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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,333 records · Page 74

Catalytic Processes to Accelerate Decarbonization in a Net-Zero Carbon World

Reducing carbon dioxide emissions is one of the critical challenges to mitigate global climate change, which is having detrimental impacts on society and the environment. Fossil fuel combustion in transportation, power generation, and industrial processes is the dominant contributor to carbon emissions. Over the past decades, sustainable solutions and strategies have been investigated and developed to enable decarbonization. Catalysis plays an essential role to address this global challenge by increasing energy efficiency, reducing carbon emissions, capturing carbon dioxide, and utilizing clean energy sources to displace fossil fuels. In this Review, the role of catalysis in reducing energy demand was discussed, enhancing process efficiency, displacing carbon-intensive feedstocks and products, and therefore, reducing carbon emissions. Here, recent advances in catalyst development were summarized, focusing on applications to enhance industrial processes efficiency and enable utilization of clean energy sources. Emerging approaches in catalysis were reviewed, including the manufacture of iron and steel, direct air capture of CO 2 , production of ethylene, ammonia, and sustainable aviation fuels, plastic recycling, and the synthesis of biobased plastics. The Review was concluded with suggested research directions to achieve a carbon net-zero world.

36 MATERIALS SCIENCE↗

Reduction of Equivalent System Mass of a Trash Compaction Processing System with an Emphasis on Improved Thermal Efficiency

A spacecraft life support system has been under development at NASA called the Trash Compaction Processing System that manages trash generated on human spaceflight missions. The trash composite typically includes components such as plastic pouches that contain wet food and drinks, used cotton clothing such as underwear and T-shirts, exercise clothing, used washcloths, expended deodorant containers, adhesive tapes, plastic bubble wrap, and other sundry items. The system uses compaction in combination with heat to turn the waste composite into a sturdy and well-defined shape, typically called a tile, which maintains structural integrity and makes the most efficient use of storage space. In addition to reducing the volume of the trash, the Trash Compaction Processing System removes water from the trash. The heating and removal of water from the trash renders it safe against microbial activity. This paper primarily focuses on work aimed at reducing the Equivalent System Mass of a Trash Compaction Processing System via a focus on improving the system’s thermal efficiency.

Trash Compaction Processor↗

Integrated Risk-Informed Condition Based Maintenance Capability and Automated Platform: Technical Report 3

This project is a collaborative research effort between PKMJ Technical Services LLC, Idaho National Laboratory, and Public Service Enterprise Group (PSEG) Nuclear, LLC. The collaboration, led by PKMJ Technical Services LLC, is part of the industry Funding Opportunity Announcement (FOA) award under Advanced Nuclear Technology Development FOA #DE-FOA-0001817. The pilot demonstration focuses on the Circulating Water System (CWS), an important non-safety-related system that impacts the power generation capability of the plant site. Achieving riskinformed condition-based Predictive Maintenance (PdM) on the CWS will result in significant economic benefits, and the developed methodologies can also be applied to other plant systems. This approach supports an industry goal of ensuring that nuclear power generation remains a viable, economically competitive option in the energy market. Operation and Maintenance (O&M) costs include labor-intensive Preventive Maintenance (PM) programs that involve manually performed inspection, calibration, testing, and maintenance of plant assets at periodic frequencies as well as time-based replacement of assets, irrespective of condition. This project offers an alternative by focusing on riskinformed condition-based maintenance to reduce O&M costs while still maintaining plant health and safety. This report summarizes the progress made toward achieving a risk-informed condition-based maintenance approach. The research and development (R&D) activities presented in this report are associated with development of a nuclear digital platform application, integration of fault signature models, and automated work management processes. The fault signatures and Machine Learning (ML) models are key components in predictive analytics and are heavily leveraged to improve the insights received by existing plant process data sources. Availability of the analysis results within a centralized digital platform enhances efficiency by enabling automation of activities otherwise performed manually. Personnel are presented with enhanced information that can be used to evaluate plant status and risks. Utilizing the enhancements to data analytics supports automated responses, (i.e. issuance of work orders) to address developing equipment faults and thus preventing forced, unplanned shutdowns of components or systems. The R&D activities described within this report lay the foundation for developing and demonstrating a digital automated platform to centralize the implementation of condition monitoring and response to equipment faults. The digital automated platform is cloud-based and designed to enable improved efficiency of plant processes. The digital platform includes content related to maintenance optimization, fault signature analysis, and plant records, which can all be used to support efficiencies when located within a centralized digital platform. These efficiencies could be further enhanced when deployed through industry-wide deployment of the technology to improve insights and processes based upon economies of scale.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

