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At least 1,279 records · Page 71

Scale Mixtures of Frechet Distributions as Asymptotic Approximations of Extreme Precipitation

This paper is a further development of the results of [20] where, based on the negative binomial model for the duration of wet periods measured in days [16], an asymptotic approximation was proposed for the distribution of the maximum daily precipitation volume within a wet period. This approximation has the form of a scale mixture of the Fr´echet distribution with the gamma mixing distribution and coincides with the distribution of a positive power of a random variable having the Snedecor–Fisher distribution. Here we extend this result to the mth extremes, m ∈ ℕ, and sample quantiles. The proof of this result is based on the representation of the negative binomial distribution as a mixed geometric (and hence, mixed Poisson) distribution [17] and limit theorems for extreme order statistics in samples with random sizes having mixed Poisson distributions [10]. Some analytic properties of the obtained limit distribution are described. In particular, it is demonstrated that under certain conditions the limit distribution of the maximum precipitation is mixed exponential and hence, is infinitely divisible. It is shown that under the same conditions this limit distribution can be represented as a scale mixture of stable or Weibull or Pareto or folded normal laws. The corresponding product representations for the limit random variable can be used for its computer simulation. The results of fitting this distribution to real data are presented illustrating high adequacy of the proposed model. It is also shown that the limit distribution of sample quantiles is the well-known Student distribution. Several methods are proposed for the estimation of the parameters of the asymptotic distributions. The obtained mixture representations for the limit laws and the corresponding asymptotic approximations provide better insight into the nature of mixed probability (“Bayesian”) models.

97 MATHEMATICS AND COMPUTING↗

Refining instrument response functions with 3-D Monte Carlo simulations of differential hard x-ray spectrometers

Three x-ray spectrometers – the hard x-ray detector (HXRD), the bremsstrahlung MeV x-ray spectrometer (BMXS), and the hard x-ray image plate (HXIP) – areused here to estimate hot-electron bremsstrahlung spectrum parameters for inertial confinement fusion experiments on OMEGA. Using 1-D deterministically calculated response functions, they show significantly different estimates of spectrum slope temperature. For all three detectors, 3-D Geant4 Monte Carlo simulations are developed and used to compute instrument response functions. Simulations explain features in raw image-plate data, but only significantly improve systematic errors in predicted detector channel signals for BMXS and do not entirely eliminate the discrepancy between estimates of slope temperature.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

DESAlert: Enabling Real-Time Transient Follow-Up with Dark Energy Survey Data

Here, the Dark Energy Survey is undertaking an observational programme imaging 1/4 of the southern hemisphere sky with unprecedented photometric accuracy. In the process of observing millions of faint stars and galaxies to constrain the parameters of the dark energy equation of state, the Dark Energy Survey will obtain pre-discovery images of the regions surrounding an estimated 100 gamma-ray bursts over 5 yr. Once gamma-ray bursts are detected by, e.g., the Swift satellite, the DES data will be extremely useful for follow-up observations by the transient astronomy community. We describe a recently-commissioned suite of software that listens continuously for automated notices of gamma-ray burst activity, collates information from archival DES data, and disseminates relevant data products back to the community in near-real-time. Of particular importance are the opportunities that non-public DES data provide for relative photometry of the optical counterparts of gamma-ray bursts, as well as for identifying key characteristics (e.g., photometric redshifts) of potential gamma-ray burst host galaxies. We provide the functional details of the DESAlert software, and its data products, and we show sample results from the application of DESAlert to numerous previously detected gamma-ray bursts, including the possible identification of several heretofore unknown gamma-ray burst hosts.

