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At least 127 records · Page 7

Downwind dispersion of CO 2 from a major subsea blowout in shallow offshore waters

Growing interest in offshore geologic carbon sequestration (GCS) motivates risk assessment of large-scale subsea CO 2 well blowouts or pipeline ruptures. For major leaks of CO 2 from wells or pipelines, significant fluxes of CO 2 may occur from the sea surface depending on water depth. In the context of risk assessment of human health and safety, we have used previously simulated coupled well-reservoir and water column model results as a source term for dense gas dispersion of CO 2 above the sea surface. The models are linked together by one-way coupling, that is, output of one model is used as input to the next model. These first-of-their-kind coupled flow results are applicable to assessing the hazard of CO 2 to people at and downwind of the sea surface location of emission. Hazard is quantified by plotting the downwind dispersion length (DDL), which we define in the study as the distances from the emission source to the point at which the emitted CO 2 has been diluted to 5% and 1.5% in air by volume. Here results suggest that large-scale blowouts in shallow water (10 m) may cause hazardous CO 2 plumes extending on the order of several hundred meters downwind. Details of the modeling show DDL has a maximum for windspeed (at an elevation of 10 m) of approximately 5 m/s, with smaller DDL for both weaker and stronger winds. This is explained by the fact that wind favors transport but also causes dispersion; therefore there is a certain wind speed that maximizes DDL.

54 ENVIRONMENTAL SCIENCES↗

NRAP-Open-IAM Multisegmented Wellbore Reduced-Order Model

Geologic carbon storage is one of the promising strategies to mitigate climate change by reducing the emission of carbon dioxide to the atmosphere. As part of the National Risk Assessment Partnership (NRAP), a systems-level stochastic analysis tool called the open source integrated assessment model, NRAP-Open-IAM, has been developed to estimate and manage the risk of containment loss at a geological carbon sequestration site. NRAP-Open-IAM contains several wellbore leakage model components that estimate the fluid leak rate that may occur through compromised legacy wells due to the increase in pressure resulting from CO 2 injection activities. Coupled to a reservoir component model, these components estimate the leakage of CO 2 and/or brine from a storage reservoir to overlying aquifer layers and the atmosphere through legacy wells. This report presents the theoretical framework and quality testing of the multisegmented wellbore reduced-order model. The model allows for segmenting of the legacy wells passing through the overlying stratigraphy into several intervals to simulate a site’s specific stratigraphic and hydrogeologic properties. For quality assurance, the analytical model is validated against numerical reservoir flow simulations for single and multiple aquifer(s) models. The results indicate that the model accurately predicts the transport of two-phase fluids (brine and injected CO 2 ) through the well over time. A detailed description of the model helps users to understand the model and provides a basis for future improvements.

58 GEOSCIENCES↗

Alteration of Fractured Foamed Cement Exposed to CO2-Saturated Water: Implications for Well Integrity

Geologic CO2 storage (GCS) is a method to mitigate the adverse impact of global climate change. Potential leakage of CO2 from fractured cement at the wellbore poses a risk to the feasibility of GCS. Foamed cement is widely applied in deepwater wells where fragile geologic formations cannot support the weight of conventional cement. Thus, it is critical to know whether fractures in foamed cement self-seal in a similar manner as conventional cement systems. This study is the first to investigate the changes in physical and chemical attributes of foamed cement under dynamic flow conditions using CO2-saturated water. Self-sealing of fractures in the cement was observed at a solution flow rate of 0.1 mL/min and a pressure of 6.9 MPa. The formation of CaCO3 precipitates in pore spaces and fractures led to a decrease in permeability by 1 order of magnitude. The extents of self-sealing in foamed cement samples, specifically the 20 and 30% air volume formulations, were similar to that of conventional cements. We attribute this to the greater alteration depth in the foamed cement, which compensated for the reduced availability of Portlandite and higher initial porosity. The results can be used to evaluate the risk of leakage associated with foamed cement.

