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At least 1,315 records · Page 73

How to Build an Empirical Speed Distribution for Dark Matter in the Solar Neighborhood

The dark matter flux in a direct detection experiment depends on its local speed distribution. This distribution has been inferred from simulations of Milky Way–like galaxies, but such models serve only as proxies, given that no simulation directly captures the detailed evolution of our own Galaxy. This motivates alternative approaches that obtain this distribution directly from observations. In this work, we utilize 98 Milky Way analogues from the TNG50 simulation to develop and validate a procedure for inferring the dark matter speed distribution using the kinematics of nearby stars. We find that the dark matter that originated from old mergers, plus that from recent nonluminous accretions, is well described by a Maxwell–Boltzmann speed distribution centered at the local standard-of-rest velocity. Meanwhile, recently accreted dark matter from massive mergers has speeds that can be traced from the associated stellar debris of these events. The stellar populations systematically underestimate the velocity dispersion of their dark matter counterparts, but a simple kinematic boost brings the two into good alignment. Using the TNG50 host galaxies, we demonstrate that combining these two contributions provides an accurate reconstruction of the local dark matter speeds. As an application of the procedure to our own Galaxy, we utilize stellar kinematic data from Gaia to quantify how the dark matter remnants from the Milky Way’s last major merger impact its speed distribution in the solar neighborhood.

Shpigel, Tal [Princeton Univ., NJ (United States)]↗

Point-spread Function Deconvolution of the IFU Data and Restoration of Galaxy Stellar Kinematics

We present a performance test of the point-spread function (PSF) deconvolution algorithm applied to astronomical integral field unit (IFU) spectroscopy data for restoration of galaxy kinematics. We deconvolve the IFU data by applying the Lucy–Richardson algorithm to the 2D image slice at each wavelength. We demonstrate that the algorithm can effectively recover the true stellar kinematics of the galaxy, by using mock IFU data with a diverse combination of surface brightness profile, signal-to-noise ratio, line-of-sight geometry, and line-of-sight velocity distribution (LOSVD). In addition, we show that the proxy of the spin parameter ${\lambda }_{{R}_{e}}$ can be accurately measured from the deconvolved IFU data. We apply the deconvolution algorithm to the actual SDSS-IV MaNGA IFU survey data. The 2D LOSVD, geometry, and ${\lambda }_{{R}_{e}}$ measured from the deconvolved MaNGA IFU data exhibit noticeable differences compared to the ones measured from the original IFU data. The method can be applied to any other regular-grid IFU data to extract the PSF-deconvolved spatial information.

79 ASTRONOMY AND ASTROPHYSICS↗

BASS. XXIX. The Near-infrared View of the Broad-line Region (BLR): The Effects of Obscuration in BLR Characterization

Virial black hole (BH) mass (M BH ) determination directly involves knowing the broad-line region (BLR) clouds' velocity distribution, their distance from the central supermassive BH (R BLR ), and the virial factor (f). Understanding whether biases arise in M BH estimation with increasing obscuration is possible only by studying a large (N > 100) statistical sample of obscuration-unbiased (hard) X-ray-selected active galactic nuclei (AGNs) in the rest-frame near-infrared (0.8–2.5 μm) since it penetrates deeper into the BLR than the optical. We present a detailed analysis of 65 local Burst Alert Telescope (BAT) selected Seyfert galaxies observed with Magellan/FIRE. Adding these to the near-infrared BAT AGN spectroscopic survey database, we study a total of 314 unique near-infrared spectra. While the FWHMs of Hα and near-infrared broad lines (He i, Paβ, Paα) remain unbiased to either BLR extinction or X-ray obscuration, the Hα broad-line luminosity is suppressed when N H ≳ 10 21 cm –2 , systematically underestimating M BH by 0.23–0.46 dex. Near-infrared line luminosities should be preferred to Hα until N H < 10 22 cm –2 , while at higher obscuration a less-biased R BLR proxy should be adopted. We estimate f for Seyfert 1 and 2 using two obscuration-unbiased M BH measurements, i.e., the stellar velocity dispersion and a BH mass prescription based on near-infrared and X-ray, and find that the virial factors do not depend on the redshift or obscuration, but some broad lines show a mild anticorrelation with M BH . Furthermore, our results show the critical impact obscuration can have on BLR characterization and the importance of the near-infrared and X-rays for a less-biased view of the BLR.

