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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,297 records · Page 72

Effective Utilization of Commercial Wireless Networking Technology in Planetary Environments

The purpose of this research is to investigate the use of commercial, off-the-shelf wireless networking technology in planetary exploration applications involving rovers and sensor webs. The three objectives of this research project are to: 1) simulate the radio frequency environment of proposed landing sites on Mars using actual topographic data, 2) analyze the performance of current wireless networking standards in the simulated radio frequency environment, and 3) propose modifications to the standards for more efficient utilization. In this annual report, we present our results for the second year of research. During this year, the effort has focussed on the second objective of analyzing the performance of the IEEE 802.11a and IEEE 802.1lb wireless networking standards in the simulated radio frequency environment of Mars. The approach builds upon our previous results which deterministically modelled the RF environment at selected sites on Mars using high-resolution topographical data. These results provide critical information regarding antenna coverage patterns, maximum link distances, effects of surface clutter, and multipath effects. Using these previous results, the physical layer of these wireless networking standards has now been simulated and analyzed in the Martian environment. We are looking to extending these results to the and medium access layer next. Our results give us critical information regarding the performance (data rates, packet error rates, link distances, etc.) of IEEE 802.1 la/b wireless networks. This information enables a critical examination of how these wireless networks may be utilized in future Mars missions and how they may be possibly modified for more optimal usage.

Caulev, Michael↗

SEVO (Space Environment Viability of Organics) Preliminary Results from Orbit

SEVO (Space Environment Viability of Organics) is one of two astrobiology experiments onboard the NASA Organism/Organics Exposure to Orbital Stresses (O/OREOS) cubesat, launched in November 2010. The satellite is still operational with nominal performance and records data on a regular basis. In the SEVO experiment, four astrobiologically relevant organic thin films are exposed to radiation in low-earth orbit, including the unfiltered solar spectrum from approximately 120 - 2600 nm. The thin films are contained in each of four separate micro-environments: an atmosphere containing CO2, a low relative humidity (approximately 2%) atmosphere, an inert atmosphere representative of interstellar/interplanetary space, and a SiO2 mineral surface to measure the effects of surface catalysis. The UV/Vis spectrum of each sample is monitored in situ, with a spectrometer onboard the satellite.

Cook, A.↗

Nonlinear Dynamic Control Derivative Analysis for Aircraft with Application to Transonic Truss-Braced Wing

This paper presents the development of a nonlinear dynamic control derivative estimation method. A nonlinear aerodynamic model is developed to account for the effects of large control surface deflections on aircraft aerodynamic forces and moments. A series of unsteady RANS CFD simulations is performed to simulate the control surface oscillations at various reduced frequencies. The time-domain data are transformed into the frequency-domain data by a Fourier series analysis. Transfer functions of the dynamic control derivatives are then estimated by a frequency-domain regression. The method is applied to the Transonic Truss-Braced Wing (TTBW) to estimate the dynamic control derivatives for the elevator, aileron, and rudder.

Aircraft Control Derivatives↗

The Aerodynamic Characteristics of Airfoils as Affected by Surface Roughness

The effect on airfoil characteristics of surface roughness of varying degrees and types at different locations on an airfoil was investigated at high values of the Reynolds number in a variable density wind tunnel. Tests were made on a number of National Advisory Committee for Aeronautics (NACA) 0012 airfoil models on which the nature of the surface was varied from a rough to a very smooth finish. The effect on the airfoil characteristics of varying the location of a rough area in the region of the leading edge was also investigated. Airfoils with surfaces simulating lap joints were also tested. Measurable adverse effects were found to be caused by small irregularities in airfoil surfaces which might ordinarily be overlooked. The flow is sensitive to small irregularities of approximately 0.0002c in depth near the leading edge. The tests made on the surfaces simulating lap joints indicated that such surfaces cause small adverse effects. Additional data from earlier tests of another symmetrical airfoil are also included to indicate the variation of the maximum lift coefficient with the Reynolds number for an airfoil with a polished surface and with a very rough one.