Geologcial Carbon Storage, Well Integrity in CO2 S↗

Scale effects on core design, fuel costs, and spent fuel volume of pressurized water reactors

The desire to improve the economic competitiveness and deployment pace of nuclear energy through modularization, manufacturing, and series production had led to the development of smaller size reactors. As the standard 17x17 fuel technology is mainly maintained in the pressurized water reactors (PWRs) category, this translates into a lower number of fuel assemblies in the core and sometimes a reduced fuel height. To assess the impact of such scale change in core design on fuel cycle cost and spent fuel volume, a scoping analysis tool is developed based on infinite lattice calculations, leakage, fuel management reduced models, and levelized unit cost of electricity (LCOE) estimate. As such, cost dynamics driven by fuel specific power, burnup, core leakage, feed, cycle length, fuel assembly height as well as uranium market data are captured with consistent set of assumptions and analysis methods. A selection of 5 reactor designs representative of leading PWR developers is assessed and compared. Pursuing higher specific powers and optimal burnups are highlighted as the main fuel cost reduction drivers, nevertheless, practical limitations and opportunities must be evaluated to establish the feasibility of such enhanced fuel operation. In consequence, a detailed core design is performed using SIMULATE3 code for 5 PWR variations including natural and forced coolant circulation modes, two reactor scales, power densities of 73, 112, and 123 kW/l and higher discharge burnups. Design and optimization are performed at the lattice level, for the reflector, and at the core loading level. Satisfactory steady-state operation including power distribution, coolant operating limits, and reactivity requirements are analyzed and reported in this paper. The fuel economics of the detailed core designs confirm the scoping analysis findings. Despite the unlocked power uprates in small PWRs, the achievable burnup for a given fuel specific power requires more enrichment and shorter fuel height results in higher fabrication costs per mass of fuel, which makes scaling down core size a more expensive endeavor on the fuel cycle front. Spent fuel volumes are reported for the PWRs designed in this paper. Furthermore, these volumes are driven by the core average discharge burnup regardless of the scale in consideration. Additional cost and core performance aspects related to heavy reflector gains, fuel-reflector substitution, and disposal cost policy in the U.S. are examined.

42 ENGINEERING↗

Characterization and microbial mitigation of fugitive methane emissions from oil and gas wells: Example from Indiana, USA

Hydrocarbon gas emissions from active, inactive, and improperly sealed or abandoned oil/gas wells significantly contribute to anthropogenically emitted greenhouse gases, predominantly in the form of methane (CH 4 ). We explored the extent of hydrocarbon gas emissions from 20 active, inactive, plugged and abandoned oil/gas wells in Indiana (USA), where it is estimated that there are more than 80,000 well sites throughout the state. After this initial survey, using a static flux tent, we quantified fugitive CH4 emissions from an active gas well to approximately 2 L h -1 . To evaluate the potential for microbial mitigation of hydrocarbon emissions to the atmosphere, we conducted laboratory microcosm experiments to quantify the CH 4 oxidizing potential of soils collected from sites with varying distances to the leaking gas well. Soils in close proximity to the well (0.5 m) efficiently consumed nearly all (97 %) of the added CH 4 , while only 14 % of added CH 4 was consumed by soils that were more distant from the well (20 m). These results suggest that fugitive CH 4 emissions enrich methanotrophic bacteria in soils immediately adjacent to the well. Consistent with this view, we found that prolonged exposure of soils to elevated concentrations of CH 4 enhanced the methanotrophic activity. Together, these findings prompted us to design a “methanotrophic soil mound” to assess the feasibility of mitigating point sources of CH 4 by harnessing the natural methanotrophic capacity of soil microbial communities. We found that a methanotrophic soil mound from a landfill could sustainably mitigate the CH 4 emission from the artificial source, providing a promising low-cost solution to ameliorate fugitive CH 4 emissions from abandoned oil and gas wells to the atmosphere. Finally, the effectiveness of microbe-based remediation is limited in cold climates and arid environments.

