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At least 1,279 records · Page 71

χ{sup (3)} measurements of axial ligand modified high valent tin(IV) porphyrins using degenarete four wave mixing at 532nm

Porphyrins and metalloporphyrins are unique class of molecules for Nonlinear Optical applications because of their unique structure of altering the central metal atom, large extended π-system, high thermal stability, tunable shape, symmetry and synthetic versatility Here, we report χ{sup (3)} Measurements of a simple phenyl porphyrins and its highvalent tin(IV) porphyrins with Bromination characterized by UV-Visible spectroscopic method. In this study, we employed the Degenerate Four Wave Mixing technique using forward Boxcar geometry with an Nd:YAG nano second pulsed laser as source and it was found that the tin(IV) porphyrin with Bromination exhibits good χ{sup (3)} value and figure of merit.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Investigation of gas sensing properties of InN nanoparticles

InN nanoparticles were grown by chemical vapor deposition technique using In{sub 2}O{sub 3} as precursor material. Raman spectroscopic studies show the presence of the wurtzite phase of as-grown InN. Size of the nanoparticles were in range from quantum dot (<8 nm) to larger sized particles (100 nm). We studied the gas sensing properties of InN nanoparticles with CH{sub 4} gas. Sensors substrates were fabricated with interdigitated Au electrodes. InN nanoparticles show high response towards CH{sub 4} with minimum detectable concentration of 50 ppm at 200 °C.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Iterative subspace algorithms for finite-temperature solution of Dyson equation

One-particle Green’s functions obtained from the self-consistent solution of the Dyson equation can be employed in the evaluation of spectroscopic and thermodynamic properties for both molecules and solids. However, typical acceleration techniques used in the traditional quantum chemistry self-consistent algorithms cannot be easily deployed for the Green’s function methods because of a non-convex grand potential functional and a non-idempotent density matrix. Moreover, the optimization problem can become more challenging due to the inclusion of correlation effects, changing chemical potential, and fluctuations of the number of particles. In this paper, we study acceleration techniques to target the self-consistent solution of the Dyson equation directly. We use the direct inversion in the iterative subspace (DIIS), the least-squared commutator in the iterative subspace (LCIIS), and the Krylov space accelerated inexact Newton method (KAIN). We observe that the definition of the residual has a significant impact on the convergence of the iterative procedure. Based on the Dyson equation, we generalize the concept of the commutator residual used in DIIS and LCIIS and compare it with the difference residual used in DIIS and KAIN. The commutator residuals outperform the difference residuals for all considered molecular and solid systems within both GW and GF2. For a number of bond-breaking problems, we found that an easily obtained high-temperature solution with effectively suppressed correlations is a very effective starting point for reaching convergence of the problematic low-temperature solutions through a sequential reduction of temperature during calculations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

MEAN-FLUX-REGULATED PRINCIPAL COMPONENT ANALYSIS CONTINUUM FITTING OF SLOAN DIGITAL SKY SURVEY Ly{alpha} FOREST SPECTRA

Continuum fitting is an important aspect of Ly{alpha} forest science, since errors in the derived optical depths scale with the fractional continuum error. However, traditional methods of estimating continua in noisy and moderate-resolution spectra (e.g., Sloan Digital Sky Survey, SDSS; S/N {approx}< 10 pixel{sup -1} and R {approx} 2000), such as power-law extrapolation or dividing by the mean spectrum, achieve no better than {approx}15% rms accuracy. To improve on this, we introduce mean-flux-regulated principal component analysis (MF-PCA) continuum fitting. In this technique, PCA fitting is carried out redward of the quasar Ly{alpha} line in order to provide a prediction for the shape of the Ly{alpha} forest continuum. The slope and amplitude of this continuum prediction is then corrected using external constraints for the Ly{alpha} forest mean flux. This requires prior knowledge of the mean flux, (F), but significantly improves the accuracy of the flux transmission, F {identical_to} exp (- {tau}), estimated from each pixel. From tests on mock spectra, we find that MF-PCA reduces the errors to 8% rms in S/N {approx} 2 spectra, and <5% rms in spectra with S/N {approx}> 5. The residual Fourier power in the continuum is decreased by a factor of a few in comparison with dividing by the mean continuum, enabling Ly{alpha} flux power spectrum measurements to be extended to {approx}2 Multiplication-Sign larger scales. Using this new technique, we make available continuum fits for 12,069 z > 2.3 Ly{alpha} forest spectra from SDSS Data Release 7 for use by the community. This technique is also applicable to future releases of the ongoing Baryon Oscillations Spectroscopic Survey, which obtains spectra for {approx}150, 000 Ly{alpha} forest spectra at low signal-to-noise (S/N {approx} 2).