79 ASTRONOMY AND ASTROPHYSICS↗

Probabilistic Assessment of Above Zone Pressure Predictions at a Geologic Carbon Storage Site

Carbon dioxide (CO2) storage into geological formations is regarded as an important mitigation strategy for anthropogenic CO2 emissions to the atmosphere. This study first simulates the leakage of CO2 and brine from a storage reservoir through the caprock. Then, we estimate the resulting pressure changes at the zone overlying the caprock also known as Above Zone Monitoring Interval (AZMI). A data-driven approach of arbitrary Polynomial Chaos (aPC) Expansion is then used to quantify the uncertainty in the above zone pressure prediction based on the uncertainties in different geologic parameters. Finally, a global sensitivity analysis is performed with Sobol indices based on the aPC technique to determine the relative importance of different parameters on pressure prediction. The results indicate that there can be uncertainty in pressure prediction locally around the leakage zones. The degree of such uncertainty in prediction depends on the quality of site specific information available for analysis. The scientific results from this study provide substantial insight that there is a need for site-specific data for efficient predictions of risks associated with storage activities. The presented approach can provide a basis of optimized pressure based monitoring network design at carbon storage sites.

54 ENVIRONMENTAL SCIENCES↗

Sequential data assimilation for single-molecule FRET photon-counting data

Data assimilation is a statistical method designed to improve the quality of numerical simulations in combination with real observations. Here, we develop a sequential data assimilation method that incorporates one-dimensional time-series data of smFRET (single-molecule Förster resonance energy transfer) photon-counting into conformational ensembles of biomolecules derived from “replicated” molecular dynamics (MD) simulations. A particle filter using a large number of “replicated” MD simulations with a likelihood function for smFRET photon-counting data is employed to screen the conformational ensembles that match the experimental data. We examine the performance of the method using emulated smFRET data and coarse-grained (CG) MD simulations of a dye-labeled polyproline-20. The method estimates the dynamics of the end-to-end distance from smFRET data as well as revealing that of latent conformational variables. The particle filter is also able to correct model parameter dependence in CG MD simulations. We discuss the applicability of the method to real experimental data for conformational dynamics of biomolecules.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Enhancing the formation of ionic defects to study the ice Ih/XI transition with molecular dynamics simulations

Ice Ih, the common form of ice in the biosphere, contains proton disorder. Its proton-ordered counterpart, ice XI, is thermodynamically stable below 72 K. However, the formation of ice XI is kinetically hindered, and experimentally it is obtained by doping with KOH. Doping creates ionic defects that promote the migration of protons and the associated change in proton configuration. In this article, we mimic the effect of doping with a bias potential that enhances the formation of ionic defects in molecular dynamics simulations. The recombination of the ions thus formed proceeds through fast migration of the hydroxide along hydrogen bond loops, providing a physical and expedite way to change the proton configuration. Here, a key ingredient of this approach is a machine learning potential trained with density functional theory data and capable of modelling molecular dissociation. We exemplify the usefulness of this idea by studying the order-disorder transition using an appropriate order parameter that distinguishes the proton environments in ice Ih and XI. We calculate the changes in free energy, enthalpy, and entropy associated with the transition. Our estimated entropy agrees with experiment within the error bars of the calculation.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Year six photometric measurements of known Trans-Neptunian Objects and Centaurs by the Dark Energy Survey

ABSTRACT We identified known Trans-Neptunian Objects (TNOs) and Centaurs in the complete Dark Energy Survey (DES) year six catalogue (DES Y6) through the Sky Body Tracker (SkyBoT) tool. We classified our data set of 144 objects into a widely used 4-class taxonomic system of TNOs. No such previous classification was available in the literature for most of these objects. From absolute magnitudes and average albedos, an estimation of the diameters of all these objects is obtained. Correlations involving colours, orbital parameters, dynamical classes, and sizes are also discussed. In particular, our largest reddest object has a diameter of $390^{+68}_{-53}$ km and our largest cold classical, $255^{+19}_{-17}$ km. Also, a weak correlation between colour and inclination is found within the population of resonant TNOs in addition to weak correlations between colour and phase slope in different bands.

