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At least 1,315 records · Page 73

Topography inversion in scanning tunneling microscopy of single-atom-thick materials from penetrating substrate states

Scanning tunneling microscopy (STM) is one of the indispensable tools to characterize surface structures, but the distinction between atomic geometry and electronic effects based on the measured tunneling current is not always straightforward. In particular, for single-atomic-thick materials (graphene or boron nitride) on metallic substrates, counterintuitive phenomena such as a larger tunneling current for insulators than for metal and a topography opposite to the atomic geometry are reported. Using first-principles density functional theory calculations combined with analytical modeling, we reveal the critical role of penetrating states of metallic substrates that surpass 2D material states, hindering the measurement of intrinsic 2D materials states and leading to topography inversion. Our finding should be instrumental in the interpretation of STM topographies of atomic-thick materials and in the development of 2D material for (opto)electronic and various quantum applications.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Triton's surface-atmosphere energy balance

A model encompassing the turbulent transfer of sensible heat as well as insolation, reradiation, and latent heat transport is presently used to investigate the energetics of the surface-atmosphere system of Triton. Under the assumption of a physically plausible range of heat transfer coefficients, the atmospheric temperature 1 km above the surface is found to be 1-3 K hotter than the Triton surface. The observed N2 frosts must have an emissivity lower than unity in order to match a frost temperature at the surface of about 38 K.

Stansberry, John A.↗

Study of the Effects of Photometric Geometry on Spectral Reflectance Measurements

The objective of this research is to investigate how the spectrophotometric properties of planetary surface materials depend on photometric geometry by refining and applying radiative transfer theory to data obtained from spacecraft and telescope observations of planetary surfaces, studies of laboratory analogs, and computer simulations. The goal is to perfect the physical interpretation of photometric parameters in the context of planetary surface geological properties and processes. The purpose of this report is to document the research achievements associated with this study.

Helfenstein, Paul↗

Remote Sensing of Smoke, Land and Clouds from the NASA ER-2 during SAFARI 2000

The NASA ER-2 aircraft was deployed to southern Africa between August 17 and September 25, 2000 as part of the Southern Africa Regional Science Initiative (SAFARI) 2000. This aircraft carried a sophisticated array of multispectral scanners, multiangle spectroradiometers, a monostatic lidar, a gas correlation radiometer, upward and downward spectral flux radiometers, and two metric mapping cameras. These observations were obtained over a 3200 x 2800 km region of savanna, woody savanna, open shrubland, and grassland ecosystems throughout southern Africa, and were quite often coordinated with overflights by NASA's Terra and Landsat 7 satellites. The primary purpose of this sophisticated high altitude observing platform was to obtain independent observations of smoke, clouds, and land surfaces that could be used to check the validity of various remote sensing measurements derived by Earth-orbiting satellites. These include such things as the accuracy of the Moderate Resolution Imaging Spectro-radiometer (MODIS) cloud mask for distinguishing clouds and heavy aerosol from land and ocean surfaces, and Terra analyses of cloud optical and micro-physical properties, aerosol properties, leaf area index, vegetation index, fire occurrence, carbon monoxide, and surface radiation budget. In addition to coordination with Terra and Landsat 7 satellites, numerous flights were conducted over surface AERONET sites, flux towers in South Africa, Botswana, and Zambia, and in situ aircraft from the University of Washington, South Africa, and the United Kingdom.

King, Michael D.↗

Bio Inspired Surface Structures to Mitigate Interfacial Particle Adhesion: A Review

