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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,279 records · Page 71
All sourcesNASA NTRSDOE OSTI
DOE OSTI2012

The role of carboxylic acids in TALSQueak separations

Recent reports have indicated TALSPEAK-type separations chemistry can be improved through the replacement of bis-2-ethyl(hexyl) phosphoric acid (HDEHP) and diethylenetriamine-N,N,N,N,N-pentaacetic acid (DTPA) with the weaker reagents 2-ethyl(hexyl) phosphonic acid mono-2-ethylhexyl ester (HEH[EHP]) and N-(2-hydroxyethyl)ethylenediamine-N,N',N'-triacetic acid (HEDTA), respectively. This modified TALSPEAK has been provided with an adjusted acronym of TALSQueak (Trivalent Actinide Lanthanide Separation using Quicker Extractants and Aqueous Komplexes). Among several benefits, TALSQueak chemistry provides more rapid phase transfer kinetics, is less reliant on carboxylic acids to mediate lanthanide extraction and allows a simplified thermodynamic description of the separations process that generally requires only parameters available in the literature to describe metal transfer. This manuscript focuses on the role of carboxylic acids in aqueous ternary (M-HEDTA-carboxylate) complexes, americium/lanthanide separations, and extraction kinetics. Spectrophotometry (UV-vis) of the Nd hypersensitive band indicates the presence of aqueous ternary species (K111 = 1.83 {+-} 0.01 at 1.0 M ionic strength, Nd(HEDTA) + Lac <-> Nd(HEDTA)Lac). Varying the carboxylic acid does not have a significant impact on Ln/Am separations or extraction kinetics. TALSqueak separations come to equilibrium in five minutes at the conventional operational pH of 3.6 using only 0.1 M total lactate or citrate.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Comparative study of machine learning techniques for post-combustion carbon capture systems

Computational analysis of countercurrent flows in packed absorption columns, often used in solvent-based post-combustion carbon capture systems (CCSs), is challenging. Typically, computational fluid dynamics (CFD) approaches are used to simulate the interactions between a solvent, gas, and column's packing geometry while accounting for the thermodynamics, kinetics, heat, and mass transfer effects of the absorption process. These simulations can then be used explain a column's hydrodynamic characteristics and evaluate its CO 2 -capture efficiency. However, these approaches are computationally expensive, making it difficult to evaluate numerous designs and operating conditions to improve efficiency at industrial scales. In this work, we comprehensively explore the application of statistical ML methods, convolutional neural networks (CNNs), and graph neural networks (GNNs) to aid and accelerate the scale-up and design optimization of solvent-based post-combustion CCSs. We apply these methods to CFD datasets of countercurrent flows in absorption columns with structured packings characterized by several geometric parameters. We train models to use these parameters, inlet velocity conditions, and other model-specific representations of the column to estimate key determinants of CO 2 -capture efficiency without having to simulate additional CFD datasets. We also evaluate the impact of different input types on the accuracy and generalizability of each model. We discuss the strengths and limitations of each approach to further elucidate the role of CNNs, GNNs, and other machine learning approaches for CO 2 -capture property prediction and design optimization.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2021

Concurrent Changes in Extreme Hydroclimate Events in the Colorado River Basin

Extreme events resulting in catastrophic damage have more than doubled in the last five years, costing hundreds of lives and thousands of homes, and heavily undermining regional economic stability. At present, most of these hydroclimatic extreme events are documented by the media as individual events; however, in scientific terms, many are better understood as concurrent events—concurrent extremes of both temperature and precipitation (e.g., drought, floods). This paper considers concurrent changes in hydroclimate extremes, including heatwaves, drought, flooding, and low flows, in six historical-to-future (1970–1999, 2070–2099) Earth System Model (ESM) climate scenarios for the Colorado River basin. Results indicate that temperature-driven Impacts (heatwaves, drought) have the strongest responses while precipitation-driven Impacts have weaker responses. All Impacts exhibit an increase in magnitude from synoptic to annual time scales, with heatwaves increasing in strength about three times at the annual time scale versus the synoptic, while low flows only increase slightly. Critical watersheds in the Colorado were identified, highlighting the Blue River basin, Uncompahgre, East Taylor, Salt/Verde watersheds, locations of important water infrastructures, water resources, and hydrological research. Our results indicate that concurrent extreme hydroclimate events are projected to increase in the future and intensify within critical regions of the Colorado River basin. Considering extreme hydroclimate events concurrently is an important step towards linking economic and social effects of these events and their associated instabilities on a regional scale.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1984

ACEE composite structures technology

Topics addressed include: strength and hygrothermal response of L-1011 fin components; wing fuel containment and damage tolerance development; impact dynamics; acoustic transmission; fuselage structure; composite transport wing technology development; spar/assembly concepts.