79 ASTRONOMY AND ASTROPHYSICS↗

Full calibration of the tomographic redshift distribution from the HSC PDR3 Shape Catalog with DESI

The calibration of tomographic redshift distributionsis essential for cosmological analysis of weak lensing data.In this work, we calibrate all four tomographic bins of the Hyper Suprime Camera (HSC) weak lensing catalog with the Dark Energy Spectroscopic Instrument (DESI) Data Release 1 and 2 using the clustering redshifts technique. We include z > 1.2 redshift sources such as emission line galaxies (ELG) and quasars (QSO) sources in our calibration, which were not available in the previous HSC calibration (Rau et al. (2022), Mon. Not. Roy. Astron. Soc. 524 (2023) 5109), allowing a complete calibration of all the redshift bins. We find the first tomographic bin exhibits a small shift towards low redshifts. The second bin is in good agreement with the photometric calibration, while third and fourth bin exhibit a shift towards higher redshifts. However, these shifts are considerably smaller than the shifts obtained in the HSC Year 3 cosmic shear analyses. We evaluate the impact of galaxy bias and magnification effects from all the samples on the measurements, finding them to be small, and we propose corrections to reduce them further. Specifically, we relax the assumption of linear bias and only assume no redshift evolution of the cross-correlation coefficient, allowing us to leverage smaller clustering scales. We model the redshift distributions with splines and compare our results to previous analyses as well as to other parameterizations found in literature. For the two high-redshift tomographic bins, we find the shifts to higher redshifts with respect to the measurements performed in Rau+2022 to be Δz$_{3}$ =-0.039$^{+0.020}$$_{-0.021}$ and Δz$_{4}$ = -0.048$^{+0.012}$$_{-0.012}$.

Choppin de Janvry, J. [LBL, Berkeley; UC, Berkeley↗

The unrelaxed dynamical structure of the galaxy cluster Abell 85

For the first time, we explore the dynamics of the central region of a galaxy cluster within r {sub 500} ∼ 600 h{sup −1} kpc from its center by combining optical and X-ray spectroscopy. We use (1) the caustic technique, which identifies the cluster substructures and their galaxy members with optical spectroscopic data, and (2) the X-ray redshift fitting procedure, which estimates the redshift distribution of the intracluster medium (ICM). We use the spatial and redshift distributions of the galaxies and of the X-ray-emitting gas to associate the optical substructures to the X-ray regions. When we apply this approach to Abell 85 (A85), a complex dynamic structure of A85 emerges from our analysis: a galaxy group, with redshift z = 0.0509 ± 0.0021 is passing through the cluster center along the line of sight dragging part of the ICM present in the cluster core; two additional groups, at redshift z = 0.0547 ± 0.0022 and z = 0.0570 ± 0.0020, are going through the cluster in opposite directions, almost perpendicularly to the line of sight, and have substantially perturbed the dynamics of the ICM. An additional group in the outskirts of A85, at redshift z = 0.0561 ± 0.0023, is associated with a secondary peak of X-ray emission, at redshift z=0.0583{sub −0.0047}{sup +0.0039}. Although our analysis and results on A85 need to be confirmed by high-resolution spectroscopy, they demonstrate how our new approach can be a powerful tool to constrain the formation history of galaxy clusters by unveiling their central and surrounding structures.