79 ASTRONOMY AND ASTROPHYSICS↗

Electric-current Neutralization, Magnetic Shear, and Eruptive Activity in Solar Active Regions

The physical conditions that determine whether or not solar active regions (ARs) produce strong flares and coronal mass ejections (CMEs) are not yet well understood. Here, we investigate the association between electric-current neutralization, magnetic shear along polarity inversion lines (PILs), and eruptive activity in four ARs: two emerging and two well-developed ones. We find that the CME-producing ARs are characterized by a strongly non-neutralized total current, while the total current in the ARs that did not produce CMEs is almost perfectly neutralized. The difference in the PIL shear between these two groups is much less pronounced, which suggests that the degree of current neutralization may serve as a better proxy for assessing the ability of ARs to produce CMEs.

79 ASTRONOMY AND ASTROPHYSICS↗

Can the Distance–Redshift Relation be Determined from Correlations between Luminosities?

We explore whether an independent determination of the distance–redshift relation, and hence cosmological model parameters, can be obtained from the apparent correlations between two different wave-band luminosities or fluxes, as has been claimed in recent works using the X-ray and ultraviolet luminosities and fluxes of quasars. We show that such an independent determination is possible only if the correlation between luminosities is obtained independently of the cosmological model and measured fluxes and redshifts, for example, based on sound theoretical models or unrelated observations. In particular, we show that if the correlation is determined empirically for two luminosities obtained from fluxes and redshifts, then the method suffers from circularity. In the case where the observed correlation between fluxes in very narrow redshift bins is used as a proxy for the luminosity correlation, we show that one is dealing with a pure tautology with no information on distances and cosmological model. We argue that the problem arises because of the incomplete treatment of the correlation, and we use numerical methods with a joint X-ray and ultraviolet quasar data set to demonstrate this shortcoming.

79 ASTRONOMY AND ASTROPHYSICS↗

Measuring Black Hole Light Echoes with Very Long Baseline Interferometry

Light passing near a black hole can follow multiple paths from an emission source to an observer due to strong gravitational lensing. Photons following different paths take different amounts of time to reach the observer, which produces an echo signature in the image. The characteristic echo delay is determined primarily by the mass of the black hole, but it is also influenced by the black hole spin and inclination to the observer. In the Kerr geometry, echo images are demagnified, rotated, and sheared copies of the direct image and lie within a restricted region of the image. Echo images have exponentially suppressed flux, and temporal correlations within the flow make it challenging to directly detect light echoes from the total light curve. In this Letter, we propose a novel method to search for light echoes by correlating the total light curve with the interferometric signal at high spatial frequencies, which is a proxy for indirect emission. We explore the viability of our method using numerical general relativistic magnetohydrodynamic simulations of a near-face-on accretion system scaled to M87-like parameters. We demonstrate that our method can be used to directly infer the echo delay period in simulated data. An echo detection would be clear evidence that we have captured photons that have circled the black hole, and a high-fidelity echo measurement would provide an independent measure of fundamental black hole parameters. Our results suggest that detecting echoes may be achievable through interferometric observations with a modest space-based very long baseline interferometry mission.

79 ASTRONOMY AND ASTROPHYSICS↗

Using Maximum Circular Velocity in Halo Occupation Distribution Models to Predict Galaxy Clustering

Abstract Standard halo occupation distribution (HOD) models predict how galaxies occupy halos based on a single property, the virial mass, M vir . To incorporate galaxy assembly bias, we consider alternative halo mass proxies to use in the HOD. A promising replacement is maximum circular velocity, V max , which measures the halo’s potential well, and successfully predicts galaxy clustering in subhalo abundance matching models. We fit galaxy clustering measurements from SDSS DR7 with two modified HODs besides the standard M vir -based model: one where V max is used as the halo property that determines galaxy occupation, and the other adopting an adjustable combination of M vir and V max . Except for the reduced volume M r < − 20 threshold sample fit with V max alone, neither change improves the model performance in predicting the projected two-point correlation function, w p . We conclude that switching the primary variable to V max does not significantly improve the HOD model’s ability to fit galaxy clustering.