Nature has perfected surface chemical and topographical engineering to enable survival in extreme environments. Biomimetics is a rapidly expanding field where biologically inspired design facilitates elegant, yet practical, solutions across many applications. NASA’s ARTEMIS program focused on lunar missions will require unique ways to solve the challenge of highly abrasive, chemically reactive and electrostatically charged lunar dust that adheres strongly to all exposed surfaces and degrades functionality. While seeking solutions to find a surface for mitigating lunar dust adhesion, we looked at natural terrestrial surfaces that successfully minimize dust adhesion and wear for inspiration. Lunar dust is comprised of highly abrasive particles, more than 90% of which are composed of silicate materials. Adapting to somewhat similar particulates in hot and arid deserts of the world, the sandfish lizard has a skin structure that allows it to swim in the sand with minimum friction and adhesion. Special surface adaptations of the tamarisk plant help protect it from severe sandstorms. The desert scorpion has grooves and bumps on its carapace that have been shown to minimize erosion in the sand. Beyond these examples, there are numerous other natural surfaces that have evolved to mitigate particle adhesion and wear. Several efforts have been made by different researchers to replicate these natural surfaces using methods such as laser patterning, 3D printing, chemical vapor deposition and other physical and chemical processes. The resulting bio-inspired patterned surfaces have shown reduction in interfacial particle adhesion, friction, and wear, among other properties. This paper aims to review published research on the subject that might help develop lunar dust adhesion and wear mitigating material surfaces for future lunar applications.

Lunar dust, Lunar surface, Adhesion mitigation, Bi↗

A Method for Measuring Optical Distortion in Curved Optical Surfaces using Moiré Interferometry

In FY2020, KSC’s Applied Physics Lab created a computer based image processing system to allow inspection of the new visors being developed for the Artemis Program. This system was based on an ASTM standard where the distortion of an image is used to determine the optical aberrations in a visor, but this approach is restricted to small fields-of-view (small areas of the visor) and is limited in its ability to reliably detect and measure distortion. From our experience with flat surface inspection, we know that other optical techniques can offer higher sensitivity and accuracy. [1] This memorandum describes a method to model and measure the distortion in curved optical surfaces using moir´e interferometry. We were able to apply this process to examine samples of the xEMU Artemis astronaut helmets. Design details are provided along with examples to illustrate performance.

Optical Distortion↗

Assessments of Physiology and Cognition in Hybrid-Reality Environments (APACHE)