79 ASTRONOMY AND ASTROPHYSICS↗

Quantum spin ice response to a magnetic field in the dipole-octupole pyrochlore Ce 2 Zr 2 O 7

The pyrochlore magnet Ce 2 Zr 2 O 7 has attracted much attention as a quantum spin ice candidate whose novelty derives in part from the dipolar-octupolar nature of the Ce 3+ pseudospin-1/2 degrees of freedom it possesses. We report heat capacity measurements on single crystal samples of Ce 2 Zr 2 O 7 down to T~0.1K in a magnetic field along the [$1,\bar{1},0$] direction. These measurements show that the broad hump in the zero-field heat capacity moves higher in temperature with increasing field strength and is split into two separate humps by the [$1,\bar{1},0$] magnetic field at ~2T. These separate features are due to the decomposition of the pyrochlore lattice into effectively decoupled chains for fields in this direction: One set of chains (α chains) is polarized by the field while the other (β chains) remains free. This situation is similar to that observed in the classical spin ices Ho 2 Ti 2 O 7 and Dy 2 Ti 2 O 7 , but with the twist that here the strong transverse exchange interactions produce substantial quantum effects. Our theoretical modeling suggests that the β chains are close to a critical state, with nearly-gapless excitations. We also report elastic and inelastic neutron scattering measurements on single crystal Ce 2 Zr 2 O 7 in [$1,\bar{1},0$] and [0,0,1] magnetic fields at temperatures down to T=0.03K. The elastic scattering behaves consistently with the formation of independent chains for a [$1,\bar{1},0$] field, while the [0,0,1] field produces a single field-induced elastic magnetic Bragg peak at (0,2,0) and equivalent wavevectors, indicating a polarized spin ice state for fields above ~3T. For both [$1,\bar{1},0$] and [0,0,1] magnetic fields, our inelastic neutron scattering results show an approximately dispersionless continuum of scattering that increases in both energy and intensity with increasing field strength. By modeling the complete set of experimental data using numerical linked cluster and semiclassical molecular dynamics calculations, we demonstrate the dominantly multipolar nature of the exchange interactions in Ce 2 Zr 2 O 7 and the smallness of the parameter θ, which controls the mixing between dipolar and octupolar degrees of freedom. Finally, these results support previous estimates of the microscopic exchange parameters and place strong constraints on the theoretical description of this prominent spin ice candidate.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

A Copula-Based Conditional Probabilistic Forecast Model for Wind Power Ramps

Efficient management of wind ramping characteristics can significantly reduce wind integration costs for balancing authorities. By considering the stochastic dependence of wind power ramp (WPR) features, this paper develops a conditional probabilistic wind power ramp forecast (cp-WPRF) model based on Copula theory. The WPRs dataset is constructed by extracting ramps from a large dataset of historical wind power. Each WPR feature (e.g., rate, magnitude, duration, and start-time) is separately forecasted by considering the coupling effects among different ramp features. To accurately model the marginal distributions with a copula, a Gaussian mixture model (GMM) is adopted to characterize the WPR uncertainty and features. The Canonical Maximum Likelihood (CML) method is used to estimate parameters of the multivariable copula. The optimal copula model is chosen based on the Bayesian information criterion (BIC) from each copula family. Finally, the best conditions based cp-WPRF model is determined by predictive interval (PI) based evaluation metrics. Numerical simulations on publicly available wind power data show that the developed copula-based cp-WPRF model can predict WPRs with a high level of reliability and sharpness.

17 WIND ENERGY↗

Life-Cycle Analysis of Shale Gas and Natural Gas

The technologies and practices that have enabled the recent boom in shale gas production have also brought attention to the environmental impacts of its use. Using the current state of knowledge of the recovery, processing, and distribution of shale gas and conventional natural gas, we have estimated up-to-date, life-cycle greenhouse gas emissions. In addition, we have developed distribution functions for key parameters in each pathway to examine uncertainty and identify data gaps - such as methane emissions from shale gas well completions and conventional natural gas liquid unloadings - that need to be addressed further. Our base case results show that shale gas life-cycle emissions are 6% lower than those of conventional natural gas. However, the range in values for shale and conventional gas overlap, so there is a statistical uncertainty regarding whether shale gas emissions are indeed lower than conventional gas emissions. This life-cycle analysis provides insight into the critical stages in the natural gas industry where emissions occur and where opportunities exist to reduce the greenhouse gas footprint of natural gas.