54 ENVIRONMENTAL SCIENCES↗

Integration of seismic-pressure-petrophysics inversion of continuous active-seismic monitoring data for monitoring and quantifying CO 2 plume (Final Report)

The overall objective of this project is to develop and validate an integrated package of joint seismic-pressure-petrophysics inversion (jSPPI) of continuous active-source seismic monitoring dataset capable of providing real-time monitoring of CO 2 plume during geologic carbon sequestration (GCS). The three specific developments include: (a) the methodologies for fast seismic full waveform inversion of continuous active source seismic monitoring, (CASSM) datasets for simultaneously estimating velocity and attenuation, and with data assimilation; (b) joint Bayesian petrophysical inversion of seismic models and pressure data for providing and updating CO 2 saturation models; (c) the methods using multiple datasets including (Crainfield and Frio-II borehole) synthetic, laboratory, and field CASSM datasets. The outcomes of jSPPI include (a) a workflow for processing CASSM data, (b) Bayesian inversion algorithms using CASSM data and pressure response data, and (c) integration with data assimilation algorithms for continuously updating site-specific models used for prediction and reservoir management. The validation of joint FWI will be conducted using synthetic models based on the Cranfield and Frio experiments as well as field CASSM datasets collected as part of the Frio-II pilot injection. To quantify and map the mass and distribution of CO 2 (saturation), we will jointly invert velocity and attenuation measurements from the FWI with a Bayesian approach using a rock physics model for attenuation (e.g., White’s attenuation model with two selected patch sizes (White, 1976; Dutta and Seriff, 1979)). The Bayesian inversion will be applied to each time step in the CASSM survey in an updating scheme, which integrates with an ensemble of reservoir simulations at each step. A more complete experimental validation dataset will be collected as part of a mesoscale (2-3 m) gas-CO 2 injection experiment utilizing a higher frequency version of the CASSM system developed for laboratory studies; the integrated inversion will be demonstrated using this dataset which will provide both a dense geometry as well as more precise secondary confirmation measurements (e.g. saturation) typically not available in the field. The resulting real-time map of CO 2 saturation is able to provide a deeper scientific understanding of the complex, time-varying dynamics of subsurface fluid flow migration path as well as the rapid detection of CO 2 leakage hazards.

25 ENERGY STORAGE↗

Improved isolation in double-balanced mixers

Bypass circuit eliminates unwanted leakage in output RF signal. Correction circuit was developed for phase-shift-keyed transmitters. Principle can be adapted to correct leakage in other types of RF circuitry as well.

Stanton, P. H.↗

Development of braided rope engine seals

In this study, after reviewing current seal design concepts, the potential of textile structures for seal design is examined from the material, structural, and fabrication points of view. Braided structures are identified as potential candidates for hypersonic seal structures because of their conformability and design flexibility. A large family of braided structures using 2-D and 3-D architecture can be designed using well established methods to produce a wide range of braiding yarn orientation for wear resistance as well as seal porosity control. As a first demonstration of the approach, 2-D braided fiberglass seals were fabricated according to a factorial design experiment by varying braiding angles, fractional longitudinal fibers, and preload pressure levels. Factorial diagrams and response surfaces were constructed to elucidate the inter-relationship of the braiding parameters as well as the effect of preload pressures on leakage resistance of the seal. It was found that seal resistance is a strong function of fractional longitudinal fiber content. As braiding angle increases, seal leakage resistance increases, especially at high preload pressures and in seals having high proportion of longitudinal fibers.

Ko, Frank K.↗

Use of a Frequency Divider to Evaluate an SOI NAND Gate Device, Type CHT-7400, for Wide Temperature Applications