NASA is planning to return to the Moon in the mid-2020s as a stepping stone to Mars missions in the 2030s. Spacewalks, or extravehicular activities (EVAs), performed on the Moon and Mars will differ in a variety of ways from those that have been performed in decades past. NASA has identified multiple risks to human health and performance associated with a crewed mission to Mars, especially those associated with exploration EVAs which are expected to be a primary mission activity. Crew may be expected to conduct up to 24 hours of EVA per person per week, where the likelihood of injury and/or mental mistakes are increased compared to ground-based training or current microgravity EVAs and the consequences of which can be catastrophic. Current test environments for exploration EVA research and technology development are large, costly facilities that are limited in their availability or capabilities. Spacesuit testing in a reduced gravity environment such as NASA’s Neutral Buoyancy Laboratory, while a good representation of the crew’s physical workload during exploration EVAs, typically has small datasets and is difficult to integrate physiological sensors or other types of crew performance measures. Meanwhile, scientific field-based testing such as NASA’s Desert Research and Technology Studies offers an operationally relevant environment for exploration EVAs, particularly for cognitive workload, but is also limited by small datasets, lack of a pressurized spacesuit, and obtrusive measures. The limitations of current analogs for exploration EVAs identify a need for a new test environment that can approximate both the physical and cognitive demands associated with exploration EVAs to enable rapid, controlled, and repeatable evaluations of human health and performance risks of exploration missions. In response, the Human Physiology, Performance, Protection, and Operations Laboratory (H-3PO) at NASA Johnson Space Center has developed a hybrid reality exploration EVA analog named the Assessments of Physiology And Cognition in Hybrid-reality Environments (APACHE) to address these limitations using a combination of virtual, physical, and hybrid reality techniques. The APACHE facility resides at NASA Johnson Space Center and serves as a large “sandbox” for EVA research and simulation. At its center is a roughly 15x20ft space surrounded by a 14” tall sandbox partially filled with lunar regolith simulant to emulate the physical feeling of walking on a planetary surface and to allow for simulated geology operations. Nearby, a curved passive treadmill (Skillmill Connect, Technogym, Fairfield, NJ) and an omnidirectional treadmill (Infinadeck, Infinadeck, Rocklin, CA) are included to enable exploration of these large virtual environments while also imposing the physical demands, representative timelines, and cognitive burdens required to navigate and traverse these distances during exploration EVA. A 6DOF motion platform is used to simulate rover operations and supports various human performance evaluations and associated risks. Lastly, APACHE can support two extravehicular (EV) crewmembers working in tandem. A computer workstation is located nearby and also supports an intravehicular (IV) crewmember as part of a full mission simulation. The IV crewmember has direct video and audio communication with the EV crew in VR to provide operational and procedural support. The software used in APACHE was created by the JSC Engineering Directorate, in partnership with Buendea, powered by a custom Unreal Engine 5 (UE5.3, Epic Games) project. APACHE currently utilizes the HTC Vive Pro Eye in a wireless configuration for VR simulations. There are two virtual environments that subjects can explore within APACHE, a Lunar and Martian surface. The virtual Lunar surface was created from LIDAR data of the Lunar South Pole to create roughly 16 sq km of explorable terrain. The virtual Martian surface contains roughly 400 sq km of explorable terrain derived from Mars Reconnaissance Orbiter LIDAR data of the Jezero Crater. The immersion and related cognitive burdens of conducting a planetary EVA is simulated through a series of EVA-relevant tasks performed in the VR environment, using these high-fidelity visual representations. Additionally, APACHE includes biosensor driven informatics, such as real-time heart rate monitoring and/or derived values from model simulations, for active monitoring by the EV crew and added cognitive demand. A “Wizard of Oz” control panel enables test operators to activate contingency events such as simulated spacesuit malfunctions, loss of communications, and/or limited visibility. Embedded performance measures such as accuracy, completeness, and execution time have been developed for various exploration tasks to objectively quantify crew performance during an EVA and compare impacts to performance when different environmental stressors, both physical and cognitive, are added to or removed from the simulation. Additionally, validated cognitive and operational performance measures such as the Digit Symbol Substitution Task have been recreated and embedded in VR for direct and relatively unobtrusive measurement of motor perception. The APACHE environment currently supports multiple research studies at NASA. Examples include the CHAPEA project, a series of simulated year-long missions on Mars by a 4-person crew; and the CO2 Contingency Walk Back Study, an investigation of elevated CO2 exposure on crew performance during a contingency EVA scenario. APACHE also provides a test environment to support the development of the Crew State and Risk Model, which is a collection of individualized, mathematical models of crew physical and cognitive state; and the Personalized EVA Informatics and Decision Support system, an operational tool for flight controllers, and eventually a self-reliant Martian crew, to make biomedically-informed decisions in real-time to optimize the EVA planning and execution with respect to crew health and performance. Some technical challenges associated with developing the APACHE environment, as well as current limitations, include VR limitless natural walking with a hybrid spacesuit simulator, optimizing performance for wireless PC VR streaming while maintaining a high degree of visual fidelity, and the integration of various physiological (metabolic masks) and psychometric (eye tracking) sensors with the VR headset.

Human Performance↗

Interim Report of the Astronomy Spacelab Payloads Study: Ultraviolet and Optical Astronomy - Volume 2