Mezini, Lorena↗

Impact of Lateral Alignment on the Energy Savings of a Truck Platoon

A truck platooning system was tested using two heavy-duty tractor-trailer trucks on a closed test track to investigate the sensitivity of intentional lateral offsets over a range of intervehicle spacings. The fuel consumption for both trucks in the platoon was measured using the SAE J1321 gravimetric procedure while travelling at 65 mph and loaded to a gross weight of 65,000 lb. In addition, the SAE J1939 instantaneous fuel rate was calibrated against the gravimetric measurements and used as proxy for additional analyses. The testing campaign demonstrated the effects of intervehicle gaps, following-vehicle longitudinal control, and manual lateral control. The new results are compared to previous truck-platooning studies to reinforce the value of the new information and demonstrate similarity to past trends. Fuel savings for the following vehicle was observed to exceed 10% at closer following distances. The results showed that energy savings generally increased in a non-linear fashion as the gap was reduced. The impact of different following-truck lateral offsets had a measurable impact, with up to 4% reduction in total fuel-savings (relative to an isolated vehicle condition) observed for offsets up to 1.3 m. The fuel-consumption savings on the straight segments of the track exceeded those on the curved segments by upwards of 6% and highlight some potential differences expected between close-track testing and on-highway use.

adaptive cruise control↗

Impact of Mixed Traffic on the Energy Savings of a Truck Platoon

A two-truck platoon based on a prototype cooperative adaptive cruise control (CACC) system was tested on a closed test track in a variety of realistic traffic and transient operating scenarios - conditions that truck platoons are likely to face on real highways. The fuel consumption for both trucks in the platoon was measured using the SAE J1321 gravimetric procedure as well as calibrated J1939 instantaneous fuel rate, serving as proxies to evaluate the impact of aerodynamic drag reduction under constant-speed conditions. These measurements demonstrate the effects of: the presence of a multiple-passenger-vehicle pattern ahead of and adjacent to the platoon, cut-in and cut-out manoeuvres by other vehicles, transient traffic, the use of mismatched platooned vehicles (van trailer mixed with flatbed trailer), and the platoon following another truck with adaptive cruise control (ACC). These scenarios are intended to address the possibility of “background aerodynamic platooning” impacting realized savings on public roads. Using calibrated J1939 fuel rate analysis, fuel savings for curved track sections versus straight track sections were also evaluated for these scenarios, highlighting differences in the implementation of the CACC control strategies compared to a stock ACC implementation. The use of different trailer types and the presence of passenger-vehicle traffic patterns showed a measurable impact on platoon performance in some conditions, but the basic fuel savings trends were retained.

adaptive cruise control↗

Real-World Driving Features for Identifying Intelligent Driver Model Parameters

Driver behavior models play a significant role in representing different driving styles and the associated relationships with traffic patterns and vehicle energy consumption in simulation studies. The models often serve as a proxy for baseline human driving when assessing energy-saving strategies that alter vehicle velocity. Such models are especially important in connectivity-enabled energy-saving strategy research because they can easily adapt to changing driving conditions like posted speed limits or change in traffic light state. While numerous driver models exist, parametric driver models provide the flexibility required to represent variability in real-world driving through different combinations of model parameters. These model parameters must be informed by a representative set of parameter values for the driver model to adequately represent a real-world driver. It stands to reason that determining the parameter values from real-world driving data would serve the purpose of representing a real-world driver. Although the published literature is replete with techniques and consequences of using real-world driving data to determine parameter values for parametric driver models, none have explored them in the context of using shorter driving features where the parameter values may change over the course of a single trip for the same driver. In this study we consider the “intelligent driver model” (IDM) as our driver behavior model and use real-world driving data from the Transportation Secure Data Center (TSDC) maintained at the National Renewable Energy Laboratory (NREL). The TSDC includes real-world travel data from across the United States, from which NREL has created a wide range of driving routes consisting of road features such as speed limits, stop locations, and turn locations. The real-world driving data are categorized into different driving regimes and extracted into driving features. The driving features are then used to calibrate the parameter values for the IDM. The distribution of the parameters and the relationships among them are reported. The insights obtained from this study enable judicious usage of IDM or similar parametric driver models to represent baseline human driver behavior in simulations.

