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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

SATS Enhanced Capabilities and Demonstration of Improved Ramp Rates for In-Cell Testing

This report presents the development of the second-generation Severe Accident Test Station, referred to as SATS 2.0. SATS 2.0 represents a major advancement in addressing critical research needs for the United States nuclear industry, particularly in relation to fuel fragmentation, relocation, and dispersal (FFRD) concerns associated with the nuclear industry’s goal to extend fuel burnup beyond a peak rod average of 62 GWd/tU. The central objective of SATS 2.0 was the deployment a new furnace capable of achieving heating rates up to 100°C/s. This achievement addresses critical capability gaps, enabling assessment of prioritized research objectives established by the Electric Power Research Institute’s (EPRI) Collaborative Research on Advanced Fuel Technologies (CRAFT) working group. These research objectives are directly related to high-burnup loss-of-coolant accident (LOCA) conditions and the effects of prolonged exposure to elevated temperatures, both of which are crucial to enhancing nuclear safety and efficiency. The SATS 2.0 system builds upon prior experience with the original SATS system, which focused on evaluating accident-tolerant fuel (ATF) cladding concepts during accident conditions. However, the new system not only expands upon prior core capabilities by achieving higher heating rates with a better furnace but also plans to incorporate novel auxiliary systems to create a versatile platform for addressing current research needs. For example, a system was developed for the quantification and characterization of fission gas released during high-temperature transients. Additionally, in situ measurement capabilities were developed, such as digital image correlation which enabled the real-time capture of strain related to balloon and burst events and fiber-optic sensors that allowed for high-fidelity characterization of temperature gradients. Demonstration tests of the new 12-lamp furnace achieved heating rates up to 120°C/s. Notably, SATS 2.0 demonstrated its capacity to simulate LOCA burst tests at different pressures, yielding burst data that align with historical empirical models. Moreover, the system exhibited its capability to simulate complex conditions observed in anticipated operational occurrences, while effectively mitigating temperature overshoots. These accomplishments mark significant progress toward overcoming FFRD challenges and advancing the United States nuclear industry's safety basis and technical capabilities for extended burnup.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
NASA NTRS1992

The nearby 2-solar mass Bok globule LBN 11 - Sub-sonic molecular clumps in a magnetic environment

A multiwavelength study of the nearby small Bok globule LBN 11 is performed in order to investigate the relationship between embedded magnetic fields, cloud structure, and star formation. Optical polarimetry of background stars is used to characterize and trace the embedded magnetic field direction. High-dispersion CO isotopic mapping is employed to determine the radial density distribution of the gas, measure cloud rotation, and identify individual gas clumps. CS and SO mapping revealed dense cores within the (C-13)O clumps. Analysis of coadded IRAS images reveal the cloud to be free of current or recent star formation: there are no IR point sources of sufficient flux or proper colors to signify young stars associated with the cloud. The molecular line maps show the cloud to be extremely clumpy. Clumps are found to range in size from 0.2 pc for the largest CO clump to about 0.04 pc for the smallest CS feature. It is concluded that, at least in the envelope of the cloud, the magnetic field and the CO clumps are coupled.

Clemens, Dan P.↗
NASA NTRS2010

Testing of an Integrated Reactor Core Simulator and Power Conversion System with Simulated Reactivity Feedback

A Direct Drive Gas-Cooled (DDG) reactor core simulator has been coupled to a Brayton Power Conversion Unit (BPCU) for integrated system testing at NASA Glenn Research Center (GRC) in Cleveland, Ohio. This is a closed-cycle system that incorporates an electrically heated reactor core module, turboalternator, recuperator, and gas cooler. Nuclear fuel elements in the gas-cooled reactor design are replaced with electric resistance heaters to simulate the heat from nuclear fuel in the corresponding fast spectrum nuclear reactor. The thermodynamic transient behavior of the integrated system was the focus of this test series. In order to better mimic the integrated response of the nuclear-fueled system, a simulated reactivity feedback control loop was implemented. Core power was controlled by a point kinetics model in which the reactivity feedback was based on core temperature measurements; the neutron generation time and the temperature feedback coefficient are provided as model inputs. These dynamic system response tests demonstrate the overall capability of a non-nuclear test facility in assessing system integration issues and characterizing integrated system response times and response characteristics.