HOCKER RAY W↗

Computational Study of Surface Tension and Wall Adhesion Effects on an Oil Film Flow Underneath an Air Boundary Layer

The fringe-imaging skin friction (FISF) technique, which was originally developed by D. J. Monson and G. G. Mateer at Ames Research Center and recently extended to 3-D flows, is the most accurate skin friction measurement technique currently available. The principle of this technique is that the skin friction at a point on an aerodynamic surface can be determined by measuring the time-rate-of-change of the thickness of an oil drop placed on the surface under the influence of the external air boundary layer. Lubrication theory is used to relate the oil-patch thickness variation to shear stress. The uncertainty of FISF measurements is estimated to be as low as 4 percent, yet little is known about the effects of surface tension and wall adhesion forces on the measured results. A modified version of the free-surface Navier-Stokes solver RIPPLE, developed at Los Alamos National Laboratories, was used to compute the time development of an oil drop on a surface under a simulated air boundary layer. RIPPLE uses the volume of fluid method to track the surface and the continuum surface force approach to model surface tension and wall adhesion effects. The development of an oil drop, over a time period of approximately 4 seconds, was studied. Under the influence of shear imposed by an air boundary layer, the computed profile of the drop rapidly changes from its initial circular-arc shape to a wedge-like shape. Comparison of the time-varying oil-thickness distributions computed using RIPPLE and also computed using a greatly simplified numerical model of an oil drop equation which does not include surface tension and wall adhesion effects) was used to evaluate the effects of surface tension on FISF measurement results. The effects of surface tension were found to be small but not necessarily negligible in some cases.

Celic, Alan↗

Effect of nonlifting empennage surfaces on single-engine afterbody/nozzle drag at Mach numbers from 0.5 to 2.2

The effect of empennage interference on the drag characteristics of a model with a single engine fighter aft end with convergent-divergent nozzles was studied. The dry and maximum afterburning nozzle power settings were investigated. A high pressure air system was used to provide jet total pressure ratios up to 20.0. In an attempt to quantify and reduce adverse empennage interference and decrease aft-end drag, several empennage arrangements (variable tail surface location), contour bump configurations, and locally contoured afterbodies were investigated. The results of the investigation indicate that empennage interference effects can be significant at transonic and supersonic speeds. The most effective means of reducing adverse empennage interference is the proper relocation of individual tail surfaces. The aft or conventional empennage arrangement produced the highest aft-end drag at all conditions investigated.

Berrier, B. L.↗

An experimental investigation of silicon wafer surface roughness and its effect on the full strength of plated metals

Plated silicon wafers with surface roughness ranging from 0.4 to 130 microinches were subjected to tensile pull strength tests. Electroless Ni/electroless Cu/electroplated Cu and electroless Ni/electroplated Cu were the two types of plate contacts tested. It was found that smoother surfaces had higher pull strength than rougher, chemically etched surfaces. The presence of the electroless Cu layer was found to be important to adhesion. The mode of fracture of the contact as it left the silicon was studied, and it was found that in almost all cases separation was due to fracture of the bulk silicon phase. The correlation between surface roughness and mode of contact failure is presented and interpreted.

Spiers, G. D.↗

Improvements in MDC and TWT overall efficiency through the application of carbon electrode surfaces

The effects of secondary electron emission losses on TWT efficiency are investigated and techniques for minimizing these losses are described. The TWT-multistage depressed collector performance was optimized and measured over a wide range of operating conditions using geometrically identical collectors that utilized copper, pyrolytic graphite, and isotropic graphite electrodes. The data reveal that carbon rather than copper electrodes improve the TWT efficiency, and the ion-textured graphite is most effective in minimizing the secondary electron emission losses. It is noted that degradation of the collector efficiency can be limited to a small percentage with the proper MDC design and the use of low secondary electron yield carbon electrode surfaces.

Ramins, Peter↗

The mechanisms and seasonal differences of the impact of aerosols on daytime surface urban heat island effect