27 ARPA - Advanced Research Projects Agency-Energy↗

Reexamining Circular Dichroism in Photoemission From a Topological Insulator

The orbital angular momentum (OAM) of electron states is an essential ingredient for topological and quantum geometric quantities in solids. For example, Dirac surface states with helical spin- and orbital-angular momenta are a hallmark of a 3D topological insulator. Angle-resolved photoemission spectroscopy (ARPES) with variable circular light polarization, known as circular dichroism (CD), has been assumed to be a direct probe of OAM and, by proxy, of the Berry curvature of electronic bands in energy- and momentum-space. Indeed, topological surface states have been shown to exhibit angle-dependent CD (CDAD), and more broadly, CD is often interpreted as evidence of spin-orbit coupling. Meanwhile, it is well-established that CD originates from the photoemission matrix elements, which can have extrinsic contributions related to the experimental geometry and the inherently broken inversion symmetry at the sample surface. Therefore, it is important to broadly examine CD-ARPES to determine the scenarios in which it provides a robust probe of intrinsic material physics. We performed CD-ARPES on the canonical topological insulator $\mathrm{Bi}_2\mathrm{Se}_3$ over a wide range of incident photon energies. Not only do we observe angle-dependent CD in the surface states, as expected, but we also find CD of a similar magnitude in virtually all bulk bands. Since OAM is forbidden by inversion symmetry in the bulk, we conclude this originates from symmetry-breaking in the photoemission process. Comparison with theoretical calculations supports this view and suggests that $\textit{hidden}$ OAM - localized to atomic sites within each unit cell - contributes significantly. Additional effects, including inter-atomic interference and final-state resonances, are responsible for the rapid variation of the CDAD signal with photon energy.

FOS: Physical sciences↗

Correlating Superconducting Qubit Performance Losses to Sidewall Near-Field Scattering via Terahertz Nanophotonics

Elucidating dielectric losses, structural heterogeneity, and interface imperfections is critical for improving coherence in superconducting qubits. However, most diagnostics rely on destructive electron microscopy or low-throughput millikelvin quantum measurements. Here, we demonstrate noninvasive terahertz (THz) nano-imaging/-spectroscopy of encapsulated niobium transmon qubits, revealing sidewall near-field scattering that correlates with qubit coherence. We further employ a THz hyperspectral line scan to probe dielectric responses and field participation at Al junction interfaces. These findings highlight the promise of THz near-field methods as a high-throughput proxy characterization tool for guiding material selection and optimizing processing protocols to improve qubit and quantum circuit performance.

Kim, Richard H.J. [Ames Lab]↗

FIREFLY: heat load and particle exhaust approximations for rapid evaluation of divertor designs

The divertor in a magnetic confinement fusion reactor is an essential component for power dissipation and particle removal. The FIREFLY package for rapid evaluation of divertor designs is presented as an extension of the FLARE code for field line reconstruction from a flux tube mesh. First, divertor loads are approximated with a simplified heat transport model. Neutralized particles are then sampled from the resulting load distribution, and the EIRENE code is used to track molecules and atoms in a plasma background while accounting for dissociation, charge exchange and ionization. Particles are removed on pumping surfaces in order to estimate the exhaust efficiency for a given divertor geometry. Optimization of the divertor geometry for more efficient particle exhaust is explored by using W7-X as an example, and the sensitivity to model parameters for the plasma background in the proxy calculations is evaluated.

mesh generation, magnetic field lines, scrape-off ↗

Impacts of solar-absorbing aerosol layers on the transition of stratocumulus to trade cumulus clouds

Abstract. The effects of an initially overlying layer of solar-absorbing aerosol on the transition of stratocumulus to trade cumulus clouds are examined using large-eddy simulations. For lightly drizzling cloud the transition is generally hastened, resulting mainly from increased cloud droplet number concentration (Nc) induced by entrained aerosol. The increased Nc slows sedimentation of cloud droplets and shortens their relaxation time for diffusional growth, both of which accelerate entrainment of overlying air and thereby stratocumulus breakup. However, the decrease in albedo from cloud breakup is more than offset by redistributing cloud water over a greater number of droplets, such that the diurnal-average shortwave forcing at the top of the atmosphere is negative. The negative radiative forcing is enhanced by sizable longwave contributions, which result from the greater cloud breakup and a reduced boundary layer height associated with aerosol heating. A perturbation of moisture instead of aerosol aloft leads to a greater liquid water path and a more gradual transition. Adding absorbing aerosol to that atmosphere results in substantial reductions in liquid water path (LWP) and cloud cover that lead to positive shortwave and negative longwave forcings on average canceling each other. Only for heavily drizzling clouds is the breakup delayed, as inhibition of precipitation overcomes cloud water loss from enhanced entrainment. Considering these simulations as an imperfect proxy for biomass burning plumes influencing Namibian stratocumulus, we expect regional indirect plus semi-direct forcings to be substantially negative to negligible at the top of the atmosphere, with its magnitude sensitive to background and perturbation properties.