79 ASTRONOMY AND ASTROPHYSICS↗

Blazars at the Cosmic Dawn

The uncharted territory of the high-redshift (z ≳ 3) universe holds the key to understanding the evolution of quasars. In an attempt to identify the most extreme members of the quasar population, that is, blazars, we have carried out a multiwavelength study of a large sample of radio-loud quasars beyond z = 3. Our sample consists of nine γ-ray-detected blazars and 133 candidate blazars selected based on the flatness of their soft X-ray spectra (0.3–10 keV photon index $\leqslant$ 1.75), including 15 with Nuclear Spectroscopic Telescope Array (NuSTAR) observations. The application of the likelihood profile stacking technique reveals that the high-redshift blazars are faint γ-ray emitters with steep spectra. The high-redshift blazars host massive black holes ($\langle$log M BH , M$\bigodot$ $\rangle$> 9) and luminous accretion disks ($\langle$L disk $\rangle$ > 10 46 erg s -1 ). Their broadband spectral energy distributions are found to be dominated by high-energy radiation, indicating their jets are among the most luminous ones. Focusing on the sources exhibiting resolved X-ray jets (as observed with the Chandra satellite), we find the bulk Lorentz factor to be larger with respect to other z > 3 blazars, indicating faster moving jets. In this paper, we conclude that the presented list of high-redshift blazars may act as a reservoir for follow-up observations, such as with NuSTAR, to understand the evolution of relativistic jets at the dawn of the universe.

79 ASTRONOMY AND ASTROPHYSICS↗

Design and operation of the Pioneer Venus Orbiter ultraviolet spectrometer

The University of Colorado's ultraviolet spectrometer instrument carried on the Pioneer Venus Orbiter spacecraft is a 125-mm f/5 Ebert-Fastie design with a 250-mm Cassegrain telescope. The instrument has extensive logic to control the grating motor drive and to adapt the basic spectrometer to the constraints and opportunities of the mission. Success has been achieved in reconciling the conflicting requirements of spectroscopic, limb profile, and imaging observations. A description of the instrument operating techniques is given together with representative results of all three types.

Stewart, A. I. F.↗

Spectral Indices to Monitor Nitrogen-Driven Carbon Uptake in Field Corn

Climate change is heavily impacted by changing vegetation cover and productivity with large scale monitoring of vegetation only possible with remote sensing techniques. The goal of this effort was to evaluate existing reflectance (R) spectroscopic methods for determining vegetation parameters related to photosynthetic function and carbon (C) dynamics in plants. Since nitrogen (N) is a key constituent of photosynthetic pigments and C fixing enzymes, biological C sequestration is regulated in part by N availability. Spectral R information was obtained from field corn grown at four N application rates (0, 70, 140, 280 kg N/ha). A hierarchy of spectral observations were obtained: leaf and canopy with a spectral radiometer; aircraft with the AISA sensor; and satellite with EO-1 Hyperion. A number of spectral R indices were calculated from these hyperspectral observations and compared to geo-located biophysical measures of plant growth and physiological condition. Top performing indices included the R derivative index D730/D705 and the normalized difference of R750 vs. R705 (ND705), both of which differentiated three of the four N fertilization rates at multiple observation levels and yielded high correlations to these carbon parameters: light use efficiency (LUE); C:N ratio; and crop grain yield. These results advocate the use of hyperspectral sensors for remotely monitoring carbon cycle dynamics in managed terrestrial ecosystems.

Corp, Lawrence A.↗

Kinetic theory for charge-exchange spectroscopy: Effects of magnetic and electric fields on the distribution function after charge-exchange

In plasmas equipped with neutral beam injection, excitation of atomic spectral lines via charge-exchange with neutral atoms is the basis of one of the standard plasma diagnostic techniques for ion density, temperature, and velocity. In order to properly interpret the spectroscopic results, one must consider the effects of the energy dependence of the charge-exchange cross-section as well as the motion of the ion after charge-exchange during the period when it is still in the excited state. This motion is affected by the electric and magnetic fields in the plasma. The present paper gives results for the velocity distribution function of the excited state ions and considers in detail the cross-section and ion motion effects on the post charge-exchange velocity. The expression for this velocity in terms of the charge-exchange cross-section and the pre charge-exchange velocity allows that latter velocity to be determined. The present paper is the first to consider the effect of the electric as well as the magnetic field and demonstrates that electric field and diamagnetic terms appear in the expression for the inferred velocity. The present formulation also leads to a novel technique for assessing the effect of the energy dependence of the charge-exchange cross-section on the inferred ion temperature.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

