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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,297 records · Page 72

Monolithic mtesla-level magnetic induction by self-rolled-up membrane technology

Monolithic strong magnetic induction at the mtesla to tesla level provides essential functionalities to physical, chemical, and medical systems. Current design options are constrained by existing capabilities in three-dimensional (3D) structure construction, current handling, and magnetic material integration. We report here geometric transformation of large-area and relatively thick (~100 to 250 nm) 2D nanomembranes into multiturn 3D air-core microtubes by a vapor-phase self-rolled-up membrane (S-RuM) nanotechnology, combined with postrolling integration of ferrofluid magnetic materials by capillary force. Hundreds of S-RuM power inductors on sapphire are designed and tested, with maximum operating frequency exceeding 500 MHz. An inductance of 1.24 μH at 10 kHz has been achieved for a single microtube inductor, with corresponding areal and volumetric inductance densities of 3 μH/mm 2 and 23 μH/mm 3 , respectively. The simulated intensity of the magnetic induction reaches tens of mtesla in fabricated devices at 10 MHz.

42 ENGINEERING↗

Determination of Non-Thermal Velocity Distributions from SERTS Linewidth Observations

Non-thermal velocities obtained from the measurement of coronal Extreme Ultraviolet (EUV) linewidths have been consistently observed in solar EUV spectral observations and have been theorized to result fro m many plausible scenarios including wave motions, turbulence, or magnetic reconnection. Constraining these velocities can provide a physical limit for the available energy resulting from unresolved motions in the corona. We statistically determine a series of non-thermal velocity distributions from linewidth measurements of 390 emission lines from a wide array of elements and ionization states observed during the Solar Extreme Ultraviolet Research Telescope and Spectrograph 1991-1997 flights covering the spectral range 174-418 A and a temperature range from 80,000 K to 12.6 MK. This sample includes 248 lines from active regions, 101 lines from quiet-Sun regions, and 41 lines were observed from plasma off the solar limb. We find a strongly peaked distribution corresponding to a non-thermal velocity of 19-22 km/s in all three of the quiet-Sun, active region, and off-limb distributions. For the possibility of Alfven wave resonance heating, we find thai velocities in the core of these distributions do not provide sufficient energy, given typical densities and magnetic field strengths for the coronal plasma, to overcome the estimated coronal energy losses required to maintain the corona at the typical temperatures working as the sole mechanism. We find that at perfect efficiency 50%-60% of the needed energy flux can be produced from the non-thermal velocities measured.

Coyner, Aaron J.↗

27 Al NMR diffusometry of Al 13 Keggin nanoclusters

Although nanometer-sized aluminum hydroxide clusters (i.e., ϵ-Al 13 , [Al 13 O 4 (OH) 24 (H 2 O) 12 ] 7+ ) command a central role in aluminum ion speciation and transformations between minerals, measurement of their translational diffusion is often limited to indirect methods. Here, in this work, 27 Al pulsed field gradient stimulated echo nuclear magnetic resonance (PFGSTE NMR) spectroscopy has been applied to the AlO 4 core of the ϵ-Al 13 cluster with complementary theoretical simulations of the diffusion coefficient and corresponding hydrodynamic radii from a boundary element-based calculation. The tetrahedral AlO 4 center of the ϵ-Al 13 cluster is symmetric and exhibits only weak quadrupolar coupling, which results in favorable T 1 and T 2 27 Al NMR relaxation coefficients for 27 Al PFGSTE NMR studies. Stokes–Einstein relationship was used to relate the 27 Al diffusion coefficient of the ϵ-Al 13 cluster to the hydrodynamic radius for comparison with theoretical simulations, dynamic light scattering from literature, and previously published 1 H PFGSTE NMR studies of chelated Keggin clusters. This first-of-its-kind observation proves that 27 Al PFGSTE NMR diffusometry can probe symmetric Al environments in polynuclear clusters of greater molecular weight than previously considered.

27Al↗

Local Chemical Strain in PtFe Alloy Nanoparticles

Precise deciphering of the atomic-insight chemical strain and distribution in nanosolids, especially in nanoalloys with disordered structure, is significant to correlate the structure and chemical properties. In this report, we found an abnormally enhanced negative thermal expansion (NTE) along the c axis in a 3.5 nm PtFe magnetic L1 0 alloy, which was usually weakened by the reduced contribution of invar behavior in a nanosized magnetic material. 57 Fe Mössbauer spectra and extended X-ray absorption fine structure studies indicated the local disordered state of chemical coordination of the L1 0 phase. Pair distribution function and reverse Monte Carlo simulation revealed a surface A1-phase coating and atomic-level stretching chemical strain on the heteroatomic pair along the c axis. Local tensile chemical strain and increasing magnetic moments of Fe atoms on the surface of the L1 0 core made a dominant contribution to the enhanced NTE behavior. Furthermore, the present work brings an atomic reveal for the local chemical strain in bimetallic nanomaterials and provides an innovative perspective to tailoring the functional properties according to the local chemical environment.