54 ENVIRONMENTAL SCIENCES↗

Mixing times of organic molecules within secondary organic aerosol particles: a global planetary boundary layer perspective

When simulating the formation and life cycle of secondary organic aerosol (SOA) with chemical transport models, it is often assumed that organic molecules are well mixed within SOA particles on the timescale of 1h. While this assumption has been debated vigorously in the literature, the issue remains unresolved in part due to a lack of information on the mixing times within SOA particles as a function of both temperature and relative humidity. Using laboratory data, meteorological fields, and a chemical transport model, we estimated how often mixing times are < 1h within SOA in the planetary boundary layer (PBL), the region of the atmosphere where SOA concentrations are on average the highest. First, a parameterization for viscosity as a function of temperature and RH was developed for α-pinene SOA using room-temperature and low-temperature viscosity data for α-pinene SOA generated in the laboratory using mass concentrations of ~1000µg m -3 . Based on this parameterization, the mixing times within α-pinene SOA are < 1h for 98.5% and 99.9% of the occurrences in the PBL during January and July, respectively, when concentrations are significant (total organic aerosol concentrations are > 0.5µg m -3 at the surface). Next, as a starting point to quantify how often mixing times of organic molecules are < 1h within α-pinene SOA generated using low, atmospherically relevant mass concentrations, we developed a temperature-independent parameterization for viscosity using the room-temperature viscosity data for α-pinene SOA generated in the laboratory using a mass concentration of ~70µg m -3 . Based on this temperature-independent parameterization, mixing times within α-pinene SOA are < 1h for 27 and 19.5% of the occurrences in the PBL during January and July, respectively, when concentrations are significant. However, associated with these conclusions are several caveats, and due to these caveats we are unable to make strong conclusions about how often mixing times of organic molecules are < 1h within α-pinene SOA generated using low, atmospherically relevant mass concentrations. Finally, a parameterization for viscosity of anthropogenic SOA as a function of temperature and RH was developed using sucrose–water data. Based on this parameterization, and assuming sucrose is a good proxy for anthropogenic SOA, 70 and 83% of the mixing times within anthropogenic SOA in the PBL are < 1h for January and July, respectively, when concentrations are significant. These percentages are likely lower limits due to the assumptions used to calculate mixing times.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Laboratory study of the heterogeneous ice nucleation on black-carbon-containing aerosol

Abstract. Soot and black carbon (BC) particles are generated in the incomplete combustion of fossil fuels, biomass, and biofuels. These airborne particles affect air quality, human health, aerosol–cloud interactions, precipitation formation, and climate. At present, the climate effects of BC particles are not well understood. Their role in cloud formation is obscured by their chemical and physical variability and by the internal mixing states of these particles with other compounds. Ice nucleation in field studies is often difficult to interpret. Nonetheless, most field studies seem to suggest that BC particles are not efficient ice-nucleating particles (INPs). On the other hand, laboratory measurements show that in some cases, BC particles can be highly active INPs under certain conditions. By working with well-characterized BC particles, our aim is to systematically establish the factors that govern the ice nucleation activity of BC. The current study focuses on laboratory measurements of the effectiveness of BC-containing aerosol in the formation of ice crystals in temperature and ice supersaturation conditions relevant to cirrus clouds. We examine ice nucleation on BC particles under water-subsaturated cirrus cloud conditions, commonly understood as deposition-mode ice nucleation. We study a series of well-characterized commercial carbon black particles with varying morphologies and surface chemistries as well as ethylene flame-generated combustion soot. The carbon black particles used in this study are proxies for atmospherically relevant BC aerosols. These samples were characterized by electron microscopy, mass spectrometry, and optical scattering measurements. Ice nucleation activity was systematically examined in temperature and saturation conditions in the ranges of 217≤T≤235 K and 1.0≤Sice≤1.5 and 0.59≤Swater≤0.98, respectively, using a SPectrometer for Ice Nuclei (SPIN) instrument, which is a continuous-flow diffusion chamber coupled with instrumentation to measure light scattering and polarization. To study the effect of coatings on INPs, the BC-containing particles were coated with organic acids found in the atmosphere, namely stearic acid, cis-pinonic acid, and oxalic acid. The results show significant variations in ice nucleation activity as a function of size, morphology, and surface chemistry of the BC particles. The measured ice nucleation activity dependencies on temperature, supersaturation conditions, and the physicochemical properties of the BC particles are consistent with an ice nucleation mechanism of pore condensation followed by freezing. Coatings and surface oxidation modify the initial formation efficiency of pristine ice crystals on BC-containing aerosol. Depending on the BC material and the coating, both inhibition and enhancement in INP activity were observed. Our measurements at low temperatures complement published data and highlight the capability of some BC particles to nucleate ice under low ice supersaturation conditions. These results are expected to help refine theories relating to soot INP activation in the atmosphere.