J-PLUS: Systematic impact of metallicity on photometric calibration with the stellar locus

Here, we present the photometric calibration of the twelve optical passbands for the Javalambre Photometric Local Universe Survey (J-PLUS) second data release (DR2), comprising 1088 pointings of two square degrees, and study the systematic impact of metallicity on the stellar locus technique. The [Fe/H] metallicity from the Large Sky Area Multi-Object Fiber Spectroscopic Telescope (LAMOST) for 146 184 high-quality calibration stars, defined with signal-to-noise ratio larger than ten in J-PLUS passbands and larger than three in Gaia parallax, was used to compute the metallicity-dependent stellar locus (ZSL). The initial homogenization of J-PLUS photometry, performed with a unique stellar locus, was refined by including the metallicity effect in colors via the ZSL. The variation of the average metallicity along the Milky Way produces a systematic offset in J-PLUS calibration. This effect is well above 1% for the bluer passbands and amounts 0.07, 0.07, 0.05, 0.03, and 0.02 mag in u, J0378, J0395, J0410, and J0430, respectively. We modeled this effect with the Milky Way location of the J-PLUS pointing, also providing an updated calibration for those observations without LAMOST information. The estimated accuracy in the calibration after including the metallicity effect is at 1% for the bluer J-PLUS passbands and below for the rest. Photometric calibration with the stellar locus technique is prone to significant systematic bias in the Milky Way for passbands bluer than λ = 4500 Å. The calibration method for J-PLUS DR2 reaches 1–2% precision and 1% accuracy for 12 optical filters within an area of 2176 square degrees.

79 ASTRONOMY AND ASTROPHYSICS↗

Inversion technique to obtain local ion temperature profiles for an axisymmetric plasma with toroidal and radial velocities

A matrix inversion technique is derived to calculate local ion temperature from line-integrated measurements of an extended emission source in an axisymmetric plasma which exactly corrects for both toroidal velocity and radial velocity components. Local emissivity and toroidal velocity can be directly recovered from line-integrated spectroscopic measurements, but an independent measurement of the radial velocity is necessary to complete the temperature inversion. The extension of this technique to handle the radial velocity is relevant for magnetic reconnection and merging compression devices where temperature inversion from spectroscopic measurements is desired. A simulation demonstrates the effects of radial velocity on the determination of ion temperature.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Inversion technique to obtain local ion temperature profiles for an axisymmetric plasma with toroidal and radial velocities

A matrix inversion technique is derived to calculate local ion temperature from line-integrated measurements of an extended emission source in an axisymmetric plasma which exactly corrects for both toroidal velocity and radial velocity components. Local emissivity and toroidal velocity can be directly recovered from line-integrated spectroscopic measurements, but an independent measurement of the radial velocity is necessary to complete the temperature inversion. The extension of this technique to handle the radial velocity is relevant for magnetic reconnection and merging compression devices where temperature inversion from spectroscopic measurements is desired. A simulation demonstrates the effects of radial velocity on the determination of ion temperature.

ion temperature↗

Thin-Layer Spectroelectrochemistry on an Aqueous Microdrop

In this paper, we report a technique for conducting spectroelectrochemistry on an aqueous micro-drop containing an analyte in a bulk electrolysis system, as an easy, rapid and economic way of investigating spectroelectrochemical behavior and correlating spectroscopic properties with thermodynamic potentials on a small scale. The chemical systems used to demonstrate the aqueous micro-drop technique are an absorbance based molecular probe [Fe(CN)6]3-/4- and an emission based molecular probe [Re(dmpe)3]2+/+ . These chemical systems in a micro-drop are evaluated using cyclic voltammetry, UV-visable absorbance spectroscopy, and fluorescence spectrometry.

electrochemistry, UV-visable absorbance spectrosco↗

An analysis of parameter compression and Full-Modeling techniques with Velocileptors for DESI 2024 and beyond