Frequency dividers constitute essential elements in designing phase-locked loop circuits and microwave systems. In addition, they are used in providing required clocking signals to microprocessors and can be utilized as digital counters. In some applications, particularly space missions, electronics are often exposed to extreme temperature conditions. Therefore, it is required that circuits designed for such applications incorporate electronic parts and devices that can tolerate and operate efficiently in harsh temperature environments. While present electronic circuits employ COTS (commercial-off- the-shelf) parts that necessitate and are supported with some form of thermal control systems to maintain adequate temperature for proper operation, it is highly desirable and beneficial if the thermal conditioning elements are eliminated. Amongst these benefits are: simpler system design, reduced weight and size, improved reliability, simpler maintenance, and reduced cost. Devices based on silicon-on-insulator (SOI) technology, which utilizes the addition of an insulation layer in the device structure to reduce leakage currents and to minimize parasitic junctions, are well suited for high temperatures due to reduced internal heating as compared to the conventional silicon devices, and less power consumption. In addition, SOI electronic integrated circuits display good tolerance to radiation by virtue of introducing barriers or lengthening the path for penetrating particles and/or providing a region for trapping incident ionization. The benefits of these parts make them suitable for use in deep space and planetary exploration missions where extreme temperatures and radiation are encountered. Although designed for high temperatures, very little data exist on the operation of SOI devices and circuits at cryogenic temperatures. In this work, the performance of a divide-by-two frequency divider circuit built using COTS SOI logic gates was evaluated over a wide temperature range and thermal cycling to determine suitability for use in space exploration missions and terrestrial fields under extreme temperature conditions.

Patterson, Richard L.↗

Long-length Scintillating Fibers for Nuclear Geological Repositories

This research focuses on the usage of plastic scintillating fibers as ruggedized detectors in long-length sections coupled to long-length standard optical fiber segments for the purpose of radiation detection and monitoring. This technology addresses a need for monitoring radiation in difficult-to-access or inaccessible areas, such as monitoring: radioactive waste within geological repositories, nuclear material storage facilities, spent fuel dry storage areas, inaccessible areas within nuclear facilities including reactors and reprocessing facilities, decommissioning of nuclear facilities, and other similar areas. The fiber can be placed along the tunnels of a geological repository to monitor the radiation field along its length. This can detect an increase of radiation due to movement, leakage, or unexpected opening of the containers, as well as decrease in the radiation due to removal of material. These capabilities have been demonstrated at INL’s Radioactive Scrap Waste Facility by successfully detecting the removal of an interim storage containers from the storage area. The poster focuses on explaining the technology and its capability in monitoring deep geological repositories (DGRs), especially in the domain of safety and international safeguards. As more countries consider the development of DGRs, technologies such as the one being presented can help establish continuity of knowledge of the material, maintain public confidence, and ensure safe operation of the facility. Furthermore, the poster looks at the future steps of the technology and its potential role in the international safeguards regime.

98 - NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL↗

Self-Healing Cements with Improved Toughness at Casing and Formation Interfaces for Subsurface Applications (CRADA 530)

Over the three-year CRADA, Pacific Northwest National Laboratory (PNNL) advanced a new class of Molecular Velcro™ self-healing wellbore cements designed to improve the long-term integrity of wells used for geothermal energy production and carbon storage. Conventional wellbore cement can crack due to repeated mechanical loading, temperature swings, and exposure to aggressive subsurface fluids. Once cracks form, they can create leakage pathways, drive expensive remediation (“workovers”), and in extreme cases shorten well life. This project addressed that problem by developing polymer-modified cement systems that can autonomously re-seal cracks and better tolerate the extreme conditions experienced in subsurface wells, while remaining compatible with practical cementing operations.

15 GEOTHERMAL ENERGY↗

Development Fiber Optic Distributed System for Direct Detection of Subsurface Gases Leakages