Bragg-Sitton, Shannon M.↗
NASA NTRS2012

Aerothermal Ground Testing of Flexible Thermal Protection Systems for Hypersonic Inflatable Aerodynamic Decelerators

Flexible TPS development involves ground testing and analysis necessary to characterize performance of the FTPS candidates prior to flight testing. This paper provides an overview of the analysis and ground testing efforts performed over the last year at the NASA Langley Research Center and in the Boeing Large-Core Arc Tunnel (LCAT). In the LCAT test series, material layups were subjected to aerothermal loads commensurate with peak re-entry conditions enveloping a range of HIAD mission trajectories. The FTPS layups were tested over a heat flux range from 20 to 50 W/cm with associated surface pressures of 3 to 8 kPa. To support the testing effort a significant redesign of the existing shear (wedge) model holder from previous testing efforts was undertaken to develop a new test technique for supporting and evaluating the FTPS in the high-temperature, arc jet flow. Since the FTPS test samples typically experience a geometry change during testing, computational fluid dynamic (CFD) models of the arc jet flow field and test model were developed to support the testing effort. The CFD results were used to help determine the test conditions experienced by the test samples as the surface geometry changes. This paper includes an overview of the Boeing LCAT facility, the general approach for testing FTPS, CFD analysis methodology and results, model holder design and test methodology, and selected thermal results of several FTPS layups.

Bruce, Walter E., III↗
NASA NTRS2009

Testing of an Integrated Reactor Core Simulator and Power Conversion System with Simulated Reactivity Feedback

A Direct Drive Gas-Cooled (DDG) reactor core simulator has been coupled to a Brayton Power Conversion Unit (BPCU) for integrated system testing at NASA Glenn Research Center (GRC) in Cleveland, OH. This is a closed-cycle system that incorporates an electrically heated reactor core module, turbo alternator, recuperator, and gas cooler. Nuclear fuel elements in the gas-cooled reactor design are replaced with electric resistance heaters to simulate the heat from nuclear fuel in the corresponding fast spectrum nuclear reactor. The thermodynamic transient behavior of the integrated system was the focus of this test series. In order to better mimic the integrated response of the nuclear-fueled system, a simulated reactivity feedback control loop was implemented. Core power was controlled by a point kinetics model in which the reactivity feedback was based on core temperature measurements; the neutron generation time and the temperature feedback coefficient are provided as model inputs. These dynamic system response tests demonstrate the overall capability of a non-nuclear test facility in assessing system integration issues and characterizing integrated system response times and response characteristics.

Bragg-Sitton, Shannon M.↗
NASA NTRS1994

(abstract) Gravity Investigation of the Manson Impact Structure, Iowa

The Manson Impact Structure (MIS) is located in northwest Iowa, has an age of approximately 74 Ma, and diameter of approximately 35 km. MIS is characterized by a central uplift of crystalline rock surounded by a depression filled with breccia and in turn surrounded by a terraced rim of slumped blocks. MIS is buried by glacial till; hence the geology must be studied through coring and geophysical techniques. Here, results of a gravity survey are reported. The residual gravity pattern is complicated by numerous highs and lows associated with density variations within the crystalline basement. The gravity data indicate a complex central uplift, perhaps a pitted central peak; a breccia unit approximately 3000 m thick surrounding the central uplift, and a diameter of about 35 km.

impact↗
DOE OSTI2018

Broad Genomic Sampling Reveals a Smut Pathogenic Ancestry of the Fungal Clade Ustilaginomycotina