The Space Shuttle will comprise NASA's primary transportation system into near-earth orbit during the 1980s. The Shuttle will provide the astronomical community with a major new capability to send a wide variety of instrumentation into orbit, to utilize it there under manned or automatic control for periods from seven to thirty days, and to return it to the ground. To this end the European Space Research Organization (ESRO) is developing Spacelab, an array of interchangeable components -pressurized manned modules, unpressurized pallets and related support systems - to be mounted in the Shuttle payload bay. Spacelab will offer important opportunities to carry out astronomical research with instruments optimized for specific objectives. With a high flight frequency and with the ability to modify or interchange telescopes and instruments between flights, one will not need to make rigid long-term commitments to specific and compromised telescope/instrument/ detector combinations as is the case for automated satellites. Observational techniques demanding the physical return of data and equipment - in particular the use of photographic film, instruments requiring tight calibration controls, cryogens, high-risk detectors and degradeable optical coatings -will open research areas not readily addressed by automated satellites. Although Shuttle flight duration will be limited to periods from seven to thirty days, substantial data can be obtained with a single instrument on short missions, if targets are carefully selected and prioritized, and a large number of instruments can be accommodated on a single flight. Important astronomical data are regularly obtained on sounding rocket flights of five minutes duration. Spacelab will provide far longer observing periods for large and small telescopes, with resources greatly exceeding those of sounding rockets, while retaining much of the sounding rocket philosophy in terms of instrument flexibility, simplicity, reliability assurance and development costs. The Ultraviolet and Optical Astronomy Program on Spacelab is being planned to provide optical astronomers with relatively simple and regular access to the extended wavelength coverage, the superior image quality and the darkness of the night sky available above the earth's atmosphere. In a rapidly evolving science one cannot predict what problems will be timely in the 1980s. Extrapolating from the current epoch, however, one can envision a continuing interest in such areas as the structure, composition and phenomenology of planetary surfaces and atmospheres; the composition and physical nature of the interstellar medium; the composition, structure and life history of stars, especially those in advanced stages of evolution; the stellar population of other galaxies; such enigmatic phenomena as X-ray binary black holes, pulsars, active galactic nuclei and quasars; large scale interactions between galaxies and the nature of the intergalactic medium; precise calibration of the Hubble law for the expansion of the universe; the average density of the universe; and the existence of extraterrestrial life.

Source record↗

Phase Diagram of a Deep Potential Water Model

Using the Deep Potential methodology, we construct a model that reproduces accurately the potential energy surface of the SCAN approximation of density functional theory for water, from low temperature and pressure to about 2400 K and 50 GPa, excluding the vapor stability region. The computational efficiency of the model makes it possible to predict its phase diagram using molecular dynamics. Satisfactory overall agreement with experimental results is obtained. Here, the fluid phases, molecular and ionic, and all the stable ice polymorphs, ordered and disordered, are predicted correctly, with the exception of ice III and XV that are stable in experiments, but metastable in the model. The evolution of the atomic dynamics upon heating, as ice VII transforms first into ice VII" and then into an ionic fluid, reveals that molecular dissociation and breaking of the ice rules coexist with strong covalent fluctuations, explaining why only partial ionization was inferred in experiments.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Impact of nuclear reactor radiation on the performance of AlN/sapphire surface acoustic wave devices

The performance of an AlN/sapphire surface acoustic wave (SAW) delay line device was characterized in real time under irradiation inside a nuclear reactor. Both its resonant frequency and transmission efficiency were observed to respond to a change in reactor power. The response follows an exponentially saturating behavior after a step power increase, followed by an exponentially decaying recovery after reactor shutdown. A sensitivity analysis based on the governing electro-mechanical equations shows that the frequency shift can be attributed to the softening of sapphire’s elastic constants under neutron radiation. Additionally, a kinetic rate equation is adopted to interpret device response and describe its microstructural evolution. These results suggest that the AlN/sapphire SAW device remains functional under irradiation, is sensitive to neutron and gamma ray fluxes, and offers an opportunity for remote sensing and in-situ measurement of material properties when exposed to nuclear reactor environment.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Energy gap of topological surface states in proximity to a magnetic insulator

Abstract Topological surface-states can acquire an energy gap when time-reversal symmetry is broken by interfacing with a magnetic insulator. This gap has yet to be measured. Such topological-magnetic insulator heterostructures can host a quantized anomalous Hall effect and can allow the control of the magnetic state of the insulator in a spintronic device. In this work, we observe the energy gap of topological surface-states in proximity to a magnetic insulator using magnetooptical Landau level spectroscopy. We measure Pb 1-x Sn x Se–EuSe heterostructures grown by molecular beam epitaxy exhibiting a record mobility and low Fermi energy. Through temperature dependent measurements and theoretical calculations, we show this gap is likely due to quantum confinement and conclude that the magnetic proximity effect is weak in this system. This weakness is disadvantageous for the realization of the quantum anomalous Hall effect, but favorable for spintronic devices which require the preservation of spin-momentum locking at the Fermi level.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Refined potentials for rare gas atom adsorption on rare gas and alkali-halide surfaces

The utilization of models of interatomic potential for physical interaction to estimate the long range attractive potential for rare gases and ions is discussed. The long range attractive force is calculated in terms of the atomic dispersion properties. A data base of atomic dispersion parameters for rare gas atoms, alkali ion, and halogen ions is applied to the study of the repulsive core; the procedure for evaluating the repulsive core of ion interactions is described. The interaction of rare gas atoms on ideal rare gas solid and alkali-halide surfaces is analyzed; zero coverage absorption potentials are derived.