James, A. M.↗
NASA NTRS1994

The O(+) 834-A dayglow: Revised cross sections

This study assesses the impact of new O((sup 3)P) photoionization and N2 photoabsorption cross sections, and O(+) oscillator strengths and transition probabilities, on O II 834-A airglow calculations. The 834-A intensities computed using the new emission parameters are in good agreement with rocket measurements obtained in 1978 and 1980. The present study does not support a suggested reduction in the N2 photoabsorption cross section based on an earlier analysis of the rocket data. This study also explores the problem of determining F region electron densities from satellite limb scans of the O(+) 834-A emission. Our results indicate that electron density profiles inferred from limb scans are not necessarily unique; estimates of N(sub m)F(sub 2) and h(sub m)F(sub 2) can vary by at least a factor of 2 and 50 km, respectively.

Link, R.↗
NASA NTRS1999

Aerospace Engineering Systems and the Advanced Design Technologies Testbed Experience

Continuous improvement of aerospace product development processes is a driving requirement across much of the aerospace community. As up to 90% of the cost of an aerospace product is committed during the first 10% of the development cycle, there is a strong emphasis on capturing, creating, and communicating better information (both requirements and performance) early in the product development process. The community has responded by pursuing the development of computer-based systems designed to enhance the decision-making capabilities of product development individuals and teams. Recently, the historical foci on sharing the geometrical representation and on configuration management are being augmented: 1) Physics-based analysis tools for filling the design space database; 2) Distributed computational resources to reduce response time and cost; 3) Web-based technologies to relieve machine-dependence; and 4) Artificial intelligence technologies to accelerate processes and reduce process variability. The Advanced Design Technologies Testbed (ADTT) activity at NASA Ames Research Center was initiated to study the strengths and weaknesses of the technologies supporting each of these trends, as well as the overall impact of the combination of these trends on a product development event. Lessons learned and recommendations for future activities are reported.

VanDalsem, William R.↗
NASA NTRS1999

The Effects of Partial Mechanical Loading and Ibandronate on Skeletal Tissues in the Adult Rat Hindquarter Suspension Model for Microgravity

We report initial data from a suspended rat model that quantitatively relates chronic partial weightbearing to bone loss. Chronic partial weightbearing is our simulation of the effect of limited artificial gravity aboard spacecraft or reduced planetary gravity. Preliminary analysis of bone by PQCT, histomorphometry, mechanical testing and biochemistry suggest that chronic exposure to half of Earth gravity is insufficient to prevent severe bone loss. The effect of episodic full weightbearing activity (Earth Gravity) on rats otherwise at 50% weightbearing was also explored. This has similarity to treatment by an Earth G-rated centrifuge on a spacecraft that normally maintained artificial gravity at half of Earth G. Our preliminary evidence, using the above techniques to analyze bone, indicate that 2 hours daily of full weightbearing was insufficient to prevent the bone loss observed in 50% weightbearing animals. The effectiveness of partial weightbearing and episodic full weightbearing as potential countermeasures to bone loss in spaceflight was compared with treatment by ibandronate. Ibandronate, a long-acting potent bisphosphonate proved more effective in preventing bone loss and associated functionality based upon structure than our first efforts at mechanical countermeasures. The effectiveness of ibandronate was notable by each of the testing methods we used to study bone from gross structure and strength to tissue and biochemistry. These results appear to be independent of generalized systemic stress imposed by the suspension paradigm. Preliminary evidence does not suggest that blood levels of vitamin D were affected by our countermeasures. Despite the modest theraputic benefit of mechanical countermeasures of partial weightbearing and episodic full weightbearing, we know that some appropriate mechanical signal maintains bone mass in Earth gravity. Moreover, the only mechanism that correctly assigns bone mass and strength to oppose regionally specific force applied to bone is mechanical, a process based upon bone strain. Substantial evidence indicates that the specifics of dynamic loading i.e. time-varying forces are critical. Bone strain history is a predictor of the effect that mechanical conditions have on bone structure mass and strength. Using servo-controlled force plates on suspended rats with implanted strain gauges we manipulated impact forces of ambulation in the frequency (Fourier) domain. Our results indicate that high frequency components of impact forces are particularly potent in producing bone strain independent of the magnitude of the peak force or peak energy applied to the leg. Because a servo-system responds to forces produced by the rat's own muscle activity during ambulation, the direction of ground-reaction loads act on bone through the rat's own musculature. This is in distinction to passive vibration of the floor where forces reach bone through the natural filters of soft tissue and joints. Passive vibration may also be effective, but it may or may not increase bone in the appropriate architectural pattern to oppose the forces of normal ambulatory activity. Effectiveness of high frequency mechanical stimulation in producing regional (muscle directed) bone response will be limited by 1. the sensitivity of bone to a particular range of frequencies and 2. the inertia of the muscles, limiting their response to external forces by increasing tension along insertions. We have begun mathematical modeling of normal ambulatory activity. Effectiveness of high frequency mechanical stimulation in producing regional (muscle directed) bone response will be limited by 1. the sensitivity of bone to a particular range of frequencies and 2. the inertia of the muscles, limiting their response to external forces by increasing tension along insertions. We have begun mathematical modeling of the rat forelimb as a transfer function between impact force and bone strain to predict optimal dynamic loading conditions for this system. We plan additional studies of mechanical counter-measures that incorporate improved dynamic loading, features relevant to anticipated evaluation of artificial gravity, exercise regimens and exposure to Martian gravity, The combination of mechanical countermeasures with ibandronate will also be investigated for signs of synergy.