Ustilaginomycotina is home to a broad array of fungi including important plant pathogens collectively called smut fungi. Smuts are biotrophs that produce characteristic perennating propagules called teliospores, one of which, Ustilago maydis , is a model genetic organism. Broad exploration of smut biology has been hampered by limited phylogenetic resolution of Ustilaginiomycotina as well as an overall lack of genomic data for members of this subphylum. In this study, we sequenced eight Ustilaginomycotina genomes from previously unrepresented lineages, deciphered ordinal-level phylogenetic relationships for the subphylum, and performed comparative analyses. Unlike other Basidiomycota subphyla, all sampled Ustilaginomycotina genomes are relatively small and compact. Ancestral state reconstruction analyses indicate that teliospore formation was present at the origin of the subphylum. Divergence time estimation dates the divergence of most extant smut fungi after that of grasses (Poaceae). However, we found limited conservation of well-characterized genes related to smut pathogenesis from U. maydis , indicating dissimilar pathogenic mechanisms exist across other smut lineages. The genomes of Malasseziomycetes are highly diverged from the other sampled Ustilaginomycotina, likely due to their unique history as mammal-associated lipophilic yeasts. Despite extensive genomic data, the phylogenetic placement of this class remains ambiguous. Although the sampled Ustilaginomycotina members lack many core enzymes for plant cell wall decomposition and starch catabolism, we identified several novel carbohydrate active enzymes potentially related to pectin breakdown. Finally, ~50% of Ustilaginomycotina species-specific genes are present in previously undersampled and rare lineages, highlighting the importance of exploring fungal diversity as a resource for novel gene discovery.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2025

Enhanced Carbon Dioxide Uptake in Drilled Hollow Core Fibers for Raman Spectroscopy

Fiber-based Raman spectroscopy enhances the Raman signal by maximizing the overlap of the optical field and the gas species. However, filling the hollow-core fiber (HCF) with gas requires time that is dependent on the fiber core diameter, fiber length, and pressure of the gas. At ambient pressure, the fiber gas uptake is driven by diffusion into the fiber ends, severely limiting the response time of the system. By laser drilling access holes to the core along the length of the fiber, the uptake time of the gas is reduced, improving the system response time. In this work, we study the carbon dioxide (CO 2 ) sensor dynamics based on Raman signal intensity generated in HCFs. The signal intensity versus gas concentration is characterized by controlling the CO 2 concentration in the surrounding environment of the fiber. Next, we characterize the gas uptake time in HCFs as a function of fiber length. Finally, we optimize the access hole configuration along the fiber, demonstrating reduced sensor uptake time by a factor of three.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Comparison of PID Shunting in Polycrystalline and Single-Crystal Silicon Modules via Multi-Scale, Multi-Technique Characterization

We used the methods we reported last year to investigate potential-induced degradation (PID). We have now applied these methods to single-crystalline silicon modules that have degraded during field deployment, as well as in minimodules stressed in the laboratory. We will compare these results to the polycrystalline results presented last year. Small cores have been removed from the modules and subjected to analysis. We use a combination of photoluminescence and dark lock-in thermography imaging, laser marking, electron-beam induced current measurements, and subsequent focused ion-beam marking to allow analysis of individual defects via time-of-flight secondary-ion mass spectrometry (TOF-SIMS) to investigate the root-cause mechanism for PID shunting. We see a direct correlation between recombination active shunts and sodium content. The sodium content in shunted areas peaks at the SiN/Si interface and is consistently observed at a concentration of 0.1%-1% in shunted areas. TOF-SIMS data taken on degraded and non-degraded single-crystalline sample areas show a similar trend as in the polycrystalline samples: more sodium is seen in the degraded areas.

14 SOLAR ENERGY↗
NASA NTRS2003

Use of Computed Tomography for Characterizing Materials Grown Terrestrially and in Microgravity

Computed Tomography (CT) has advanced considerably since being responsible for such dramatic advances in diagnostics within the medical field. It has become a major tool in non destructive evaluation (NDE), and is used in many fields as diverse as coal-mining to metal solidification to examination of rock cores. A review of industrial applications has been written by Dennis. It is only recently that the technique has been seriously used to determine composition through precise measurement of density. While such applications are restricted to cases when there is no ambiguity in the relationship of composition to density. Thus alloy solid solutions lend themselves to compositional analysis provided there is a large change in density with composition. The technique is most useful when rapid non-destructive evaluation is needed. Such cases will occur with samples returning from the International Space Station (ISS) when knowledge of the results could affect future strategies for processing of on-board samples. Experiments from those Principal Investigators (PI) that are most likely to benefit from early CT scanning are discussed. With a dearth of samples, the major emphasis in the first part of this project has been on preparing suitable standards, optimizing the CT technique for these applications, and using the CT system to determine density variations with temperature. An interesting application of CT has been in the examination of meteorites, which can be classified as space-grown materials and will certainly have solidified in a low gravity environment.