Wilson, J. W.↗

Legacy surface change analyses of the 1993 Rock Valley earthquake sequence for direct comparison to planned NA-22 underground conventional high-explosive experiments (Source Physics Experiment 3 (SPE3) - RV/DC Task 1.3 FY22 Final Report)

Recent work under two previous phases of the NNSA NA-22 Source Physics Experiment (SPE) have shown that underground chemical high-explosive experiments can produce detectable surface changes that differ in spatial extent and vertical magnitude depending on the geologic media at the site (Schultz-Fellenz et al., 2018; 2020; Crawford et al., 2021). Neither of these two prior phases of SPE identified natural earthquake-related surface effects in the same region that occurred at a similar depth as the explosive experiments for direct comparison. While earthquakes can also produce surface changes that are detectable using remote sensing data analyses, it is expected that the pattern and spatial extent of surface changes would vary between earthquakes and explosions. However, no direct-observed surface-change signature comparison between earthquakes and explosions has ever been performed. The SPE Phase 3 Rock Valley/Direct Comparison (RV/DC) program presents a unique opportunity to investigate and characterize co-occurrence of both earthquakes and explosions. In this project, we worked to address five tasks in a workflow, as follows: 1. Identify and obtain existing high-resolution legacy satellite and aerial imagery as close in time before and after the 1993 Rock Valley earthquake sequence to temporally constrain the analyses. 2. Transform these pre-earthquake and post-earthquake datasets into digital elevation models (DEMs) using geospatial analysis software packages (e.g., ArcGIS, Agisoft Metashape, and Google Earth Engine). 3. Perform DEM differencing analyses to assess and quantify earthquake-related changes from the 1993 sequence, and develop map products that visualize these analyses. 4. Use the analyses from (3) to: (a) assess spatial distribution and magnitude of surface changes due to the 1993 Rock Valley earthquake sequence, and (b) determine parameters of forthcoming, planned explosion-related surface change data collection from sensors mounted on unmanned aerial vehicles (UAVs) (e.g., spatial extent of collection, design and density of survey control, sensors to deploy, forward speed and line spacing of UAV flight lines, flight altitude). 5. Develop a summary report on the analyses, including how the analyses define parameters and identify focus areas for any future surface change analytical field campaigns related to the explosive experiment. Analyzing these legacy data and identifying whether they can detect any surface changes related to the earthquake sequence facilitates opportunities for direct signature comparison of surface change from explosions at one location, which has never previously been performed. Comparing the surface change signatures from a co-located and depth-equivalent earthquake and an explosion could help to advance remote sensing event discrimination techniques. This report summarizes the work completed toward this ambitious goal.

42 ENGINEERING↗

Separability of H 2 O molecular potential surfaces in hyperspherical coordinates via adiabatic approximation

An adiabatic scheme for separation of the three-dimensional (3D) nuclear dynamics on the ground electronic Born-Oppenheimer potential energy surface of an H 2 O molecule in hyperspherical coordinates is presented. It is found that the three vibrational modes are weakly coupled and the 3D vibrational wave function can be approximated as a product of three separable functions: one represented by the hyperradius and two by the two hyperangles individually. Additionally, this framework is then used for investigation of the formation and the role of a saddlelike barrier arising in the two hyperspherical angles that is to moderate the OH + H dissociation process. In order to test the validity of the framework, vibrational states with energies up to 19 500 cm -1 are constructed under the assumptions of adiabaticity and separability and compared to full three-dimensional high-precision numerical calculations yielding remarkable correspondence. As a result we present a simple construction scheme for separated molecular vibration states as the first step towards theoretical investigation of laser-driven molecular dynamics of triatomic molecules.