In anticipation of forthcoming data releases of current and future spectroscopic surveys, we present the validation tests and analysis of systematic effects within velocileptors modeling pipeline when fitting mock data from the AbacusSummit N-body simulations. We compare the constraints obtained from parameter compression methods to the direct fitting (Full-Modeling) approaches of modeling the galaxy power spectra, and show that the ShapeFit extension to the traditional template method is consistent with the Full-Modeling method within the standard ΛCDM parameter space. We show the dependence on scale cuts when fitting the different redshift bins using the ShapeFit and Full-Modeling methods. We test the ability to jointly fit data from multiple redshift bins as well as joint analysis of the pre-reconstruction power spectrum with the post-reconstruction BAO correlation function signal. We further demonstrate the behavior of the model when opening up the parameter space beyond ΛCDM and also when combining likelihoods with external datasets, namely the Planck CMB priors. Finally, we describe different parametrization options for the galaxy bias, counterterm, and stochastic parameters, and employ the halo model in order to physically motivate suitable priors that are necessary to ensure the stability of the perturbation theory.

79 ASTRONOMY AND ASTROPHYSICS↗

Star-spots and magnetism: testing the activity paradigm in the Pleiades and M67

We measure star-spot filling fractions for 240 stars in the Pleiades and M67 open star clusters using APOGEE high-resolution H-band spectra. For this work, we developed a modified spectroscopic pipeline which solves for star-spot filling fraction and star-spot temperature contrast. We exclude binary stars, finding that the large majority of binaries in these clusters (80 per cent) can be identified from Gaia DR3 and APOGEE criteria – important for field star applications. Our data agree well with independent activity proxies, indicating that this technique recovers real star-spot signals. In the Pleiades, filling fractions saturate at a mean level of 0.248 ± 0.005 for active stars with a decline at slower rotation; we present fitting functions as a function of Rossby number. In M67, we recover low mean filling fractions of 0.030 ± 0.008 and 0.003 ± 0.002 for main sequence GK stars and evolved red giants, respectively, confirming that the technique does not produce spurious spot signals in inactive stars. Star-spots also modify the derived spectroscopic effective temperatures and convective overturn time-scales. Effective temperatures for active stars are offset from inactive ones by −109 ± 11 K, in agreement with the Pecaut & Mamajek empirical scale. Star-spot filling fractions at the level measured in active stars changes their inferred overturn time-scale, which biases the derived threshold for saturation. Finally, we identify a population of stars statistically discrepant from mean activity–Rossby relations and present evidence that these are genuine departures from a Rossby scaling. Our technique is applicable to the full APOGEE catalogue, with broad applications to stellar, galactic, and exoplanetary astrophysics.

79 ASTRONOMY AND ASTROPHYSICS↗

Highlights of NASA’s Orbital Debris Program Office In Situ and Laboratory Measurements

NASA’s Orbital Debris Program Office (ODPO) maintains various returned spacecraft materials, capabilities, and facilities used for in situ and laboratory measurements that directly support orbital debris environmental models. In situ measurements include the analysis of exposed and returned hardware surfaces. These surfaces serve as passive sensors for the small-sized micrometeoroid and orbital debris (MMOD) flux below the sensitivity of ground-based radar and optical sensors. Various instruments and techniques are used to determine the size and depth of selected impact features, and – if feasible – the composition of the projectile material. Analysis of the impactor residues enables the differentiation of MM and OD for debris below 1 mm to support modeling the OD environment. In addition, projectiles identified as OD can be further differentiated in low-, medium-, and high- density impactors based on chemical analyses. In addition to in situ measurements, the ODPO has also worked in collaboration with the U.S. Space Force Space Systems Command (formerly the U.S. Air Force Space and Missile Systems Center), the Aerospace Corporation, and the University of Florida on a laboratory-based hypervelocity impact test, DebriSat, conducted at the Air Force Arnold Engineering Development Complex in 2014. The resulting data from this impact test series are being analyzed to assess the fragments’ sizes/masses, materials/densities, shapes, and other parameters of interest. The DebriSat project provides the data needed to update NASA’s breakup models and size estimation models using the simulated orbital breakup of a modern, low Earth orbit spacecraft. Ultimately, over 200,000 fragments from this impact test will be stored at NASA Johnson Space Center (JSC) and further analyzed by the ODPO. This project will also use machine learning techniques to infer physical parameters of fragments embedded in the soft-catch foam used in the impact experiment. Applied to X-ray imagery of the foam panels, these techniques promise to minimize human-in-the-loop processes for fragment extraction and physical characterization. A brief overview of this project and data collected will be presented. Lastly, the ODPO provides various capabilities hosted at NASA JSC for optical inspections and measurements using a variety of techniques and scientific instrumentation to support both in situ and laboratory measurements. The ODPO’s Optical Measurement Center (OMC) is an advanced facility for photometric and spectroscopic laboratory measurements of targets, including fragments from the DebriSat project. The OMC simulates telescopic observations by using space-like illumination conditions and source-target-sensor orientation techniques. Additionally, the OMC is uniquely equipped to acquire pseudo-bidirectional reflectance distribution data for broadband photometric measurements, thus removing aspect angle dependencies that can affect target size estimates using the optical size estimation model. Narrow-band surface material characterization using spectroscopic instrumentation gives insight into how the albedo parameter – also important in the optical size estimation model – may vary depending on the state of the material. The OMC also performs simulations of photometric measurements using optical ray-tracing software to model the OMC optical throughput. In addition to the OMC, the ODPO houses a start-of-the-art Fragment Analysis Facility that uses multiple microscopic inspection instruments to support in situ measurements and material characterization. An overview of both facilities will be highlighted in this paper.