Gillies, Donald C.↗
DOE OSTI2018

A valine-to-lysine substitution at position 210 induces structural conversion of prion protein into a β-sheet rich oligomer

Highlights: • A V210I mutation has been associated with pathogenic conversion of PrP to PrP{sup Sc}. • A V210K mutation (but not the V210I mutation) impacts on the PrP structure. • The resulting structure adopts a β-sheet-rich oligomer with low stability. • A lysine substitution in the hydrophobic core induces the α→β conversion in vitro. Prion diseases are fatal neurodegenerative diseases associated with structural conversion of α-helical prion protein (PrP) into its β-sheet rich isoform (PrP{sup Sc}). Previous genetic analyses have indicated that several amino acid residues involved in the hydrophobic core of PrP (such as V180, F198, and V210) play a critical role in the development of prion diseases. To understand how these hydrophobic residues would contribute to the α-to-β conversion process of PrP, we substituted the V210 residue with bulkier (V210F, V210I, and V210L), smaller (V210A), and charged amino acids (V210K) and characterized its effects. Interestingly, although most of the mutations had little or no effect on the biochemical properties of PrP, the V210K mutation induced structural conversion of PrP into a β-structure. The β-inducing effect was prominent and observed even under a physiological condition (i.e., in the absence of denaturant, acidic pH, reducing agent, and high temperature) in contrast to the disease-associated mutations in the PrP gene. We also examined structural features of V210K PrP using guanidine-hydrochloride unfolding, dynamic light scattering, 8-anilino-1-naphthalene sulfonate fluorescence, and electron microscopy, and revealed that V210K PrP assembles into a non-fibrillar β-rich oligomer. Thus, the α-to-β conversion can be induced by introduction of a charged residue into the hydrophobic core, which provide novel insight into the structural dynamics of PrP.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2020

Sensitivity of the latitude of the westerly jet stream to climate forcing

The latitude of the westerly jet stream is influenced by a variety of climate forcings. Their effects often manifest as a tug-of-war between tropical forcing, characterized by tropical upper-tropospheric warming, and polar forcing, with a signature of Antarctic stratospheric cooling or Arctic amplification. Here we present a unified forcing-feedback frame work relating different climate forcings to their forced jet changes, in which the interactions between the westerly jet and synoptic storms are synthesized by a zonal advection feedback, analogous to the feedback framework for assessing climate sensitivity. This framework is supported by a prototype feedback analysis in the atmospheric dynamical core of a climate model with diverse thermal and mechanical forcings. Our analysis indicates that the latitude of a westerly jet is most sensitive to the thermally-induced jet speed changes near the tropopause. The jet shift also displays a larger sensitivity than linearity for the equatorward shift.

atmospheric dynamics, atmospheric variability, cli↗
NASA NTRS1997

Interstellar and Cometary Dust

'Interstellar dust' forms a continuum of materials with differing properties which I divide into three classes on the basis of observations: (a) diffuse dust, in the low-density interstellar medium; (b) outer-cloud dust, observed in stars close enough to the outer edges of molecular clouds to be observed in the optical and ultraviolet regions of the spectrum, and (c) inner-cloud dust, deep within the cores of molecular clouds, and observed only in the infrared by means of absorption bands of C-H, C=O, 0-H, C(triple bond)N, etc. There is a surprising regularity of the extinction laws between diffuse- and outer-cloud dust. The entire mean extinction law from infrared through the observable ultraviolet spectrum can be characterized by a single parameter. There are real deviations from this mean law, larger than observational uncertainties, but they are much smaller than differences of the mean laws in diffuse- and outer-cloud dust. This fact shows that there are processes which operate over the entire distribution of grain sizes, and which change size distributions extremely efficiently. There is no evidence for mantles on grains in local diffuse and outer-cloud dust. The only published spectra of the star VI Cyg 12, the best candidate for showing mantles, does not show the 3.4 micro-m band which appreciable mantles would produce. Grains are larger in outer-cloud dust than diffuse dust because of coagulation, not accretion of extensive mantles. Core-mantle grains favored by J. M. Greenberg and collaborators, and composite grains of Mathis and Whiffen (1989), are discussed more extensively (naturally, I prefer the latter). The composite grains are fluffy and consist of silicates, amorphous carbon, and some graphite in the same grain. Grains deep within molecular clouds but before any processing within the solar system are presumably formed from the accretion of icy mantles on and within the coagulated outer-cloud grains. They should contain a mineral/carbonaceous matrix, without organic refractory mantles, in between the ices. Unfortunately, they may be significantly processed by chemical processes accompanying the warming (over the 10 K of the dark cloud cores) which occurs in the outer solar system. Evidence of this processing is the chemical anomalies present in interplanetary dust particles collected in the stratosphere, which may be the most primitive materials we have obtained to date. The comet return mission would greatly clarify the situation, and probably provide samples of genuine interstellar grains.