Schultheis, Lester W.↗
NASA NTRS1999

Aerospace Engineering Systems

Continuous improvement of aerospace product development processes is a driving requirement across much of the aerospace community. As up to 90% of the cost of an aerospace product is committed during the first 10% of the development cycle, there is a strong emphasis on capturing, creating, and communicating better information (both requirements and performance) early in the product development process. The community has responded by pursuing the development of computer-based systems designed to enhance the decision-making capabilities of product development individuals and teams. Recently, the historical foci on sharing the geometrical representation and on configuration management are being augmented: Physics-based analysis tools for filling the design space database; Distributed computational resources to reduce response time and cost; Web-based technologies to relieve machine-dependence; and Artificial intelligence technologies to accelerate processes and reduce process variability. Activities such as the Advanced Design Technologies Testbed (ADTT) project at NASA Ames Research Center study the strengths and weaknesses of the technologies supporting each of these trends, as well as the overall impact of the combination of these trends on a product development event. Lessons learned and recommendations for future activities will be reported.

VanDalsem, William R.↗
NASA NTRS2005

Atmospheric Fragmentation of the Gold Basin Meteoroid as Constrained from Cosmogenic Nuclides

Since the discovery of the Gold Basin L4 chondrite shower almost ten years ago in the northwestern corner of Arizona, many thousands of L-chondrite specimens have been recovered from an area of approx.22 km long and approx.10 km wide. Concentrations of cosmogenic 14C and 10Be in a number of these samples indicated a terrestrial age of approx.15,000 years and a large pre-atmospheric size [1]. Additional measurements of cosmogenic Be-10, Al-26, Cl-36, and Ca-41 in the metal and stone fractions of fifteen Gold Basin samples constrained the pre-atmospheric radius to 3-5 m [2]. This implies that Gold Basin is by far the largest stone meteorite in the present meteorite collection, providing us with an opportunity to study the fragmentation process of a large chondritic object during atmospheric entry. Knowledge about the fragmentation process provides information about the mechanical strength of large meteoroids, which is important for the evaluation of future hazards of small asteroid impacts on Earth and possible defensive scenarios to avoid those impacts.

Welten, K. C.↗
NASA NTRS2005

Participation in the Analysis of the Far-Infrared/Submillimeter Interferometer

We have contributed to the development of the Submillimeter Probe of the Evolution of Cosmic Structure (SPECS) by analyzing various aspects related to the tethers that connect the spacecraft of this space interferometer. We have focused our analysis on key topics as follows: (a) helping in the configuration selection; (b) computing the system eigenfrequencies as a function of baseline length; (c) developing techniques and conceptual design of devices for damping the tether oscillations; (d) carrying out numerical simulations of tethered formation to assess the effects of environmental perturbations upon the baseline length variation; (e) devising control laws for fast retargeting of the interferometer at moderate baseline lengths; (f) estimating the survivability to micrometeoroid impacts of a tether at L2; and (g) developing a conceptual design of a high-strength and survivable tether.