03 NATURAL GAS↗

Jobs and Economic Development Impact (JEDI) User Reference Guide: Fast Pyrolysis Biorefinery Model

This guide -- the JEDI Fast Pyrolysis Biorefinery Model User Reference Guide -- was developed to assist users in operating and understanding the JEDI Fast Pyrolysis Biorefinery Model. The guide provides information on the model's underlying methodology, as well as the parameters and data sources used to develop the cost data utilized in the model. This guide also provides basic instruction on model add-in features and a discussion of how the results should be interpreted. Based on project-specific inputs from the user, the JEDI Fast Pyrolysis Biorefinery Model estimates local (e.g., county- or state-level) job creation, earnings, and output from total economic activity for a given fast pyrolysis biorefinery. These estimates include the direct, indirect and induced economic impacts to the local economy associated with the construction and operation phases of biorefinery projects.Local revenue and supply chain impacts as well as induced impacts are estimated using economic multipliers derived from the IMPLAN software program. By determining the local economic impacts and job creation for a proposed biorefinery, the JEDI Fast Pyrolysis Biorefinery Model can be used to field questions about the added value biorefineries might bring to a local community.

09 BIOMASS FUELS↗

System Study: High-Pressure Safety Injection 1998-2022

This report presents an unreliability evaluation of the high-pressure safety injection system (HPSI) at 62 U.S. commercial operating nuclear reactors. New Standardized Plant Analysis Risk (SPAR) models with the most recent SPAR parameter update results were used in this report. Demand, run hours, and failure data from calendar years 1998–2022 for selected components were obtained from the Institute of Nuclear Power Operations Industry Reporting and Information System. The unreliability results are trended for the most recent 10-year period while yearly estimates for system unreliability are provided for the entire active period. Highly statistically significant increasing trends were identified in both the HPSI system start-only unreliability and 8-hour mission unreliability.

99 GENERAL AND MISCELLANEOUS↗

System Study: Auxiliary Feedwater 1998-2022

This report presents an unreliability evaluation of the auxiliary feedwater (AFW) system at 62 U.S. commercial operating nuclear reactors. New Standardized Plant Analysis Risk (SPAR) models with the most recent SPAR parameter update results were used in this report. Demand, run hour, and failure data from calendar year 1998–2022 for selected components were obtained from the Institute of Nuclear Power Operations Industry Reporting and Information System. The unreliability results are trended for the most recent 10 year period while yearly estimates for system unreliability are provided for the entire active period. No statistically significant increasing or decreasing trends were identified in the industry-wide estimates of AFW system start-only unreliability, but a highly statistically significant decreasing trend was identified in the industry-wide estimates of AFW system 8-hour mission unreliability.

99 GENERAL AND MISCELLANEOUS↗

System Study: Reactor Core Isolation Cooling 1998-2022

This report presents an unreliability evaluation of the reactor core isolation cooling (RCIC) system at 28 U.S. commercial operating boiling water reactors. New Standardized Plant Analysis Risk (SPAR) models with the most recent SPAR parameter update results were used in this report. Demand, run hour, and failure data from calendar years 1998–2022 for selected components were obtained from the Institute of Nuclear Power Operations Industry Reporting and Information System. The unreliability results are trended for the most recent 10 year period while yearly estimates for system unreliability are provided for the entire active period. Statistically significant decreasing trends were identified in both the RCIC system start-only unreliability and 8-hour mission unreliability.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Testing the ΛCDM Cosmological Model with Forthcoming Measurements of the Cosmic Microwave Background with SPT-3G

We forecast constraints on cosmological parameters enabled by three surveys conducted with SPT-3G, the third-generation camera on the South Pole Telescope. The surveys cover separate regions of 1500, 2650, and 6000 deg$^{2}$ to different depths, in total observing 25% of the sky. These regions will be measured to white noise levels of roughly 2.5, 9, and 12μK-armin, respectively, in cosmic microwave background (CMB) temperature units at 150 GHz by the end of 2024. The survey also includes measurements at 95 and 220 GHz, which have noise levels a factor of ∼1.2 and 3.5 times higher than 150 GHz, respectively, with each band having a polarization noise level ∼2times higher than the temperature noise. We use a novel approach to obtain the covariance matrices for jointly and optimally estimated gravitational lensing potential band powers and unlensed CMB temperature and polarization band powers. We demonstrate the ability to test the ΛCDM model via the consistency of cosmological parameters constrained independently from SPT-3G and Planck data, and consider the improvement in constraints on ΛCDM extension parameters from a joint analysis of SPT-3G and Planck data. The ΛCDM cosmological parameters are typically constrained with uncertainties up to ∼2 times smaller with SPT-3G data, compared to Planck, with the two data sets measuring significantly different angular scales and polarization levels, providing additional tests of the standard cosmological model.