High surface area magnetic double perovskite La 2 AlFeO 6 as an efficient and stable photo-Fenton catalyst under a wide pH range

Photo-Fenton process is an efficient way to treat the organic pollutants in wastewater. However, the efficiency is limited by serious leaching of iron ion, separation of spent catalyst from reaction system for facile recycling, low (pH<4) reaction environment. Herein, we report a preparation of a novel magnetic double perovskite photocatalyst La2AlFeO6, and refractory organic pollutants like phenol, etc. were used as probes to test the efficiency of catalyst. The results showed that the catalytic material retained high surface area and high ratio of Fe 3+ on its surface, and the generated ·OH, ·O 2 - and 1 O 2 lead to a highly photocatalytic efficiency even at neutral pH condition. In addition, the as prepared double perovskite photocatalyst La 2 AlFeO 6 also exhibits excellent stable and magnetic properties. There is no iron ion leaching detected during the courses of the reaction. Furthermore, the spent catalyst can be separated by magnetic field easily, and thus can be reused after simple air drying without any further treatment or calcination.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

VLSI mixed signal processing system

An economical and efficient VLSI implementation of a mixed signal processing system (MSP) is presented in this paper. The MSP concept is investigated and the functional blocks of the proposed MSP are described. The requirements of each of the blocks are discussed in detail. A sample application using active acoustic cancellation technique is described to demonstrate the power of the MSP approach.

Alvarez, A.↗

Efficient fully-coherent quantum signal processing algorithms for real-time dynamics simulation

Simulating the unitary dynamics of a quantum system is a fundamental problem of quantum mechanics, in which quantum computers are believed to have significant advantage over their classical counterparts. One prominent such instance is the simulation of electronic dynamics, which plays an essential role in chemical reactions, non-equilibrium dynamics, and material design. These systems are time-dependent, which requires that the corresponding simulation algorithm can be successfully concatenated with itself over different time intervals to reproduce the overall coherent quantum dynamics of the system. In this paper, we quantify such simulation algorithms by the property of being fully-coherent: the algorithm succeeds with arbitrarily high success probability 1 − δ while only requiring a single copy of the initial state. Here we subsequently develop fully-coherent simulation algorithms based on quantum signal processing (QSP), including a novel algorithm that circumvents the use of amplitude amplification while also achieving a query complexity additive in time t, ln(1/δ), and ln(1/ϵ) for error tolerance ϵ: $Θ‖\mathscr{H}‖|t|+ln(1/ϵ)+ln(1/δ)$. Furthermore, we numerically analyze these algorithms by applying them to the simulation of the spin dynamics of the Heisenberg model and the correlated electronic dynamics of an H2 molecule. Since any electronic Hamiltonian can be mapped to a spin Hamiltonian, our algorithm can efficiently simulate time-dependent ab initio electronic dynamics in the circuit model of quantum computation. Accordingly, it is also our hope that the present work serves as a bridge between QSP-based quantum algorithms and chemical dynamics, stimulating a cross-fertilization between these exciting fields.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A Plasma Instability Theory of Gamma-Ray Burst Emission

A plasma instability theory is presented for the prompt radiation from gamma-ray bursts. In the theory, a highly relativistic shell interacts with the interstellar medium through the filamentation and the two-stream instabilities to convert bulk kinetic energy into electron thermal energy and magnetic field energy. The processes are not efficient enough to satisfy the Rankine-Hugoniot conditions, so a shock cannot form through this mechanism. Instead, the interstellar medium passes through the shell, with the electrons radiating during this passage. Gamma-rays are produced by synchrotron self-Compton emission. Prompt optical emission is also produced through this mechanism, while prompt radio emission is produced through synchrotron emission. The model timescales are consistent with the shortest burst timescales. To emit gamma-rays, the shell's bulk Lorentz factor must be $\simg 10(exp 3)$. For the radiative processes to be efficient, the interstellar medium density must satisfy a lower limit that is a function of the bulk Lorentz factor. Because the limits operate as selection effects, bursts that violate them constitute new classes. In particular, a class of optical and ultraviolet bursts with no gamma-ray emission should exist. The lower limit on the density of the interstellar medium is consistent with the requirements of the Compton attenuation theory, providing an explanation for why all burst spectra appear to be attenuated. Several tests of the theory are discussed, as are the next theoretical investigations that should be conducted.