Orbital Debris↗

Highlights of NASA’s Orbital Debris Program Office In Situ and Laboratory Measurements

NASA’s Orbital Debris Program Office (ODPO) maintains various returned spacecraft materials, capabilities, and facilities used for in situ and laboratory measurements that directly support orbital debris environmental models. In situ measurements include the analysis of exposed and returned hardware surfaces. These surfaces serve as passive sensors for the small-sized micrometeoroid and orbital debris (MMOD) flux below the sensitivity of ground-based radar and optical sensors. Various instruments and techniques are used to determine the size and depth of selected impact features, and – if feasible – the composition of the projectile material. Analysis of the impactor residues enables the differentiation of MM and OD for debris below 1 mm to support modeling the OD environment. In addition, projectiles identified as OD can be further differentiated in low-, medium-, and high- density impactors based on chemical analyses. In addition to in situ measurements, the ODPO has also worked in collaboration with the U.S. Space Force Space Systems Command (formerly the U.S. Air Force Space and Missile Systems Center), the Aerospace Corporation, and the University of Florida on a laboratory-based hypervelocity impact test, DebriSat, conducted at the Air Force Arnold Engineering Development Complex in 2014. The resulting data from this impact test series are being analyzed to assess the fragments’ sizes/masses, materials/densities, shapes, and other parameters of interest. The DebriSat project provides the data needed to update NASA’s breakup models and size estimation models using the simulated orbital breakup of a modern, low Earth orbit spacecraft. Ultimately, over 200,000 fragments from this impact test will be stored at NASA Johnson Space Center (JSC) and further analyzed by the ODPO. This project will also use machine learning techniques to infer physical parameters of fragments embedded in the soft-catch foam used in the impact experiment. Applied to X-ray imagery of the foam panels, these techniques promise to minimize human-in-the-loop processes for fragment extraction and physical characterization. A brief overview of this project and data collected will be presented. Lastly, the ODPO provides various capabilities hosted at NASA JSC for optical inspections and measurements using a variety of techniques and scientific instrumentation to support both in situ and laboratory measurements. The ODPO’s Optical Measurement Center (OMC) is an advanced facility for photometric and spectroscopic laboratory measurements of targets, including fragments from the DebriSat project. The OMC simulates telescopic observations by using space-like illumination conditions and source-target-sensor orientation techniques. Additionally, the OMC is uniquely equipped to acquire pseudo-bidirectional reflectance distribution data for broadband photometric measurements, thus removing aspect angle dependencies that can affect target size estimates using the optical size estimation model. Narrow-band surface material characterization using spectroscopic instrumentation gives insight into how the albedo parameter – also important in the optical size estimation model – may vary depending on the state of the material. The OMC also performs simulations of photometric measurements using optical ray-tracing software to model the OMC optical throughput. In addition to the OMC, the ODPO houses a start-of-the-art Fragment Analysis Facility that uses multiple microscopic inspection instruments to support in situ measurements and material characterization. An overview of both facilities will be highlighted in this paper.

Orbital Debris↗