36 MATERIALS SCIENCE↗

Chemical Design of Spin Frustration to Realize Topological Spin Glasses

Patterning spins to generate collective behavior is at the core of condensed matter physics. Physicists develop techniques, including the fabrication of magnetic nanostructures and precision layering of materials specifically to engender frustrated lattices. As chemists, we can access such exotic materials through targeted chemical synthesis and create new lattice types by chemical design. Here, in this study, we introduce a new approach to induce magnetic frustration on a modified honeycomb lattice through a competition of alternating antiferromagnetic (AFM) and ferromagnetic (FM) nearest-neighbor interactions. By subtly modulating these two types of interactions through facile synthetic modifications, we created two systems: (1) a topological spin glass and (2) a frustrated spin-canted magnet with low-temperature exchange bias. To design this unconventional magnetic lattice, we used a metal–organic framework (MOF) platform, Ni 3 (pymca) 3 X 3 (NipymcaX where pymca = pyrimidine-2-carboxylato and X = Cl, Br). We isolated two MOFs, NipymcaCl and NipymcaBr, featuring canted Ni 2+ -based moments. Despite this similarity, differences in the single-ion anisotropies of the Ni 2+ spins result in distinct magnetic properties for each material. NipymcaCl is a topological spin glass, while NipymcaBr is a rare frustrated magnet with low-temperature exchange bias. Density functional theory calculations and Monte Carlo simulations on the NipymcaX lattice support the presence of magnetic frustration as a result of alternating AFM and FM interactions. Our calculations enabled us to determine the ground-state spin configuration and the distribution of spin–spin correlations relative to paradigmatic kagomé and triangular lattices. This modified honeycomb lattice is similar to the electronic Kekulé-O phase in graphene and provides a highly tunable platform to realize unconventional spin physics.

Exchange bias↗

Numerical solution of large scale Hartree–Fock–Bogoliubov equations

The Hartree–Fock–Bogoliubov (HFB) theory is the starting point for treating superconducting systems. However, the computational cost for solving large scale HFB equations can be much larger than that of the Hartree–Fock equations, particularly when the Hamiltonian matrix is sparse, and the number of electrons N is relatively small compared to the matrix size N b . We first provide a concise and relatively self-contained review of the HFB theory for general finite sized quantum systems, with special focus on the treatment of spin symmetries from a linear algebra perspective. We then demonstrate that the pole expansion and selected inversion (PEXSI) method can be particularly well suited for solving large scale HFB equations. For a Hubbard-type Hamiltonian, the cost of PEXSI is at most $\mathcal{O}$(N b 2 ) for both gapped and gapless systems, which can be significantly faster than the standard cubic scaling diagonalization methods. We show that PEXSI can solve a two-dimensional Hubbard-Hofstadter model with N b up to 2.88 × 10 6 , and the wall clock time is less than 100 s using 17 280 CPU cores. Finally, this enables the simulation of physical systems under experimentally realizable magnetic fields, which cannot be otherwise simulated with smaller systems.

97 MATHEMATICS AND COMPUTING↗

Imaging crystal spectrometer for high-resolution x-ray measurements on electron beam ion traps and tokamaks

Here, we describe a crystal spectrometer implemented on the Livermore electron beam ion traps that employ two spherically bent quartz crystals and a cryogenically cooled back-illuminated charge-coupled device detector to measure x rays with a nominal resolving power of λ/Δλ ≥ 10 000. Its focusing properties allow us to record x rays either with the plane of dispersion perpendicular or parallel to the electron beam and, thus, to preferentially select one of the two linear x-ray polarization components. Moreover, by choice of dispersion plane and focussing conditions, we use the instrument either to image the distribution of the ions within the 2 cm long trap region, or to concentrate x rays of a given energy to a point on the detector, which optimizes the signal-to-noise ratio. We demonstrate the operation and utility of the new instrument by presenting spectra of Mo 34+ , which prepares the instrument for use as a core impurity diagnostic on the NSTX-U spherical torus and other magnetic fusion devices that employ molybdenum as plasma facing components.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Computed Tomography Scanning and Petrophysical Measurements of the Lively Grove #1 Well Core