Brainerd, Jerome J.↗

Current challenges in hydrate‐based desalination: Kinetic and thermodynamic perspective

Abstract Water scarcity is becoming a severe problem worldwide due to inadequate freshwater resources and swift population growth. Seawater desalination is one of the vital approaches to meet the demand for freshwater. However, energy and associated costs with conventional seawater desalination techniques are incentivizing non‐conventional water desalination processes. Water desalination using gas hydrates formation is one of the emerging non‐conventional processes. In this perspective article, recent advances in hydrate‐based seawater desalination (HBSD) have been critically analyzed to outline a future path towards a clean and efficient hydrate‐based desalination process. It provides a detailed comparison of various processes developed over decades, and measured desalination efficiencies with their process details. Moreover, the current challenges, limitations, and future perspectives of hydrate‐based desalination are also discussed. The study also recapitulates the thermodynamics and kinetics aspects of the hydrate‐based desalination process. In addition, various factors controlling the desalination efficiencies, such as control of the separation of hydrate crystals, salt deposition on hydrate particles, and hydrate morphology, were thoroughly investigated with their proposed process designs. The kinetics of hydrate formation is also assessed, with the possibility of a zero‐induction regime and its consequent impact on hydrate morphology. The current capabilities of the thermodynamics models (Gibbs energy minimization + electrolyte equation of state) were discussed using various commercially available software. Additionally, the role of hydrate promotors is also discussed, which can reduce the higher cost associated with the hydrate‐based desalination process.

Khan, Muhammad Naveed↗

Catalysts synthesized by selective deposition of Fe onto Pt for the water-gas shift reaction

FePt bimetallic catalysts with intimate contact between the two metals were synthesized by controlled surface reactions (CSR) of (cyclohexadiene)iron tricarbonyl with hydrogen-treated supported Pt nanoparticles. Adsorption of the iron precursor on a Pt/SiO2 catalyst was studied, showing that the Fe loading could be increased by performing multiple CSR cycles, and the efficiency of this process was linked to the renewal of adsorption sites by a reducing pretreatment. The catalytic activity of these bimetallic catalysts for the water gas shift reaction was improved due to promotion by iron, likely linked to H2O activation on FeOx species at or near the Pt surface, mostly in the (II) oxidation state.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Scalable and Memory-Efficient Algorithms for Controlling Networked Epidemic Processes Using Multiplicative Weights Update Method

We study the problem of designing scalable algorithms to find effective intervention strategies for controlling stochastic epidemic processes on networks. This is a common problem arising in agent based models for epidemic spread. Previous approaches to this problem focus on either heuristics with no guarantees or approximation algorithms that scale only to networks corresponding to county-sized populations, typically, with less than a million nodes. In particular, the mathematical-programming based approaches need to solve the Linear Program (LP) relaxation of the problem using an LP solver, which restricts the scalability of this approach. In this work, we overcome this restriction by designing an algorithm that adapts the multiplicative weights update (MWU) framework, along with the sample average approximation (SAA) technique, to approximately solve the linear program (LP) relaxation for the problem. To scale this approach further, we provide a memory-efficient algorithm that enables scaling to large networks, corresponding to country-size populations, with over 300 million nodes and 30 billion edges. Furthermore, we show that this approach provides near-optimal solutions to the LP in practice.

Sambaturu, Prathyush↗

In Situ Catalytic Fast Pyrolysis using Red Mud Catalyst: Impact of catalytic fast pyrolysis temperature and biomass feedstocks

Catalytic fast pyrolysis (CFP) has been considered as a very promising approach for converting lignocellulosic biomass into higher-quality bio-oils followed by hydrotreating to produce fuelrange products. A reactive, robust, and low-cost catalyst is required to drive the CFP process. Red mud, a side-product produced during the refining of bauxite to alumina, appears to be an effective catalyst for in situ CFP of biomass. In this paper, we report the impact of CFP reaction temperature on the conversion of a pinyon juniper feedstock to bio-oils using red mud as the catalyst and then to fuel-range hydrocarbons by hydrotreating of the produced bio-oil. The yield and quality of the CFP bio-oil produced and the yield and quality of hydrotreated final products were determined. When the CFP process temperature was lowered from 450 to 400ºC, the bio-oil yield increased with minimal differences in the oxygen content, hydrogen-to-carbon ratio, water content, etc. In addition, CFP bio-oils at both temperatures were processed in a single-stage continuous hydrotreater without reactor plugging during the testing period (i.e., ~100 hours on stream). The yield of CFP bio-oil produced at 400ºC was lower than the yield at 450ºC. However, the overall yield, from biomass to hydrocarbon fuel, was still higher for CFP processing at 400ºC than for processing at 450ºC. This indicates the potential for enhancing overall carbon efficiency, including CFP processing and hydrotreating, by employing red mud catalysts for biomass pyrolysis and tuning the CFP parameters. Detailed analysis of bio-oil and hydrotreated products showed a lower content of lignin-derived species in both samples. Furthermore, CFP processing of three different biomass feedstocks corroborated red mud catalyst development for producing improved quality bio-oil and, when combined with hydrotreating, for the production of fuel range hydrocarbons.