The urban heat island intensity (UHII) is the temperature difference between urban areas and their rural surroundings. It is commonly attributed to changes in the underlying surface structure caused by urbanization. Air pollution caused by aerosol particles can affect the UHII through changing (1) the surface energy balance by the aerosol radiative effect (ARE) and (2) planetary-boundary-layer (PBL) stability and airflow intensity by modifying thermodynamic structure, which is referred to as the aerosol dynamic effect (ADE). By analyzing satellite data and ground-based observations collected from 2001 to 2010 at 35 cities in China and using the WRF-Chem model, we find that the impact of aerosols on UHII differs considerably: reducing the UHII in summer but increasing the UHII in winter. This seasonal contrast is proposed to be caused by the different strengths of the ARE and ADE between summer and winter. In summer, the ARE on UHII is dominant over the ADE, cooling down surface temperature more strongly in urban areas than in rural areas because of much higher aerosol loading, and offsets the urban heating, therefore weakening UHII. In winter, however, the ADE is more dominant, because aerosols stabilize the PBL more in the polluted condition, weakening the near-surface heat transport over urban areas in both vertical and horizontal directions. This means that the heat accumulated in urban areas is dispersed less effectively, and thus the UHII is enhanced. These findings shed new light on the impact of the interaction between urbanization-induced surface changes and air pollution on urban climate.urban areas and their rural surroundings. It is commonly attributed to changes in the underlying surface structure caused by urbanization. Air pollution caused by aerosol particles can affect the UHII through changing (1) the surface energy balance by the aerosol radiative effect (ARE) and (2) planetary-boundary-layer (PBL) stability and airflow intensity by modifying thermodynamic structure, which is referred to as the aerosol dynamic effect (ADE). By analyzing satellite data and ground-based observations collected from 2001 to 2010 at 35 cities in China and using the WRF-Chem model, we find that the impact of aerosols on UHII differs considerably: reducing the UHII in summer but increasing the UHII in winter. This seasonal contrast is proposed to be caused by the different strengths of the ARE and ADE between summer and winter. In summer, the ARE on UHII is dominant over the ADE, cooling down surface temperature more strongly in urban areas than in rural areas because of much higher aerosol loading, and offsets the urban heating, therefore weakening UHII. In winter, however, the ADE is more dominant, because aerosols stabilize the PBL more in the polluted condition, weakening the near-surface heat transport over urban areas in both vertical and horizontal directions. This means that the heat accumulated in urban areas is dispersed less effectively, and thus the UHII is enhanced. These findings shed new light on the impact of the interaction between urbanization-induced surface changes and air pollution on urban climate.

54 ENVIRONMENTAL SCIENCES↗

Reconstruction of the Bi 2 Sr 2 CaCu 2 O 8 + δ Fermi surface

The effects of structural supermodulation with the period $λ ≈ 26$ Å along the $b$ axis of Bi 2 Sr 2 CaCu 2 O 8 + δ have been observed in photoemission studies from the early days as the presence of “diffraction replicas” of the intrinsic electronic structure. Although predicted to affect the electronic structure of the Cu-O plane, the influence of supermodulation potential on Cu-O electrons has never been observed in photoemission. In the present study, we clearly see the effects on the Bi 2 Sr 2 CaCu 2 O 8 + δ electronic structure; we observe a hybridization of the intrinsic bands with the supermodulation replica bands in the form of avoided crossings and a corresponding reconstruction of the Fermi surface. We estimate the hybridization gap, $2Δ_h ~ 25$ meV, in the slightly underdoped samples. The hybridization weakens with doping and the anticrossing can no longer be resolved in strongly overdoped samples. In contrast, the “shadow” replica, shifted by ($π , π$) , is found not to hybridize with the original bands within our detection limits.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Key role of antibonding electron transfer in bonding on solid surfaces

The description of the chemical bond between a solid surface and an atom or a molecule is the fundamental basis for understanding surface reactivity and catalysis. Despite considerable research efforts, the physics that rules the strength of such chemical bonds remains elusive, especially on semiconductor surfaces. Widespread understandings are mostly based on the degree of filling of antibonding surface-adsorbate states that weaken the surface adsorption. The unoccupied antibonding surface-adsorbate states are often considered to have no effects on surface bonding. Here in this paper, we show that the energy levels of unoccupied antibonding surface-adsorbate states relative to the Fermi-level play a critical role in determining the trends in variations of surface adsorption energies. The electrons that would occupy those high-energy antibonding states are transferred to the Fermi-level, leading to an energy gain that largely controls surface bonding. To illustrate this picture, as a validating case, we study the hydrogen evolution reaction (HER) catalyzed by MoS 2 from density functional theory calculations. We find that the majority of antibonding surface-hydrogen states are positioned well above the Fermi-energy. A clear linear relationship between the energy gain from antibonding electron transfer and the adsorption energy is identified for hydrogen binds to either molybdenum or sulfur atoms at different sites. The antibonding-electron transfer energy can thus serve as a primary catalytic activity descriptor. The emerging picture identifies the origin of HER on MoS 2 , which is related to the empty in-gap states induced by sulfur vacancies or edges. Under this picture, the effects of surface inhomogeneity (e.g., defects, step edges) on surface bonding strength can be understood. This antibonding electron transfer picture also offers a physically different explanation for the well-known d-band theory for hydrogen adsorption on transition metal surfaces. The results provide guidelines for understanding and optimizing catalyst performance and designing new solid catalysts.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Enhancing Oxygen Exchange Activity by Tailoring Perovskite Surfaces

