encapsulation materials. In addition, a mathematical model was developed and tests were conducted to predict hygroscopic and thermal expansion and contraction on a plastic coated wooden substrate. Thermal cycle and humidity freezing cycle tests, partial discharge tests, and hail impact tests were also carried out. Finally, the effects of soiling on the surface of photovoltaic modules were investigated. Two antisoiling coatings, a fluorinated silane and perflourodecanoic acid were considered.
Cuddihy, E. F.↗
Polyfunctional epoxies - Different molecular weights of brominated polymeric additives as flame retardants in graphite composites
The imparting of flame retardancy to graphite-reinforced composites without incurring mechanical property deterioration is investigated for the case of an experimental, trifunctional epoxy resin incorporating brominated polymeric additives (BPAs) of the diglycidyl type. Such mechanical properties as flexural strength and modulus, and short beam shear strength, were measured in dry and in hot/wet conditions, and the glass transition temperature, flammability, and water absorption were measured and compared with nonbromilated systems. Another comparison was made with a tetrafunctional epoxy system. The results obtained are explained in terms of differences in the polymeric backbone length of the bromine carrier polymer. BPAs are found to be a reliable bromine source for fire inhibition in carbon-reinforced composites without compromise of mechanical properties.
Nir, Z.↗
Verification tests of durable TPS concepts
Titanium multiwall, superalloy honeycomb, and Advanced Carbon-Carbon (ACC) multipost Thermal Protection System (TPS) concepts are being developed to provide durable protection for surfaces of future space transportation systems. Verification tests including thermal, vibration, acoustic, water absorption, lightning strike, and aerothermal tests are described. Preliminary results indicate that the three TPS concepts are viable up to a surface temperature in excess of 2300 F.
Shideler, J. L.↗
Verification tests of durable TPS concepts
Titanium multiwall, superalloy honeycomb, and Advanced Carbon-carbon (ACC) multipost Thermal Protection System (TPS) concepts are being developed to provide durable protection for surfaces of future space transportation systems. Verification tests including thermal, vibration, acoustic, water absorption, lightning strike, and aerothermal tests are described. Preliminary results indicate that the three TPS concepts are viable up to a surface temperature in excess of 2300 F.
Shideler, J. L.↗
Polymer-water interaction studies
Polymer water interactions were investigated. The following interactions were studied: (1) water absorption and desorption kinetics in EVA and PVB; (2) humidity dependence of electrical properties of EVA and PVB; (3) plasticizer effects in PVB; and (4) radiation effects in PVB and EVA.
Orehotsky, J.↗