Santosa, Daniel M.↗

Electroless process for depositing refractory metals

The invention provides an inexpensive, scalable process for coating materials with a film of a refractory metal. As an example, the immersion process can comprise the deposition of a sacrificial zinc coating which is galvanically displaced by the ether-mediated reduction of oxophilic WCl6 to form a complex WOxCly film, and subsequently annealed to crystalline, metallic tungsten. The efficacy of this process was demonstrated on a carbon foam electrode, showing a 50% decrease in electrode resistance and significant gains in electrochemical performance. This process enables voltage efficiency gains for electrodes in batteries, redox flow batteries, and industrial processes where high conductivity and chemical stability are paramount.

36 MATERIALS SCIENCE↗

AVANTech's Liquid Radwaste (LRW) Processing System Upgrade at the Farley Nuclear Plant - 20328

This paper looks at the Liquid Radioactive Waste (LRW) processing system configuration at Joseph M. Farley Nuclear Plant (Plant Farley). A combination of factors led the staff at Plant Farley to seek a better way to manage and process liquid waste. These factors were: - Reduce effluent activity; - Reduce waste volume; - Improve cost efficiency. The LRW processing system changes made at Plant Farley are identified and discussed. The information and technologies cited in this paper are directly applicable to other nuclear power plants who might contemplate an upgrade of LRW processing systems or of individual system components. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Thermal-hydraulic performance of a high-temperature zigzag-channel printed circuit heat exchanger - 18563

Advanced nuclear reactors, such as high-temperature gas-cooled reactors (HTGRs) from the Generation IV nuclear systems, are designed with the capability of delivering high-pressure, high-temperature helium to power conversion units for electricity generation and industrial plants for process heat applications. The efficiency of the electricity generation and process heat applications of HTGRs is critically dependent upon an intermediate heat exchanger (IHX), which is a key component in transferring thermal energy from the primary coolant to a secondary coolant. Printed circuit heat exchangers (PCHEs) are promising to be employed in HTGR designs due to their capability for high-temperature, high-pressure applications and compactness. In the current study, a laboratory-scale zigzag-channel PCHE was fabricated and its heat transfer and pressure drop characteristics were investigated experimentally in a high-temperature helium test facility (HTHF). A commercial computational fluid dynamics (CFD) code, STARCCM+, was used to simulate the thermal-hydraulic performance of the fabricated PCHE with a simplified geometry model. Comparisons showed some differences between experimental data available for the zigzag-channel PCHE and the numerical results. Local thermal-hydraulic performance analyses indicated that fully-developed flow conditions and periodic changes were not observed, which could be attributed to the temperature variations along the flow channels, resulting in large fluid property variations. In addition, the effects of sharp-edged or rounded zigzag channel geometry were numerically evaluated. The use of rounded corners at each bend of the channels is recommended since this method can reduce the pressure drop on both the hot and cold sides of the heat exchanger while maintaining similar heat transfer capabilities. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Why Is Improvement of Earth System Models so Elusive? Challenges and Strategies from Dust Aerosol Modeling

Past decades have seen an accelerating increase in computing efficiency, while climate models are representing a rapidly widening set of physical processes. Yet simulations of some fundamental aspects of climate like precipitation or aerosol forcing remain highly uncertain and resistant to progress. Dust aerosol modeling of soil particles lofted by wind erosion has seen a similar conflict between increasing model sophistication and remaining uncertainty. Dust aerosols perturb the energy and water cycles by scattering radiation and acting as ice nuclei, while mediating atmospheric chemistry and marine photosynthesis (and thus the carbon cycle). These effects take place across scales from the dimensions of an ice crystal to the planetary-scale circulation that disperses dust far downwind of its parent soil. Representing this range leads to several modeling challenges. Should we limit complexity in our model, which consumes computer resources and inhibits interpretation? How do we decide if a process involving dust is worthy of inclusion within our model? Can we identify a minimal representation of a complex process that is efficient yet retains the physics relevant to climate? Answering these questions about the appropriate degree of representation is guided by model evaluation, which presents several more challenges. How do we proceed if the available observations do not directly constrain our process of interest? (This could result from competing processes that influence the observed variable and obscure the signature of our process of interest.) Examples will be presented from dust modeling, with lessons that might be more broadly applicable. The end result will either be clinical depression or there assuring promise of continued gainful employment as the community confronts these challenges.