Mathis, John S.↗
DOE OSTI2018

Fabrication of highly efficient carbon coated exfoliated tungsten disulfide nanosheets core-shell nanostructure as a promising solar-light driven photocatalyst

Highlights: • Investigated the benefits of exfoliation mechanism of WS{sub 2} nanosheets. • C@e-WS{sub 2} was successfully synthesized via two step exfoliation -hydrothermal process. • C@e-WS{sub 2} core-shell confirmed by HRTEM. • C@e-WS{sub 2} core-shell photocatalyst exhibited excellent photocatalytic activity. • Photodegradation mechanism of C@e-WS{sub 2} photocatalyst is elucidated and discussed. - Abstract: Exfoliated Tungsten disulfide (e-WS{sub 2}) nanosheets were obtained from bulk Tungsten disulfide (WS{sub 2}) in a liquid-phase ultrasonic exfoliation method using a DMF solvent. Core-shell mannered carbon coating was developed by hydrothermal process on exfoliated Tungsten disulfide (e-WS{sub 2}) to enhance the efficient charge separation, specific surface area with mesoporosity and stability for chemical processes and mechanical strains. The carbon coated e-WS{sub 2} nanosheets (C@e-WS{sub 2}) was performed by series of characterization techniques and explored to the photocatalytic degradation of malachite green (MG) dye by comparing with bulk WS{sub 2} and e-WS{sub 2}. Among all the photocatalysts highest performance was observed for the C@e-WS{sub 2}. C@e-WS{sub 2} catalyst displays more than 11 fold enhancements in the photocomposition rate of MG over bulk WS{sub 2} and nearly 8 fold improvements over e-WS{sub 2} for 90 min irradiation. In addition, for complete degradation of MG dye over the bulk WS{sub 2}, e-WS{sub 2}, and C@e-WS{sub 2} catalysts were observed at 150, 130, and 90 min under simulated solar light irradiation. The results obtained using core-shell mannered C@e-WS{sub 2} are stepping stone for developing cost-effective and noble metal-free catalysts for photodegradation.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2023

Experimental Characterization of an Additively Manufactured Inconel 718 Heat Exchanger for High-Temperature Applications

This work presents the experimental results of a novel, air-to-air, additively manufactured manifold-microchannel heat exchanger with straight fins on both sides. The heat exchanger was made of Inconel 718 using a direct metal laser sintering technique. The overall core size of the heat exchanger was 94 mm × 87.6 mm × 94.4 mm, with a fin thickness of 0.220 mm on both the hot and cold sides. The heat exchanger was tested with pressurized nitrogen gas at 300 °C and 340 kPa for the hot side, while air at an ambient condition was used for the cold side. An overall heat transfer of 276 W/m2K was obtained for Reynolds number values of 132 and 79 for the cold and hot sides, respectively. A gravimetric heat transfer density (Q/m∆T) of 4.7–6.7 W/kgK and a volumetric heat transfer density (Q/V∆T) of 6.9–9.8 kW/m3K were recorded for this heat exchanger with a coefficient of performance value that varied from 42 to 52 over the operating conditions studied here. The experimental pressure drop results were within 10% of the numerical values, while the corresponding heat transfer results were within 17% of the numerical results, mainly due to imperfections in the fabrication process. Despite this penalty, the performance of the tested heat exchanger was superior to the conventional plate-fin heat exchangers: more than 60% of improvements in both gravimetric and volumetric heat transfer densities were recorded for the entire range of experimental data.