74 ATOMIC AND MOLECULAR PHYSICS↗

Accurate in vivo tumor detection using plasmonic-enhanced shifted-excitation Raman difference spectroscopy (SERDS)

For the majority of cancer patients, surgery is the primary method of treatment. In these cases, accurately removing the entire tumor without harming surrounding tissue is critical; however, due to the lack of intraoperative imaging techniques, surgeons rely on visual and physical inspection to identify tumors. Surface-enhanced Raman scattering (SERS) is emerging as a non-invasive optical alternative for intraoperative tumor identification, with high accuracy and stability. However, Raman detection requires dark rooms to work, which is not consistent with surgical settings. Methods: Herein, we used SERS nanoprobes combined with shifted-excitation Raman difference spectroscopy (SERDS) detection, to accurately detect tumors in xenograft murine model. Results: We demonstrate for the first time the use of SERDS for in vivo tumor detection in a murine model under ambient light conditions. We compare traditional Raman detection with SERDS, showing that our method can improve sensitivity and accuracy for this task. Conclusion: Our results show that this method can be used to improve the accuracy and robustness of in vivo Raman/SERS biomedical application, aiding the process of clinical translation of these technologies.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Seeing big things: overestimation of heights is greater for real objects than for objects in pictures

In six experiments we demonstrate that the vertical-horizontal illusion that is evoked when viewing photographs and line drawings is relatively small, whereas the magnitude of this illusion when large objects are viewed is at least twice as great. Furthermore, we show that the illusion is due more to vertical overestimation than horizontal underestimation. The lack of a difference in vertical overestimation between pictures and line drawings suggests that vertical overestimation in pictures depends solely on the perceived physical size of the projection on the picture surface, rather than on what is apparent about an object's represented size. The vertical-horizontal illusion is influenced by perceived physical size. It is greater when viewing large objects than small pictures of these same objects, even when visual angles are equated.

NASA Discipline Space Human Factors↗

Stochastic Kinetics of Nanocatalytic Systems

Catalytic reaction events occurring on the surface of a nanoparticle constitute a complex stochastic process. Although advances in modern single-molecule experiments enable direct measurements of individual catalytic turnover events occurring on a segment of a single nanoparticle, we do not yet know how to measure the number of catalytic sites in each segment or how the catalytic turnover counting statistics and the catalytic turnover time distribution are related to the microscopic dynamics of catalytic reactions. Here, we address these issues by presenting a stochastic kinetics for nanoparticle catalytic systems. We propose a new experimental measure of the number of catalytic sites in terms of the mean and variance of the catalytic event count. By considering three types of nanocatalytic systems, we investigate how the mean, the variance, and the distribution of the catalytic turnover time depend on the catalytic reaction dynamics, the heterogeneity of catalytic activity, and communication among catalytic sites. This work enables accurate quantitative analyses of single-molecule experiments for nanocatalytic systems and enzymes with multiple catalytic sites.

Statistical Physics↗

Evaluation of CFD for Simulation of High-Supersonic Control-Surface Effectiveness

As part of studying the ability of Computational Fluid Dynamics (CFD) to accurately model important flow physics in the high-supersonic Mach number range, control-surface effectiveness on an entry vehicle for Mars exploration was examined. As with several other important flow regimes studied under the CFD as Surrogate for Wind Tunnel Testing at High Supersonic Speeds Project, a combined CFD and wind-tunnel study of a proposed Mars landing configuration was undertaken. The testing was performed in high-speed test section of the NASA Langley Research Center’s Unitary Plan Wind Tunnel. The CFD team was an integral part of the overall evaluation team throughout the model development and test planning process and performed pre-test computations predicting the results of the testing. For the CFD predictions of the model in the wind tunnel, the flow into the test section was imposed as a boundary condition. The imposed inflow was based on a previous flow characterization study and companion CFD simulating the flow from the settling chamber through the test section.

James C. Ross↗