Carbon, natural gas, and hydrogen gas storage is an emerging solution to safeguard us against pollution, support goals of negative carbon emission, and protect sources of renewable energy. Properly constructed storage wells provide a virtually impervious barrier to any unintended subsurface transmission. The ability to ensure the long-term integrity of such wells is vital to the success of any storage operation and be successful in the public eyes. Therefore, robust monitoring of any gas migration into the subsurface is highly sought. A fiber-optic distributed chemical sensor (DCS) enables monitoring of long-term well integrity along its depth, ensuring the success of any storage operation and bolsters public acceptance of the safety of the reservoir via leak early detection. The same technique can be applied to gas monitoring in pipeline networks and nuclear stockpile monitoring applications. Fiber based Raman spectroscopy enables DCS, as optical fibers can be deployed in virtually any environment and relay spectroscopic information over long distances back to the user. Hollow core fibers (HCF) make excellent DCSs as the air core of the fiber allows gas from the environment to diffuse into the core, which interacts with the laser signal that is carried in the air core. This work builds upon the previous LDRD project, Fiber Optic System for Direct Detection of Carbon Dioxide Leakage in Carbon Storage Wells (21-FS-003), in which the feasibility of Raman spectroscopy detection of Carbon Dioxide (CO2) in HCF detection was demonstrated. We mitigated the risk of this DCS technology by establishing and completing five objectives. The first objective was to model and optically characterize HCF uptake of CO2, establishing the relationship between HCF length, gas diffusion time, detectable gas concentration, and measured Raman intensity. In objective two, we developed a fiber core drilling recipe to enable additional diffusion ports in the fiber core and established a method for maintaining fiber strength and integrity post drilling. Objective three characterized the drilled fibers against the undrilled fibers, establishing the differences in the gas mechanics and optical properties and provided parameters to iterate the drilling process. In objective four, a fusion splicing technique was developed to join the HCF to conventional single-mode fibers, localizing the gas detection point at the drilled HCF hole, emulating a DCS. Lastly, objective five was the testing of the sensor in Edgar Mines at Colorado School of Mines on a CO2 pipeline with a simulated leak, to showcase the ability to detect CO2 leaks. This capstone result showed CO2 leak detection in < 10 minutes, raising the technology readiness level of HCF segments as deployable DCS.

organic↗

A Study of Neutron Leakage in Finite Objects

A computationally efficient 3DHZETRN code capable of simulating High charge (Z) and Energy (HZE) and light ions (including neutrons) under space-like boundary conditions with enhanced neutron and light ion propagation was recently developed for simple shielded objects. Monte Carlo (MC) benchmarks were used to verify the 3DHZETRN methodology in slab and spherical geometry, and it was shown that 3DHZETRN agrees with MC codes to the degree that various MC codes agree among themselves. One limitation in the verification process is that all of the codes (3DHZETRN and three MC codes) utilize different nuclear models/databases. In the present report, the new algorithm, with well-defined convergence criteria, is used to quantify the neutron leakage from simple geometries to provide means of verifying 3D effects and to provide guidance for further code development.

Wilson, John W.↗

NRAP Toolkit Screening for CarbonSAFE Illinois - Macon County

In this report we take stratigraphic data from the ISGS-led Macon County Phase 2 CarbonSAFE’s proposed site in Christian County, Illinois, and conduct reservoir simulations to generate pressure and CO 2 saturation plume data as a function of time. We then use this plume data along with the stratigraphic data as inputs to the NRAP Open-source Integrated Assessment Model (NRAP-Open-IAM) to evaluate project risks. For this report we focus on the probabilistic risk associated with hypothetical leakage of CO 2 and brine along the injection well and one monitoring well. We also study the resulting impact to two overlying aquifers, which could be used to inform monitoring technology selection.

54 ENVIRONMENTAL SCIENCES↗

Development of a Particle Flow Control Mechanism

The next generation of Concentrated Solar Power (CSP) systems are utilizing solid particles as the heat transfer medium. The state-of-the-art particle flow control mechanism currently utilized is the slide-gate mechanism which functions by linearly actuating a gate across a tear-drop shaped opening. The sensitivity, which is a measure of the change in mass flow rate per unit movement of the slide-gate, is 0.354 g/s-mm[1]. The slide-gate’s main shortcomings include particle lodging and particle leakage between the plates, and difficulty actuating under the pressure from the particles. The goal of a new device is to minimize or eliminate these flaws. The new proposed device functions similar to a chuck mechanism in a drill where a rotation of an outer ring produces a change in outlet area through moving “jaws” diagonally. This mechanism aims to solve the issues of the slide-gate by having the jaws on the outside of the particle flow volume to reduce the probability of particle lodging, and the jaw tips are designed to overlap as they actuate to reduce particle leakage. Additionally, the vertical orientation of the device as well as the inclined movement of the jaws allows for easier actuation of the device under pressure. Experiments involving 3D printed prototypes have been carried out, producing a max mass flowrate of about 50 g/s and a sensitivity curve with the equation 𝑦 (𝑔/𝑠) = 0.0851𝑥^2(𝑔/𝑠−𝑚𝑚2) +3.6993𝑥(𝑔/𝑠−𝑚𝑚). These experiments validated the device’s capability to address the shortcomings of the slide-gate. Currently, an aluminum model of the device is being tested at room temperature, and a stainless-steel model is being developed to be tested at 700oC, which is the expected operating temperature of the CSP system. Furthermore, simulations are on-going to predict the mass flowrate of different device configurations at room and high temperatures.