A detailed understanding of the effects of surface chemical and geometric composition is essential for understanding the electrochemical performance of the perovskite (ABO 3 ) oxides commonly used as electrocatalysts in the cathodes of ceramic fuel cells. In this work, we report how the addition of submonolayer quantities of A- and B-site cations affect the rate of the Oxygen Reduction Reaction (ORR) of Sr-doped LaFeO 3 (LSF), LaMnO 3 (LSM), and LaCoO 3 (LSCo). Density functional theory (DFT) calculations were performed to determine the stability of different active sites on a collection of surfaces. With LSF and LSM, rates for ORR are significantly higher on the A-site terminated surface, while surface termination is less important for LSCo. Our findings highlight the importance of tailoring the surface termination of the perovskite to obtain its ultimate ORR performance.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Changes in boron fiber strength due to surface removal by chemical etching

The effects of chemical etching on the tensile strength of commercial boron/tungsten fibers were investigated. Fibers with as-received diameters of 203, 143, and 100 micrometers were etched to diameters as small as 43 micrometers. The etching generally resulted in increasing fiber tensile strength with decreasing fiber diameter. And for the 203 micrometer fibers there was an accompanying significant decrease in the coefficient of variation of the tensile strength for diameters down to 89 micrometers. Heat treating these fibers above 1,173 K in a vacuum caused a marked decrease in the average tensile strength of at least 80 percent. But after the fibers were etched, their strengths exceeded the as-received strengths. The tensile strength behavior is explained in terms of etching effects on surface flaws and the residual stress pattern of the as-received fibers.

Smith, R. J.↗

Numerical solution of fluid flow and heat tranfer problems with surface radiation

This paper presents a numerical scheme, based on the finite element method, to solve strongly coupled fluid flow and heat transfer problems. The surface radiation effect for gray, diffuse and isothermal surfaces is considered. A procedure for obtaining the view factors between the radiating surfaces is discussed. The overall solution strategy is verified by comparing the available results with those obtained using this approach. An analysis of a thermosyphon is undertaken and the effect of considering the surface radiation is clearly explained.

Ahuja, S.↗

Gas-phase hydrogen permeation through alpha-titanium - Surface film and dimensional effects

The two techniques normally used to determine diffusivity and permeability in metals are considered and a description is presented of experiments which had been conducted to determine the direct effect of oxide and nitride films on the membrane surface as a function of location and thickness. The test specimens used in the experiments has been machined from commercially pure titanium rod. The results of the experiments show that hydrogen transport in alpha-titanium is partially or completely controlled by surface reactions depending upon membrane wall thickness and the composition and thickness of the surface film.

Shah, K. K.↗

Decoupling in the Vertical Shape of HCHO During a Sea Breeze Event: the Effect on Trace Gas Satellite Retrievals and Column-to-Surface Translation

The effect of sea breeze circulation on stratification of the vertical formaldehyde (HCHO) concentration vertical profiles is explored using a regional atmospheric chemical transport model (CTM) for three synoptically stagnant days focused on the east coast of the U.S in June 2018. During this event, a significant thermal contrast between the Atlantic Ocean and the terrestrial regions (12–17 °C), observed by moderate resolution imaging spectroradiometer (MODIS) and well-captured by the WRF-CMAQ model (15–18 °C), is conducive to monsoon-like flow, perpendicular to the shorelines, carrying clean marine air masses over the land within a few hundreds of meters above the surface. In contrast, the westerly continental polluted air masses prevail in higher altitudes. These two conflicting flows result in atypical vertical shapes of HCHO concentrations increasing with altitude. This decoupling pattern is so pronounced that we observe total column HCHO negatively correlate with surface concentrations. Comparisons of an accredited global model, GEOS-CF, to surface wind measurements and MODIS skin temperature indicate its poor representation of the sea breeze timing and strength, resulting in GEOS-CF HCHO vertical shapes being drastically different from the WRF-CMAQ. Based on radiative transfer calculations, the differences in the vertical distribution of HCHO between the WRF-CMAQ and that of GEOS-CF in the first 3 km are sufficient to induce a 20–30% error in air mass factors (thus total vertical HCHO column abundances). Through an experiment involving converting HCHO total columns to surface mixing ratios, we demonstrate that GEOS-CF allocates noticeably more HCHO molecules (40–150%) to the surface layer due to the misrepresentation of the vertical shape of HCHO during the sea breeze event. It is known that a significant fraction of the human population lives in coastal areas prone to detrimental effects caused by air pollution, and elevated pollutant concentrations usually occur in synoptically stagnant atmospheric conditions when local circulation patterns come into play; accordingly, our experiments emphasize the importance of the effect a priori profiles can have on satellite-derived applications under such conditions. To ensure that the quantitative representation of satellite-based trace gas retrievals on a daily basis is trustworthy and useable for air quality applications, atmospheric models providing a priori profiles for satellite retrievals should be well-tuned to reproduce complex local circulation such as sea-land breezes.

sea breeze↗