42 ENGINEERING↗
DOE OSTI2021

Bulk nanocrystalline Al alloys with hierarchical reinforcement structures via grain boundary segregation and complexion formation

Grain size engineering, particularly reducing grain size into the nanocrystalline regime, offers a promising pathway to further improve the strength-to-weight ratio of Al alloys. Unfortunately, the fabrication of nanocrystalline metals often requires non-equilibrium processing routes, which typically limit the specimen size and require large energy budgets. In this study, multiple dopant elements in ternary Al alloys are deliberately selected to enable segregation to the grain boundary region and promote the formation of amorphous complexions. Three different fully dense bulk nanocrystalline Al alloys (Al-Mg-Y, Al-Fe-Y, and Al-Ni-Y) with small grain sizes were successfully fabricated using a simple powder metallurgy approach, with full densification connected directly to the onset of amorphous complexion formation. All the compositions demonstrate densities above 99% with grain sizes <60 nm following consolidation via hot pressing at 585 °C. The very fine grain structure results in excellent mechanical properties, as evidenced by nanoindentation hardness values in the range of 2.2-2.8 GPa. Detailed microstructural characterization verifies the segregation of all dopant species to grain boundaries as well as the formation of amorphous complexions, which suggests their influential role in aiding effective consolidation and endowing thermal stability in the alloys. Moreover, nanorods with a core-shell structure are also observed at the grain boundaries, which likely contribute to the stabilization of the grain structure while also strengthening the materials. Lastly, intermetallic particles with sizes of hundreds of nanometers form in all systems. As a whole, the results presented here demonstrate a general alloy design strategy of segregation and boundary evolution pathway that enables the fabrication of multiple nanocrystalline Al alloys with hierarchical microstructures and improved performance.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Electron-Withdrawing Effects in the Photodissociation of CH 2 ICl To Form CH 2 Cl Radical, Simultaneously Viewed Through the Carbon K and Chlorine L 2,3 X-ray Edges

A fundamental chlorine-containing radical, CH 2 Cl, is generated by the ultrafast photodissociation of CH 2 ICl at 266 nm and studied at both the carbon K edge (~284 eV) and chlorine L 2,3 edge (~200 eV) by femtosecond X-ray transient absorption spectroscopy. The electronic structure of CH 2 Cl radical is characterized by a prominent new carbon 1s X-ray absorption feature at lower energy, resulting from a transition to the half-filled frontier carbon 2p orbital (singly occupied molecular orbital of the radical; SOMO). Shifts of other core-to-valence absorption features upon photodissociation of CH 2 ICl to yield &middot;CH 2 Cl indicate changes in the energies of core-level transitions of carbon and chlorine to the σ*(C-Cl) valence orbital. When the C-I bond breaks, loss of the electron-withdrawing iodine atom donates electron density back to carbon and shields the carbon 1s core level, resulting in a ~0.8 eV red shift of the carbon 1s to σ*(C-Cl) transition. Meanwhile, the 2p inner shell of the chlorine atom in the radical is less impacted by the iodine atom removal, as demonstrated by the observation of a ~0.6 eV blue shift of the transitions at the chlorine L 2,3 edges, mainly due to the stronger C-Cl bond and the increased energy of the σ* (C-Cl) orbital. The results suggest that the shift in the carbon 1s orbital is greater than the shift in the σ* (C-Cl) orbital upon going from the closed-shell molecule to the radical. Ab initio calculations using the equation of motion coupled-cluster theory establish rigorous assignment and positions of the X-ray spectral features in the parent molecule and the location of the SOMO in the CH 2 Cl radical.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Surface warming in global cities is substantially more rapid than in rural background areas

Warming trends in cities are influenced both by large-scale climate processes and by local-scale urbanization. However, little is known about how surface warming trends of global cities differ from those characterized by weather observations in the rural background. Here, through statistical analyses of satellite land surface temperatures (2002 to 2021), we find that the mean surface warming trend is 0.50 ± 0.20 K·decade –1 (mean ± one S.D.) in the urban core of 2000-plus city clusters worldwide, and is 29% greater than the trend for the rural background. On average, background climate change is the largest contributor explaining 0.30 ± 0.11 K·decade –1 of the urban surface warming. In city clusters in China and India, however, more than 0.23 K·decade –1 of the mean trend is attributed to urban expansion. We also find evidence of urban greening in European cities, which offsets 0.13 ± 0.034 K·decade –1 of background surface warming.

54 ENVIRONMENTAL SCIENCES↗