The computed tomography (CT) facilities and the Multi-Sensor Core Logger (MSCL) at the National Energy Technology Laboratory (NETL) in Morgantown, West Virginia were used to characterize core from the Lively Grove #1 Well (API 121892494700), drilled near Marissa, Washington County, Illinois. Core from the well was obtained as part of the Illinois Storage Corridor’s Carbon Storage Assurance Facility Enterprise (CarbonSAFE) project (DE FE0031892). The primary impetus of this work was to capture a detailed digital representation of the core from the Lively Grove #1 Well. The collaboration between the U.S. Department of Energy’s (DOE) NETL and the Illinois State Geological Survey (ISGS) enables other research entities to access information about this potential carbon storage location and Cambro-Ordovician Storage Complex formations of the Illinois Basin. The resultant datasets are presented in this report and can be accessed from NETL’s Energy Data eXchange (EDX) online system. All equipment and techniques used were non-destructive, enabling future examinations and analyses to be performed on these cores. Fractures, discontinuities, and millimeter-scale features were readily detectable with the medical CT scanner-acquired images. Imaging with the NETL medical CT scanner was performed on entire cores. Qualitative analysis of the medical CT images, coupled with X-ray fluorescence (XRF), gamma density, and magnetic susceptibility measurements from the MSCL were useful in identifying zones of interest for potential future analysis. Higher-resolution industrial and micro-CT images were acquired from selected zones along the depth of the core to visualize the structure in higher detail. The ability to quickly identify key areas for more detailed study with higher resolution will save time and resources in future studies. The combination of methods used provides a multi-scale analysis of the core; with the resulting macro- and micro-descriptions relevant to many subsurface energy related examinations traditionally performed at NETL.

54 ENVIRONMENTAL SCIENCES↗

Computed Tomography Scanning and Petrophysical Measurements of Eastern Williston Basin Twin Buttes and Hagel Formations

The computed tomography (CT) facilities and the Multi-Sensor Core Logger (MSCL) at the U.S. Department of Energy’s (DOE) National Energy Technology Laboratory (NETL) in Morgantown, West Virginia, were used to characterize core from two wells that represent coal resources across North Dakota. These include the MC23080C Well in Mercer County and the 23-B001 Well in Oliver County. The primary impetus of this work was to capture a detailed digital representation of the core from the MC23080C and 23-B001 Wells. The collaboration between the NETL and the Energy and Environment Research Center (EERC) enables other research entities to access information about this potential carbon ore, rare earth, and critical mineral resource plays in the Williston Basin. All equipment and techniques used were non-destructive, enabling future examinations and analyses to be performed on these cores. Fractures, discontinuities, and millimeter-scale features were readily detectable with the medical CT scanner acquired images. Imaging with the NETL medical CT scanner was performed on entire cores. Qualitative analysis of the medical CT images, coupled with X-ray fluorescence (XRF), gamma density, and magnetic susceptibility measurements from the MSCL were useful in identifying zones of interest for potential future analysis. Higher-resolution industrial and micro-CT images were acquired from selected zones along the depth of the core to visualize the structure in higher detail. The ability to quickly identify key areas for more detailed study with higher resolution will save time and resources in future studies. The combination of methods used provides a multi-scale analysis of the core, with the resulting macro- and micro-descriptions relevant to many subsurface energy-related examinations traditionally performed at NETL.

01 COAL, LIGNITE, AND PEAT↗

Constraints on lunar structure

A brief review is given of the constraints placed on lunar structure and composition by seismic data and density models. Bounds on the crustal velocity structure in Mare Cognitum are derived using travel-time data from artificial impacts, and a velocity model is determined on the basis of synthetic seismograms. It is shown that the velocities of P- and S-waves in the mantle can be fixed by a least-squares analysis of arrival times from meteor impacts and moonquakes, and that lunar density can be determined from the seismic structure, mean density, and moment of inertia. Olivine-pyroxene mixtures and certain olivine-rich compositions are found to be consistent with the seismic-velocity and density limits. Maximum radii are calculated for pure Fe and pure FeS cores, and it is concluded that the possibility of an ancient lunar magnetic dynamo may have to be reevaluated in the light of these figures.

Dainty, A. M.↗

On the question of the energy of the precessional dynamo

The various estimates for the coupling mechanism by which precession transfers rotational, kinetic energy of earth into the energy of its magnetic field are generally considering hydromagnetic stresses that originate between mantle and core. Estimates of the energy of the geomagnetic field calculated from the data of spherical harmonic analysis derive precession energy values in reasonable agreement with the observed external energy of the geomagnetic field and with the rate of ohmic dissipation of energy in the core.