54 ENVIRONMENTAL SCIENCES↗

Liquid–liquid phase separation and viscosity within secondary organic aerosol generated from diesel fuel vapors

Information on liquid–liquid phase separation (LLPS) and viscosity (or diffusion) within secondary organic aerosol (SOA) is needed to improve predictions of particle size, mass, reactivity, and cloud nucleating properties in the atmosphere. Here we report on LLPS and viscosities within SOA generated by the photooxidation of diesel fuel vapors. Diesel fuel contains a wide range of volatile organic compounds, and SOA generated by the photooxidation of diesel fuel vapors may be a good proxy for SOA from anthropogenic emissions. In our experiments, LLPS occurred over the relative humidity (RH) range of ~70 % to ~100 %, resulting in an organic-rich outer phase and a water-rich inner phase. These results may have implications for predicting the cloud nucleating properties of anthropogenic SOA since the presence of an organic-rich outer phase at high-RH values can lower the supersaturation with respect to water required for cloud droplet formation. At ≤10 % RH, the viscosity was ≥1×10 8 Pa s, which corresponds to roughly the viscosity of tar pitch. At 38 %–50 % RH, the viscosity was in the range of 1×10 8 to 3×10 5 Pa s. These measured viscosities are consistent with predictions based on oxygen to carbon elemental ratio (O:C) and molar mass as well as predictions based on the number of carbon, hydrogen, and oxygen atoms. Based on the measured viscosities and the Stokes–Einstein relation, at ≤10 % RH diffusion coefficients of organics within diesel fuel SOA is ≤5.4×10 -17 cm 2 s -1 and the mixing time of organics within 200 nm diesel fuel SOA particles (τ mixing ) is 50 h. These small diffusion coefficients and large mixing times may be important in laboratory experiments, where SOA is often generated and studied using low-RH conditions and on timescales of minutes to hours. At 38 %–50 % RH, the calculated organic diffusion coefficients are in the range of 5.4×10 -17 to 1.8×10 -13 cm 2 s -1 and calculated τ mixing values are in the range of ~0.01 h to ~50 h. These values provide important constraints for the physicochemical properties of anthropogenic SOA.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Complex plant-derived organic aerosol as ice-nucleating particles – more than the sums of their parts?

Quantifying the impact of complex organic particles on the formation of ice crystals in clouds remains challenging, mostly due to the vast number of different sources ranging from sea spray to agricultural areas. In particular, there are many open questions regarding the ice nucleation properties of organic particles released from terrestrial sources such as decaying plant material. In this work, we present results from laboratory studies investigating the immersion freezing properties of individual organic compounds commonly found in plant tissue and complex organic aerosol particles from vegetated environments, without specifically investigating the contribution from biological particles, which may contribute to the overall ice nucleation efficiency observed at high temperatures. To characterize the ice nucleation properties of plant-related aerosol samples for temperatures between 242 and 267 K, we used the Aerosol Interaction and Dynamics in the Atmosphere (AIDA) cloud chamber and the Ice Nucleation SpEctrometer of the Karlsruhe Institute of Technology (INSEKT), which is a droplet freezing assay. Individual plant components (polysaccharides, lignin, soy and rice protein) were mostly less ice active, or similarly ice active, compared to microcrystalline cellulose, which has been suggested by recent studies to be a proxy for quantifying the primary cloud ice formation caused by particles originating from vegetation. In contrast, samples from ambient sources with a complex organic matter composition (agricultural soils and leaf litter) were either similarly ice active or up to 2 orders of magnitude more ice active than cellulose. Of all individual organic plant components, only carnauba wax (i.e., lipids) showed a similarly high ice nucleation activity as that of the samples from vegetated environments over a temperature range between 245 and 252 K. Hence, based on our experimental results, we suggest considering cellulose as being representative for the average ice nucleation activity of plant-derived particles, whereas lignin and plant proteins tend to provide a lower limit. In contrast, complex biogenic particles may exhibit ice nucleation activities which are up to 2 orders of magnitude higher than observed for cellulose, making ambient plant-derived particles a potentially important contributor to the population of ice-nucleating particles in the troposphere, even though major uncertainties regarding their transport to cloud altitude remain.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