79 ASTRONOMY AND ASTROPHYSICS↗

3-D Modeling of the CFR Engine for the Investigation of Knock on Natural Gas

Engine knock and misfire are barriers to pathways leading to higher efficiency natural gas (NG) engines, where the general tendency to knock is highly dependent on engine operating conditions and the fuel reactivity. The problem is further complicated by low emissions limits and the wide range of chemical reactivity in pipeline quality NG, making the understanding of fuel-engine interactions essential to achieving high efficiencies in spark-ignited NG engines. The present work highlights a three-dimensional computational fluid dynamics (CFD) model of the Cooperative Fuel Research (CFR) engine to investigate knock behavior when running on NG. Using a Converge CFD model of the CFR engine fuel-engine interactions that lead to knock with NG, including effects of fuel reactivity, engine operating parameters, and exhaust gas recirculation, are being investigated. A GT-Power model is used to estimate appropriate initial conditions in the Converge CFD model, including cylinder wall, piston, valves, and port surface temperatures as well as residual gas fraction. In order to validate the model, in-cylinder pressure data taken with a CFR engine is compared to model predictions while varying compression ratio, CA50, and BMEP.

Bestel, Diego↗

3-D Modeling of the CFR Engine for the Investigation of Knock on Natural Gas

Abstract: Engine knock and misfire are barriers to pathways leading to higher efficiency natural gas (NG) engines, where the general tendency to knock is highly dependent on engine operating conditions and the fuel reactivity. The problem is further complicated by low emissions limits and the wide range of chemical reactivity in pipeline quality NG, making the understanding of fuel- engine interactions essential to achieving high efficiencies in spark-ignited NG engines. The present work highlights a three-dimensional computational fluid dynamics (CFD) model of the Cooperative Fuel Research (CFR) engine to investigate knock behavior when running on NG. Using a Converge CFD model of the CFR engine fuel-engine interactions that lead to knock with NG, including effects of fuel reactivity, engine operating parameters, and exhaust gas recirculation, are being investigated. A GT-Power model is used to estimate appropriate initial conditions in the Converge CFD model, including cylinder wall, piston, valves, and port surface temperatures as well as residual gas fraction. In order to validate the model, in-cylinder pressure data taken with a CFR engine is compared to model predictions while varying compression ratio, CA50, and BMEP.

CFR Engine, Converge CFD, knock, Natural Gas↗

A Proposal for a Three Detector Short-Baseline Neutrino Oscillation Program in the Fermilab Booster Neutrino Beam

A Short-Baseline Neutrino (SBN) physics program of three LAr-TPC detectors located along the Booster Neutrino Beam (BNB) at Fermilab is presented. This new SBN Program will deliver a rich and compelling physics opportunity, including the ability to resolve a class of experimental anomalies in neutrino physics and to perform the most sensitive search to date for sterile neutrinos at the eV mass-scale through both appearance and disappearance oscillation channels. Using data sets of 6.6e20 protons on target (P.O.T.) in the LAr1-ND and ICARUS T600 detectors plus 13.2e20 P.O.T. in the MicroBooNE detector, we estimate that a search for muon neutrino to electron neutrino appearance can be performed with ~5 sigma sensitivity for the LSND allowed (99% C.L.) parameter region. In this proposal for the SBN Program, we describe the physics analysis, the conceptual design of the LAr1-ND detector, the design and refurbishment of the T600 detector, the necessary infrastructure required to execute the program, and a possible reconfiguration of the BNB target and horn system to improve its performance for oscillation searches.

43 PARTICLE ACCELERATORS↗