Lorenzini, Enrico C.↗
NASA NTRS2010

Use of Traditional and Novel Methods to Evaluate the Influence of an EVA Glove on Hand Performance

The gloved hand is one of an astronaut s primary means of interacting with the environment, and any restrictions imposed by the glove can strongly affect performance during extravehicular activity (EVA). Glove restrictions have been the subject of study for decades, yet previous studies have generally been unsuccessful in quantifying glove mobility and tactility. Past studies have tended to focus on the dexterity, strength, and functional performance of the gloved hand; this provides only a circumspect analysis of the impact of each type of restriction on the glove s overall capability. The aim of this study was to develop novel capabilities to provide metrics for mobility and tactility that can be used to assess the performance of a glove in a way that could enable designers and engineers to improve their current designs. A series of evaluations were performed to compare unpressurized and pressurized (4.3 psi) gloved conditions with the ungloved condition. A second series of evaluations were performed with the Thermal Micrometeoroid Garment (TMG) removed. This series of tests provided interesting insight into how much of an effect the TMG has on gloved mobility - in some cases, the presence of the TMG restricted glove mobility as much as pressurization did. Previous hypotheses had assumed that the TMG would have a much lower impact on mobility, but these results suggest that an improvement in the design of the TMG could have a significant impact on glove performance. Tactility testing illustrated the effect of glove pressurization, provided insight into the design of hardware that interfaces with the glove, and highlighted areas of concern. The metrics developed in this study served to benchmark the Phase VI EVA glove and to develop requirements for the next-generation glove for the Constellation program.

Benson, Elizabeth A.↗
NASA NTRS1998

Disruption of Kilometer-Sized Asteroids by Energetic Collisions

Past collisions determine the current mechanical properties of asteroids, and hence their response to future collisions. To understand the evolution of their diverse shapes, structures and spin states, we model hypervelocity impacts into small asteroids using a modern 3D smooth-particle hydrocode (SPH3D) that takes material strength and fracture into account.

Asteroids↗
DOE OSTI2019

Loading Capabilities of Irradiated 3-D Printed Polymers

Gamma radiation is the emission of a high-energy photon from a radioactive source. The photon then interacts with an atom potentially damaging it. While time has shown that gamma radiation has a little effect on metals, the same cannot be said about plastic. The use of these types of materials in radioactive areas has increased for many reasons ranging from the weight difference between plastics and metals to the costs associated with doing so. For example, a potential use for radiation resistant plastics could be longer lasting, cost effective, and light weight radiation detection devices sent to probe an area that may present unsafe conditions for humans to survey. For these reasons and more, finding a plastic polymer that can withstand radiation for an extended period of time would make a great impact on the nuclear industry. In this experiment, two different polymers will undergo a series of strength tests before and after being exposed to radiation after different amounts of time up to two weeks. There are two sets of plastic polymers that will be used. Each set will consist of an nonirradiated, control subset, and subsets subject to radiation for one day, one week, and two weeks. The radiation source is 1100 Ci cobalt- 60. The specimens are placed on a foam platform such that they will be exposed as evenly as possible. They are then lowered into the radiation chamber where they are surround by cobalt-60 sources and irradiated for the given amount of time. The specimens will be tested for tensile strength and flexural strength according to ASTM standards. For tensile testing, the specimen has a 'dog bone' shape. The specimen is gripped at the wide ends, and pulled away from the center at a constant rate until failure. To test flexural strength, the specimens will be subject to a 3-point bend test. The specimen is held in place by three points, center top side and both ends bottom side. Load is applied at a constant rate on the center of the specimen until failure. The calculations to be considered for comparison after performing these tests include the tensile strength and stress, elongation, flexural stress and strain, and elasticity. Once these tests are completed, testing specimens that have been 3D printed with different print orientations will be considered and tested. The results from both experiments will help create strong, radiation resistant products in a expeditious manner that could really push the current limitations and expand the use of radiation resistant material.