Climate models↗

Advanced Thin Zeolite/Metal Flat Sheet Membrane for Energy Efficient Air Dehumidification and Conditioning

Traditional vapor compression cooling has high power consumption in warm and humid climates due to the water condensation on the evaporator coils. The combining membrane dehumidification and vapor compression cooling process holds promise for efficient drying and conditioning of warm and humid air. In this approach, the water vapor content in fresh incoming air is first reduced below dew point through a high-efficient, in-line membrane dehumidifier, followed by sensible cooling. A membrane with excellent air/water separation performance and low cost is needed to realize this design idea. In this paper, we, for the first time, report on the development of novel thin flat sheet of zeolite membranes for air dehumidification application. The membrane is prepared by deposition of an ultra-thin H 2 O-selective zeolite membrane film (< 2 µm) on a thin (~ 50 µm) porous metal sheet support. Under the testing condition of 32oC and 90% RH feed air, the optimal membrane shows water permeance as high as 1.74×10 -5 mol m -2 Pa -1 s -1 , which is about 1 to 3 orders of magnitude higher than previously reported in the literature, and a water vapor/air separation factor over 500, which allows selective and energy-efficient removal of water out of the humid air by vacuum. In addition, this zeolite/metal sheet membrane exhibits excellent stability as no apparent decline of separation performance is observed during 8-day continuous testing with humid in-house air. To simulate various climate conditions, the membrane is tested over a wide range of separation conditions which include variation in feed air temperature, feed air RH, and permeate pressure. It is estimated that 50% or higher energy efficiency gain over the conventional vapor compression system can be obtained when the membrane separation factor is equal or high than 200. A sensitivity analysis shows that the membrane separation factor and the condenser pressure have significant impacts on the process energy efficiency.

Xing, Rong↗

Sterile neutrinos with secret interactions — lasting friendship with cosmology

Sterile neutrinos with mass ≃1 eV and order 10% mixing with active neutrinos have been proposed as a solution to anomalies in neutrino oscillation data, but are tightly constrained by cosmological limits. It was recently shown that these constraints are avoided if sterile neutrinos couple to a new MeV-scale gauge boson A{sup ′}. However, even this scenario is restricted by structure formation constraints when A{sup ′}-mediated collisional processes lead to efficient active-to-sterile neutrino conversion after neutrinos have decoupled. In view of this, we reevaluate in this paper the viability of sterile neutrinos with such “secret” interactions. We carefully dissect their evolution in the early Universe, including the various production channels and the expected modifications to large scale structure formation. We argue that there are two regions in parameter space — one at very small A{sup ′} coupling, one at relatively large A{sup ′} coupling — where all constraints from big bang nucleosynthesis (BBN), cosmic microwave background (CMB), and large scale structure (LSS) data are satisfied. Interestingly, the large A{sup ′} coupling region is precisely the region that was previously shown to have potentially important consequences for the small scale structure of dark matter halos if the A{sup ′} boson couples also to the dark matter in the Universe.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

A Software Developer’s Guide to Informal Evaluation of Visual Analytics Environments Using VAST Challenge Information

The VAST Challenge has been a popular venue for academic and industry participants for over ten years. Many participants comment that the majority of their time in preparing VAST Challenge entries is discovering elements in their software environments that need to be redesigned in order to solve the given task. Fortunately, there is no need to wait until the VAST Challenge is announced to test out software systems. The Visual Analytics Benchmark Repository contains all past VAST Challenge tasks, data, solutions and submissions. This paper details the various types of evaluations that may be conducted using the Repository information. In this paper we describe how developers can do informal evaluations of various aspects of their visual analytics environments using VAST Challenge information. Aspects that can be evaluated include the appropriateness of the software for various tasks, the various data types and formats that can be accommodated, the effectiveness and efficiency of the process supported by the software, and the intuitiveness of the visualizations and interactions. Researchers can compare their visualizations and interactions to those submitted to determine novelty. In addition, the paper provides pointers to various guidelines that software teams can use to evaluate the usability of their software. While these evaluations are not a replacement for formal evaluation methods, this information can be extremely useful during the development of visual analytics environments.

evaluation↗