14 SOLAR ENERGY↗

The Sun and the Solar Wind Close to the Sun

The structure of the solar corona is directly reflected in the structure of the solar wind. But, the importance of this simple observation to coronal modeling has become much greater with the arrival of results from Ulysses and SOHO. High speed wind is relatively smooth and uniform (Ulysses) but the coronal holes from which it comes contain highly filamented flows that expand in area by factors of two to sevenfold between the solar surface and 10 solar radii (SOHO). Different models of the relationship between solar and interplanetary magnetic fields produce similar predictions and are still being reconciled. Slow wind seems to come from the boundaries of streamers (Ulysses) by a process which is even less well understood. Again, there are different ideas for the leakage of slow wind from streamers but these models are quickly becoming highly constrained by new data on composition in the core and boundaries of streamers (SOHO). Perhaps the most significant conclusion is that there is a changing paradigm for the processes governing solar wind acceleration and energy flow, one that requires the presence of filamented, energetic, transient flows in a low-beta plasma close to the Sun that become mixed to produce the evolving turbulent MHD plasma that Is observed in the interplanetary medium.

Suess, S. T.↗

Contamination Control and Hardware Processing Solutions at Marshall Space Flight Center

The Contamination Control Team of Marshall Space Flight Center's Materials and Processes Laboratory supports many Programs/ Projects that design, manufacture, and test a wide range of hardware types that are sensitive to contamination and foreign object damage (FOD). Examples where contamination/FOD concerns arise include sensitive structural bondline failure, critical orifice blockage, seal leakage, and reactive fluid compatibility (liquid oxygen, hydrazine) as well as performance degradation of sensitive instruments or spacecraft surfaces such as optical elements and thermal control systems. During the design phase, determination of the sensitivity of a hardware system to different types or levels of contamination/FOD is essential. A contamination control and FOD control plan must then be developed and implemented through all phases of ground processing, and, sometimes, on-orbit use, recovery, and refurbishment. Implementation of proper controls prevents cost and schedule impacts due to hardware damage or rework and helps assure mission success. Current capabilities are being used to support recent and on-going activities for multiple Mission Directorates / Programs such as International Space Station (ISS), James Webb Space Telescope (JWST), Space Launch System (SLS) elements (tanks, engines, booster), etc. The team also advances Green Technology initiatives and addresses materials obsolescence issues for NASA and external customers, most notably in the area of solvent replacement (e.g. aqueous cleaners containing hexavalent chrome, ozone depleting chemicals (CFC s and HCFC's), suspect carcinogens). The team evaluates new surface cleanliness inspection and cleaning technologies (e.g. plasma cleaning), and maintains databases for processing support materials as well as outgassing and optical compatibility test results for spaceflight environments.

Burns, DeWitt H.↗

Brush Seal Arrangement for the RS-68 Turbopump Set

The nature of the RS-68 turbopumps requires that the hydrogen seals separating the pump from the turbine must have extremely low levels of leakage and be contained in small packages. Conventional seal technologies are not able to reasonably satisfy such design requirements. A review of experimental measurements and analysis publications suggests that brush seals are well suited for the design requirements. Brush seals are shown to have less leakage than conventional labyrinth and damper seals and have no adverse effects on the rotordynamics of the machine. The bulk-flow analysis presented by Hendricks et al. is used as a guideline to create a spreadsheet that provides mass flow through the seal and heat generated by the rubbing contact of the bristles on the shaft. The analysis is anchored to published data for LN2 and LH2 leakage tests. Finally, the analysis is used to design seals for both applications. It is observed that the most important analysis parameter is the thickness of the bristle pack and its relationship to seal clearance, lay angle and pressure drop.

Nunez, D.↗