36 MATERIALS SCIENCE↗
NASA NTRS2022

The Impact of Winds on AMOC in a Fully-Coupled Climate Model

Here we investigate the role of the atmospheric circulation in AMOC by comparing a fully-coupled large ensemble, a forced-ocean simulation, and new experiments using a fully-coupled global climate model where winds above the boundary layer are nudged towards reanalysis. When winds are nudged north of 45°N, agreement with RAPID array observations of AMOC at 26.5°N improves across several metrics. The phasing of interannual variability is well-captured due to the response of the local Ekman component in both wind-nudging and forced-ocean simulations, however the variance remains underestimated. The mean AMOC strength is substantially reduced relative to the fully-coupled model large ensemble, which is biased high, due to the impact of winds on surface buoyancy fluxes over the subpolar gyre. Nudging winds towards observations also reduces the 1979-2016 trend in AMOC, suggesting that improvement in the representation of the high-latitude atmosphere is important for projecting long-term AMOC changes.

AMOC↗
DOE OSTI2019

The Spall Strength and Dynamic Yield Stress of Hafnium

The spall strength and dynamic yield stress of polycrystalline hafnium have been measured in a series of plane-wave shock loading experiments using flat sample–transparent window composite targets, with the transparent windows representing polymethyl methacrylate or lithium fluoride plates arranged on the rear side of a hafnium sample. The front side of the target was subjected to shock impact of a copper striker, the rear surface velocity was measured, and the sample was recovered for subsequent metallographic examination. The results were also used for evaluation of the accuracy of spall strength measurements and the analysis of features of high-rate deformation of hafnium.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Magnetic Field Strength Effects on Nucleosynthesis from Neutron Star Merger Outflows

Abstract Magnetohydrodynamic turbulence drives the central engine of post-merger remnants, potentially powering both a nucleosynthetically active disk wind and the relativistic jet behind a short gamma-ray burst. We explore the impact of the magnetic field on this engine by simulating three post-merger black hole accretion disks using general relativistic magnetohydrodynamics with Monte Carlo neutrino transport, in each case varying the initial magnetic field strength. We find increasing ejecta masses associated with increasing magnetic field strength. We find that a fairly robust main r -process pattern is produced in all three cases, scaled by the ejected mass. Changing the initial magnetic field strength has a considerable effect on the geometry of the outflow and hints at complex central engine dynamics influencing lanthanide outflows. We find that actinide production is especially sensitive to magnetic field strength, with the overall actinide mass fraction calculated at 1 Gyr post-merger increasing by more than a factor of 6 with a tenfold increase in magnetic field strength. This hints at a possible connection to the variability in actinide enhancements exhibited by metal-poor, r -process-enhanced stars.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

The effect of substrate temperature on the critical velocity in microparticle impact bonding

A number of nascent coating and micromanufacturing processes involve particles sprayed at a high velocity, which impact a substrate, deform, and adhere. Successful bonding between the particles and the substrate requires impact velocities higher than the so-called critical adhesion velocity. This critical velocity is influenced by the temperature of the substrate, a variable that we isolate in this work by conducting single-particle impacts on a variable-temperature substrate for three systems (Al–Al, Sn–Sn, and Ti–Ti) with particles individually selected within a narrow size distribution. Our results quantitatively connect the increase in substrate temperature to a significant lowering of the critical velocity, which we attribute to the lower dynamic strength of the thermally softened substrate. The data are generally consistent with expectations for bonding being controlled by a hydrodynamic process of jetting upon impact.

36 MATERIALS SCIENCE↗
NASA NTRS1973

Impact resistance of fiber composite blades used in aircraft turbine engines

Resistance of advanced fiber reinforced epoxy matrix composite materials to ballistic impact was investigated as a function of impacting projectile characteristics, and composite material properties. Ballistic impact damage due to normal impacts, was classified as transverse (stress wave delamination and splitting), penetrative, or structural (gross failure). Steel projectiles were found to be gelatin ice projectiles in causing penetrative damage leading to reduced tensile strength. Gelatin and ice projectiles caused either transverse or structural damage, depending upon projectile mass and velocity. Improved composite transverse tensile strength, use of dispersed ply lay-ups, and inclusion of PRD-49-1 or S-glass fibers correlated with improved resistance of composite materials to transverse damage. In non-normal impacts against simulated blade shapes, the normal velocity component of the impact was used to correlate damage results with normal impact results. Stiffening the leading edge of simulated blade specimens led to reduced ballistic damage, while addition of a metallic leading edge provided nearly complete protection against 0.64 cm diameter steel, and 1.27 cm diameter ice and gelatin projectiles, and partial protection against 2.54 cm diameter projectiles of ice and gelatin.

Friedrich, L. A.↗