Dolginov, S. S.↗

Energy storage and deposition in a solar flare

X-ray pictures of a solar flare taken with the S-056 X-ray telescope aboard Skylab are interpreted in terms of flare energy deposition and storage. The close similarity between calculated magnetic-field lines and the overall structure of the X-ray core is shown to suggest that the flare occurred in an entire arcade of loops. It is found that different X-ray features brightened sequentially as the flare evolved, indicating that some triggering disturbance moved from one side to the other in the flare core. A propagation velocity of 180 to 280 km/s is computed, and it is proposed that the geometry of the loop arcade strongly influenced the propagation of the triggering disturbance as well as the storage and site of the subsequent energy deposition. Some possible physical causes for the sequential X-ray brightening are examined, and a magnetosonic wave is suggested as the triggering disturbance. 'Correct' conditions for energy release are considered

Vorpahl, J. A.↗

Solar wind helium ions - Observations of the Helios solar probes between 0.3 and 1 AU

A Helios solar probe survey of solar wind helium ion velocity distributions and derived parameters between 0.3 and 1 AU is presented. Distributions in high-speed wind are found to generally have small total anisotropies, with some indication that, in the core part, the temperatures are greater parallel rather than perpendicular to the magnetic field. The anisotropy tends to increase with heliocentric radial distance, and the average dependence of helium ion temperatures on radial distance from the sun is described by a power law. Differential ion speeds with values of more than 150 km/sec are observed near perihelion, or 0.3 AU. The role of Coulomb collisions in limiting differential ion speeds and the ion temperature ratio is investigated, and it is found that collisions play a distinct role in low-speed wind, by limiting both differential ion velocity and temperature.

Marsch, E.↗

Multifrequency observations of the flaring quasar 1156+295

A report is presented on the optically violent variable quasar 1156+295, known also as 4C 29.45 and Ton 599. A large outburst of this quasar was discovered in April 1981 in the course of a program to obtain simultaneous multifrequency spectra of variable quasars. Ultraviolet observations taken with the International Ultraviolet Explorer satellite were coordinated with ground-based observations at radio, infrared, and optical wavelengths. Measurements were made at four epochs starting immediately after the outburst was discovered, when the B-magnitude was 14.0, and at intervals of 4 days, 60 days and 1 year. The luminosity integrated only over observed wavelength bands was approximately 3 x 10 to the 48th ergs/sec on the first epoch of observation. Modeling of the source with a synchrotron self-Compton model suggests that the core of the source has a linear dimension of 0.01 pc, a magnetic field strength in the range 0.1-30 gauss, and a bulk relativistic motion in the quasar rest frame characterized by a Lorentz factor in the range 2-8.

Glassgold, A. E.↗

Orbital Manuvering System Design and Performance For the Magnetosperic Multiscale Constellation

The Magnetospheric Multiscale (MMS) mission, launched on March 13, 2015, is the fourth mission of NASA's Solar Terrestrial Probe program. The MMS mission consists of four identically instrumented observatories that function as a constellation to provide the first definitive study of magnetic reconnection in space. Since it is frequently desirable to isolate electric and magnetic field sensors from stray effects caused by the spacecraft's core-body, the suite of instruments on MMS includes six radial and two axial instrument-booms with deployed lengths ranging from 5-60 meters (see Figure 1). The observatory is spin-stabilized about its positive z-axis with a nominal rate slightly above 3 rev/min (RPM). The spin is also used to maintain tension in the four radial wire-booms. Each observatory's Attitude Control System (ACS) consists of digital sun sensors, star cameras, accelerometers, and mono-propellant hydrazine thrusters-responsible for orbital adjustments, attitude control, and spin adjustments. The sections that follow describe performance requirements, the hardware and algorithms used for 6-DOF estimation, and then similarly for 6-DOF control. The paper concludes with maneuver performance based on both simulated and on-orbit telem.

Determination and Control↗

Core Losses in Co-Rich Inductors with Tunable Permeability

High frequency, low loss power systems enable electrified aircraft propulsion. Filter inductors that reduce noise in high current systems can account for 50% of the motor drive mass. Efficient inductor cores with tunable permeability reduce system mass by producing less heat, that removes heat sink mass. Requirements for filter inductors vary based on the chosen topology, but all inductor cores must operate below saturation levels. As the saturation flux density is limited (less than ~2 T), high differential current applications require cores with low relative permeabilities. The large induced anisotropies possible in Co-rich metal amorphous nanocomposite materials enables gapless inductors with relative permeabilities down to ~20. These materials have fine grain size ~8nm with a faulted, close packed structure. The impact of different processing methods on core losses are presented along with comparison to other low permeability soft magnetic materials.

Leary, Alex↗

Recommended Practice for Use of ExB Probes in Electric Propulsion Testing

An ExB probe is an electric propulsion plume diagnostic that has at its core a Wien filter. Ions entering the instrument experience perpendicular electric and magnetic fields and are filtered based on their velocity. While the ExB probe can be used to estimate the ion velocity distribution function, in the electric propulsion community, it is commonly used to measure species fractions. There are numerous probe designs, implementation and operation procedures, and data analysis approaches described and in use across the community. This paper provides recommendations and descriptions of best practices for design, implementation, and data analysis for the ExB probe, with a particular emphasis on Hall and ion thrusters. This work contributes to the broader community goal to standardize the use of diagnostics in electric propulsion testing.

ExB probe↗